Radical polymerization inside carbon nanotube and its application
| Project/Area Number |
15K21073
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
Nanomaterials chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
Omachi Haruka 名古屋大学, 物質科学国際研究センター, 助教 (60711497)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | カーボンナノチューブ / 内包 / ラジカル / １次元 / ダイヤモンドポリマー / ポリチオフェン / １次元ナノ物質 / チオフェン / ポリマー / グラフェンナノリボン / 1次元ナノ物質 |
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| Outline of Final Research Achievements |
Utilizing inner space of carbon nanotubes, new synthetic methods for one-dimensional nanomaterials were accomplished. Instead of the thermal coalescence of encapsulated molecules, novel one-dimensional nanomaterials were synthesized efficiently through carbon-carbon bond or hydrogen bond formation under mid conditions. We demonstrate the synthesis of one-dimensional diamondoid polymers or long polythiophenes. Especially, polythiophenes, encapsulated in carbon nanotubes, showed s-trans co-planar conformation even at solid state. In addition, selective p-doing to metallic carbon nanotubes were observed after the encapsulation of polythiophenes.
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Report
(4 results)
Research Products
(68 results)
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[Journal Article] Fabrication and Optical Probing of Highly Extended, Ultrathin Graphene Nanoribbons in Carbon Nanotubes2015
Author(s)
H.E. Lim, Y. Miyata, M. Fujihara, S. Okada, Z. Liu, Arifin, K. Sato, H. Omachi, R. Kitaura, S. Irle, K. Suenaga, H. Shinohara
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Journal Title
ACS nano
Volume: 未確定
Issue: 5
Pages: 5034-5040
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Presentation] Synthesis of Sulfur-doped Graphene Oxides2016
Author(s)
大町遼, Zois Syrgiannis, 金野泰弘, Maurizio Prato, 篠原久典
Organizer
The 7th A3 Symposium on Emerging Materials, Nanomaterials for Energy and Electronics
Place of Presentation
Buyo, Korea
Year and Date
2016-10-30
Related Report
Int'l Joint Research
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[Presentation] 新規Gd内包フラーレン誘導体の単離2016
Author(s)
中川 綾乃, 青柳 忍, 大町 遼, 王 志永, 石野 勝真, 北浦 良, 篠原 久典
Organizer
第51回フラーレン・ナノチューブ・グラフェン総合シンポジウム
Place of Presentation
札幌
Year and Date
2016-09-07
Related Report
Int'l Joint Research
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