Development of late transition metal-doped lithium oxide as cathode materials for a new battery system

• Project/Area Number: 15K18326
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Energy engineering
• Research Institution: The University of Tokyo
• Principal Investigator: Ogasawara Yoshiyuki 東京大学, 大学院工学系研究科(工学部), 特任助教 (10638638)
• Project Period (FY): 2015-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
• Keywords: エネルギー全般 / 無機工業化学 / 二次電池

Outline of Final Research Achievements

A series of Li2O-based cathode materials was synthesized by doping late transition metals, such as cobalt, iron, and copper, with a planetary ball mill. These transition metal-doped Li2O were demonstrated as cathode materials for rechargeable batteries using a redox reaction between oxide and peroxide ions. The cathode property of Co-doped Li2O cathode material was improved by treatment with vinylene carbonate. The Co-doped Li2O cathode material treated with vinylene carbonate exhibited a specific capacity of 400 mAh/g with a 50-cycle durability.

Research Products

• [Journal Article] Cathode Performance of Co-doped Li2O with Specific Capacity (400 mAh/g) Enhanced by Vinylene Carbonate (2017)
  • Author(s): Hiroaki Kobayashi, Mitsuhiro Hibino, Yuki Kubota, Yoshiyuki Ogasawara, Kazuya Yamaguchi, Tetsuichi Kudo, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
  • Journal Title: Journal of The Electrochemical Society Volume: 164 Issue: 4 Pages: A750-A753
  • DOI: 10.1149/2.1291704jes
  • Peer Reviewed
• [Journal Article] Synthesis of Cu-doped Li2O and its cathode properties for lithium-ion batteries based on oxide/peroxide redox reactions (2017)
  • Author(s): Hiroaki Kobayashi, Mitsuhiro Hibino, Tetsuya Makimoto, Yoshiyuki Ogasawara, Kazuya Yamaguchi, Tetsuichi Kudo, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
  • Journal Title: Journal of Power Sources Volume: 340 Pages: 365-372
  • DOI: 10.1016/j.jpowsour.2016.11.050
  • Peer Reviewed
• [Journal Article] Improved performance of Co-doped Li2O cathodes for lithium-peroxide batteries using LiCoO2 as a dopant source (2016)
  • Author(s): Hiroaki Kobayashi, Mitsuhiro Hibino, Yoshiyuki Ogasawara, Kazuya Yamaguchi, Tetsuichi Kudo, Shin-ichi Okuoka, Koji Yonehara, Hironobu Ono, Yasutaka Sumida, Masaharu Oshima, Noritaka Mizuno
  • Journal Title: Journal of Power Sources Volume: 306 Pages: 567-572
  • DOI: 10.1016/j.jpowsour.2015.12.041
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Charge/discharge mechanism of a new Co-doped Li2O cathode material for a rechargeable sealed lithium-peroxide battery analyzed by X-ray absorption spectroscopy (2015)
  • Author(s): Y. Ogasawara, M. Hibino, H. Kobayashi, T. Kudo, D. Asakura, Y. Nanba, E. Hosono, N. Nagamura, Y. Kitada, I. Honma, M. Oshima, S. Okuoka, H. Ono, K. Yonehara, Y. Sumida, N. Mizuno
  • Journal Title: Journal of Power Sources Volume: 287 Pages: 220-225
  • DOI: 10.1016/j.jpowsour.2015.04.050
  • Peer Reviewed / Acknowledgement Compliant
• [Presentation] 高容量コバルトドープ酸化リチウム正極の充放電反応追跡 (2017)
  • Author(s): 小笠原義之，日比野光宏，小林弘明，嶋田裕太，工藤徹一，山口和也，朝倉大輔，奥岡晋一，小野博信，米原宏司，住田康隆，水野哲孝
  • Organizer: 電気化学会第84回大会
  • Place of Presentation: 首都大学東京（東京・八王子）
  • Year and Date: 2017-03-27
• [Presentation] X-Ray Absorption Spectroscopic Analysis of a Cathode Material for a Rechargeable Battery Using Reactions between Oxide and Peroxide (2017)
  • Author(s): Yoshiyuki Ogasawara, Hiroaki Kobayashi, Mitsuhiro Hibino, Tetsuichi Kudo, Kazuya Yamaguchi, Daisuke Asakura, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
  • Organizer: International Battery Association Meeting 2017
  • Place of Presentation: Nara Kasugano International Forum (Nara, Nara)
  • Year and Date: 2017-03-09
  • Int'l Joint Research
• [Presentation] Electrochemical Redox Reactions of Oxygen Species in Solid State Materials and Their Applications to High Energy Rechargeable Batteries (2017)
  • Author(s): Mitsuhiro Hibino, Hiroaki Kobayashi, Yoshiyuki Ogasawara, Tetsuichi Kudo, Kazuya Yamaguchi, Shin-ichi Okuoka, Koji Yonehara, Hironobu Ono, Yasutaka Sumida, Noritaka Mizuno
  • Organizer: International Battery Association Meeting 2017
  • Place of Presentation: Nara Kasugano International Forum (Nara, Nara)
  • Year and Date: 2017-03-07
  • Int'l Joint Research / Invited
• [Presentation] The Charge/Discharge Properties of Copper-Doped Lithium Oxide Cathode for Lithium-Peroxide Batteries (2017)
  • Author(s): Hiroaki Kobayashi, Mitsuhiro Hibino, Tetsuya Makimoto, Yoshiyuki Ogasawara, Kazuya Yamaguchi, Tetsuichi Kudo, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
  • Organizer: International Battery Association Meeting 2017
  • Place of Presentation: Nara Kasugano International Forum (Nara, Nara)
  • Year and Date: 2017-03-07
  • Int'l Joint Research
• [Presentation] コバルトドープ酸化リチウム正極のX線吸収分光法による充放電反応解析 (2016)
  • Author(s): 小笠原義之，小林弘明，日比野光宏，山口和也，工藤徹一，朝倉大輔，奥岡晋一，小野博信，米原宏司，住田康隆，水野哲孝
  • Organizer: 第57回電池討論会
  • Place of Presentation: 幕張メッセ国際会議場（千葉・千葉）
  • Year and Date: 2016-11-30
• [Presentation] コバルトドープ酸化リチウムの電気化学的酸化還元挙動と高容量充放電特性 (2016)
  • Author(s): 小林弘明，日比野光宏，久保田雄起，小笠原義之，山口和也，工藤徹一，奥岡晋一，小野博信，米原宏司，住田康隆，水野哲孝
  • Organizer: 第57回電池討論会
  • Place of Presentation: 幕張メッセ国際会議場（千葉・千葉）
  • Year and Date: 2016-11-30
• [Presentation] Electrochemical Redox Reactions of Oxide Ions in Solids and Their Application to High Energy Rechargeable Batteries (2016)
  • Author(s): Mitsuhiro Hibino, Hiroaki Kobayashi, Kosuke harada, Yoshiyuki Ogasawara, Noritaka Mizuno
  • Organizer: The 33rd International Korea-Japan Seminar on Ceramics
  • Place of Presentation: Daejeon (South Korea)
  • Year and Date: 2016-11-17
  • Int'l Joint Research / Invited
• [Presentation] 固体内酸化物イオンレドックスを利用した電池の電極材料探索 (2016)
  • Author(s): 槇本哲也，日比野光宏，小笠原義之，工藤徹一，奥岡晋一，米原宏司，小野博信，住田康隆，水野哲孝
  • Organizer: 第6回CSJ化学フェスタ
  • Place of Presentation: タワーホール船堀（東京・東京）
  • Year and Date: 2016-11-16
• [Presentation] 酸化物イオンのレドックスを利用した電池正極材料のX線吸収分光法による充放電反応追跡 (2016)
  • Author(s): 小笠原義之，小林弘明，日比野光宏，山口和也，工藤徹一，奥岡晋一，小野博信，米原宏司，住田康隆，水野哲孝
  • Organizer: 立命館大学SRセンター公開シンポジウム
  • Place of Presentation: 立命館大学びわこ・くさつキャンパス（滋賀・草津）
  • Year and Date: 2016-11-11
• [Presentation] The Charge/Discharge Properties of Vinylene Carbonate-Treated Cobalt-Doped Lithium Oxide Cathode for Lithium Peroxide Batteries (2016)
  • Author(s): Hiroaki Kobayashi, Mitsuhiro Hibino, Yoshiyuki Ogasawara, Kazuya Yamaguchi, Tetsuichi Kudo, Shin-ichi Okuoka, Koji Yonehara, Hironobu Ono, Yasutaka Sumida, Noritaka Mizuno
  • Organizer: PRiME 2016
  • Place of Presentation: Honolulu (USA)
  • Year and Date: 2016-10-06
  • Int'l Joint Research
• [Presentation] X-Ray Absorption Spectroscopic Analysis of Cobalt-Doped Lithium Oxide Cathode Material for a Lithium-Peroxide Battery during Charge and Discharge (2016)
  • Author(s): Yoshiyuki Ogasawara, Hiroaki Kobayashi, Mitsuhiro Hibino, Kazuya Yamaguchi, Tetsuichi Kudo, Daisuke Asakura, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
  • Organizer: PRiME 2016
  • Place of Presentation: Honolulu (USA)
  • Year and Date: 2016-10-04
  • Int'l Joint Research
• [Presentation] 固体内酸素の関わる電極反応設計と高容量二次電池への展開 (2016)
  • Author(s): 日比野光宏，小笠原義之，水野哲孝
  • Organizer: 第12回固体イオニクスセミナー
  • Place of Presentation: 休暇村指宿（鹿児島・指宿）
  • Year and Date: 2016-09-28
  • Invited
• [Presentation] 固体内酸化物イオンの電気化学的酸化還元反応と高エネルギー密度電池への展開 (2016)
  • Author(s): 日比野光宏，小笠原義之，水野哲孝
  • Organizer: 第382回電池技術委員会
  • Place of Presentation: 安保ホール（愛知・名古屋）
  • Year and Date: 2016-09-15
  • Invited
• [Presentation] 固体内酸素の関わる電極反応と新しい二次電池への展開 (2016)
  • Author(s): 日比野光宏，小笠原義之，水野哲孝
  • Organizer: 第74回マテリアルズ・テーラリング研究会
  • Place of Presentation: 加藤山崎教育基金軽井沢研修所（長野・軽井沢）
  • Year and Date: 2016-08-04
  • Invited
• [Presentation] コバルトドープ酸化リチウムを正極材料とした高容量リチウムイオン二次電池 (2016)
  • Author(s): 小林 弘明、日比野 光宏、小笠原 義之、山口 和也、工藤 徹一、奥岡 晋一、米原 宏司、小野 博信、住田 康隆、水野 哲孝
  • Organizer: 電気化学会第83回大会
  • Place of Presentation: 大阪大学（大阪・吹田）
  • Year and Date: 2016-03-29
• [Presentation] Charge/discharge behavior of Co-doped Li2O of a battery utilizing a redox of oxide and peroxide (2015)
  • Author(s): Hiroaki Kobayashi, Mitsuhiro Hibino, Yoshiyuki Ogasawara, Tetsuichi Kudo, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
  • Organizer: Pacifichem 2015
  • Place of Presentation: Honolulu (USA)
  • Year and Date: 2015-12-17
  • Int'l Joint Research
• [Presentation] Cathode reactions and basic property of lithium peroxide batteries (2015)
  • Author(s): Mitsuhiro Hibino, Hiroaki Kobayashi, Kosuke Harada, Yoshiyuki Ogasawara, Noritaka Mizuno
  • Organizer: Pacifichem 2015
  • Place of Presentation: Honolulu (USA)
  • Year and Date: 2015-12-17
  • Int'l Joint Research
• [Presentation] メカノケミカル反応で合成したリチウム銅酸化物中の酸素レドックス反応を利用したリチウム電池正極特性 (2015)
  • Author(s): 小林 弘明、日比野 光宏、小笠原 義之、工藤 徹一、奥岡 晋一、米原 宏司、小野 博信、住田 康隆、水野 哲孝
  • Organizer: 第41回固体イオニクス討論会
  • Place of Presentation: 北海道大学（北海道・札幌）
  • Year and Date: 2015-11-27
• [Presentation] 鉄ドープ酸化リチウム中の酸素レドックスを利用したリチウム電池正極の反応解析 (2015)
  • Author(s): 原田 耕佑、日比野 光宏、小笠原 義之、工藤 徹一、奥岡 晋一、米原 宏司、小野 博信、住田 康隆、水野 哲孝
  • Organizer: 第41回固体イオニクス討論会
  • Place of Presentation: 北海道大学（北海道・札幌）
  • Year and Date: 2015-11-27
• [Presentation] 鉄ドープ酸化リチウムの酸素レドックス利用型高容量電池正極特性 (2015)
  • Author(s): 原田 耕佑、日比野 光宏、小笠原 義之、工藤 徹一、奥岡 晋一、米原 宏司、小野 博信、住田 康隆、水野 哲孝
  • Organizer: 第56回電池討論会
  • Place of Presentation: 愛知県産業労働センターウインクあいち（愛知・名古屋）
  • Year and Date: 2015-11-13
• [Presentation] 酸素レドックスを利用する過酸化物電池の性能向上に向けたコバルトドープ酸化リチウム正極の開発 (2015)
  • Author(s): 小林 弘明、日比野 光宏、小笠原 義之、工藤 徹一、奥岡 晋一、米原 宏司、小野 博信、住田 康隆、水野 哲孝
  • Organizer: 第56回電池討論会
  • Place of Presentation: 愛知県産業労働センターウインクあいち（愛知・名古屋）
  • Year and Date: 2015-11-13
• [Presentation] コバルトドープした酸化リチウムを正極に用いたリチウム過酸化物電池 (2015)
  • Author(s): 小林 弘明、小笠原 義之、日比野 光宏、水野 哲孝
  • Organizer: 第71回マテリアルズ・テーラリング研究会
  • Place of Presentation: 加藤山崎教育基金軽井沢研修所（長野・軽井沢）
  • Year and Date: 2015-08-06