Formation of Diffusion Barrier Bond Coat to Realize High Reliable and Long Life Thermal Barrier Coatings

• Project/Area Number: 16001004
• Research Category: Grant-in-Aid for Specially Promoted Research
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering; Engineering
• Research Institution: Hokkaido University
• Principal Investigator: NARITA Toshio Hokkaido University, 大学院・工学研究科, 名誉教授 (60001252)
• Co-Investigator(Kenkyū-buntansha): HARA Motoi 秋田大学, 工学資源学部, 教授 (50156494) ; TAKASHIMA Toshiyuki 北海道工業大学, 機会システム工学科, 教授 (20094815) ; 村上 秀之 (独)物質・材料研究機構, 材料研究所, 主席研究員 (30343867)
• Project Period (FY): 2004 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥588,510,000 (Direct Cost: ¥452,700,000、Indirect Cost: ¥135,810,000); Fiscal Year 2008: ¥67,340,000 (Direct Cost: ¥51,800,000、Indirect Cost: ¥15,540,000); Fiscal Year 2007: ¥73,060,000 (Direct Cost: ¥56,200,000、Indirect Cost: ¥16,860,000); Fiscal Year 2006: ¥109,850,000 (Direct Cost: ¥84,500,000、Indirect Cost: ¥25,350,000); Fiscal Year 2005: ¥158,470,000 (Direct Cost: ¥121,900,000、Indirect Cost: ¥36,570,000); Fiscal Year 2004: ¥179,790,000 (Direct Cost: ¥138,300,000、Indirect Cost: ¥41,490,000)
• Keywords: 遮熱コーティング / 拡散バリヤ / 高温酸化 / タービン / Ni基合金 / 拡散バリア / Ni基単結晶超合金 / クリープ / 熱酸化物層 / 二次反応層 / 超合金 / アルミナスケール / Re基合金 / バーナーリグ / Ni基超合金 / TCP相 / 溶融塩めっき / 拡散バリヤー / ガスタービン / 拡散バリヤボンドコート / レニウム基合金 / 耐酸化性 / 基材とコーティングの相互作用 / 状態図 / 相互拡散

Research Abstract

タービンの燃焼ガス温度上昇は省エネと炭酸ガス排出抑制の実効的手段である。本研究では、拡散バリヤ型ボンドコート(DBCシステム:基材/Re-Cr-W-Niバリヤ/Alリザバ/Al_2O_3/雰囲気)を提案し、システムの最適解を決定する手法を採用して、高効率GT,JEに適用できる長寿命・高信頼性ボンドコートを開発した。本DBCシステムはFe,Ni、Nb等の耐熱合金にも適用できることを示した。

Research Products

• [Journal Article] Formation of Ni Aluminide Containing Hf by Simultaneous Electro-deposition of Al and Hf and Cyclic-oxidation Resistance (2010)
  • Author(s): M.Fukumoto, T.Ono, T.Meguro, M.Hara, T.Narita
  • Journal Title: Materials Transactions 51,No.4 Pages: 720-726
  • NAID: 10026266835
• [Journal Article] Effect of the Electro-deposition Temperature on the Cyclic-Oxidation Resistance of Ni Aluminide Containing Zr Formed by Molten-Salt Electro-deposition (2009)
  • Author(s): M.Fukumoto, T.Suzuki, M.Hara, T.Narita
  • Journal Title: Materials Transactions 50 Pages: 335-340
  • NAID: 10024811868
  • Peer Reviewed
• [Journal Article] Effect of Re-W- Cr-Ni Diffusion Barrier on High-Temperature Oxidation of Pt- Modified β-NiAl Coated Superalloy (2008)
  • Author(s): T.Izumi, T.Yoshioka, T.Narita
  • Journal Title: J.Japan Inst.Metals 72,No.9 Pages: 728-732
  • NAID: 10024273272
• [Journal Article] Tie-Lined Compositions of the σ and (γ,γ',β) Phases in a Ni-Al-Re-Cr System at 1423K (2008)
  • Author(s): S.Saito, K.Kurokawa, T.Takashima, T.Narita
  • Journal Title: J.Japan Inst.Metals 72,No.9 Pages: 639-643
  • NAID: 10024273010
• [Journal Article] Experimental Determination of Isothermal Phase Diagram at 1423K in Ternary Re-Cr-Ni System (2008)
  • Author(s): S.Saito, K.Kurokawa, S.Hayashi, T.Takashima, T.Narita
  • Journal Title: J.Japan Inst.Metals 72 Pages: 132-137
  • NAID: 10021149740
  • Peer Reviewed
• [Journal Article] Formation of Pt-Modified γ'-Ni_3Al and Re-Based Alloy Coating System and Cyclic Oxidation Behavior of Coated Superalloy (2008)
  • Author(s): T.Narita, S.Ford, T.Yoshioka, T.Nishimoto, T.Izumi, S.Hayashi
  • Journal Title: Materials Science Forum 595-598 Pages: 135-141
  • Peer Reviewed
• [Journal Article] Re-Cr-Ni系における1423Kの等温状態図の実験的決定 (2008)
  • Author(s): 斉藤繁, 黒川一哉, 林重成, 高島敏行, 成田敏夫
  • Journal Title: 日本金属学会誌 72 Pages: 132137-132137
  • NAID: 10021149740
  • Peer Reviewed
• [Journal Article] Thermal Stability of a Rhenium-Based Diffusion Barrier Coating Layer on a Ni-based Superalloy (2007)
  • Author(s): Y.Wang, S.Ohnuki, S.Hayashi, T.Yoshioka, M.Hara, T.Narita
  • Journal Title: Materials Transactions 48,No.2 Pages: 127-132
  • NAID: 10018508476
• [Journal Article] Deformation behavior of ReCr Sigma Phase Diffusion Barrier on Ni-Based Superalloy (2007)
  • Author(s): S.Miura, K.Ohkubo, T.Mohri, T.Yoshioka, T.Narita
  • Journal Title: Mater.Res.Soc.Sympo.Proc. 980
• [Journal Article] TiAl合金の高温変形挙動に及ぼす耐酸化コーティングの影響 (2007)
  • Author(s): 西本工, 林重成, 成田敏夫
  • Journal Title: 日本金属学会誌 71 Pages: 25-33
  • NAID: 10018665581
  • Peer Reviewed
• [Journal Article] The Effect of an Applied External Tensile Stress on the oxidation behavior of a Nickel base Alloy with a Re-base Diffusion Barrier Coating (2007)
  • Author(s): M. Sakata, S. Hayashi, T. Nishimoto, T. Yoshioka, T. Narita
  • Journal Title: Oxi.Met. 68 Pages: 295311-295311
  • Peer Reviewed
• [Journal Article] Formation of Rhenium-base Diffusion-barrier-coating System on Ni-base Signle Crystal Superalloy and its Stability at 1423K (2007)
  • Author(s): D. Sumoyama, K. Z. Zaini, T. Nishimoto, S. Hayashi, T. Yoshioka, T. Izumi, T. Narita
  • Journal Title: Oxi.Met. 68 Pages: 313329-313329
  • Peer Reviewed
• [Journal Article] Formation and Oxidation behavior of a Diffusion Barrier Coating System on a Ni-Mo base alloy at 1373K in Air (2007)
  • Author(s): Y. katsumata, T. Yoshioka, K. Z. Thosin, S. Hayashi, T. Nishimoto, T. Izumi, T. Narita
  • Journal Title: Oxi.Met. 68 Pages: 331342-331342
  • Peer Reviewed
• [Journal Article] Thermal Stability of Rhenium-Based Diffusion barrier Coating layer on a Ni-Based Superalloy (2007)
  • Author(s): Y.Wang, S.Ohnuki, S.Hayashi, T.Yoshioka, M.Hara, T.Narita
  • Journal Title: Materials Transactions 48・2 Pages: 127-132
  • NAID: 10018508476
• [Journal Article] Deformation Behavior of ReCr-Sigma Diffusion barrier on Ni-Based Superalloy (2007)
  • Author(s): S.Miura, K.Ohkubo, T.Mohri, T.Yoshioka, T.Narita
  • Journal Title: Mater. Res. Soc. Symp. Proc. 980
• [Journal Article] Effect of Alloying Element on Microstructure of NiAl-X / Oxide Scale Interface (2006)
  • Author(s): S.Kawata, K.Kurokawa, A.Yamauchi, S.Watanabe, T.Narita
  • Journal Title: J.Japan High- Temperature Materials 32,No.2 Pages: 118-122
  • NAID: 10029253869
• [Journal Article] Formation of Ni aluminide Layer Containing La by Molten-Salt Electro deposition and Cyclic-oxidation Resistance (2006)
  • Author(s): M.Fukumoto, M.Hara, T.Narita
  • Journal Title: Materials Science Forum 522-523 Pages: 377-381
• [Journal Article] Influence of Pre-oxidation on the Corrosion and mechanical Strength of Fe-25Cr and Fe-25Cr-2ONi Alloys at 973K (2006)
  • Author(s): II Ryoung Sohn, T. Narita
  • Journal Title: Oxidation of Metals 65・3/4 Pages: 181-194
• [Journal Article] Hastelloy-Xの高温クリープ変形挙動に及ぼす拡散バリアコーティングの影響 (2006)
  • Author(s): 坂田幹宏, 林重成, 成田敏夫
  • Journal Title: 耐熱金属材料123委員会研究報告 47・1 Pages: 99-107
• [Journal Article] The Role of Bond Coat in Advanced Thermal Barrier Coating、 (2005)
  • Author(s): T.Narita, S.Hayashi, L.Fengqun, K.Z.Thosin
  • Journal Title: Materials Science Forum Vol.502 Pages: 99-104
• [Journal Article] Ni-Al系耐酸化コーティングを施したHastelloy Xの酸化挙動におよぼす拡散障壁層の効果、 (2005)
  • Author(s): 勝又雄一, 吉岡隆幸, Kemas Zaini Thosin, 林重成, 成田敏夫
  • Journal Title: 耐熱金属材料123委員会研究報告 Vol.46、No.2 Pages: 183-189
• [Journal Article] Changes of an Outer β-NiAl and Inner α-Cr Coating on Ni-40at%Cr Alloy during Oxidation at 1373K in Air (2005)
  • Author(s): D.Yoshida, Y.Shibata, S.Hayashi, T.Narita
  • Journal Title: Oxidation of Metals 64(1/2) Pages: 119-130
• [Journal Article] 溶融塩電析法によるLaを含むNiアルミナイド表面層の形成とその耐サイクル酸化性 (2005)
  • Author(s): 福本倫久, 原基, 成田敏夫
  • Journal Title: 日本金属学会誌 69巻8号 Pages: 695-698
  • NAID: 130004455616
• [Journal Article] Formation of Ni aluminides layer coatnining La by molten-salt electro-deposition and cyclic-oxidation resistance, (2005)
  • Author(s): M.Fukumoto, M.Hara, T.Narita
  • Journal Title: Proceedings of 5^<th> ICMC Vol. No.1 Pages: 282-286
• [Journal Article] Re-Cr-Ni系合金の平衡状態図 (2005)
  • Author(s): 斎藤繁, 高島敏行
  • Journal Title: 2005Symposium on materials and Systems for Energy Conversion Vol.1 No.1 Pages: 245-250
• [Journal Article] レーザー顕微鏡を用いた環境下高温3点曲げ変形挙動の観察の試み (2005)
  • Author(s): 三浦誠司, 岡和彦, 毛利哲雄, 成田敏夫
  • Journal Title: 実験力学 5 Pages: 203-208
• [Journal Article] Formation and oxidation behavior of Ni_2Al_3 coating on heat-resistant Ti-alloy (2005)
  • Author(s): Takeshi Izumi, Takumi Nishimoto, Toshio Narita
  • Journal Title: Intermetallics 13 Pages: 615-619
• [Journal Article] Oxidation Behavior of a Re-Base Diffusion-Barrier/β-NiAl Coating on Nb-5Mo-15W at High Temperatures (2004)
  • Author(s): Y.Matsumura, M.Fukumoto, S.Hayashi, A.Kasama, I.Iwanaga, R.Tanaka, T.Narita
  • Journal Title: Oxidation of Metals Vol.61 Nos.1/2 Pages: 105-124
• [Journal Article] Sulfidation behavior of Fe-40Al sheet in H_2-H_2S mixtures at high temperatures (2004)
  • Author(s): Fengqun Lang, Zhiming Yu, Shalva Gedevanishvili, SeetharamaC.Deevi, Shigenari Hayashi, Toshio Narita
  • Journal Title: Intermetallics 12 Pages: 469-475
• [Journal Article] Oxidation behavior of TiAl (Cr,Ag) at 900℃ in water vapor (2004)
  • Author(s): Zhenyu Liu, Toshio Narita
  • Journal Title: Intermetallics 12 Pages: 459-468
• [Journal Article] Improvement in Oxidation Resistance of Stainless Steel by Molten-Salt Electrodeposition of La (2004)
  • Author(s): Michihisa Fukumoto, Rie Yamashita, Motoi Hara
  • Journal Title: Oxidation of Metals Vol.62, No.5/6 Pages: 309-322
• [Journal Article] 電析法による金属Nb上へのNi-Al金属間化合物のコーティングとその耐酸化性 (2004)
  • Author(s): 福本倫久, 松井亮, 原基, 成田敏夫
  • Journal Title: 日本金属学会誌 Vol.68, No.8 Pages: 548-551
  • NAID: 10013466258
• [Journal Article] Yの溶融塩電析処理によるステンレス鋼の耐サイクル酸化性の改善 (2004)
  • Author(s): 福本倫久, 原基
  • Journal Title: 日本金属学会誌 Vol.68, No.2 Pages: 101-104
  • NAID: 10012647684
• [Journal Article] Effect of Al Electrodeposition Treatment Using Molten Salt on the High Temperature Oxidation of TiAl (2004)
  • Author(s): Michihisa Fukumoto, Motoi Hara, Toshiro Nagataki
  • Journal Title: Oxidation of Metals Vol.61, No.1/2 Pages: 1-16
• [Journal Article] 耐酸化コーティング 化学ポテンシャルと相互拡散の利用 (2000)
  • Author(s): 林重成, 成田敏夫
  • Journal Title: 材料と環境 55・11 Pages: 476-482
  • NAID: 10019371790
• [Presentation] Diffusion Coating of Hf and Al on Ni-base Alloys by Co-packing Process (2009)
  • Author(s): T.Narita
  • Organizer: ASEAN-INDIA Workshop and Annual Meeting on Surface Engineering II-2009
  • Place of Presentation: Bandung, Indonesia(Plenary Presentation)
  • Year and Date: 2009-12-01
• [Presentation] The Use of Diffusion Barrier Coating System to Extend the Life of β-phase and γ'+ γ Coatings Under Cyclic Oxidation (2009)
  • Author(s): T.Narita
  • Organizer: Golden Research Conference -High Temperature Corrosion-New London
  • Place of Presentation: NH, USA(Invited Presentation)
  • Year and Date: 2009-07-29
• [Presentation] The Use of Diffusion Barrier Coating System to Extend the Life of β-phase and γ'+γ Coatings Under Cyclic Oxidation (2009)
  • Author(s): T.Narita
  • Organizer: Golden Research Conference
  • Place of Presentation: New London, NH, USA Colby-Sawyer College
  • Year and Date: 2009-07-29
• [Presentation] Creep and Oxidation Behavior of Heat-Resistant Alloys with Diffusion Barrier Coating System (2009)
  • Author(s): T.Narita, T.Izumi, T.Yoshioka, S.Ford, S.Hayashi, T.Nishimoto
  • Organizer: The 12th International Conference on Fracture
  • Place of Presentation: Ottawa, Canada(Keynote Presentation)
  • Year and Date: 2009-07-15
• [Presentation] Creep and Oxidation Behavior of Heat-Resistant Alloys with Diffusion Barrier Coating System (2009)
  • Author(s): T.Narita, T.Izumi, T.Yoshioka, S.Ford, S.Hayashi, T.Nishimoto
  • Organizer: The 12^<th> International Conference on Fracture
  • Place of Presentation: Ottawa, Canada, The Westin Ottawa
  • Year and Date: 2009-07-15
• [Presentation] Strategic Research Collaboration in Materials for Energy (2009)
  • Author(s): T.Narita
  • Organizer: International Workshop on Advanced Materials for New and Renewable Energy
  • Place of Presentation: Jakarta, Indonesia(Plenary Presentation)
  • Year and Date: 2009-06-10
• [Presentation] Beneficial Effect of Ti on α-Al2O3 Formation of Coatings at 1173K (2009)
  • Author(s): T.Narita, T.Nishimoto, Y.Kitazima, S.Hayashi
  • Organizer: The 2nd Workshop on Thermal barrier Coating for Gas Turbines
  • Place of Presentation: Kyoto, Japan(Keynote Presentation)
  • Year and Date: 2009-05-27
• [Presentation] Beneficial Effect of Ti on α-Al_2O_3 Formation of Coatings at 1173K (2009)
  • Author(s): T.Narita, T.Nishimoto, Y.Kitajima, S.Hayashi
  • Organizer: The 2^<nd> Workshop on Thermal barrier Coating for Gas Turbines
  • Place of Presentation: Kyoto, Japan Ritsumeikan Univ.
  • Year and Date: 2009-05-27
• [Presentation] 耐熱合金の機械的特性と耐酸化性コーティングの両立をめざして (2007)
  • Author(s): 成田敏夫
  • Organizer: 耐熱金属材料第123委員会50周年記念フォーラム
  • Place of Presentation: 東京(東工大)
  • Year and Date: 2007-11-19
• [Patent(Industrial Property Rights)] 多層合金皮膜およびそれを有する耐熱性金属部材 (2006)
  • Inventor(s): 成田敏夫
  • Industrial Property Rights Holder: 北海道大学
  • Filing Date: 2006-11-16
• [Patent(Industrial Property Rights)] ALLOY COATING, METHOD FOR FORMING THE SAME< AND MEMBER FOR HIGH TEMPERATURE APPARATUSS (2001)
  • Inventor(s): Toshio Narita, Shigenari Hayashi, Hiroshi Yakuwa, Manabu Noguchi, Matsuho Miyasaka
  • Industrial Property Rights Holder: Toshio Narita, Ebara Corporation
  • Filing Date: 2001-03-06
  • Acquisition Date: 2004-12-14