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Light-Induced Hierarchical Morphology of Polymer Mixtures Confined in the Mesoscopic Length Scales.

Research Project

Project/Area Number 16072210
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyoto Institute of Technology

Principal Investigator

QUI Tran-Cong-Miyata  Kyoto Institute of Technology, Department of Macromolecular Science & Engineering Graduate School of Science & Technology, Professor (50188827)

Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥22,900,000 (Direct Cost: ¥22,900,000)
Fiscal Year 2006: ¥4,900,000 (Direct Cost: ¥4,900,000)
Fiscal Year 2005: ¥9,000,000 (Direct Cost: ¥9,000,000)
Fiscal Year 2004: ¥9,000,000 (Direct Cost: ¥9,000,000)
KeywordsMulticomponent Polymers / Photopolymerization and photocross-link / Phase seaparation / Laser-scanning confocal microscope / Reaction-induced elastic strain / Hierarchical structures / Spatially graded morphology / Mach-Zehnder Interferometry / Reversible phase separation / 可逆相分離 / 相互侵入高分子網目(IPNs) / 反応誘起相分離 / 光架橋反応 / 共連続構造 / 傾斜構造 / ヘキサゴナル相 / コンピュータ支援光照射法 / 高分子相互侵入IPNs / 共連続傾斜構造 / ポリスチレン / 光架橋重合 / 自己触媒反応 / Computer-Assisted Irradiation(CAI)法 / ポリマーブレンド / アントラセンの光二量化 / メゾスケール / スピノーダル分解過程 / 階層構造ダイナミクス
Research Abstract

In this study, light-induced phase separation phenomena were studied by using photochemical reactions to drive a polymer mixture from the one-phase into the unstable region on the phase diagram. The competition between the phase separation and the reaction was investigated by using laser scanning confocal microscope. The following results were obtained.:
1) Measurements of elastic deformation in photo-reactive multicomponent polymers by using Mach-Zehnder Interferometry.
2) Developments of Computer-Assisted Irradiation (CAI) method for designing polymers with an arbitrary distribution of characteristic length scales in the micrometers range.
3) Designing multiphase polymer materials with hierarchical morphology by using irradiation with a time delay.
4) Synthesis of interpenetrating polymer networks (IPNs) with spatially graded morphology and an arbitrary distribution of characteristic length scales.
With the above-mentioned results, we are able to conclude that multiphase polymer materials with a variety of morphologies can be controlled and designed by using photochemical reactions

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (47 results)

All 2007 2006 2005 2004 Other

All Journal Article (25 results) (of which Peer Reviewed: 3 results) Presentation (14 results) Book (5 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Phase Separation of Binary Polymer Mixtures Under an Electric Field2007

    • Author(s)
      H.Hori, O.Urakawa, O.Yano, Q.Tran-Cong-Miyata
    • Journal Title

      Macromolecules 40

      Pages: 389-394

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 光で制限したミクロン域における光IPNの相分離キネティクスとモルフォロジー制御2007

    • Author(s)
      増永 淳史, 宮田 貴章, 他3名
    • Journal Title

      高分子論文集 (印刷中)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Interpenetrating Polymer Networks with Spatially Graded Morphology Controllable by UV-Radiation Curin2006

    • Author(s)
      H. Nakanishi, et al.
    • Journal Title

      Macromol. Symposia. 242

      Pages: 157-164

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Phase Separation of Interpenetrating Polymer Networks Synthesized by Using an Autocatalytic Reaction2006

    • Author(s)
      H. Nakanishi, et al
    • Journal Title

      Macromolecules 39

      Pages: 9456-9466

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Designing a Polymer Blend with Phase Separation Tunable by Visible Light for Computer-Assisted Irradiation Experiments"2006

    • Author(s)
      S. Ishino, et al
    • Journal Title

      Macromolecular Rapid Communication 27

      Pages: 758-762

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Interpenetrating Polymer Networks with Spatially Graded Morphology Controllable by UV-Radiation Curing2006

    • Author(s)
      H. Nakanishi, N. Namikawa, T. Norisuye, ^*Q. Tran-Cong-Miyata
    • Journal Title

      Macromol. Symposia 242

      Pages: 157-164

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Phase Separation of Interpenetrating Polymer Networks Synthesized by Using an Autocatalytic Reaction2006

    • Author(s)
      H. Nakanishi, M. Satoh, T. Norisuye, ^*Q. Tran-Cong-Miyata
    • Journal Title

      Macromolecules 39

      Pages: 9456-9466

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Designing a Polymer Blend with Phase Separation Tunable by Visible Light for Computer-Assisted Irradiation Experiments2006

    • Author(s)
      S. Ishino, H. Nakanishi, T. Norisuye, ^*Q. Tran-Cong-Miyata
    • Journal Title

      Macromolecular Rapid Communication 27

      Pages: 758-762

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Autocatalytic Phase Separation and Graded Co-Continuous Morphology Generated by Photocuring2006

    • Author(s)
      H. Nakanishi, N. Namikawa, T. Norisuye, ^*Q. Tran-Cong-Miyata
    • Journal Title

      Soft Matter 2

      Pages: 149-156

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Interpenetrating Polymer Networks with Spatially Graded Morphology Controllable by UV-Radiation Curing2006

    • Author(s)
      H.Nakanishi, Q.Tran-Cong-Miyata et al.
    • Journal Title

      Macromolecular Symposia 242

      Pages: 157-164

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Phase Separation of Interpenetrating Polymer Networks Synthesized by Using an Autocatalytic Reaction2006

    • Author(s)
      H.Nakanishi, Q.Tran-Cong-Miyata et al.
    • Journal Title

      Macromolecules 39・26

      Pages: 9456-9466

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Designing a polymer blend with phase separation tunable by visible light for computer-assisted irradiation experiments2006

    • Author(s)
      S.Ishino, Q.Tran-Cong et al.
    • Journal Title

      Macromolecular Rapid Communication 27

      Pages: 758-762

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Autocatalytic Phase Separation and Graded Co-continuous Morphology Generated by Photo-Curing2006

    • Author(s)
      H.Nakanishi, Q.Tran-Cong-Miyata
    • Journal Title

      Soft Matter 2

      Pages: 149-156

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Designing a Polymer Blend with Phase Separation Tunable by Visible Light for Computer-Assisted Irradiation Experiments,2006

    • Author(s)
      S.Ishino, H.Nakanishi, T.Norisuye, Y.Awatsuji, Q.Tran-Cong-Miyata
    • Journal Title

      Macromolecular Rapid Communications 27(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Autocatalytic phase separation and graded co-continuous morphology generated by photocuring2006

    • Author(s)
      H.Nakanishi, N.Namikawa, T.Norisuye, Q Tran-Cong-Miyata
    • Journal Title

      Soft Matter 2

      Pages: 149-156

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Local Deformation in Photo-Crosslinked Polymer Blends Monitored by Mach-Zehnder Interferometry,2006

    • Author(s)
      K.Inoue, S.Komatsu, X.-A.Trinh, T.Norisuye, Q.Tran-Cong-Miyata
    • Journal Title

      J.Polym.Sci.Polym.Phys.Ed. 43

      Pages: 2898-2913

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Observation and Analysis of 3-Dimensional Gradient Morphology Generated by Photochemical Reaction in IPNs,2005

    • Author(s)
      H.Nakanishi, N.Namikawa, T.Norisuye, Q.Tran-Cong-Miyata
    • Journal Title

      高分子論文集 62・10

      Pages: 519-522

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Controlling the Morphology of Polymer Blends Using Periodic Irradiation2004

    • Author(s)
      ^*Q. Tran-Cong-Miyata, S. Nishigami, T. Ito, S. Komatsu, T. Norisuye
    • Journal Title

      Nature Materials 3

      Pages: 448-451

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Generation and Manipulation of Hierarchical Morphology in Interpenetrating Polymer Networks by Using Photochemical Reactions2004

    • Author(s)
      H. Nakanishi, M. Satoh, T. Norisuye, ^*Q. Tran-Cong-Miyata
    • Journal Title

      Macromolecules 37

      Pages: 8495-8498

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Dynamic Inhomogeneities in Polymer Gels Investigated by Dynamic Light Scattering2004

    • Author(s)
      ^*T. Norisuye, Q. Tran-Cong-Miyata, M. Shibayama
    • Journal Title

      Macromolecules 37

      Pages: 2944-2953

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Dynamic Inhomogeneities in Polymer Gels Investigated by Dynamic Light Scattering2004

    • Author(s)
      T.Norisuye, Q.Tran-Cong-Miyata, M.Shibayama
    • Journal Title

      Macromolecules 36

      Pages: 2944-2953

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Controlling the Morphology of Polymer Blends Using Periodic Irradiation2004

    • Author(s)
      Q.Tran-Cong-Miyata, S.Nishigami, T.Ito, S.Komatsu, T.Norisuye
    • Journal Title

      Nature Materials 3

      Pages: 448-451

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Generation and Manipulation of Hierarchical Morphology in Interpenetrating Polymer Networks by Using Photochemical Reactions2004

    • Author(s)
      H.Nakanishi, M.Satoh, T.Norisuye, Q.Tran-Cong-Miyata
    • Journal Title

      Macromolecules 37

      Pages: 8495-8498

    • Related Report
      2004 Annual Research Report
  • [Journal Article] k-Carrageenan from Kappaphycus Alvarezii : Isolation and Characterization2004

    • Author(s)
      T.T.Thanh-Thi, T.V.Tran-Thi, Q.Tran-Cong, H.Urakawa
    • Journal Title

      Journal of Chemistry (VietNam) 42

      Pages: 379-383

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Local Deformation in Photo-Crosslinked Polymer Blends Monitored by Mach-Zehnder Interferometry

    • Author(s)
      K. Inoue, S. Komatsu, X. -A. Trinh, T. Norisuye, ^*Q. Tran-Cong-Miyata
    • Journal Title

      K. Inoue, S. Komatsu, X. -A. Trinh, T. Norisuye, ^*Q. Tran-Cong-Miyata "Local Deformation in Photo-Crosslinked Polymer Blends Monitored by Mach-Zehnder Interferometry"

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Manipulation and Control of Polymer Blend Morphology by Using Photochemical Reactions2006

    • Author(s)
      Q. Tran-Cong-Miyata
    • Organizer
      The First International Symposium on Polymer Materials Science
    • Place of Presentation
      Kyoto, Japan
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Reaction-Induced Hierarchical Structures in Multiphase Polymer Materials2006

    • Author(s)
      Q. Tran-Cong-Miyata
    • Organizer
      The 4th International Symposium on Engineering of Chemical Complexity, Max-Planck Fritz-Haber Institute
    • Place of Presentation
      Berlin, German
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Architecturing of Hierarchical Structure in Reacting Soft Matter by Using Photochemical Reactions with Time Delay2005

    • Author(s)
      H. Nakanishi, M. Satoh, T. Norisuye, Q. Tran-Cong-Miyata
    • Organizer
      International Symposium on Physics of Non-Equilibrium Systems : Development of Non-Equilibrium Physics in Material and Biological Sciences
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2005-08-02
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Phase Separation in Reacting Soft Matter (I) : Formation of Co-continuous Structures with Spatial Gradients2005

    • Author(s)
      N. Namikawa, H. Nakanishi, T. Norisuye, Q. Tran-Cong-Miyata
    • Organizer
      Yukawa Institute for Theoretical Physics (YITP) Soft Matter Workshop
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2005-08-02
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Phase Separation in Reacting Soft Matter (II) : Ordering by Long-Range Interaction2005

    • Author(s)
      M. Satoh, H. Nakanishi, T. Norisuye, Q. Tran-Cong-Miyata
    • Organizer
      Yukawa Institute for Theoretical Physics (YITP) Soft Matter Workshop
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2005-08-02
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Morphological Architecturing of Interpenetrating Polymer Networks by UV Irradiation with Time Delay2005

    • Author(s)
      Hideyuki Nakanishi, Masahiro Satoh, Tomohisa Norisuye, Qui Tran-Cong-Miyata
    • Organizer
      International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2005)
    • Place of Presentation
      Hawaii, USA
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] "Hierarchy and Regularity in Morphology of Polymer Blends Controlled by Photochemical Reactions : Emergence and Mechanism" (Invited)2005

    • Author(s)
      Qui Tran-Cong-Miyata
    • Organizer
      International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2005)
    • Place of Presentation
      Hawaii, USA
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Mode-Selection in Phase Separation of Polymer Mixtures Driven by a Cross-Link Reaction with Controlled Reversibility2005

    • Author(s)
      Qui Tran-Cong-Miyata
    • Organizer
      International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2005)
    • Place of Presentation
      Hawaii, USA
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] "Pattern-Selection Driven by Chemical Reactions in Polymer Mixtures Undergoing Phase Separation Far-From-Equilibrium" (Invited)2005

    • Author(s)
      Qui Tran-Cong-Miyata
    • Organizer
      International Symposium on Molecular Nanotechnology
    • Place of Presentation
      Nara, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Recent Developments in Light-Driven Phase Separation of Multicomponent Polymers2005

    • Author(s)
      Qui Tran-Cong-Miyata
    • Organizer
      International Symposium on Forefront of Nonlinear Science and Its Application to Materials Science in the 21st Century (MATNON'05)
    • Place of Presentation
      Kyoto, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] "Morphological Regularity and Hierarchy Driven by Competing Interactions in Reacting Polymer Mixtures" (Invited)2005

    • Author(s)
      Q. Tran-Cong-Miyata
    • Organizer
      International Symposium on Self-Organization-Initiative Nano-Engineering (SINE)
    • Place of Presentation
      Saitama, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] "Designing Polymer Morphology by Spatial and Temporal Forcing" (Invited)2004

    • Author(s)
      Q. Tran-Cong-Miyata
    • Organizer
      Gordon Research Conference on "Oscillations & Dynamic Instabilities in Chemical Systems
    • Place of Presentation
      Maine, USA
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Temporally Periodic Forcing of Phase Separation in Polymer Blends (Invited)2004

    • Author(s)
      Q. Tran-Cong-Miyata
    • Organizer
      International Symposium on Polymer Physics
    • Place of Presentation
      Dali, China
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Light-Induced Interpenetrating Polymer Networks : Kinetics and Morphology2004

    • Author(s)
      H. Nakanishi, M. Satoh, T. Norisuye, Q. Tran-Cong-Miyata
    • Organizer
      International Symposium on Polymer Physics
    • Place of Presentation
      Dali, China
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] 自己組織化ナノマテリアル(分担執筆)2007

    • Author(s)
      中西 英行, 宮田 貴章
    • Total Pages
      392
    • Publisher
      フロンティア出版
    • Related Report
      2006 Annual Research Report
  • [Book] 「自己組織化ナノマテリアル」、 下村政嗣、山口智彦 編集2006

    • Author(s)
      中西英行,宮田貴章(第7章,分担執筆)
    • Publisher
      フロンティア出版社
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] 自己組織化ナノマテリアル〜フロントランナー60名に聞くナノテクノロジーの新潮流(下村政嗣, 山口智彦 監修)2006

    • Author(s)
      宮田貴章, 中西英行
    • Total Pages
      320
    • Publisher
      フロンティア出版社(近刊)
    • Related Report
      2005 Annual Research Report
  • [Book] Self-Organized Morphology in Nanostructured Materials' (K.Al-Shamery, S.C.Mueller, J.Parisi Eds.)2005

    • Author(s)
      Q.Tran-Cong-Miyata, H.Nakanishi
    • Publisher
      Springer Verlag, Germany(印刷中)
    • Related Report
      2004 Annual Research Report
  • [Book] Nonlinear Dynamics in Polymeric Systems (Totally 27 Chapters)2004

    • Author(s)
      John A.Pojman, Q.Tran-Cong-Miyata Eds.
    • Publisher
      American Chemical Society, Symposium Series
    • Related Report
      2004 Annual Research Report
  • [Remarks] 「研究成果報告書概要(和文)」より

    • URL

      http://www.cis.kit.ac.jp/~matnon/IJS-PMS_1st/index.html

    • Related Report
      2006 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 「深さ方向の傾斜構造を有する共連続構造体および光照射を用いた共連続構造体の生産方法」2006

    • Inventor(s)
      宮田貴章, 中西英行, 並河信寛
    • Industrial Property Rights Holder
      京都工芸繊維大学
    • Industrial Property Number
      2006-013172
    • Filing Date
      2006
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 深さ方向の傾斜構造を有する共連続構造体および光照射を用いた共連続構造体の生産方法2005

    • Inventor(s)
      宮田 貴重, 中西 英行, 並河 信寛
    • Industrial Property Rights Holder
      京都工芸繊維大学
    • Industrial Property Number
      2005-144417
    • Filing Date
      2005-05-17
    • Related Report
      2005 Annual Research Report

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Published: 2004-04-01   Modified: 2022-01-20  

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