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Fabrication of hollow colloidal crystals with external field response to control the arrangement of internal particles and creation on their functionality(Fostering Joint International Research)

Research Project

Project/Area Number 15KK0222
Research Category

Fund for the Promotion of Joint International Research (Fostering Joint International Research)

Allocation TypeMulti-year Fund
Research Field Nanomaterials engineering
Research InstitutionTohoku University

Principal Investigator

Nagao Daisuke  東北大学, 工学研究科, 教授 (50374963)

Project Period (FY) 2016 – 2019
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥13,910,000 (Direct Cost: ¥10,700,000、Indirect Cost: ¥3,210,000)
Keywordsナノ材料 / 中空粒子 / 集積 / 可動 / 規則配列
Outline of Final Research Achievements

The present work synthesized colloidal crystals of particles comprising a movable inner sphere and outer shell with aiming on creation of novel functions from the colloidal crystals. A combination of the synthetic technique on monodisperse particles in Tohoku University with the characterization technique of colloids in Utrecht University is allowed to find a possibility of unprecedented functions that have not been reported in both solid-like previous colloidal crystals and liquid-like suspension of particles.

Academic Significance and Societal Importance of the Research Achievements

従来のコロイド系材料の問題点は、その比表面積の大きさによる粒子凝集にあった。これを回避するため、本研究では、中空粒子の外殻を物理障壁として利用し、その外殻に閉じ込めた粒子が互いに凝集しないコロイド結晶を作製した。粒子をその表面が露出した状態で閉じ込めることで、粒子体積に依存する機能だけでなく、粒子表面に依存する機能も活用できる点に本研究の独創性がある。閉じ込めた粒子の大きさを数100 nmから数10 nmまで微小化しただけでなく、閉じ込めた粒子に可動性を与えたことから、外部刺激を利用した刺激応答性としての用途も期待される。

Report

(5 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (39 results)

All 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (4 results) Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (21 results) (of which Int'l Joint Research: 11 results) Book (1 results) Remarks (4 results)

  • [Int'l Joint Research] Utrecht University(オランダ)2017

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] RWTH Aachen University(ドイツ)2017

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] CIC biomaGUNE(スペイン)2016

    • Year and Date
      2016-09-18
    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] University of Melbourne(オーストラリア)2016

    • Year and Date
      2016-05-17
    • Related Report
      2019 Annual Research Report
  • [Journal Article] Compartmentalization of gold nanoparticle clusters in hollow silica spheres and their assembly induced by an external electric field2020

    • Author(s)
      Kanako Watanabe, Tom A. J. Welling, Sina Sadighikia, Haruyuki Ishii, Arnout Imhof, Marijn A. van Huis, Alfons van Blaaderen, Daisuke Nagao
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: 566(15) Pages: 202-210

    • DOI

      10.1016/j.jcis.2020.01.094

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Three-dimensional periodic structures of gold nanoclusters in the interstices of sub-100 nm polymer particles toward surface-enhanced Raman scattering2019

    • Author(s)
      Ayumi Yahata, Haruyuki Ishii, Kosuke Nakamura, Kanako Watanabe, Daisuke Nagao
    • Journal Title

      Advanced Powder Technology

      Volume: 30(12) Issue: 12 Pages: 2957-2963

    • DOI

      10.1016/j.apt.2019.09.003

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Permittivity enhancement of transparent poly(vinylidene fluoride) nanocomposite films by loading titania-coated barium titanate nanoparticles2018

    • Author(s)
      Jun Kanazawa, Tsuyoshi Kanamori, Masaki Sato, Haruyuki Ishii, Mikio Konno, Daisuke Nagao
    • Journal Title

      Journal of Nanoparticle Research

      Volume: 20 Issue: 7 Pages: 186-186

    • DOI

      10.1007/s11051-018-4289-0

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] External-Stimuli-Assisted Control over Assemblies of Plasmonic Metals2018

    • Author(s)
      Kanako Watanabe, Kotaro Kuroda, Daisuke Nagao
    • Journal Title

      Materials

      Volume: 11 Issue: 5 Pages: 794-794

    • DOI

      10.3390/ma11050794

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Uniform formation of mesoporous silica shell on micron-sized cores in the presence of hydrocarbon used as a swelling agent2018

    • Author(s)
      Haruyuki Ishii, Mitsunobu Nara, Yuri Hashimoto, Arata Kanno, Shunho Ishikawa, Daisuke Nagao, Mikio Konno
    • Journal Title

      Journal of Sol-Gel Science and Technology

      Volume: 85 Issue: 3 Pages: 539-545

    • DOI

      10.1007/s10971-018-4589-y

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Yolk/Shell Colloidal Crystals Incorporating Movable Cores with Their Motion Controlled by an External Electric Field2017

    • Author(s)
      Kanako Watanabe, Haruyuki Ishii, Mikio Konno, Arnout Imhof , Alfons van Blaaderen, Daisuke Nagao
    • Journal Title

      Langmuir

      Volume: 33 Issue: 1 Pages: 296-302

    • DOI

      10.1021/acs.langmuir.6b03116

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Phosphor-free silica-coating of monodisperse cores for dual functionalization with luminescent and mesoporous shell2017

    • Author(s)
      Haruyuki Ishii, Shunsuke Kawai, Daisuke Nagao, Mikio Konno
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 241 Pages: 366-371

    • DOI

      10.1016/j.micromeso.2016.12.014

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Optimized Thermal Treatment for Preparation of Double Inverse Opals Incorporating Movable Cores2017

    • Author(s)
      Kenta Yamada, Daisuke Nagao, Haruyuki Ishii, Mikio Konno
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 50 Issue: 1 Pages: 64-67

    • DOI

      10.1252/jcej.16we146

    • NAID

      130005290306

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Low-temperature synthesis of water-dispersible magnetic composite particles with high monodispersity2016

    • Author(s)
      Chika Suwabe, Noriko Yamauchi, Daisuke Nagao, Haruyuki Ishii, Mikio Konno
    • Journal Title

      Colloid and Polymer Science

      Volume: 294(12) Issue: 12 Pages: 2079-2085

    • DOI

      10.1007/s00396-016-3971-y

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] Fabrication of non-close-packed colloidal crystals composed of hollow particles incorporating movable cores2019

    • Author(s)
      H. Namigata, K. Watanabe, E. Tanaka, D. Nagao
    • Organizer
      2019 International Symposium on Chemical-Environmental-Biomedical Technology(isCEBT2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Colloidal stability of gold nanoparticle clusters encapsulated into hollow silica spheres2019

    • Author(s)
      K. Watanabe, T. A. J. Welling, S. Sadighikia, H. Ishii, A. Imhof, M. A. Huis, A. van Blaaderen, D. Nagao
    • Organizer
      OKINAWA COLLOIDS 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of silica encapsulation on plasmon characteristics of gold nanotriangle2019

    • Author(s)
      K. Nakamura, K. Watanabe, D. Nagao
    • Organizer
      OKINAWA COLLOIDS 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金ナノトライアングルのシリカ被覆プロセスとプラズモン特性に関する研究2019

    • Author(s)
      中村幸佑、黒田昂太郎、渡部花奈子、長尾大輔
    • Organizer
      第21回先端研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 誘電性ナノコンポジット膜に及ぼすTEMPO酸化セルロースナノファイバーの補強効果2019

    • Author(s)
      佐藤昌紀、金澤惇、石井治之、長尾大輔
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Research-status Report
  • [Presentation] メソポーラスシリカ粒子の細孔径拡大に向けたゾル-ゲル反応溶媒組成の検討2019

    • Author(s)
      藤本洸太、石川椿峰、石井治之、長尾大輔
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Research-status Report
  • [Presentation] チタン酸バリウムおよびTEMPO酸化セルロースナノファイバーを充填した多機能ナノコンポジット薄膜の作製2019

    • Author(s)
      佐藤昌紀、金澤惇、石井治之、長尾大輔
    • Organizer
      マテリアル・ファブリケーション・デザインセミナー
    • Related Report
      2018 Research-status Report
  • [Presentation] Fluorescence enhancement of nanocomposite films composed of phosphor-free luminescent silica nanoparticles by loading dielectric nanoparticles2018

    • Author(s)
      J. Kanazawa, H. Ishii, D. Nagao
    • Organizer
      13th Japan-Korea Symposium on Materials and Interfaces
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] 蛍光シリカ透明ナノコンポジット膜の蛍光特性に及ぼす誘電性ナノ粒子添加の影響2018

    • Author(s)
      金澤惇、石井治之、長尾大輔
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 微小空間での粒子配向制御に向けた金ナノロッド複合中空粒子の合成2018

    • Author(s)
      黒田昂太郎、渡部花奈子、石井治之、長尾大輔
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Rattle-type colloidal crystals incorporating a movable silica/titania core developed for switchable materials2018

    • Author(s)
      K. Watanabe, E. Tanaka, H. Ishii, D. Nagao
    • Organizer
      32nd Conference of the European Colloid and Interface Society (ECIS)2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Sub-micron core-shell mesoporous silica particles as a new generation for HPLC applications2018

    • Author(s)
      S. Ishikawa, H. Ishii, D. Nagao
    • Organizer
      32nd Conference of the European Colloid and Interface Society (ECIS)2018
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] ゾル-ゲル反応におけるメソポーラスシェル形成過程の実験的検討2018

    • Author(s)
      石川椿峰、石井治之、長尾大輔
    • Organizer
      第20回先端研究発表会
    • Related Report
      2018 Research-status Report
  • [Presentation] Motions of cores incorporated into a rattle particle under an external electric field2018

    • Author(s)
      K. Watanabe, E. Tanaka, H. Ishii, M. Konno, D. Nagao
    • Organizer
      16th Conference of the International Association of Colloid and Interface Scientists
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] Characterization of 2D and 3D rattle-type colloidal crystals incorporating movable, electro-responsive cores for new optical devices2017

    • Author(s)
      K. Watanabe, E. Tanaka, H. Ishiim, M. Konno, D. Nagao
    • Organizer
      10th World Congress of Chemical Engineering
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 3次元周期構造を有するコア-シェル粒子配列体の光学特性に及ぼす内包コア種の影響2017

    • Author(s)
      田中恵理、石井治之、今野幹男、長尾大輔
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Controls over motion and location of movable cores incorporated into yolk/shell colloidal crystal by external electric fiel2016

    • Author(s)
      K. Watanabe、H. Ishii、M. Konno、D. Nagao
    • Organizer
      12th Japan-Korea Symposium on Materials & Interfaces
    • Place of Presentation
      Gotemba Kogen Resort-Toki No Sumika(Shizuoka・Japan)
    • Year and Date
      2016-11-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fabrication of 3D assemblies of hollow particles incorporating movable cores for novel optical materials2016

    • Author(s)
      E. Tanaka、H. Ishii、M. Konno、D. Nagao
    • Organizer
      12th Japan-Korea Symposium on Materials & Interfaces
    • Place of Presentation
      Gotemba Kogen Resort-Toki No Sumika(Shizuoka・Japan)
    • Year and Date
      2016-11-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ラトル型粒子配列体に内包した可動性コアの電場による運動制御2016

    • Author(s)
      渡部花奈子、石井治之、今野幹男、長尾大輔
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(神奈川県・横浜市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 可動性コア内包型3次元中空粒子集積体の作製と特性評価2016

    • Author(s)
      田中恵理、石井治之、今野幹男、長尾大輔
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学(徳島県・徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] Electric-field-assisted location control over inner cores incorporated into rattle-type colloidal crystals2016

    • Author(s)
      K. Watanabe、D. Nagao、H. Ishii、M. Konno
    • Organizer
      6th International Colloids Conference
    • Place of Presentation
      Maritim proArte Hotel Berlin(Berlin・Germany)
    • Year and Date
      2016-06-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Book] 高分子微粒子ハンドブック「Yolk/Shell 構造粒子」2017

    • Author(s)
      渡部花奈子、 長尾大輔
    • Total Pages
      10
    • Publisher
      株式会社シーエムシー出版
    • Related Report
      2017 Research-status Report
  • [Remarks] 長尾研究室HP

    • URL

      https://www.che.tohoku.ac.jp/~mpe/

    • Related Report
      2019 Annual Research Report
  • [Remarks] 東北大学大学院工学研究科 化学工学専攻 長尾研究室HP

    • URL

      http://www.che.tohoku.ac.jp/~mpe/

    • Related Report
      2018 Research-status Report
  • [Remarks] 東北大学大学院工学研究科 化学工学専攻 長尾研究室HP

    • URL

      https://www.che.tohoku.ac.jp/~mpe/

    • Related Report
      2017 Research-status Report
  • [Remarks] 長尾研HP

    • URL

      https://www.che.tohoku.ac.jp/~mpe/

    • Related Report
      2016 Research-status Report

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Published: 2016-10-04   Modified: 2021-12-27  

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