| Project/Area Number |
15K21127
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Inorganic chemistry
Nanostructural chemistry
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
|
|---|
| Research Collaborator |
KONNO Takumi 大阪大学, 大学院理学研究科, 教授
IGASHIRA Asako 明治学院大学, 法学部, 准教授
KUWAMURA Naoto 大阪大学, 大学院理学研究科, 助教
KAWANO Masaki 東京工業大学, 理学院, 教授
KOJIMA Tatsuhiro 大阪大学, 大学院理学研究科, 助教
|
|---|
| Project Period (FY) |
2015-04-01 – 2018-03-31
|
| Project Status |
Completed (Fiscal Year 2017)
|
| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
|---|
| Keywords | 金属多核錯体 / 構造変換 / 熱分解 / 金属引き抜き反応 / キラリティ / 含硫アミノ酸 / 結晶構造 / 多核金属錯体 / キラル増幅 / チオラト錯体 / ペニシラミン / 発光性 / ジホスフィン / 金属クラスター / 欠損型クラスター |
|---|
| Outline of Final Research Achievements |
In this research project, new synthetic methodology for the structural conversion from stable coordination compounds that involve saturated atoms to reactive products that contain unsaturated atoms was developed using multinuclear metal complexes. As a result, a thermal-induced ligand-dissociation reaction on a luminescent digold(I) complex ([Au2(dppm)3]2+) and a ligand-induced rhodium atom abstraction reaction on an octanuclear complex cation ([Rh4Zn4(aet)12O]6+) were achieved.
|
