| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Outline of Final Research Achievements |
Considerable research attention has been devoted to create well functionalized materials based on supramolecular assemblies. One of the grand challenges in the supramolecular assemblies is to regulate polydispersity. Achieving supramolecular living polymerization requires a cooperative self-assembly that involves two assembly regimes with distinct association constants. We developed planar π-conjugated molecules that cooperatively assemble with the assistance of dipole-dipole interaction, van der Waals interaction and Pt-Pt interactions. In the course of study for the monomer with the Pt-Pt interaction, a living polymerization is realized. Our study demonstrated that dipole－dipole interactions, van der Waals interactions and Pt-Pt interaction can drive the cooperative assembly of planar π-conjugated molecules.
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