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Charge Density Level Structure of Molecular Doped Functional Nano Coordination Space

Research Project

Project/Area Number 16074220
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionThe Institute of Physical and Chemical Research (2006-2007)
Japan Synchrotron Radiation Research Institute (2004-2005)

Principal Investigator

TAKATA Masaki  The Institute of Physical and Chemical Research, Structural Materials Science Laboratory, Chief Scientist (60197100)

Co-Investigator(Kenkyū-buntansha) KUBOTA Yoshiki  Osaka Prefeture University, School of Science, Associate Professor (50254371)
KATO Kenichi  RIKEN SPring-8 Center, Scientist (90344390)
OISHI Yasuo  Japan Synchrotron Radiation Institute, Research & Utilization Division, Scientist (20344400)
TANAKA Hiroshi  Shimane University, Interdisciplinary Faculty of Science and Engineering, Associate Professor (10284019)
安達 隆文  財団法人高輝度光科学研究センター, 利用研究促進部門I・極限構造チーム, 研究員 (80372142)
Project Period (FY) 2004 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥24,800,000 (Direct Cost: ¥24,800,000)
Fiscal Year 2007: ¥7,100,000 (Direct Cost: ¥7,100,000)
Fiscal Year 2006: ¥7,100,000 (Direct Cost: ¥7,100,000)
Fiscal Year 2005: ¥7,100,000 (Direct Cost: ¥7,100,000)
Fiscal Year 2004: ¥3,500,000 (Direct Cost: ¥3,500,000)
KeywordsMicroporous Coordination Polymer / Gas Adsorption / Snchrotron Powder Diffraction / Accurate Structure Analysis / Maximum Entropy Method / 多孔性配位高分子 / 放射光粉末加折法 / 静電ポテンシャル / MEM / 放射光 / 電子密度 / 集積型金属錯体 / 吸着 / 配位高分子 / 粉末X線回折 / 電子密度解析 / マキシマムエントロピー法 / 精密構造解析 / 水素 / 気体吸着
Research Abstract

The aim of our research is to determine the precise crystal structure, including the electron densities, of nano-coordination space and adsorbed molecules by an in situ powder diffraction experiment of gas adsorption using high brilliance synchrotron light source at SPring-8 and the MEM(maximum entropy method)/Rietveld charge density analysis. Precise structural information will allow us to understand the interaction mechanism between the host framework and guest molecules in the nano-coordination space. We have revealed various crystal structures of porous coordination polymers with the adsorption of gas molecules.
In hydrogen adsorption on CPL-1, the electron densities of adsorbed hydrogen molecules were clearly observed in the nanochannels. It was suggested from the result that the metal-oxygen unit is associated with an attractive interaction site for hydrogen molecules and the cavity on the pore wall well-suited to the size of hydrogen molecule is important for the effective hydrog … More en accommodation.
CPL-1 was found to store acetylene with extremely high density beyond the safety compression limit at room temperature. From the MEM charge density, acetylene molecule was found to be trapped by double hydrogen bonds with the oxygen atoms on the pore wall. Furthermore, an intermediate adsorption state was also revealed for acetylene adsorption for the first time. The information on structural changes throughout the adsorption phenomena is very important and required for a feasible design of a porous framework.
Recently, the electrostatic potential based on the MEM charge density was developed and was found to be useful for understanding intermolecular interaction between guest and host framework.
The precise structural information obtained in this project is important for the understanding of gas adsorption phenomena in the nano-coordination space. It will also contribute to the design and the rational synthetic strategy of novel porous coordination Polymers as functional materials. Less

Report

(5 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (74 results)

All 2008 2007 2006 2005 2004

All Journal Article (71 results) (of which Peer Reviewed: 17 results) Presentation (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Hydrogen Absorption in the Core/Shell Interface of Pd/Pt Nanoparticles2008

    • Author(s)
      Hirokazu Kobayashi
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 1818-1819

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] On the Nature of Strong Hydrogen Atom Trapping Inside Pd Nanoparticles2008

    • Author(s)
      Hirokazu Kobayashi
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 1828-1829

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of gas molecules adsorbed in the nanochannels of porous coordination polymers by the in situ synchrotron powder diffraction experiment and the MEM/Rietveld charge density analysis2007

    • Author(s)
      Yoshiki Kubota
    • Journal Title

      Coord. Chem. Rev. 251

      Pages: 2510-2521

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Observation of gas Molecules adsorbed in the nanochannels of porous coordination polymers by the in situ synchrotron powder diffraction experiment and the MEM/Rietveld charge density analysis2007

    • Author(s)
      Yoshiki Kubota, Masaki Takata, Tatsuo C. Kobayashi, S. Kitagawa
    • Journal Title

      Coord. Chem. Rev. 251

      Pages: 2510-2521

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Novel emission properties of melem caused by the heavy metal effect of lanthanides(III) in a LB film2007

    • Author(s)
      Ayumi Ishii
    • Journal Title

      Photochem. Photobiol. Sci. 6

      Pages: 804-809

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The MEM/Rietveld method with nano-applications-accurate charge-density studies of nano-structured materials by synchrotron-radiation powder diffraction2007

    • Author(s)
      Masaki Takata
    • Journal Title

      Acta Cryst. A 64

      Pages: 232-245

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Accurate structure factors and experimental charge densities from synchrotron X-ray powder diffraction date at SPring-82007

    • Author(s)
      Eiji Nishibori
    • Journal Title

      Acta Cryst. A 63

      Pages: 43-52

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metallic State in a Lime-Alumina Compound with Nanoporous Structure2007

    • Author(s)
      Sung Wng Kim
    • Journal Title

      Nano Lett. 7

      Pages: 1138-1143

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anion Incorporation-induced Cage Deformation in 12CaO・7Al_2O_3 Crystal2007

    • Author(s)
      Takatoshi Nomura
    • Journal Title

      Chem. Lett. 36

      Pages: 902-903

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A New Attachment of the Large Debye-Scherrer Camera at BL02B2 of the SPring-8 for Thin Film X-ray Diffraction2007

    • Author(s)
      Keiichi Osaka
    • Journal Title

      AIP Conference Proceedings 879

      Pages: 1771-1774

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modification of Spin Crossover Behavior through Solvent Assisted Form ation and Solvent Inclusion in a Triply Interpenetrating Three-Dimensional Network2007

    • Author(s)
      Matthias Bartel
    • Journal Title

      Inorg. Chem. 46

      Pages: 4220-4229

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extended Charge-Transfer State of RbMn[Fe(CN)_6]2007

    • Author(s)
      Kenichi Kato
    • Journal Title

      J. Phys. Soc. Jpn. 76

    • NAID

      110006532180

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Properties and Crystal Structure of Solvent-Free Sc@C_<82> Metallofllerene Micryocrystals2007

    • Author(s)
      Yasuhiro Ito
    • Journal Title

      Chem. Phys. Chem. 8

      Pages: 1019-1024

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Higher-order Structure Analysis of Polyethylene Thin Films by In-situ Synchrotron Grazing-incidence Small-angle and Wide-angle X-ray Scattering Measurements2007

    • Author(s)
      Sono Sasaki
    • Journal Title

      Transactions of the Materials Research Society of Japan 32

      Pages: 193-197

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ investigation of annealing effect on lamellar stacking structure of polyethylene thin films by synchrotron grazing-incidence small-angle and wide-angle X-ray scattering2007

    • Author(s)
      Sono Sasaki
    • Journal Title

      J. Appl. Cryst. 40

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metastable Sorption State of a Metal-Organic Porous Material Determined by In Situ Synchrotron Powder Diffraction2006

    • Author(s)
      Yoshiki Kubota
    • Journal Title

      Angew. Chem. Int. Ed. 45

      Pages: 4932-4936

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Metastable Sorption State of a Metal-Organic Porous Material Determined by In Situ Synchrotron Powder Diffraction2006

    • Author(s)
      Yoshiki Kubota, Masaki Takata, Ryotaro Matsuda, Ryo Kitaura. Susumu Kitagawa, Tatsuo C. Kobayashi
    • Journal Title

      Angew. Chem. Int. Ed. 45

      Pages: 4932-4936

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Structure Basis for Antitumor Effect of Aplyronine A2006

    • Author(s)
      Kunio Hirata et al.
    • Journal Title

      JOURNAL OF MOLECULAR BIOLOGY 356

      Pages: 945-954

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Fine Size Control of Platinum on Carbon Nanotubes : From Single Atoms to Clusters2006

    • Author(s)
      Yong-Tae Kim et al.
    • Journal Title

      Angew.Chem.Int. Ed. 45

      Pages: 407-411

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A C_2 Molecule Entrapped in the Pentagonal-Dodecahedral Y_2 Cage in Y_2C_2@C_<82>(III)2006

    • Author(s)
      Eiji Nishibori et al.
    • Journal Title

      Chem. Phys. Chem 7

      Pages: 345-348

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Single Structure Widely Distributed in a GeTe-Sb_2Te_3 Pseudobinary System : A Rock Salt Structure is Retained by Intrinsically Containing an Enormous Number of Vacancies within its Crystal2006

    • Author(s)
      Toshiyuki Matsunaga et al.
    • Journal Title

      Inorganic Chemistry 45

      Pages: 2235-2241

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Crystal symmetry and superlattice reflections in spin-Peierls system TiOBr2006

    • Author(s)
      T.Sasaki et al.
    • Journal Title

      Science and Technology of Advanced Materials 7

      Pages: 17-21

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Relationship between superconductivity and crystal structure in NbB_<2+X>2006

    • Author(s)
      H.Takagiwa et al.
    • Journal Title

      Science and Technology of Advanced Materials 7

      Pages: 22-25

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Metastable Sorption State of a Metal-Organic Porous Material Determined by In Situ Synchrotron Powder Diffraction2006

    • Author(s)
      Yoshiki Kubota et al.
    • Journal Title

      Angew. Chem. Int. Ed 45

      Pages: 4932-4936

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Stable top-up operation at Spring-82006

    • Author(s)
      Hitoshi Tanaka et al.
    • Journal Title

      Journal of Synchrotron Radiation 13

      Pages: 378-391

    • Related Report
      2006 Annual Research Report
  • [Journal Article] High-Resolution Analysis of (Sc3C2)@C80 Metallofullerene by Third Generation Synchrotron Radiation X-ray Powder Diffraction2006

    • Author(s)
      Eiji Nishibori et al.
    • Journal Title

      The Journal of Physical Chemistry B 110・39

      Pages: 19215-19219

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Electrostatic potential of ferroelectric PbTiO_3 : Visualized electron polarization of Pb ion2006

    • Author(s)
      Hiroshi Tanaka et al.
    • Journal Title

      PHYSICAL REVIEW B 74

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Structural basis for the fast phase change of Ge_2Sb_2Te_5 : Ring statistics analogy between the crystal and amorphous states2006

    • Author(s)
      Shinji Kohara et al.
    • Journal Title

      APPLIED PHYSICAL LETTERS 89

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Bent (metal)_2C_2 clusters encapsulated in (Sc_2C_2)@C_<82>(III) and (Y_2C_2)@C_<82>(III) metallofullerenes2006

    • Author(s)
      Eiji Nishibori et al.
    • Journal Title

      CHEMICAL PHYSICS LETTERS 433

      Pages: 120-124

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Accurate structure factors and experimental charge densities from synchrotron X-ray powder diffraction date at SPring-82006

    • Author(s)
      Eiji Nishibori et al.
    • Journal Title

      Acta Crystallographica A63

      Pages: 43-52

    • Related Report
      2006 Annual Research Report
  • [Journal Article] An Analytical Approach to Determine the Pore Shape and Size of MCM-41 Materials from X-ray Diffraction Data2006

    • Author(s)
      Norihiro Muroyama et al.
    • Journal Title

      J. Phys. Chem. B 110

      Pages: 10630-10635

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Crystal structures and phase stability in pseudobinary CaAl_<2-x>Zn_x2006

    • Author(s)
      Karin Soderberg et al.
    • Journal Title

      J. Sol. Stat. Chem. 179

      Pages: 2690-2697

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Fine Size Control of Platinum on Carbon Nanotubes : From Single Atoms to Clusters2006

    • Author(s)
      Yong-Tae Kim
    • Journal Title

      Angew.Chem.Int.Ed. 45

      Pages: 407-411

    • Related Report
      2005 Annual Research Report
  • [Journal Article] A C2 Molecule Entrapped in the Pentagonal-Dodecahedral Y2 Cage in Y2C2@C82(III)2006

    • Author(s)
      E.Nishibori
    • Journal Title

      ChemPhysChem 7

      Pages: 345-348

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Single Structure Widely Distributed in a GeTe-Sb2Te3 Pseudobinary System : A Rock Salt Structure is Retained by Intrinsically Containing an Enormous Number of Vacancies within its Crystal2006

    • Author(s)
      T.Matsunaga
    • Journal Title

      Inorg.Chem 45・5

      Pages: 2235-2241

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structure Basis for Antitumor Effect of Aplyronine A2006

    • Author(s)
      K.Hirata
    • Journal Title

      J.Mol.Biol. 356・4

      Pages: 945-954

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Charge-Transfer Phase Transition and Ferromagnetism of Iron Mixed-Valence Complexes (n-CnH2n+1)4N[FeIIFeIII(dto)3] (n=3-6;dto=C2O2S2)2006

    • Author(s)
      M.Itoi
    • Journal Title

      European Journal of Inorganic chemistry 2006

      Pages: 1198-1207

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Synthesis, Structure and Magnetic Properties of Li-Doped Manganese-Phthalocyanine, Li_x[MnPc] (0=x=4)2006

    • Author(s)
      Y.Taguchi
    • Journal Title

      Journal of the American Chemical Society 128

      Pages: 3313-3323

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Spontaneous Formation of Vanadium "Molecules" in a Geometrically Frustrated Crystal : AlV_2O_42006

    • Author(s)
      Y.Horibe
    • Journal Title

      Physical Review Letters 96

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Crystal symmetry and superlattice reflections in spin-Peierls system TiOBr2006

    • Author(s)
      T.Sasaki
    • Journal Title

      Science and Technology of Advanced Materials 7

      Pages: 17-21

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Direct Observation of Hydrogen Molecules Adsorbed onto a Microporous Coordination Polymer2005

    • Author(s)
      Yoshiki Kubota
    • Journal Title

      Angew. Chem. Int. Ed. 44

      Pages: 920-923

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Highly controlled acetylene accommodation in a metal-organic microporous material2005

    • Author(s)
      2) Rotaro Matsuda
    • Journal Title

      Nature 436

      Pages: 238-241

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Direct Observation of Hydrogen Molecules Adsorbed onto a Microporous Coordination Polymer2005

    • Author(s)
      Yoshiki Kubota, Masaki Takata, Ryotaro Matsuda, Ryo Kitaura, Susumu Kitagawa, Kenichi Kato, Makoto Sakata, Tatsuo C. Kobayashi
    • Journal Title

      Angew. Chem. Int. Ed. 44

      Pages: 920-923

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Highly controlled acetylene accommodation in a metal-organic microporous material2005

    • Author(s)
      Rotaro Matstuda, Ryo Kitaura, Susumu Kitagawa, Yoshiki Kubota, Rodeion V. Belosludov, Tatsuo C. Kobayashi, Hirotoshi Sakamoto, Takashi Chiba, Masaki Takata, Yoshiyuki Kawazoe, Yoshimi Mita
    • Journal Title

      Nature 436

      Pages: 238-241

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] An Anomalous Endohedral Structure of Eu@C82 Metallofullerenes2005

    • Author(s)
      Bao-Yun Sun et al.
    • Journal Title

      Angew.Chem.Int.Ed. 44

      Pages: 4568-4571

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Highly controlled acetylene accommodation in a metal-organic microporous material2005

    • Author(s)
      R.Matsuda et al.
    • Journal Title

      Nature 436

      Pages: 238-241

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Single-component Molecular Conductor[Zn(tmdt)2] and Related Zn Complexes2005

    • Author(s)
      K.Yamamoto et al.
    • Journal Title

      Chemistry Letters 34・8

      Pages: 1090-1091

    • Related Report
      2005 Annual Research Report
  • [Journal Article] A Study of Structures and Order Patameters in Antiferroelectric PbHfO3 by Synchrotron Radiation2005

    • Author(s)
      H.FUJISHITA et al.
    • Journal Title

      J.Phys.Soc.Jan. 74・10

      Pages: 2743-2747

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Observation of Phase Transition with Lattice Distortion in the Low-dimensional Quantum Spin System TiOBr by Synchrotron X-ray Diffraction -Evidence of Spin-Peierls Transition?-2005

    • Author(s)
      T.SASAKI et al.
    • Journal Title

      J.Phys.Soc.Jan. 74・8

      Pages: 2185-2188

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Phase Relationships of Crystalline Polymorphs of Mesogenic4-Cyano-4'-heptyloxybiphenyl (7OCB) and 4-Cyano-4'-octyloxybiphenyl (8OCB)2005

    • Author(s)
      K.Hori et al.
    • Journal Title

      Bulletin of the Chemical Society of Japan. 178・7

      Pages: 1223-1229

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Pressure/temperature/substitution-induced melting of A-site charge disproportionation in Bi1-xLaxNiO3 (0≦x≦0.5)2005

    • Author(s)
      S.Ishiwata et al.
    • Journal Title

      Phys.Rev.B. 72・045104

      Pages: 1-7

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Superconductivity and physical properties of Ba24Si100 determined from electric transport, specific-heat capacity, and magnetic susceptibility measurements2005

    • Author(s)
      T.Rachi et al.
    • Journal Title

      Phys.Rev.B. 72・144504

      Pages: 1-6

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Space-group symmetry for the peroviskite Ca0.3Sr0.7TiO32005

    • Author(s)
      C.J.Howard et al.
    • Journal Title

      J.Phys. : Condens.Matter 17

    • Related Report
      2005 Annual Research Report
  • [Journal Article] High-Energy SR Powder Diffraction Evidence of Multisite Disorder of Pb Atom in Cubic Phase of PbZr1-xTixO32005

    • Author(s)
      Y.Kuroiwa
    • Journal Title

      Jpn.J.Appl.Phys. 44・9B

      Pages: 7151-7155

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Conducting and Magnetic Properties of 1-Rthy1-3-methylimidazolium(EMI) Salts Containing Paramagnetic Ions : Liquids[EMI] [M III Cl4](M=Fe and Fe0.5Ga0.5) and Solid [EMI]2[FeCl4]2005

    • Author(s)
      Y.Yoshida
    • Journal Title

      Bull.Chem.Soc.Jpn. 78

      Pages: 1921-1928

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Evidence of a pressure-induced orbital transition in a layered manganite2005

    • Author(s)
      K.Kato
    • Journal Title

      Phy.Rev.B 71・012404

      Pages: 1-4

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Superconducting properties and crystallinity of as-grown MgB2 thin films synthesized using an in-plane-lattice Near-matched epitaxial butter layer2005

    • Author(s)
      T.Kato
    • Journal Title

      IEEE Transactions on Applied Superconductivity 15・2

      Pages: 3257-3260

    • Related Report
      2005 Annual Research Report
  • [Journal Article] MEM Charge Density Analysis of Orbital-ordering of Nd0.35Sr0.65Mno32005

    • Author(s)
      K.Kato
    • Journal Title

      J.P.S.J. 74・8

      Pages: 2137-2140

    • NAID

      130004539376

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Magnetic-Field Switching of Crystal Structure in an Orbital-Spin-Coupled System : Mn V2O42005

    • Author(s)
      K.Adachi
    • Journal Title

      Phy.Rev.Lett. PRL95・197202

      Pages: 1-4

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Pressure-induced charge ordering of LiV2O42005

    • Author(s)
      K.Takeda
    • Journal Title

      Physica B

      Pages: 1312-1314

    • Related Report
      2005 Annual Research Report
  • [Journal Article] High-Energy X-ray Diffraction Study of Liquid Structure of Metallic Glass-Forming Zr70Cu30 Alloy2005

    • Author(s)
      A.Mizuno
    • Journal Title

      Materials Transactions 46・12

      Pages: 2799-2802

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Formation and Characterization of Crystalline Molecular Arrays of Gas Molecules in a 1-Dimensional Ultramicropore of a Porous Copper Coordination Polymer2005

    • Author(s)
      R.Kitaura et al.
    • Journal Title

      J.Phys.Chem.B 109

      Pages: 23378-23385

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Extremely long period-stacking structure in the Sb-Te binary system2005

    • Author(s)
      K.Kifune et al.
    • Journal Title

      Acta Cryst.B 61

      Pages: 492-497

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 放射光粉末回折法による先端材料の精密構造物性の研究2005

    • Author(s)
      高田昌樹
    • Journal Title

      応用物理 74・9

      Pages: 1201-1204

    • NAID

      130007718054

    • Related Report
      2005 Annual Research Report
  • [Journal Article] BLO2B2に設置された大型デバイ-シェラーカメラついて2005

    • Author(s)
      坂田 誠
    • Journal Title

      SPring-8 利用者情報 10

      Pages: 191-193

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Direct Observation of Hydrogen Molecules Adsorbed onto a Microporous Coordination Polymer2005

    • Author(s)
      Yoshiki Kubota
    • Journal Title

      Angew.Chem.Int.Ed. 44

      Pages: 920-923

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Stability of magnesite and its high-pressure from in the lowermost mantle.2004

    • Author(s)
      Maiko Isshiki
    • Journal Title

      Nature 42

      Pages: 60-63

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Direct Obsevation of Bonding and Charge Ordering in (EDO-TTF)_2PF_62004

    • Author(s)
      Shinobu Aoyagi
    • Journal Title

      Angew.Chem.Int'l Ed. 43

      Pages: 3670-3673

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Guest Shape-Responsive Fitting of Porous Coordination Polymer with Shrinkable Framework2004

    • Author(s)
      Ryotaro Matsuda
    • Journal Title

      J.AM.CHEM.SOC. 126

      Pages: 14063-14070

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 1-D Cobalt(II)Spin Transition Compound with Strong Interchain Interaction : [Co(pyterpy)Cl_2]・X2004

    • Author(s)
      Shinya Hayami
    • Journal Title

      Inorg.Chem. 43

      Pages: 4124-4126

    • Related Report
      2004 Annual Research Report
  • [Journal Article] New Technique to measure the polarization dependence of non-resonant X-ray magnetic scattering2004

    • Author(s)
      H.Ohsumi
    • Journal Title

      Physica B 345

      Pages: 258-261

    • Related Report
      2004 Annual Research Report
  • [Presentation] Bonding nature of molecules in nanospace -X-ray charge density study by SR powder diffraction2006

    • Author(s)
      Masaki Takata
    • Organizer
      Japan-UK Joint Symposium on Chemistry of Coordination Space
    • Place of Presentation
      Chemistry Lecture Theater, University College London, UK
    • Year and Date
      2006-07-12
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Bonding nature of molecules in nanospace - X-ray charge density study by SR powder diffraction2006

    • Author(s)
      Masaki Takata
    • Organizer
      Japan-UK Joint Symposium on Chemistry of Coordination Space, Chemistry Lecture Theatre.
    • Place of Presentation
      University College London, UK
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Patent(Industrial Property Rights)] X線回折データのMEM構造解析により静電ポテンシャルを実験的に求める方法2005

    • Inventor(s)
      田中宏志, 高田昌樹
    • Industrial Property Rights Holder
      (財)高輝度光科学研究センター
    • Industrial Property Number
      2005-184553
    • Filing Date
      2005-06-24
    • Related Report
      2005 Annual Research Report

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Published: 2004-04-01   Modified: 2018-03-28  

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