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Synthesis of large graphene grain by CVD method using waste plastics and development of transparent conductive film

Research Project

Project/Area Number 15K21076
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Thin film/Surface and interfacial physical properties
Research InstitutionNagoya Institute of Technology

Principal Investigator

Kalita Golap  名古屋工業大学, 工学(系)研究科(研究院), 准教授 (20615629)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
KeywordsGraphene / グラフェン / graphene
Outline of Final Research Achievements

In this study, we investigated synthesis of large graphene grain by atmospheric and low pressure CVD method using waste plastics and polystyrene as precursor. An oxide layer on copper foil was prepared by annealing treatment to achieve large graphene domain growth. The graphene nucleation was controlled by argon and hydrogen annealing process, and synthesis of large graphene grain was achieved by the CVD method. We were able to growth graphene domain as large as 1.6 mm using waste plastic as precursor. Furthermore, transparent electrode was prepared using the synthesized graphene film form waste materials. A sheet resistance of 120 Ω / Sq was achieved with a transmittance of 90% using the synthesized graphene film.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (14 results)

All 2017 2016 2015

All Journal Article (6 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 6 results,  Acknowledgement Compliant: 6 results) Presentation (7 results) (of which Int'l Joint Research: 3 results) Book (1 results)

  • [Journal Article] Influence of copper foil polycrystalline structure on graphene anisotropic etching2017

    • Author(s)
      K. P. Sharma, R. D. Mahyavanshi, G. Kalita (corresponding author), M. Tanemura
    • Journal Title

      Applied Surface Science

      Volume: 393 Pages: 428-433

    • DOI

      10.1016/j.apsusc.2016.10.018

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Morphology-Controlled Synthesis of Hexagonal Boron Nitride Crystals by Chemical Vapor Deposition2016

    • Author(s)
      S. Sharma, K. Sharma, M. S. Rosmi, Y. Yaakob, Mona I. Araby, H. Ohtani, G. Kalita, M. Tanemura
    • Journal Title

      Cryst. Growth Des.

      Volume: 16 Issue: 11 Pages: 6440-6445

    • DOI

      10.1021/acs.cgd.6b01110

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Effect of copper foil annealing process on large graphene domain growth by solid source-based chemical vapor deposition2016

    • Author(s)
      K.P.Sharma, S.Sharma, S.M.Shinde, G.kalita (corresponding author), M.Tanemura
    • Journal Title

      Journal of Materials Science

      Volume: 51 Pages: 7220-7228

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Optimization of CVD parameters for graphene synthesis through design of experiments2016

    • Author(s)
      R. Papon, C. Pierlot, S. Sharma, S. M. Shinde, G. Kalita, and M. Tanemura
    • Journal Title

      Phys. Status Solidi B

      Volume: 00 Issue: 5 Pages: 1-7

    • DOI

      10.1002/pssb.201600629

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Effect of copper foil annealing process on large graphene domain growth by solid source-based chemical vapor deposition2016

    • Author(s)
      K.P.Sharma, S.Sharma, S.M.Shinde, G.kalita (corresponding author), M.Tanemura
    • Journal Title

      Journal of Materials Science (2016)

      Volume: - Pages: 1-9

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Structure dependent hydrogen induced etching features of graphene crystals2015

    • Author(s)
      2.A.Thangaraja, S.Shinde, G.Kalita (corresponding author), M.Tanemura
    • Journal Title

      Applied Physics Letters

      Volume: 106 Issue: 25

    • DOI

      10.1063/1.4922991

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Controlling Morphology of hBN crystals during chemical vapor deposition synthesis2017

    • Author(s)
      S. sharma, G. Kalita, M. Tanemura
    • Organizer
      第64回 応用物理学会学術講演会
    • Place of Presentation
      日本
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] CuNi binary alloy catalyst for growth of nitrogen substituted graphene by low pressure chemical vapor deposition2017

    • Author(s)
      R. Papon, K. P. Sharma, R. D. Mahayavanshi, S. Sharma, R. Vishwakarma, M. S. Rosmi, T. Kawahara, J. Cline, G. Kalita, M. Tanemura
    • Organizer
      第64回 応用物理学会学術講演会
    • Place of Presentation
      日本
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis of uniform monolayer graphene on copper from2016

    • Author(s)
      M. S. Rosmi, S. M. Shinde, N. D. A. Rahman, A. Thangaraja, S. Sharma, K. P. Sharma, Y. Yaakob, R. Vishwakarma, S. A. Bakar, G. Kalita, H. Ohtani, M. Tanemura
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      日本
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Formation of Particular Graphene Structures Through H2 Induced Anisotropic Etching2016

    • Author(s)
      R. Papon, S. Sharma, S. M. Shinde, A. Thangaraja, G. Kalita, M. Tanemura
    • Organizer
      11th Annual IEEE International Conference on Nano/Micro Engineered and Molecular Systems (IEEE-NEMS 2016)
    • Place of Presentation
      日本
    • Year and Date
      2016-04-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Role of Copper Substrate Annealing on Graphene Crystal Synthesis by Atmospheric Pressure Chemical Vapor Deposition2016

    • Author(s)
      K. P. Sharma, S. Sharma, G. Kalita, M. Tanemura
    • Organizer
      11th Annual IEEE International Conference on Nano/Micro Engineered and Molecular Systems (IEEE-NEMS 2016)
    • Place of Presentation
      日本
    • Year and Date
      2016-04-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Role of Copper Substrate Annealing on Graphene Crystal Synthesis by Atmospheric Pressure Chemical Vapor Deposition2016

    • Author(s)
      K.P.Sharma, S.Sharma, G.Kalita, M.Tanemura
    • Organizer
      11th Annual IEEE International Conference on Nano/Micro Engineered and Molecular Systems
    • Place of Presentation
      Japan
    • Year and Date
      2016-04-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Optimization of CVD parameters for graphene synthesis through designs of experiments2016

    • Author(s)
      R.Papon, C.Pierlot, S.Sharma, S.Shinde, G.Kalita, M.Tanemura
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      Japan
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Book] Graphene Science Handbook2016

    • Author(s)
      G.Kalita, M.Umeno, M.Tanemura
    • Total Pages
      20
    • Publisher
      Crc press taylor & francis group
    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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