Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2019: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2018: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2016: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2015: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
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Outline of Final Research Achievements |
In this study, organic chemistry, analytical chemistry, and computational science collaborate and share information closely to clarify the "essence of transition metal catalyzed reaction such as carbon-hydrogen bond activation reactions," which is conventionally a black box, and to "control the transition state of the above reactions" and "establish guidelines for the design of inexpensive and excellent". The goals of this project are to clarify the nature of the above reactions, control the transition state of carbon-hydrogen bond activation reactions, and establish guidelines for designing inexpensive and superior catalysts. In this study, the above reactions are measured in both homogeneous catalyst systems and nanoparticle catalyst systems. For both systems, the role of rate-limiting step determinations, bases, and solvents was investigated.
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