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Synthesis of heteroatom-containing zeolite-templated carbons from ionic liquid and their applications(Fostering Joint International Research)

Research Project

Project/Area Number 15KK0196
Research Category

Fund for the Promotion of Joint International Research (Fostering Joint International Research)

Allocation TypeMulti-year Fund
Research Field Nanomaterials engineering
Research InstitutionTohoku University

Principal Investigator

Nishihara Hirotomo  東北大学, 多元物質科学研究所, 准教授 (80400430)

Research Collaborator Shimizu George  University of Calgary, Department of Chemistry, Professor
Project Period (FY) 2016 – 2018
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥14,820,000 (Direct Cost: ¥11,400,000、Indirect Cost: ¥3,420,000)
Keywords鋳型炭素 / 有機結晶 / 金属有機構造体 / カーボンアロイ / 触媒
Outline of Final Research Achievements

Zeolite-templated carbons containing boron and nitrogen have been successfully synthesized by using ionic liquid as one of the precursors. The electrochemical properties of the resulting materials were examined and the effect of the heteroatoms was confirmed. In this project, the research was developed under the ground concept of fusion of metal-organic frameworks and nanoporous carbon materials. Thus, a new template-free synthesis pathway for new hybrid materials which possess both advantages of these two materials has been successfully developed. Also, the research was beneficial to have deep insight into the structure and the formation mechanism of zeolite-templated carbons, which greatly contributed to the carbon science. Moreover, this research project was beneficial to establish new research collaborations with Canadian experts through research visit to many researchers.

Academic Significance and Societal Importance of the Research Achievements

白金などの貴金属は触媒の分野では大量に消費されているが、資源の枯渇が世界的な問題となっている。そこで本研究では、貴金属と同じ働きをする触媒を、カーボンや安価な遷移金属といった資源豊富な元素で置き換えるための基礎的検討を行った。いわば現代の錬金術である。カナダの専門家らの協力を得て化学的手法を駆使することで、従来は不可能であった化学構造が明確なカーボン系新触媒の開発に成功した。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (27 results)

All 2018 2017 Other

All Int'l Joint Research (1 results) Journal Article (6 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 6 results,  Open Access: 3 results) Presentation (18 results) (of which Int'l Joint Research: 7 results,  Invited: 9 results) Remarks (1 results) Funded Workshop (1 results)

  • [Int'l Joint Research] University of Calgary(カナダ)2017

    • Year and Date
      2017-04-05
    • Related Report
      2018 Annual Research Report
  • [Journal Article] Zeolite-templated carbons; three-dimensional microporous graphene frameworks2018

    • Author(s)
      H. Nishihara, T. Kyotani
    • Journal Title

      ChemComm

      Volume: 54 Issue: 45 Pages: 5648-5673

    • DOI

      10.1039/c8cc01932k

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultraporous nitrogen-doped zeolite-templated carbon for high power density aqueous-based supercapacitors2018

    • Author(s)
      Maria Jose Mostazo-Lopez, Ramiro Ruiz-Rosas, Alberto Castro-Muniz, Hirotomo Nishihara, Takashi Kyotani, Emilia Morallon, Diego Cazorla-Amoros
    • Journal Title

      Carbon

      Volume: 129 Pages: 510-519

    • DOI

      10.1016/j.carbon.2017.12.050

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Microsphere Assemblies via Phosphonate Monoester Coordination Chemistry2018

    • Author(s)
      Kamila J. Bladek, Margaret E. Reid, Hirotomo Nishihara, Farid Akhtar, Benjamin S. Gelfand, George K. H. Shimizu
    • Journal Title

      Chemistry A European Journal

      Volume: 24 Issue: 7 Pages: 1533-1538

    • DOI

      10.1002/chem.201705985

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Graphene-basd ordered framework with a diverse range of carbon polygons formed in zeolite nanochannels2017

    • Author(s)
      Hirotomo Nishihara, Hiroyuki Fujimoto, Hiroyuki Ito, Keita Nomura, Hideki Tanaka, Minoru T. Miyahara, Patrick A. Bonnaud, Ryuji Miura, Ai Suzuki, Naoto Miyamoto, Nozomu Hatakeyama, Akira Miyamoto, Kazutaka Ikeda, Toshiya Otomo, Takashi Kyotani
    • Journal Title

      Carbon

      Volume: 129 Pages: 854-862

    • DOI

      10.1016/j.carbon.2017.12.055

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Synthesis of ordered carbonaceous frameworks from organic crystals2017

    • Author(s)
      H. Nishihara, T. Hirota, K. Matsuura, M. Ohwada, N. Hoshino, T. Akutagawa, T. Higuchi, H. Jinnai, Y. Koseki, H. Kasai, Y. Matsuo, J. Maruyama, Y. Hayasaka, H. Konaka, Y. Yamada, S. Yamaguchi, K. Kamiya, T. Kamimura, H. Nobukuni, F. Tani
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1 Pages: 109-109

    • DOI

      10.1038/s41467-017-00152-z

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Boron and nitrogen co-doped ordered microporous carbons with high surface areas2017

    • Author(s)
      Alberto Castro-Muniz, Hirotomo Nishihara, Tetsuya Hirota, Mao Ohwada, Li-Xiang Li, Tetsuya Tsuda, Susumu Kuwabata, Jun Maruyama, Takashi Kyotani
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 100 Pages: 13348-13351

    • DOI

      10.1039/c7cc08390d

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 化学構造が見える3次元カーボン構造体2018

    • Author(s)
      西原洋知
    • Organizer
      名古屋大学伊丹ERATOセミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 化学構造が見える3次元カーボン構造体2018

    • Author(s)
      西原洋知
    • Organizer
      理工学部講演会・関学有機化学セミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 化学構造が見える3次元カーボン構造体2018

    • Author(s)
      西原洋知
    • Organizer
      第124回黒鉛化合物研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 構造が見える3次元のカーボン構造体2018

    • Author(s)
      西原洋知
    • Organizer
      GIC平成30年度第57回研修セミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 化学構造が見える3次元カーボン構造体2018

    • Author(s)
      西原洋知
    • Organizer
      第69回コロイドおよび界面化学討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 炭素系多孔体-鋳型法と新しいアプローチ-2018

    • Author(s)
      西原洋知
    • Organizer
      2018年度第7回CPC研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] カーボン系材料のナノ空間制御とエネルギー分野への応用2018

    • Author(s)
      西原洋知
    • Organizer
      高分子・ハイブリッド材料研究センター2018年度シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] The role of carbon edge sites on electrochemical stability of supercapacitors2018

    • Author(s)
      Rui Tang, Kaihsi Taguchi, Toshihiro Asada, Naoya Kobayashi, Hiromoto Nishihara, Takashi Kyotani
    • Organizer
      平成30年度化学系学協会東北大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Understanding the origin of carbon anodic oxidation in supercapacitors from a molecular point of view2018

    • Author(s)
      Rui Tang, Kaihsi Taguchi, Hiromoto Nishihara, Takafumi Ishii, Emilia Morallon, Diego Cazorla-Amoros, Toshihiro Asada, Naoya Kobayashi, Takashi Kyotani
    • Organizer
      第45回炭素材料学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Insight into the origin of carbon corrosion in positive electrodes of supercapacitors2018

    • Author(s)
      Rui Tang, Hiromoto Nishihara, Takashi Kyotani
    • Organizer
      第18回多元物質科学研究所研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Understanding the origin of electrochemical oxidation in positive electrodes of supercapacitors2018

    • Author(s)
      Rui Tang, Hiromoto Nishihara, Takashi Kyotani
    • Organizer
      第11回酸化グラフェンシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Chemistry of ordered carbonaceous frameworks2018

    • Author(s)
      Hirotomo Nishihara
    • Organizer
      International mini-symposium on molecular and hybrid materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hydrolysis of cellulose catalyzed by oxidized carbon powder2018

    • Author(s)
      Akira Takatsuki, Hirotomo Nishihara, Masahiko Hiratani, Masato Kaneeda, Yoshiaki Kurihara, Takashi Kyotani
    • Organizer
      Carbon2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Understanding the effect of carbon edge sites on the stability of supercapacitors in an organic electrolyte2018

    • Author(s)
      Rui Tang, Kaishi Taguchi, Hirotomo Nishihara, Takashi Kyotani
    • Organizer
      International Seminar on Chemistry 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Ordered Carbonaceous Frameworks from Porphyrin-Based Crystals2017

    • Author(s)
      Hirotomo Nishihara, Mao Ohwada, Yoshiaki Matsuo, Jun Maruyama, Takuya Kamimura, Hirofumi Nobukuni, Fumito Tani
    • Organizer
      XXVI International Materials Research Congress
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Chemistry of ordered carbonaceous frameworks2017

    • Author(s)
      Hirotomo Nishihara
    • Organizer
      International mini-symposium on molecular and hybrid materials
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Design and development of functional porous materials2017

    • Author(s)
      Hirotomo Nishihara
    • Organizer
      Conferences de Chimie Hiver 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of Ordered Carbonaceous Frameworks from Porphyrin-Based Crystals2017

    • Author(s)
      Hirotomo Nishihara
    • Organizer
      Symposium on chemistry and materials 2017
    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Remarks] カーボンの中に金属が規則配列した触媒 - 貴金属に替わる安価な触媒開発を目指して

    • URL

      https://academist-cf.com/journal/?p=5529

    • Related Report
      2017 Research-status Report
  • [Funded Workshop] Symposium on chemistry and materials 20172017

    • Place of Presentation
      東北大学(仙台市)
    • Related Report
      2016 Research-status Report

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Published: 2016-10-04   Modified: 2020-03-30  

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