Transition state analysis of [2+2] cycloaddition-retroelectrocyclization
| Project/Area Number |
15KT0140
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 特設分野 |
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| Research Field |
Transition State Control
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2015-07-10 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | クリックケミストリー / [2+2]付加環化 / ドナーアクセプター構造 |
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| Outline of Final Research Achievements |
Click chemistry is a highly efficient addition reaction. In this study, [2+2] cycloaddition-retroelectrocyclization between electron-rich alkynes and electron-deficient alkenes was investigated. Reaction mechanism and product structures were studied in terms of the steric and electronic factors of the reactants. Also, the donor-acceptor products showed potent redox activities and intense charge-transfer bands. These features were successfully applied to thin film devices, such as photovoltaic cells, and specific metal ion sensors.
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Report
(4 results)
Research Products
(20 results)
