| Project/Area Number |
15K21143
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
Functional solid state chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | ひずみエネルギー / 非平面π骨格 / シクロオクタテトラエン / 反芳香族性 |
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| Outline of Final Research Achievements |
In this research, we have proposed the utilizing of strain energy in nonplanar pi-conjugated system and I attempted its functional development. The detail is planarization of tub-shaped cyclooctatetraene (COT) by pulling from each side to get a transition state of COT as well as to gain an antiaromatic property. This attempt can lead to understand the structure as well as electronic nature of transition state.
However, unfortunately, the synthesis of target compound composed of COT with bent p-quaterphenyl unit was unsuccessful even though several synthetic route were planed and tried. To achieve the purpose, I have continue the synthesis of its target compound by new synthesic route.
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