| Project/Area Number |
15K21343
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
Functional solid state chemistry
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| Research Institution | Chiba Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | 有機合成化学 / 構造有機化学 / 機能物質化学 / 光物性 / 酸化還元特性 / 星型構造 / 低分子量ゲル化剤 / 星型構造分子 / 還元的三量化反応 / 1,3,5-トリアリールベンゼン / 量子化学計算 / A(LS)3型 / 機能性分子 / DFT計算 |
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| Outline of Final Research Achievements |
An acyl group is introduced to an aromatic compound by a Friedel-Crafts reaction, followed by reductive trimerization reaction of acyl groups with a Lewis acid or protonic acid catalyst was afforded star-shaped 1,3,5-triarylbenzenes in good yield. The photophysical and electrochemical properties of triarylbenzenes were investigated by UV-vis and fluorescent and CV.
Moreover, we found that the 1,3,5-trischolesteryloxycarbonylbenzene was displayed higher gelation ability in comparison with 1,3- and 1,4-bis analogues even though it has no hydrogen bonding moiety.
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