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Enhancement of the capacitance for electrochemical capacitor electrodes utilizing metal-free organic compounds

Research Project

Project/Area Number 15K21478
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Device related chemistry
Organic and hybrid materials
Research InstitutionAichi Institute of Technology

Principal Investigator

Itoi Hiroyuki  愛知工業大学, 工学部, 准教授 (40648789)

Research Collaborator OHZAWA Yoshimi  愛知工業大学, 工学部, 教授 (80278225)
Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords電気化学キャパシタ / 多孔質炭素 / レドックス化合物 / 擬似容量 / 電気二重層キャパシタ / 無溶媒合成 / キノン誘導体 / 活性炭 / レドックスキャパシタ / メタルフリー
Outline of Final Research Achievements

In this study, we hybridized redox organic compounds, 2,5-dichloro benzoquinone (DCBQ), with porous carbon black, ketjen black (KB), to prepare high-performance electrochemical capacitor electrodes through a solvent-free method. Through this method, the KB and DCBQ weight ratios can be accurately controlled because DCBQ molecules are completely adsorbed inside the pores of KB in a gas phase without any expansion of the KB particles. Electrochemical measurements revealed that the pseudocapacitance of DCBQ exhibited the higher volumetric capacitance and power density and longer cycle lifetimes than the electric double-layer capacitance, both of which are generated inside the pores of KB.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • Research Products

    (18 results)

All 2017 2016 2015

All Journal Article (5 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results) Presentation (12 results) (of which Int'l Joint Research: 1 results,  Invited: 3 results) Book (1 results)

  • [Journal Article] Fine Dispersion of Pt4-5 Subnano-Clusters and Pt Single Atoms over Porous Carbon Supports and Their Structural Analyses with X-ray Absorption Spectroscopy2017

    • Author(s)
      Hiroyuki Itoi, Hirotomo Nishihara, Syunsuke Kobayashi, Somlak Ittisanronnachai, Takafumi Ishii, Raul Berenguer, Masashi Ito, Daiju Matsumura, Takashi Kyotani
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 121 Issue: 14 Pages: 7892-7902

    • DOI

      10.1021/acs.jpcc.7b00422

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electrochemical Synthesis of Polyaniline in the Micropores of Activated Carbon for High-Performance Electrochemical Capacitors2017

    • Author(s)
      Hiroyuki Itoi, Shinya Hayashi, Hidenori Matsufusa, Yoshimi Ohzawa
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 22 Pages: 3201-3204

    • DOI

      10.1039/c6cc08822h

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Solvent-free Preparation of Electrochemical Capacitor Electrodes Using Metal-free Redox Organic Compounds2017

    • Author(s)
      Hiroyuki Itoi, Yuka Yasue, Keita Suda, Seiya Katoh, Hideyuki Hasegawa, Shinya Hayashi, Masanao Mitsuoka, Hiroyuki Iwata, Yoshimi Ohzawa
    • Journal Title

      ACS Sustainable Chemistry and Engineering

      Volume: 5 Issue: 1 Pages: 556-562

    • DOI

      10.1021/acssuschemeng.6b01947

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of heteroatoms in ordered microporous carbons on their electrochemical capacitance2016

    • Author(s)
      H. Itoi, H. Nishihara, T. Kyotani
    • Journal Title

      Langmuir

      Volume: 32 Issue: 46 Pages: 11997-12004

    • DOI

      10.1021/acs.langmuir.6b02667

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Pseudocapacitance of Zeolite-Templated Carbon in Organic Electrolytes2015

    • Author(s)
      Khanin Nueangnoraj, Hirotomo Nishihara, Takafumi Ishii, Norihisa Yamamoto, Hiroyuki Itoi, Raúl Berenguer, Ramiro Ruiz-Rosas, Diego Cazorla-Amorós, Emilia Morallón, Masashi Ito, Takashi Kyotani
    • Journal Title

      Energy Storage Materials

      Volume: 1 Pages: 35-41

    • DOI

      10.1016/j.ensm.2015.08.003

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] CVD法によるリチウムイオン電池用負極炭素材料へのシリコンコーティングと構造評価および電気化学特性評価2016

    • Author(s)
      恩徳拓哉,糸井弘行,大澤善美
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉大学 けやき会館
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 化学気相蒸着法を用いたリチウムイオン二次電池用負極材料SiO-各種導電助剤複合材料への熱分解炭素コーティング2016

    • Author(s)
      藤原大輔,糸井弘行,大澤善美
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉大学 けやき会館
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 活性炭のミクロ孔内で生成させたポリアニリンの酸化還元反応を利用した電気化学キャパシタ電極の高性能化2016

    • Author(s)
      林真也、松房秀紀、糸井弘行、大澤善美
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉大学 けやき会館
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] Investigation of Heteroatom Effect in Ordered Microporous Carbons on Their Electrochemical Capacitance2016

    • Author(s)
      Hiroyuki Itoi, Hirotomo Nishihara, and Takashi Kyotani
    • Organizer
      2016 Autumn Meeting of Korean Carbon Society
    • Place of Presentation
      Inha University, 仁川, Korea
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 有機化合物を利用した電気化学キャパシタの高容量化2016

    • Author(s)
      糸井 弘行
    • Organizer
      名工大–中部産総研共同研究セミナー講演会「ナノカーボンのエネルギー貯蔵デバイスへの応用と基礎科学」
    • Place of Presentation
      名古屋工業大学52号棟5214室
    • Year and Date
      2016-01-13
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 多孔質炭素を担体とした複合材料のエネルギー貯蔵・触媒分野への応用2016

    • Author(s)
      糸井弘行
    • Organizer
      第79回材料理化学セミナー
    • Place of Presentation
      大阪大学吹田キャンパス
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 多孔質炭素に高分散させた均一な粒径を有する微小金属ナノ粒子のスピルオーバーを利用した水素貯蔵特性の考察2015

    • Author(s)
      三岡雅尚,糸井 弘行,大澤 善美
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      関西大学千里山キャンパス100周年記念記念館
    • Year and Date
      2015-12-02
    • Related Report
      2015 Research-status Report
  • [Presentation] 化学蒸着法を用いたリチウムイオン電池用シリコン系負極の作製と評価2015

    • Author(s)
      小田 和誠, 糸井 弘行,大澤 善美
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      関西大学千里山キャンパス100周年記念記念館
    • Year and Date
      2015-12-02
    • Related Report
      2015 Research-status Report
  • [Presentation] 多孔質炭素の細孔内部における導電性ポリマーの重合の検討と電気化学特性の考察2015

    • Author(s)
      林 真也,三岡 雅尚,糸井 弘行,大澤 善美
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      関西大学千里山キャンパス100周年記念記念館
    • Year and Date
      2015-12-02
    • Related Report
      2015 Research-status Report
  • [Presentation] パルスCVI法による熱分解炭素薄膜をコー ティングしたSiOの構造と電気化学特性評価2015

    • Author(s)
      藤原 大輔,糸井 弘行,大澤 善美
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      関西大学千里山キャンパス100周年記念記念館
    • Year and Date
      2015-12-02
    • Related Report
      2015 Research-status Report
  • [Presentation] レドックス化合物を利用した電気化学キャパシタの高容量化2015

    • Author(s)
      糸井 弘行,三岡雅尚,林 真也,大澤 善美
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      関西大学千里山キャンパス100周年記念記念館
    • Year and Date
      2015-12-02
    • Related Report
      2015 Research-status Report
  • [Presentation] Enhancement of Electrochemical Capacitance in Porous Carbons with Redox Organic Molecules2015

    • Author(s)
      Hiroyuki Itoi, Masanao Mitsuoka, Yoshimi Ohzawa
    • Organizer
      Carbon 2015
    • Place of Presentation
      International Congress Center Dresden, German
    • Year and Date
      2015-07-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Book] 全固体電池のイオン電導性向上技術と材料、製造プロセスの開発2017

    • Author(s)
      糸井弘行(共著)
    • Total Pages
      475
    • Publisher
      技術情報協会
    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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