Synthesis of heteroatom-containing zeolite-templated carbons from ionic liquid and their applications(Fostering Joint International Research)
Project/Area Number |
15KK0196
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Research Category |
Fund for the Promotion of Joint International Research (Fostering Joint International Research)
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Allocation Type | Multi-year Fund |
Research Field |
Nanomaterials engineering
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Research Institution | Tohoku University |
Principal Investigator |
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Research Collaborator |
Shimizu George University of Calgary, Department of Chemistry, Professor
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Project Period (FY) |
2016 – 2018
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Project Status |
Completed (Fiscal Year 2018)
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Budget Amount *help |
¥14,820,000 (Direct Cost: ¥11,400,000、Indirect Cost: ¥3,420,000)
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Keywords | 鋳型炭素 / 有機結晶 / 金属有機構造体 / カーボンアロイ / 触媒 |
Outline of Final Research Achievements |
Zeolite-templated carbons containing boron and nitrogen have been successfully synthesized by using ionic liquid as one of the precursors. The electrochemical properties of the resulting materials were examined and the effect of the heteroatoms was confirmed. In this project, the research was developed under the ground concept of fusion of metal-organic frameworks and nanoporous carbon materials. Thus, a new template-free synthesis pathway for new hybrid materials which possess both advantages of these two materials has been successfully developed. Also, the research was beneficial to have deep insight into the structure and the formation mechanism of zeolite-templated carbons, which greatly contributed to the carbon science. Moreover, this research project was beneficial to establish new research collaborations with Canadian experts through research visit to many researchers.
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Academic Significance and Societal Importance of the Research Achievements |
白金などの貴金属は触媒の分野では大量に消費されているが、資源の枯渇が世界的な問題となっている。そこで本研究では、貴金属と同じ働きをする触媒を、カーボンや安価な遷移金属といった資源豊富な元素で置き換えるための基礎的検討を行った。いわば現代の錬金術である。カナダの専門家らの協力を得て化学的手法を駆使することで、従来は不可能であった化学構造が明確なカーボン系新触媒の開発に成功した。
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Report
(4 results)
Research Products
(27 results)
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[Journal Article] Graphene-basd ordered framework with a diverse range of carbon polygons formed in zeolite nanochannels2017
Author(s)
Hirotomo Nishihara, Hiroyuki Fujimoto, Hiroyuki Ito, Keita Nomura, Hideki Tanaka, Minoru T. Miyahara, Patrick A. Bonnaud, Ryuji Miura, Ai Suzuki, Naoto Miyamoto, Nozomu Hatakeyama, Akira Miyamoto, Kazutaka Ikeda, Toshiya Otomo, Takashi Kyotani
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Journal Title
Carbon
Volume: 129
Pages: 854-862
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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[Journal Article] Synthesis of ordered carbonaceous frameworks from organic crystals2017
Author(s)
H. Nishihara, T. Hirota, K. Matsuura, M. Ohwada, N. Hoshino, T. Akutagawa, T. Higuchi, H. Jinnai, Y. Koseki, H. Kasai, Y. Matsuo, J. Maruyama, Y. Hayasaka, H. Konaka, Y. Yamada, S. Yamaguchi, K. Kamiya, T. Kamimura, H. Nobukuni, F. Tani
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Journal Title
Nature Communications
Volume: 8
Issue: 1
Pages: 109-109
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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