• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Syntheses of Innovative Porous Metal Complexes and Their Functional Chemistry

Research Project

Project/Area Number 16074209
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyoto University

Principal Investigator

KITAGAWA Susumu  Kyoto University, Institute for Integrated Cell-Material Sciences, Deputy Director (20140303)

Co-Investigator(Kenkyū-buntansha) OHBA Masaaki  Kyoto University, Graduate school of Engineering, Associate Professor (00284480)
CHANG Ho-Chol  Kyoto University, Graduate school of Engineering, Assistant Professor (60335198)
UEMURA Takashi  Kyoto University, Graduate School of Engineering, Assistant Professor (50346079)
INAGAKI Shinji  Kyoto University, Toyota Central R&D Labs., Inc., Group Leader (30374086)
Project Period (FY) 2004 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥127,000,000 (Direct Cost: ¥127,000,000)
Fiscal Year 2007: ¥22,200,000 (Direct Cost: ¥22,200,000)
Fiscal Year 2006: ¥22,200,000 (Direct Cost: ¥22,200,000)
Fiscal Year 2005: ¥75,500,000 (Direct Cost: ¥75,500,000)
Fiscal Year 2004: ¥7,100,000 (Direct Cost: ¥7,100,000)
KeywordsPorous metal complexes / multi-functions / polymer synthesis / mesoporous silica / ナノ空間 / 金属錯体 / ガス吸着 / 反応場 / 物性 / 多孔性多孔性配位高分子 / 分子配列 / 磁性誘電癒合 / 触媒能 / 入子構造 / 直接観測 / 動的骨格 / アセチレン / 分離 / 吸着 / 水素吸蔵
Research Abstract

In this project, we aim to develop functions with the characteristics of porous coordination polymers (PCPs)such as designable surface functionality, high regularity, and framework flexibility Highly controlled acetylene accommodation in a microporous coordination polymer has been accomplished by preparing a pore surface specific for acetylenic hydrogen atoms. The acetylene can be packed 200 times as densely as the limitation value without explosion. The adsorbed acetylene molecules are highly stabilized by the double hydrogen bonded supports in nanosized pores, which mere revealed by direct observation of the adsorbed molecules using the results of in-situ synchrotron XRD measurements and by first principles calculations.
We have designed and synthesized a bimodal microporous twofold interpenetrating PCP with two types of channel for anionic N(CN)2- and neutral water molecules, respectively. The dehydrated framework provides a dual function of specific anion exchange of free N(CN)2- for the smaller N3- anions and selective gas sorption. The N3--exchanged framework leads to a dislocation of the mutual positions of the two interpenetrating frameworks, resulting in an increase in the effective pore size in one of the counterparts of the channels and a higher accommodation of adsorbate than in the as-synthesized framework.
A few substituted acetylenes spontaneously polymerized in one-dimensional nanochannels of PCPs with pillared layer structure. In this polymerization system, only mono-substituted acetylenes with electron-withdrawing group could be polymerized in the channels. suggesting that strong hydrogen bonding interaction between the monomers and surface carboxylate moiety in the frameworks is a key factor to initiate the polymerization.

Report

(5 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (44 results)

All 2008 2007 2006 2005 2004

All Journal Article (39 results) (of which Peer Reviewed: 19 results) Presentation (2 results) Book (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Radical Polymerization of Vinyl Monomers in Porous Coordination Polymers: Nanochannel Size Effects on Reactivity, Molecular Weight, and Stereostructure2008

    • Author(s)
      Takashi Uemura, Yukari Ono, Kana Kitagawa, Susumu Kitagawa
    • Journal Title

      Macromolecules 41

      Pages: 87-94

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coordination Pillared-layer Type Compounds Having Pore Surface Functionalization by Anionic Sulfonate Groups2008

    • Author(s)
      Satoshi Horike, Sareeya Bureekaew and Susumu Kitagawa
    • Journal Title

      Chem. Commun.

      Pages: 471-473

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Isomerism, Framework Flexibility, Unsaturated Metal Center, and Porous Property of Ag(I)/Cu(I)3,3',5,5'-Tetramted Metal Center, and Porous Property of Ag(I)/Cu(I)3,3',5,5'-Tetrametyl-4,4'-Bipyrazolates2008

    • Author(s)
      Jie-Peng Zhang and Susumu Kitagawa
    • Journal Title

      J.Am. Chem. Soc. 130

      Pages: 907-917

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interpenetrated Three-Dimensional Mn^II M^III Ferrimagnets, [Mn(4dmap)_4]_3[M(CN)_6]_2・10H_2O(M = Cr, Mn):structures, Magnetic Modulation2008

    • Author(s)
      Wakako Kaneko, Masaki Mito, Susumu Kitagawa, Masaaki Ohba
    • Journal Title

      Chem.-Eur. J. 14

      Pages: 3481-3489

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Guest-Specific Function of a Flexible Undulating Channel in a 7, 7, 8, 8-Tetracyano-p-quinodimethane Dimer-Based Porous Coordination Polymer2007

    • Author(s)
      S. Shimomura, S. Horike, R. Matsuda, S. Kitagawa
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 10990-10991

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Topotactic Linear Radical Polymerization of Divinylbenzenes in Porous Coordination Polymers2007

    • Author(s)
      T. Uemura, D. Hiramatsu, Y. Kubota, M. Takata, S. Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 4987-4990

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Topotactic Linear Radical Polymerization of Divinylbenzenes in Porous Coordination Polymers2007

    • Author(s)
      T. Uemura, D. Hiramatsu, Y. Kubota, M. Takata, S. Kltagawa
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 4987-4990

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Reversible Water-lnduced Magnetic and Structural Conversion of a Flexible Microporous Ni(II)Fe(III)Ferromagnet2007

    • Author(s)
      Nobuhiro Yanai, Wakako Kaneko, Ko Yoneda, Masaaki Ohba, Susumu Kitagawa
    • Journal Title

      J.Am. Chem.Soc. 129

      Pages: 3396-3397

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Topotactic Linear Radical Polymerization of Divinylbenzenes in Porous Coordination Polymers2007

    • Author(s)
      Takashi Uemura, Daisuke Hiramatsu, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 4987-4990

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Series of Trinuclear Ni(II)Ln(III)Ni(II)Complexes Derived from 2,6-Di(acetoacetyl)pyridine: Synthesis, Structure, and Magnetism2007

    • Author(s)
      Takuya Shiga, Nobuhiro Ito, Akiko Hidaka, Hisashi Ohkawa, Susumu Kitagawa, and Masaaki Ohba
    • Journal Title

      lnorg. Chem. 46

      Pages: 3492-3501

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anthracene array-type porous coordination polymer with host-guest charge transfer interactions in excited states2007

    • Author(s)
      Daisuke Tanaka, Satoshi Horike, Susumu Kitagawa, Masaaki Ohba, Miki Hasegawa, Yoshiki Ozawa and Koshiro Toriumi
    • Journal Title

      Chem. Commun.

      Pages: 3142-3144

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Guest-Specific Function of a Flexible Undulating Channel in a 7,7,8,8-Tetracyano-p-quinodimethane Dimer-Based Porous Coordination Polymer2007

    • Author(s)
      Satoru Shimomura, Satoshi Horrike, Ryotaro Matsuda, and Susumu Kitagawa
    • Journal Title

      J.Am. Chem. Soc. 129

      Pages: 10990-10991

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Three-dimensional Ferromagnetic Frameworks of Syn-Anti-type Carboxylate-bridged Nilland Coll Coordination Polymers2007

    • Author(s)
      Ko Yoneda, Masaaki Ohba, Takuya Shiga, Hiroki Oshio, and Susumu Kitagawa
    • Journal Title

      Chem. Lett. 36

      Pages: 1184-1185

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Flexible Coordination Polymer Crystal Providing Reversible Structural and Magnetic Conversions2007

    • Author(s)
      Wakako Kaneko, Masaaki Ohba, Susumu Kitagawa
    • Journal Title

      J.Am. Chem. Soc. 129

      Pages: 13706-13712

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Topochemical Transformation of Soft Crystal of a Coordination Polymer2007

    • Author(s)
      Sujit K. Ghosh, Jie-Peng Zhang, Susumu Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 7965-7968

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemistry and application of porous coordination polymers2007

    • Author(s)
      Satoru Shimomuraa, Satoshi Horikea and Susumu Kitagawa
    • Journal Title

      Stud. Surf. Sci. Catal. 170

      Pages: 1983-1990

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemistry of coordination space of porous coordination polymers2007

    • Author(s)
      Susumu Kitagawa and Ryotaro Matsuda
    • Journal Title

      rd. Chem. Rev. 251

      Pages: 2490-2509

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of gas molecules adsorbed in the nanochannels of porous coordination polymers by the in situ synchrotron powder diffraction experiment and the MEM/Rietveld charge density analysis2007

    • Author(s)
      Yoshiki Kubota, Masaki Takata, Tatsuo C. Kobayashi and Susumu Kitagawa
    • Journal Title

      Coord. Chem. Rev. 251

      Pages: 2510-2521

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Cyanide-Bridged MnIIMnIII Ferrimagnets, [Mn (HL) (H_2O)] [Mn (CN)_6]_2H_2O (L=S- or R-1, 2- diaminopropane) : Syntheses, Structures and Magnetic Behaviors2007

    • Author(s)
      W.Kaneko, S.Kitagawa, M.Ohba
    • Journal Title

      Journal of the Americal Chemical Society 129

      Pages: 248-249

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A Flexible Interpenetrating Coordination Framework with a Bimodal Porous Functionality2007

    • Author(s)
      Tapas Kumar Maji, Ryotaro Matsuda, Susumu Kitagawa
    • Journal Title

      Nature Materials 6

      Pages: 142-148

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Guest Induced Asymmetry in a Metal-Organic Solid with Reversible Single-Crystal-to-Single-Crystal Structural Transformation2006

    • Author(s)
      T. K. Maji, G. Mostafa, R. Matsuda, S. Kitagawa
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 17152-17153

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Guest Induced Asymmetry in a Metal-Organic Solid with Reversible Single-Crystal-to-Single-Crystal Structural Transfomation2006

    • Author(s)
      T. K. Maji, G. Hostafa, R. Matsuda, S. Kitagawa
    • Journal Title

      J. Am. Chem. Soc. 127

      Pages: 17152-17153

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Novel Trimetallic Magnets, [Co_2Ln (L)_2 (H_2O)_4] [Cr (CN)_6] _2H_2O (Ln=La, Gd; H_2L=2, 6-di(acetoacetyl)pyridine) with 3-D Pillared-layer2006

    • Author(s)
      T.Shiga, H.kawa, S.Kitagawa, M.Ohba
    • Journal Title

      Journal of the Americal Chemical Society 128

      Pages: 16426-16427

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A Three-dimensional Ferromagnet, [Ni(dipn)]_3 [Cr(CN)_6]_2_3H_2O (dipn=dipropylenetriamine), Based on a Cubic Cr_8Ni_<12> Unit2006

    • Author(s)
      W.Kaneko, M.Ohba, H.kawa, S.Kitagawa
    • Journal Title

      Inorganic Chemistry 45

      Pages: 7191-7198

    • Related Report
      2006 Annual Research Report
  • [Journal Article] TCNQ Dianion-Based Coordination Polymer Whose Open Framework Shows Charge-Transfer Type Guest Inclusion2006

    • Author(s)
      Satoru Shimomura, Ryotaro Matsuda, Takashi Tsujino
    • Journal Title

      Journal of the American Chemical Society 128

      Pages: 16416-16417

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Hydrogen-Bonded Porous Coordination Polymers ; Structural Transformation, Sorption Properties, and Particle Size2006

    • Author(s)
      K.Uemura, K.Saito, S.Kitagawa, H.Kita
    • Journal Title

      Journal of the Amerizan Chemical Society 128

      Pages: 16112-16113

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Highly controlled acetylene accommodation in a metal-organic microporous material2005

    • Author(s)
      24) R. Matsuda, R. Kitaura, S. Kitagawa, Y. Kubota, R. V. Belosludov, T. C. Kobayashi, H. Sakamoto, T. Chiba, M. Takata, Y. Kawazoe, Y. Mita
    • Journal Title

      Nature 436

      Pages: 238-241

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Highly controlled acetylene accommodation in a metal-organic microporous material2005

    • Author(s)
      R. Matsuda, R. Kitaura, S. Kitagawa, Y. Kubota, R. V. Belosludov, T. C. Kobayashi, H. Sakamoto, T. Chiba, M. Takata, Y. Kawazoe, Y. Mita
    • Journal Title

      Nature 436

      Pages: 238-241

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Guest Induced Asymmetry in Metal-Organic Solid with Reversible Single-Crystal-to-Single-Crystal Stractural Transformation2005

    • Author(s)
      T.K.Maji, G.Mostafa, R.Matsuda, S.Kitagawa
    • Journal Title

      J.Am.Chem.Soc. 127

      Pages: 17152-17153

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Effects of Mtal-Assisted Assembling Mode on Redox States of Hxaazatriphenylene Hexacarbonitrile2005

    • Author(s)
      S.Furukawa, T.Ohkubo, S.Masaoka, D.Tanaka, H.-C.Chang, S.Kitagawa
    • Journal Title

      Angew.Chem.Int.Ed. 44

      Pages: 2700-2704

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Highly-controlled actylene accomodation in metal-organic microporous materilal2005

    • Author(s)
      R.Matsuda, R.Kitaura, S.Kitagawa, Y.Kubota, R.V.Belosludov, T.C.Kobayash, H.Sakamoto, T.Chiba, M.Takata.Y.Kawazoe, Y.Mita
    • Journal Title

      Nature 436

      Pages: 238-241

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Direct Observation of Hydrogen Molecules Adsorbed in a Microporous Coordination Polymer2005

    • Author(s)
      Y.Kubota, M.Takata, R.Matsuda, R.Kitaura, S.Kitagawa, K.Kato, M.Sakata, T.C.Kobayashi R.Kitaura, G.Onoyama, H.Sakamoto, R.Matsuda, S.Noro, S.Kitagawa
    • Journal Title

      Angew.Chem.Int.Ed. 44

      Pages: 913-916

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Dynamic porous properties of coordination polymers inspired by hydrogen bonds2005

    • Author(s)
      S.Kitagawa, K.Uemura
    • Journal Title

      Chem.Soc.Rev. 34

      Pages: 109-119

    • Related Report
      2005 Annual Research Report 2004 Annual Research Report
  • [Journal Article] Nanocrystals of Coordination Polymers2005

    • Author(s)
      S.Kitagawa, T.Uemura
    • Journal Title

      Chem.Lett., Highlight Review, 34

      Pages: 132-137

    • NAID

      10014363560

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Nanocrystals of Coordination Polymers2005

    • Author(s)
      S.Kitagawa, T.Uemura
    • Journal Title

      Chem.Lett., Highlight Review 34

      Pages: 132-137

    • NAID

      10014363560

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Immobilization of Metallo-Schiff-base into Microporous Coordination Polymer2004

    • Author(s)
      R.Kitaura, G.Onoyama, H.Sakamoto, R.Matsuda, S.Noro, S.Kitagawa
    • Journal Title

      Angew.Chem.Int.Ed 43

      Pages: 2684-2687

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Expanding and Shrinking Porous Modulation Based on Pillared-Layer Coordination Polymers2004

    • Author(s)
      T.K.Maji, K.Uemura, H.-C.Chang, R.Matsuda, S.Kitagawa
    • Journal Title

      Angew.Chem.Int.Ed. 43

      Pages: 3269-3272

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Guest Shape-Responsive Fitting of Porous Coordination Polymer with Shrinkable Framework2004

    • Author(s)
      R.Matsuda, R.Kitaura, S.Kitagawa, Y.Kubota, T.C.Kobayashi, S.Horike, M.Takata
    • Journal Title

      J.Am.Chem.Soc. 43

      Pages: 14063-14070

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Direct Observation of Hydrogen Molecules Adsorbed in a Microporous Coordination Polymer2004

    • Author(s)
      Y.Kubota, M.Takata, R.Matsuda, R.Kitaura, S.Kitagawa, K.Kato, M.Sakata, T.C.Kobayashi, R.Kitaura, G.Onoyama, H.Sakamoto, R.Matsuda, S.Noro, S.Kitagawa
    • Journal Title

      Angew.Chem.Int.Ed. 44

      Pages: 2920-2923

    • Related Report
      2004 Annual Research Report
  • [Presentation] Flexible Coordination Polymers as Novel Porous Materials2005

    • Author(s)
      S. Kitagawa
    • Organizer
      The 17th edition of the International Conference on the Chemistry of the Organic Solid State (ICCOSS, XVII)
    • Place of Presentation
      Los Angels, U.S.A.
    • Year and Date
      2005-07-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Flexible Coordination Polymers as Novel Porous Materials2005

    • Author(s)
      S. Kitagawa
    • Organizer
      The 17th edition of the International Conference on the Chemistry of the Organic Solid State (ICCOSS, XVII) (Plenary Talk).
    • Place of Presentation
      Los Angels, U.S.A.
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] 新時代の多孔性材料とその応用2004

    • Author(s)
      北川進
    • Total Pages
      249
    • Publisher
      シーエムシー出版
    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] 規則性ポリマー、並びに、その製造方法及びそれに用いる規則性ポリマー生成用錯体2006

    • Inventor(s)
      北川 進 他1名
    • Industrial Property Rights Holder
      京都大学
    • Industrial Property Number
      2006-066638
    • Filing Date
      2006-03-10
    • Related Report
      2005 Annual Research Report
  • [Patent(Industrial Property Rights)] 有機金属錯体構造およびその製造方法、ならびに該有機金属錯体構造体を用いた機能性膜、...2004

    • Inventor(s)
      北川進
    • Industrial Property Rights Holder
      京都大学
    • Filing Date
      2004-09-09
    • Related Report
      2004 Annual Research Report

URL: 

Published: 2004-04-01   Modified: 2018-03-28  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi