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Fate prediction and environmental monitoring and of agricultural chemicals in aquatic environment

Research Project

Project/Area Number 15K21643
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental dynamic analysis
Environmental policy and social systems
Research InstitutionNational Institute of Health Sciences

Principal Investigator

Kobayashi Norihiro  国立医薬品食品衛生研究所, 生活衛生化学部, 室長 (10450660)

Research Collaborator TSUCHIYA Yuko  
KOMATSUBARA Yumi  
ERIGUCHI Tomomi  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords農薬 / 水環境 / 動態 / シミュレーション / 分析 / モニタリング / 環境動態
Outline of Final Research Achievements

In order to predict the detections of agricultural chemicals in Japanese aquatic environment, we have developed a chemical fate prediction model. After collecting physico-chemical properties of these agricultural chemicals, we applied the model to 234 agricultural chemicals. Run-off ratio at the 30 km downstream from loading points and the mass balances of these pharmaceuticals in the river were estimated. Further, we have developed a simultaneous analysis method of agricultural chemicals in water samples by gas chromatography - mass spectrometry (GC/MS) and liquid chromatography - tandem mass spectrometry (LC/MS/MS), in order to conduct a monitoring survey of agricultural chemicals in aquatic environment. Accuracy of the analytical method was satisfactory. We have collected 75 river water samples and detected 30 agricultural chemicals. Agricultural chemicals, which were estimated high run-off ratios (>70%) from the model, were frequently detected in our environmental monitoring.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (18 results)

All 2018 2017 2016 2015

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (15 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results)

  • [Journal Article] 水道水中のイミノクタジン・ジクワット・パラコートLC/MS/MS一斉分析法の妥当性評価2016

    • Author(s)
      小林憲弘,久保田領志,齋藤信裕,木村謙治,宮﨑悦子,平林達也,水田裕進,木村慎一,宮本紫織,大倉敏裕,中村弘揮,粕谷智浩,古川浩司,塚本多矩,市川千種,髙原玲華,林田寛司,京野完,佐久井徳広,山本五秋,齊藤香織,五十嵐良明
    • Journal Title

      環境科学会誌

      Volume: 29 (1) Pages: 3-16

    • NAID

      130005598291

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] 水道水質検査とその検査方法2016

    • Author(s)
      小林憲弘
    • Journal Title

      水環境学会誌

      Volume: 39(A)(2) Pages: 64-66

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] 水道水中のグルホシネート・グリホサート・AMPAのLC/MS/MS一斉分析法の妥当性評価2016

    • Author(s)
      小林憲弘,木下輝昭,鈴木俊也,高木総吉,吉田仁,望月映希,小林浩,辻清美,上村仁,植田紘行,齋藤信裕,岩間紀知,粕谷智浩,古川浩司,塚本多矩,市川千種,久保田領志,五十嵐良明
    • Journal Title

      環境科学会誌

      Volume: 29 (3) Pages: 147-158

    • NAID

      130005277986

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 液体クロマトグラフ-質量分析計を用いた水道水中140種農薬の分析法検討と妥当性評価2018

    • Author(s)
      高木総吉,安達史恵,吉田仁,木下輝昭,小林憲弘
    • Organizer
      日本薬学会第138年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 環境水中農薬の動態予測モデルの構築と適用2017

    • Author(s)
      小林憲弘,小松原由美,江里口知己,五十嵐良明
    • Organizer
      第51回日本水環境学会年会
    • Place of Presentation
      熊本県熊本市
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Transformation to a degradation product by hydrolysis of iprodione2017

    • Author(s)
      Norihiro Kobayashi, Yuko Tsuchiya, Yoshiaki Ikarashi
    • Organizer
      Water and Environment Technology Conference 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 化学物質運命予測モデルを用いた水道水の検査対象農薬の選定2017

    • Author(s)
      小林憲弘,小松原由美,江里口知己,五十嵐良明
    • Organizer
      環境科学会2017年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Development and application of an agricultural chemicals fate prediction model in Japanese water environment2017

    • Author(s)
      Norihiro Kobayashi, Yumi Komatsubara, Tomomi Eriguchi, Yoshiaki Ikarashi
    • Organizer
      SETAC North America 38th Annual Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水中におけるイプロジオン代謝産物の生成挙動とその検査法の検討2017

    • Author(s)
      土屋裕子,小林憲弘,五十嵐良明
    • Organizer
      第54回全国衛生化学技術協議会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 液体クロマトグラフ-質量分析計による水道水中テフリルトリオンの分析法検討と妥当性評価2017

    • Author(s)
      高木総吉,安達史恵,吉田仁,小林憲弘
    • Organizer
      第54回全国衛生化学技術協議会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Application of a 3-D chemical fate prediction model for risk assessment of agricultural chemicals in Japanese river water2017

    • Author(s)
      Norihiro Kobayashi, Yumi Komatsubara, Tomomi Eriguchi, Yoshiaki Ikarashi
    • Organizer
      Society for Risk Analysis 2017 Annual Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水道水の検査対象農薬のLC/MS/MS一斉分析法の開発と妥当性評価2016

    • Author(s)
      小林憲弘,久保田領志,五十嵐良明
    • Organizer
      第53回全国衛生化学技術協議会年会
    • Place of Presentation
      青森県青森市
    • Year and Date
      2016-11-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Development of a simultaneous analytical method for agricultural chemicals in tap water using LC/MS/MS2016

    • Author(s)
      Norihiro Kobayashi, Taku Tsukamoto, Hideki Horiike, Reiji Kubota, Yoshiaki Ikarashi
    • Organizer
      7th SETAC World Congress/37th SETAC North America Annual Meeting
    • Place of Presentation
      Orlando, FL, USA
    • Year and Date
      2016-11-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 化学物質運命予測モデルを用いた環境水中農薬の動態予測2016

    • Author(s)
      小松原由美,江里口知己,小林憲弘
    • Organizer
      海洋理工学会 平成28年度秋季大会
    • Place of Presentation
      京都府京都市
    • Year and Date
      2016-10-28
    • Related Report
      2016 Research-status Report
  • [Presentation] 水道水の検査対象農薬のLC/MS/MS一斉分析法の検討2016

    • Author(s)
      小林憲弘,塚本多矩,堀池秀樹,久保田領志,五十嵐良明
    • Organizer
      第25回環境化学討論会
    • Place of Presentation
      新潟県新潟市
    • Year and Date
      2016-06-10
    • Related Report
      2016 Research-status Report
  • [Presentation] 化学物質による飲料水の水質異常への対応2016

    • Author(s)
      小林憲弘
    • Organizer
      第29回公衆衛生情報研究協議会研究会シンポジウム:飲料水の危機事案に対する関係機関の連携
    • Place of Presentation
      埼玉県和光市
    • Year and Date
      2016-01-28
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 対象農薬リスト掲載農薬の新規6分析法の妥当性評価2015

    • Author(s)
      小林憲弘,久保田領志,鈴木俊也,川元達彦,高木総吉,吉田仁,小高陽子,薗部真理奈,小林浩,望月映希,上村仁,西以和貴,佐藤学,宮本紫織,大窪かおり,五十嵐良明
    • Organizer
      第52回全国衛生化学技術協議会年会
    • Place of Presentation
      静岡県静岡市
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report
  • [Presentation] 水道水中のGC/MS分析対象農薬のLC/MS/MS一斉分析方法の検討2015

    • Author(s)
      小林憲弘,久保田領志,五十嵐良明
    • Organizer
      環境科学会2015年会
    • Place of Presentation
      大阪府吹田市
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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