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Management of triplet excitons by weak molecular interactions and application for organic semiconducting devices

Research Project

Project/Area Number 15K21220
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Device related chemistry
Research InstitutionKyushu University

Principal Investigator

KABE Ryota  九州大学, 最先端有機光エレクトロニクス研究センター, 助教 (00726490)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsリン光 / 非放射失活 / 有機半導体 / 金属有機構造体 / 有機EL / 有機エレクトロニクス / ホスト / MOF / 長寿命りん光 / 分子間相互作用 / 蓄光 / エレクトロルミネッセンス
Outline of Final Research Achievements

We developed novel host materials aiming for the harvesting of the triplet excitons into emission by suppression of the nonradiative decay. We demonstrate that long-lived emission from triplet excitons can be achieved even at high temperature by encapsulating organic emitter in metal organic frameworks (MOFs). Moreover, we demonstrate an organic light-emitting diode (OLED) containing a long-lived phosphorescence emitter that displays electroluminescence with long transient decay after it is turned off. To achieve LLP from an emitter layer, we developed the host molecule 3-(N-carbazolyl)-androst-2-ene (CzSte), which can minimize the nonradiative decay of guest emitter molecules.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (22 results)

All 2017 2016 2015

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Acknowledgement Compliant: 3 results) Presentation (16 results) (of which Int'l Joint Research: 8 results,  Invited: 3 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Long‐Lived Room‐Temperature Phosphorescence of Coronene in Zeolitic Imidazolate Framework ZIF‐82016

    • Author(s)
      H Mieno, R Kabe, N Notsuka, MD Allendorf, C Adachi
    • Journal Title

      Advanced Optical Materials

      Volume: 4 Issue: 7 Pages: 1015-1021

    • DOI

      10.1002/adom.201600103

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Blue Thermally Activated Delayed Fluorescence Molecule Having Acridane and Cyanobenzene Units2016

    • Author(s)
      H Noda, R Kabe, C Adachi
    • Journal Title

      Chemistry Letters

      Volume: 45 Issue: 12 Pages: 1463-1466

    • DOI

      10.1246/cl.160814

    • NAID

      130005475742

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Increased Vis-to-UV upconversion performance by energy level matching be tween a TADF donor and high triplet energy acceptors2016

    • Author(s)
      Nobuhiro Yanai, Mariko Kozue, Shogo Amemori, Ryota Kabe, Chihaya Adachi, and Nobuo Kimizuka
    • Journal Title

      J. Mater. Chem. C,

      Volume: 4 Issue: 27 Pages: 6447-6451

    • DOI

      10.1039/c6tc01816e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Afterglow Organic Light-Emitting Diode2016

    • Author(s)
      Ryota Kabe; Naoto Notsuka; Kou Yoshida; Chihaya Adachi
    • Journal Title

      Advanced Material

      Volume: 28 Issue: 4 Pages: 655-660

    • DOI

      10.1002/adma.201504321

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Excited state engineering for efficient reverse intersystem crossing process2017

    • Author(s)
      H. Noda, H. Nakanotani, R. Kabe, C. Adachi
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] 共蒸着法によるイッテルビウム錯体の合成と赤外有機発光ダイオードへの応用2017

    • Author(s)
      陣内 和哉・嘉部 量太・安達 千波矢
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Vacuum Co-deposition Synthesis of Ytterbium Complex for Infrared Organic Light-Emitting Diodes2016

    • Author(s)
      K. Jinnai, R. Kabe, C. Adachi
    • Organizer
      A-COE 2016
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-12-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Blue Thermally Activated Delayed Fluorescence Molecule Having Acridan and Cyanobenzene Units2016

    • Author(s)
      H. Noda, R. Kabe, C. Adachi
    • Organizer
      16th Chitose International Forum on Photonics Science and Technology
    • Place of Presentation
      Hokkaido, Japan
    • Year and Date
      2016-09-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Suppression of nonradiative decay by isolation of aromatic emitter in zeolitic imidazolate framework ZIF-8 for realization of long-lived triplet excitons2016

    • Author(s)
      H. Mieno, R. Kabe, N. Notsuka, M. D. Allendorf, C. Adachi
    • Organizer
      5th International Conference on Metal-Organic Frameworks & Open Framework Compounds (MOF2016)
    • Place of Presentation
      Long Beach, California, USA
    • Year and Date
      2016-09-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Long-lived triplet excitons in organic materials2016

    • Author(s)
      R. Kabe, N. Notsuka, H. Mieno, K. Yoshida, C. Adachi
    • Organizer
      ICNT2016
    • Place of Presentation
      Sri Lanka
    • Year and Date
      2016-04-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Afterglow organic light emitting diode2016

    • Author(s)
      R. Kabe, N. Notsuka, K. Yoshida, C. Adachi
    • Organizer
      2016 MRS Spring Meeting & Exhibit
    • Place of Presentation
      Arizona, USA
    • Year and Date
      2016-03-28
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Improved Light-Emitting Properties of Luminescent Molecules Hosted within Nanoporous Metal-Organic Frameworks2016

    • Author(s)
      H. Mieno, R. Kabe, N. Notsuka, V. Stavila, M. E. Foster, M. D. Allendorf, C. Adachi
    • Organizer
      2016 MRS Spring Meeting & Exhibit
    • Place of Presentation
      Arizona, USA
    • Year and Date
      2016-03-28
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Dual emission of both fluorescence and phosphorescence from single-emitter OLED2016

    • Author(s)
      R. Kabe, N. Notsuka, K. Yoshida, C. Adachi
    • Organizer
      International Symposium on Functional Materials 2016
    • Place of Presentation
      OIST, Okinawa
    • Year and Date
      2016-01-25
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Suppression of nonradioactive decay from triplet excited stated by weak intermolecular interactions2015

    • Author(s)
      R. Kabe, N. Notsuka, C. Adachi
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Room temperature phosphorescence from Coronene@ZIF-82015

    • Author(s)
      H. Mieno, R. Kabe, N. Notsuka, C. Adachi
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
  • [Presentation] Long-lived phosphorescence organic light emitting diodes2015

    • Author(s)
      N. Notsuka, R. Kabe, C. Adachi
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
  • [Presentation] 有機媒体による非放射失活の抑制とその応用2015

    • Author(s)
      嘉部量太、安達千波矢
    • Organizer
      情報科学用有機材料第142委員会 第66回研究会
    • Place of Presentation
      東京理科大学、東京
    • Year and Date
      2015-11-20
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] ホスト材料による非放射失活抑制効果と残光性有機ELへの応用2015

    • Author(s)
      嘉部 量太、能塚直人、吉田巧、安達千波矢
    • Organizer
      有機EL討論会第21回例会
    • Place of Presentation
      九州大学、福岡
    • Year and Date
      2015-11-12
    • Related Report
      2015 Research-status Report
  • [Presentation] 未来を切り開く長寿命励起子 -有機媒体の設計とデバイス展開-2015

    • Author(s)
      嘉部量太、安達千波矢
    • Organizer
      九州大学共進化社会システム創成拠点COIプログラム情報モビリティユニットワークショップ
    • Place of Presentation
      九州大学、福岡
    • Year and Date
      2015-09-28
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 残光性有機発光ダイオード(OLED)のEL特性2015

    • Author(s)
      能塚直人、嘉部量太、吉田巧、安達千波矢
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋大学、愛知
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 有機エレクトロルミネッセンス素子、有機エレクトロルミネッセンス素子の駆動方法および照明装置2015

    • Inventor(s)
      嘉部量太、能塚直人、安達千波矢
    • Industrial Property Rights Holder
      嘉部量太、能塚直人、安達千波矢
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-000122
    • Filing Date
      2015-06-30
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 燐光発光材料、燐光発光体から燐光を放射させる方法、燐光発光材料の製 造方法、有機発光素子およびガスセンサー2015

    • Inventor(s)
      三重野寛之、嘉部量太、能塚直人、安達千波矢
    • Industrial Property Rights Holder
      三重野寛之、嘉部量太、能塚直人、安達千波矢
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-115012
    • Filing Date
      2015-06-05
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2018-03-22  

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