| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Outline of Final Research Achievements |
Utilizing inner space of carbon nanotubes, new synthetic methods for one-dimensional nanomaterials were accomplished. Instead of the thermal coalescence of encapsulated molecules, novel one-dimensional nanomaterials were synthesized efficiently through carbon-carbon bond or hydrogen bond formation under mid conditions. We demonstrate the synthesis of one-dimensional diamondoid polymers or long polythiophenes. Especially, polythiophenes, encapsulated in carbon nanotubes, showed s-trans co-planar conformation even at solid state. In addition, selective p-doing to metallic carbon nanotubes were observed after the encapsulation of polythiophenes.
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