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Development of late transition metal-doped lithium oxide as cathode materials for a new battery system

Research Project

Project/Area Number 15K18326
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionThe University of Tokyo

Principal Investigator

Ogasawara Yoshiyuki  東京大学, 大学院工学系研究科(工学部), 特任助教 (10638638)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsエネルギー全般 / 無機工業化学 / 二次電池
Outline of Final Research Achievements

A series of Li2O-based cathode materials was synthesized by doping late transition metals, such as cobalt, iron, and copper, with a planetary ball mill. These transition metal-doped Li2O were demonstrated as cathode materials for rechargeable batteries using a redox reaction between oxide and peroxide ions. The cathode property of Co-doped Li2O cathode material was improved by treatment with vinylene carbonate. The Co-doped Li2O cathode material treated with vinylene carbonate exhibited a specific capacity of 400 mAh/g with a 50-cycle durability.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (26 results)

All 2017 2016 2015

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 2 results) Presentation (22 results) (of which Int'l Joint Research: 8 results,  Invited: 5 results)

  • [Journal Article] Cathode Performance of Co-doped Li2O with Specific Capacity (400 mAh/g) Enhanced by Vinylene Carbonate2017

    • Author(s)
      Hiroaki Kobayashi, Mitsuhiro Hibino, Yuki Kubota, Yoshiyuki Ogasawara, Kazuya Yamaguchi, Tetsuichi Kudo, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 164 Issue: 4 Pages: A750-A753

    • DOI

      10.1149/2.1291704jes

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Cu-doped Li2O and its cathode properties for lithium-ion batteries based on oxide/peroxide redox reactions2017

    • Author(s)
      Hiroaki Kobayashi, Mitsuhiro Hibino, Tetsuya Makimoto, Yoshiyuki Ogasawara, Kazuya Yamaguchi, Tetsuichi Kudo, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
    • Journal Title

      Journal of Power Sources

      Volume: 340 Pages: 365-372

    • DOI

      10.1016/j.jpowsour.2016.11.050

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved performance of Co-doped Li2O cathodes for lithium-peroxide batteries using LiCoO2 as a dopant source2016

    • Author(s)
      Hiroaki Kobayashi, Mitsuhiro Hibino, Yoshiyuki Ogasawara, Kazuya Yamaguchi, Tetsuichi Kudo, Shin-ichi Okuoka, Koji Yonehara, Hironobu Ono, Yasutaka Sumida, Masaharu Oshima, Noritaka Mizuno
    • Journal Title

      Journal of Power Sources

      Volume: 306 Pages: 567-572

    • DOI

      10.1016/j.jpowsour.2015.12.041

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Charge/discharge mechanism of a new Co-doped Li2O cathode material for a rechargeable sealed lithium-peroxide battery analyzed by X-ray absorption spectroscopy2015

    • Author(s)
      Y. Ogasawara, M. Hibino, H. Kobayashi, T. Kudo, D. Asakura, Y. Nanba, E. Hosono, N. Nagamura, Y. Kitada, I. Honma, M. Oshima, S. Okuoka, H. Ono, K. Yonehara, Y. Sumida, N. Mizuno
    • Journal Title

      Journal of Power Sources

      Volume: 287 Pages: 220-225

    • DOI

      10.1016/j.jpowsour.2015.04.050

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 高容量コバルトドープ酸化リチウム正極の充放電反応追跡2017

    • Author(s)
      小笠原義之,日比野光宏,小林弘明,嶋田裕太,工藤徹一,山口和也,朝倉大輔,奥岡晋一,小野博信,米原宏司,住田康隆,水野哲孝
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京(東京・八王子)
    • Year and Date
      2017-03-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] X-Ray Absorption Spectroscopic Analysis of a Cathode Material for a Rechargeable Battery Using Reactions between Oxide and Peroxide2017

    • Author(s)
      Yoshiyuki Ogasawara, Hiroaki Kobayashi, Mitsuhiro Hibino, Tetsuichi Kudo, Kazuya Yamaguchi, Daisuke Asakura, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
    • Organizer
      International Battery Association Meeting 2017
    • Place of Presentation
      Nara Kasugano International Forum (Nara, Nara)
    • Year and Date
      2017-03-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemical Redox Reactions of Oxygen Species in Solid State Materials and Their Applications to High Energy Rechargeable Batteries2017

    • Author(s)
      Mitsuhiro Hibino, Hiroaki Kobayashi, Yoshiyuki Ogasawara, Tetsuichi Kudo, Kazuya Yamaguchi, Shin-ichi Okuoka, Koji Yonehara, Hironobu Ono, Yasutaka Sumida, Noritaka Mizuno
    • Organizer
      International Battery Association Meeting 2017
    • Place of Presentation
      Nara Kasugano International Forum (Nara, Nara)
    • Year and Date
      2017-03-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] The Charge/Discharge Properties of Copper-Doped Lithium Oxide Cathode for Lithium-Peroxide Batteries2017

    • Author(s)
      Hiroaki Kobayashi, Mitsuhiro Hibino, Tetsuya Makimoto, Yoshiyuki Ogasawara, Kazuya Yamaguchi, Tetsuichi Kudo, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
    • Organizer
      International Battery Association Meeting 2017
    • Place of Presentation
      Nara Kasugano International Forum (Nara, Nara)
    • Year and Date
      2017-03-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] コバルトドープ酸化リチウム正極のX線吸収分光法による充放電反応解析2016

    • Author(s)
      小笠原義之,小林弘明,日比野光宏,山口和也,工藤徹一,朝倉大輔,奥岡晋一,小野博信,米原宏司,住田康隆,水野哲孝
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ国際会議場(千葉・千葉)
    • Year and Date
      2016-11-30
    • Related Report
      2016 Annual Research Report
  • [Presentation] コバルトドープ酸化リチウムの電気化学的酸化還元挙動と高容量充放電特性2016

    • Author(s)
      小林弘明,日比野光宏,久保田雄起,小笠原義之,山口和也,工藤徹一,奥岡晋一,小野博信,米原宏司,住田康隆,水野哲孝
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ国際会議場(千葉・千葉)
    • Year and Date
      2016-11-30
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electrochemical Redox Reactions of Oxide Ions in Solids and Their Application to High Energy Rechargeable Batteries2016

    • Author(s)
      Mitsuhiro Hibino, Hiroaki Kobayashi, Kosuke harada, Yoshiyuki Ogasawara, Noritaka Mizuno
    • Organizer
      The 33rd International Korea-Japan Seminar on Ceramics
    • Place of Presentation
      Daejeon (South Korea)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 固体内酸化物イオンレドックスを利用した電池の電極材料探索2016

    • Author(s)
      槇本哲也,日比野光宏,小笠原義之,工藤徹一,奥岡晋一,米原宏司,小野博信,住田康隆,水野哲孝
    • Organizer
      第6回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京・東京)
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 酸化物イオンのレドックスを利用した電池正極材料のX線吸収分光法による充放電反応追跡2016

    • Author(s)
      小笠原義之,小林弘明,日比野光宏,山口和也,工藤徹一,奥岡晋一,小野博信,米原宏司,住田康隆,水野哲孝
    • Organizer
      立命館大学SRセンター公開シンポジウム
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀・草津)
    • Year and Date
      2016-11-11
    • Related Report
      2016 Annual Research Report
  • [Presentation] The Charge/Discharge Properties of Vinylene Carbonate-Treated Cobalt-Doped Lithium Oxide Cathode for Lithium Peroxide Batteries2016

    • Author(s)
      Hiroaki Kobayashi, Mitsuhiro Hibino, Yoshiyuki Ogasawara, Kazuya Yamaguchi, Tetsuichi Kudo, Shin-ichi Okuoka, Koji Yonehara, Hironobu Ono, Yasutaka Sumida, Noritaka Mizuno
    • Organizer
      PRiME 2016
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2016-10-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] X-Ray Absorption Spectroscopic Analysis of Cobalt-Doped Lithium Oxide Cathode Material for a Lithium-Peroxide Battery during Charge and Discharge2016

    • Author(s)
      Yoshiyuki Ogasawara, Hiroaki Kobayashi, Mitsuhiro Hibino, Kazuya Yamaguchi, Tetsuichi Kudo, Daisuke Asakura, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
    • Organizer
      PRiME 2016
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2016-10-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体内酸素の関わる電極反応設計と高容量二次電池への展開2016

    • Author(s)
      日比野光宏,小笠原義之,水野哲孝
    • Organizer
      第12回固体イオニクスセミナー
    • Place of Presentation
      休暇村指宿(鹿児島・指宿)
    • Year and Date
      2016-09-28
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 固体内酸化物イオンの電気化学的酸化還元反応と高エネルギー密度電池への展開2016

    • Author(s)
      日比野光宏,小笠原義之,水野哲孝
    • Organizer
      第382回電池技術委員会
    • Place of Presentation
      安保ホール(愛知・名古屋)
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 固体内酸素の関わる電極反応と新しい二次電池への展開2016

    • Author(s)
      日比野光宏,小笠原義之,水野哲孝
    • Organizer
      第74回マテリアルズ・テーラリング研究会
    • Place of Presentation
      加藤山崎教育基金軽井沢研修所(長野・軽井沢)
    • Year and Date
      2016-08-04
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] コバルトドープ酸化リチウムを正極材料とした高容量リチウムイオン二次電池2016

    • Author(s)
      小林 弘明、日比野 光宏、小笠原 義之、山口 和也、工藤 徹一、奥岡 晋一、米原 宏司、小野 博信、住田 康隆、水野 哲孝
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学(大阪・吹田)
    • Year and Date
      2016-03-29
    • Related Report
      2015 Research-status Report
  • [Presentation] Charge/discharge behavior of Co-doped Li2O of a battery utilizing a redox of oxide and peroxide2015

    • Author(s)
      Hiroaki Kobayashi, Mitsuhiro Hibino, Yoshiyuki Ogasawara, Tetsuichi Kudo, Shin-ichi Okuoka, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Noritaka Mizuno
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Cathode reactions and basic property of lithium peroxide batteries2015

    • Author(s)
      Mitsuhiro Hibino, Hiroaki Kobayashi, Kosuke Harada, Yoshiyuki Ogasawara, Noritaka Mizuno
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] メカノケミカル反応で合成したリチウム銅酸化物中の酸素レドックス反応を利用したリチウム電池正極特性2015

    • Author(s)
      小林 弘明、日比野 光宏、小笠原 義之、工藤 徹一、奥岡 晋一、米原 宏司、小野 博信、住田 康隆、水野 哲孝
    • Organizer
      第41回固体イオニクス討論会
    • Place of Presentation
      北海道大学(北海道・札幌)
    • Year and Date
      2015-11-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 鉄ドープ酸化リチウム中の酸素レドックスを利用したリチウム電池正極の反応解析2015

    • Author(s)
      原田 耕佑、日比野 光宏、小笠原 義之、工藤 徹一、奥岡 晋一、米原 宏司、小野 博信、住田 康隆、水野 哲孝
    • Organizer
      第41回固体イオニクス討論会
    • Place of Presentation
      北海道大学(北海道・札幌)
    • Year and Date
      2015-11-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 鉄ドープ酸化リチウムの酸素レドックス利用型高容量電池正極特性2015

    • Author(s)
      原田 耕佑、日比野 光宏、小笠原 義之、工藤 徹一、奥岡 晋一、米原 宏司、小野 博信、住田 康隆、水野 哲孝
    • Organizer
      第56回電池討論会
    • Place of Presentation
      愛知県産業労働センターウインクあいち(愛知・名古屋)
    • Year and Date
      2015-11-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 酸素レドックスを利用する過酸化物電池の性能向上に向けたコバルトドープ酸化リチウム正極の開発2015

    • Author(s)
      小林 弘明、日比野 光宏、小笠原 義之、工藤 徹一、奥岡 晋一、米原 宏司、小野 博信、住田 康隆、水野 哲孝
    • Organizer
      第56回電池討論会
    • Place of Presentation
      愛知県産業労働センターウインクあいち(愛知・名古屋)
    • Year and Date
      2015-11-13
    • Related Report
      2015 Research-status Report
  • [Presentation] コバルトドープした酸化リチウムを正極に用いたリチウム過酸化物電池2015

    • Author(s)
      小林 弘明、小笠原 義之、日比野 光宏、水野 哲孝
    • Organizer
      第71回マテリアルズ・テーラリング研究会
    • Place of Presentation
      加藤山崎教育基金軽井沢研修所(長野・軽井沢)
    • Year and Date
      2015-08-06
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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