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Time-resolved X-ray diffractometry of organic crystals by using synchrotron radiation

Research Project

Project/Area Number 16072218
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionThe Institute of Physical and Chemical Research

Principal Investigator

TANAKA Yoshihito  The Institute of Physical and Chemical Research, Coherent X-ray Optics Lab., Senior Research Scientist (80260222)

Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥26,300,000 (Direct Cost: ¥26,300,000)
Fiscal Year 2006: ¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 2005: ¥12,600,000 (Direct Cost: ¥12,600,000)
Fiscal Year 2004: ¥10,400,000 (Direct Cost: ¥10,400,000)
KeywordsTime-resolved X・ray diffraction / Organic crystal / Synchrotron radiation / Photochromic crystal / Lattice dynamics / 構造ダイナミクス
Research Abstract

We have developed fast time-resolved X-ray diffraction system at the SPring-8 synchrotron radiation facility. The lattice response of a photochromic single crystal induced by pulsed laser irradiation has been investigated using the time-resolved measurement system. The details of the obtained results on the demonstration of picosecond time-resolved diffractometry for semiconductor crystals (1) and the observation of lattice response of a diarhylethene single crystal (2) are described below.
(1). Time-resolved X-ray diffraction measurement system with multi-channel scaling (MCS) and pump-probe method using the pulsed time-structure of synchrotron radiation has been developed. Triple crystal X-ray diffractometry (TCD) has been applied to the time-resolved measurement system to determine the lattice response along a specific axis in distinction from the other components of deformation. In the time-resolved TCD, a monochromatic X-ray beam is diffracted by a crystal sample, and the angle of … More the diffracted beam is analyzed using the additional single crystal before detection. We have demonstrated the time-resolved TCD to detect acoustic pulses and the echoes as dynamical lattice strain at semiconductor crystals of silicon and gallium arsenide.
(2). A photochromic crystal of diarhylethene turns blue by UV light irradiation, and is recovered to be original colorless crystal by visible light illumination. The time-evolution of the diffraction intensity has successfully been measured with the MCS by changing the color with alternate irradiation by the lasers of 400 nm and 633 nm. The results showed that the crystal expands during irradiation, and that the shear strain or local rotation as well as dilational change is kept after cooled-down at the interval of irradiations. In combination with space-resolved X-ray diffraction measurement method using an X-ray slit of 50 μm-width, local strain with a response time of a few μs has been observed around the surface on the illumination side. Less

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (36 results)

All 2007 2006 2005 2004

All Journal Article (31 results) (of which Peer Reviewed: 9 results) Presentation (2 results) Book (3 results)

  • [Journal Article] Time-resolved x-ray triple-crystal diffractometry probing dynamical strain in semic onductors2007

    • Author(s)
      Y. Hayashi, et al.
    • Journal Title

      AIP conference proceeding 879

      Pages: 1258-1261

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Detection of covalent-bonded dimer in photochemically induced crystallization of protein2007

    • Author(s)
      K. Furuta, et al.
    • Journal Title

      Chemistry Letters 36

      Pages: 714-715

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Time-resolved x-ray triple-crystal diffractometry probing dynamical strain in semiconductors2007

    • Author(s)
      Y. Hayashi, et al.
    • Journal Title

      AIP conference proceedings 879

      Pages: 1258-1261

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Time-resolved x-ray triple-crystal diffractometry probing dynamical strain in semiconductors2007

    • Author(s)
      Y.Hayashi et al.
    • Journal Title

      AIP Conference proceedings 879

      Pages: 1258-1261

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Acoustic pulse echoes probed with time-resolved x-ray triple-crystal diffractometry2006

    • Author(s)
      Y. Hayashi, et al.
    • Journal Title

      Physical Review Letters 96

      Pages: 115505-115505

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Photo-stimulated desorption from chlorinated Si(l ll) surface : Etching of SiCl by picosecond pulsed laser irradiation2006

    • Author(s)
      T. Kirimura, et al.
    • Journal Title

      Physical Review B 73

      Pages: 85309-85309

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] X線領域における超高速時間分解測定法の開発2006

    • Author(s)
      田中義人, 他
    • Journal Title

      レーザー研究 34・8

      Pages: 560-565

    • NAID

      10018207860

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Photo-stimulated desorption from chlorinated Si(111) surface : Etching of SiCl by picosecond pulsed laser irradiation2006

    • Author(s)
      T. Kirimura, et al.
    • Journal Title

      Physical Review B 73

      Pages: 85309-85309

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Development of ultrafast time-resolved techniques in the x-ray regime2006

    • Author(s)
      Y. Tanaka, et al.
    • Journal Title

      The Review of Laser Engineering 34(8)

      Pages: 560-565

    • NAID

      10018207860

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Acoustic pulse echoes probed with time-resolved x-ray triple-crystal diffractometry2006

    • Author(s)
      Y.Hayashi et al.
    • Journal Title

      Physical Review Letters 96

      Pages: 115505-115505

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Photo-stimulated desorption from chlorinated Si(111) surface : Etching of SiCl by picosecond pulsed laser irradiation2006

    • Author(s)
      T.Kirimura et al.
    • Journal Title

      Physical Review B 73

      Pages: 85309-85309

    • Related Report
      2006 Annual Research Report
  • [Journal Article] X線領域における超高速時間分解測定法の開発2006

    • Author(s)
      田中 義人 他
    • Journal Title

      レーザー研究 34・8

      Pages: 560-565

    • NAID

      10018207860

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Photo-stimulated desorption from chlorinated Si(III)surface : Etching of SiCl by picosecond pulsed laser irradiation2006

    • Author(s)
      T.Kirimura
    • Journal Title

      Physical Review B 73

      Pages: 85309-85309

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Acoustic pulse echoes probed with time-resolved x-ray triple-crystal diffractometry2006

    • Author(s)
      Y.Hayashi
    • Journal Title

      Physical Review Letters (in press)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Determination of dynamic deformation tensor by time-resolved triple crystal diffractometry2005

    • Author(s)
      Y. Hayashi, et al.
    • Journal Title

      Journal of Synchrotron Radiation 12

      Pages: 685-689

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Picosecond lattice dynamics probed by time- and angle-resolved X-ray diffraction2005

    • Author(s)
      Y. Tanaka, et al.
    • Journal Title

      Acta Crystallography A61

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Determination of dynamic deformation tensor by time-resolved triple crystal diffractometry2005

    • Author(s)
      Y.Hayashi
    • Journal Title

      Journal of Synchrotron Radiation 12

      Pages: 685-689

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Picosecond lattice dynamics probed by time-and angle-resolved X-ray diffraction2005

    • Author(s)
      Y.Tanaka
    • Journal Title

      Acta Crystallography A61

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Roles of X-ray Optics in the next generation X-ray source2005

    • Author(s)
      Y.Yabashi
    • Journal Title

      Acta Crystallography. A61

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Surface modification of Cl-adsorbed Si(lll)-7x7 by the irradiation of infrared pulsed laser2004

    • Author(s)
      T. Kirimura, et al.
    • Journal Title

      Surface Science 566-568

      Pages: 1137-1142

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Nano-Cluster Formation in Halogen Etching on Cl/Si(lll)-7x72004

    • Author(s)
      K. Shudo, et al.
    • Journal Title

      Surface Science 566-568

      Pages: 425-429

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Subnanosecond-resolved X-ray diffraction at the SPring-8 high flux beamline BL40XU2004

    • Author(s)
      S. Adachi, et al.
    • Journal Title

      AIP conference proceedings 705

      Pages: 1383-1386

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Time-to-space converter for ultrashort pulsed x-ray experiments2004

    • Author(s)
      Y. Tanaka, et al.
    • Journal Title

      AIP conference proceeding 705

      Pages: 1379-1382

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Surface modification of Cl-adsorbed Si(111)-7x7 by the irradiation of infrared pulsed laser2004

    • Author(s)
      T. Kirimura, et al.
    • Journal Title

      Surface Science 566-568

      Pages: 1137-1142

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Nano-Cluster Formation in Halogen Etching on Cl/Si(111)-7x72004

    • Author(s)
      K. Shudo, et al.
    • Journal Title

      Surface Science 566-568

      Pages: 425-429

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Subnanosecond-resolved X-ray diffraction at ng-8 high flux beamline BL40XU2004

    • Author(s)
      S. Adachi, et al.
    • Journal Title

      AIP conference proceedings the Spri 705

      Pages: 1383-1386

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Time-to-space converter for ultrashort pulsed x-ray experiments2004

    • Author(s)
      Y. Tanaka, et al.
    • Journal Title

      AIP conference proceedings 705

      Pages: 1379-1382

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Time-to-space converter for ultrashort pulsed x-ray experiments2004

    • Author(s)
      Y.Tanaka et al.
    • Journal Title

      AIP conference proceedings 705

      Pages: 1379-1382

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Subnanosecond-resolved X-ray diffraction at the SPring-8 high flux beamline BL40XU2004

    • Author(s)
      S.Adachi et al.
    • Journal Title

      AIP conference proceedings 705

      Pages: 1383-1386

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Surface modification of Cl-adsorbed Si(111)-7x7 by the irradiation pulsed laser2004

    • Author(s)
      T.Kirimura et al.
    • Journal Title

      Surface Science 566-568

      Pages: 1137-1142

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Nano-Cluster Formation in Halogen Etching on Cl/Si(111)-7x72004

    • Author(s)
      K.Shudo et al.
    • Journal Title

      Surface Science 566-568

      Pages: 425-429

    • Related Report
      2004 Annual Research Report
  • [Presentation] 時間分解X線回折法によるフォトクロミック有機結晶の格子ダイナミクスの研究2007

    • Author(s)
      田中義人, 他
    • Organizer
      第20回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      広島国際会議場, 広島市
    • Year and Date
      2007-01-13
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Time-resolved X-ray diffraction studies on lattice dynamics of organic crystals with photochromism.2007

    • Author(s)
      Y. Tanaka, et al.
    • Organizer
      Annual meeting of the Japanese Society for Synchrotron Radiation Research
    • Place of Presentation
      International Conference Center Hiroshima, Hiroshima.
    • Year and Date
      2007-01-13
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] Femtosecond Beam Science (M. Uesaka ed. )2006

    • Author(s)
      Y. Tanaka, et al.
    • Total Pages
      17
    • Publisher
      Imperial College Press/ World Scientific Pub Co Inc
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] Imperial College Press/ World Scientific Pub Co Inc2006

    • Author(s)
      Y. Tanaka, et al.
    • Total Pages
      17
    • Publisher
      Femtosecond Beam Science (M. Uesaka ed.)
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] Femtosecond Beam Science(M.Uesaka ed.)2006

    • Author(s)
      Y.Tanaka(M.Uesaka ed.)
    • Total Pages
      17
    • Publisher
      Imperial College Press/World Scientific Pub Co Inc
    • Related Report
      2005 Annual Research Report

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Published: 2004-04-01   Modified: 2018-03-28  

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