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Nano-ionic Structure for the Development of High Performance Solid Oxide Fuel Cells

Research Project

Project/Area Number 16079204
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTohoku University

Principal Investigator

MIZUSAKI Junichiro  Tohoku University, 多元物質科学研究所, 教授 (90092345)

Co-Investigator(Kenkyū-buntansha) HASHIDA Toshiyuki  東北大学, 大学院工学研究科, 教授 (40180814)
YASHIRO Keiji  東北大学, 多元物質科学研究所, 講師 (20323107)
SATO Kazuhisa  東北大学, 多元物質科学研究所, 助教 (50422077)
Project Period (FY) 2004 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥66,100,000 (Direct Cost: ¥66,100,000)
Fiscal Year 2008: ¥11,200,000 (Direct Cost: ¥11,200,000)
Fiscal Year 2007: ¥12,500,000 (Direct Cost: ¥12,500,000)
Fiscal Year 2006: ¥13,400,000 (Direct Cost: ¥13,400,000)
Fiscal Year 2005: ¥14,700,000 (Direct Cost: ¥14,700,000)
Fiscal Year 2004: ¥14,300,000 (Direct Cost: ¥14,300,000)
Keywords固体酸化物燃料電池 / 固体電解質系電極反応機構 / 機械的安定性 / 膜形成と物性 / 応力と物性 / 多層膜破壊計測制御 / アコースティックエミッション / その場計測 / 固体電質系ガス電極反応 / 薄膜化と物性 / 多層膜破壊制御アコースティックエミッション / 欠陥平衡 / 固体酸化物燃料電 / ナノコンポジット / ナノ多層膜 / ナノ構造内イオン輸送 / ナノ構造内電子輸送 / エネルギー効率化 / エネルギー全般 / 環境技術 / 機械力学・制御
Research Abstract

物質の構造を100万から1000万分の1センチメートルという細かな領域で設計制御をすることにより,新しい機能を持つ機器を作り出そうといのかナノテクノロジーである。本研究は,このナノテクの考え方が,固体内をイオンが動くイオン伝導体の世界,とくに高温で作動する燃料電池の技術にどのように関わるかの解明を目指した。ナノ構造が高温で安定に保持できる条件が明らかになり,高機能小型燃料電池の基盤が確立された。

Report

(6 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (118 results)

All 2008 2007 2006 2005 2004 Other

All Journal Article (59 results) (of which Peer Reviewed: 41 results) Presentation (49 results) Book (7 results) Remarks (3 results)

  • [Journal Article] Electrical Properties of Nb-Doped SrTiO3 Ceramics with Excess TiO2 for SOFC Anodes and Interconnects2008

    • Author(s)
      Fumimasa Horikiri, LiQun Han, Naofumi Iizawa, Kazuhisa Sato, Keiji Yashiro, Tatsuya Kawada, Junichiro Mizusak
    • Journal Title

      J. Electrochem. Soc 155(1)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Behaviors of Mixed Conducting Oxide Anodes for Solid Oxide Fuel Cell2008

    • Author(s)
      Takashi Nakamura, Tsuneyuki Kobayashi, Keiji Yashiro, Atsushi Kaimai, Takanori Otake, Kazuhisa Sato, Junichiro Mizusaki, Tatsuya Kawada
    • Journal Title

      J. Electrochem. Soc 155(6)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Oxygen Surface Exchange at the Hetero - interface of (La,Sr)CoO3 / (La,Sr)2CoO4 with PLD-Layered Films2008

    • Author(s)
      M.Sase, F.Hermes, K.Yashiro, K.Sato, J.Mizusaki, T.Kawada, N.Sakai, H.Yokokawa
    • Journal Title

      J. Electrochem. Soc 155(8)

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of oxygen exchange at the hetero interface of (La,Sr)CoO3/(La,Sr)2CoO4 in composite ceramics2008

    • Author(s)
      Maya Sase, Keiji Yashiro, Kazuhisa Sato,Junichiro Mizusaki,Tatsuya Kawada, Natsuko Sakai,Katsuhiko Yamaji, Teruhisa Horita, Harumi Yokokawa
    • Journal Title

      Solid State Ionics 178

      Pages: 1843-1852

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 固体酸化物燃料電池の損傷に及ぼす化学膨張の影響2008

    • Author(s)
      佐藤一永,八代圭司,橋田俊之,川田達也,湯上浩雄,水崎純一郎
    • Journal Title

      日本機械学会論文集 74(737)

      Pages: 68-74

    • NAID

      110006571946

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen nonstoichiometry and defect structure analysis of B-site mixed perovskite-type oxide (La,Sr)(Cr,M)O_<3-δ> (M=Ti, Mn and Fe)2008

    • Author(s)
      Masatsugu Oishi, Keiji Yashiro, Kazuhisa Sato, Junichiro Mizusaki, Tatsuya Kawada
    • Journal Title

      J. Solid State Chem 181

      Pages: 3177-3184

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical Properties of Ceria Based Oxygen Ionic Conductors for SOFC2008

    • Author(s)
      Hiroo Yugami, Fumitada Iguchi, Kazuhisa Sato, Toshiyuki Hashida
    • Journal Title

      Proc. Fuel Cell 2008 6th International Fuel Cell Science, Engineering & Technology Conference Fuel Cell 2008-65206

      Pages: 1-7

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrical Properties of Nb-Doped SrTiO_3 Ceramics with Excess TiO_2 for SOFC Anodes and Interconnects2008

    • Author(s)
      Fumimasa Horikiri, 他
    • Journal Title

      J. Electrochem. Soc 155

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Behaviors of Mixed Conducting Oxide Anodes for Solid Oxide Fuel Cell2008

    • Author(s)
      Takashi Nakamura, 他
    • Journal Title

      J. Electrochem. Soc. 155(6)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Oxygen Surface Exchange at the Hetero-interfa ce of (La, Sr) Co03 / (La, Sr) 2Co04 with PLD-Layered Films2008

    • Author(s)
      M-Sase, 他
    • Journal Title

      J. Electrochem. Soc. 155(8)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of oxygen exchange at the hetero interface of (La, Sr) Co03/ (La, Sr) 2Co04 in composite ceramics2008

    • Author(s)
      Maya Sase, 他
    • Journal Title

      Solid State Ionics 178

      Pages: 1843-1852

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 固体酸化物燃料電池の損傷に及ぼす化学膨張の影響2008

    • Author(s)
      佐藤一永, 他
    • Journal Title

      日本機械学会誌 74(737)

      Pages: 68-74

    • NAID

      110006571946

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen nonstoichiometry and defect structure analysis of B-site mixed perovskite-type oxide (La, Sr)(Cr, M)03- S (M=Ti, Mn and Fe)2008

    • Author(s)
      Masatsugu Oishi, 他
    • Journal Title

      J. Solid State Chem 181

      Pages: 3177-3184

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chapter Two Nano-Scale Energy and Mass Transport Phenomena Involved2008

    • Author(s)
      Junichiro Mizusaki, 他(分担著)
    • Journal Title

      Fuel Cell Processes: in Nano-Mega Sclae Flow Dynamics in Energy Systems, The 21st Century COE Program, International COE of Flow Dynamics, Lecture Series, Vol.9. Ed Shigenao Maruyama, Tohoku Univ. Press

      Pages: 39-78

    • Related Report
      2007 Annual Research Report
  • [Journal Article] Junichiro Mizusaki Oxygen nonstoichiometry of B-site doped LaCrO32007

    • Author(s)
      Masatsugu Oishi, Keiji Yashiro, Jeong-Oh Hong, Yutaka Nigara, Tatsuya Kawada
    • Journal Title

      Solid State Ionics 178

      Pages: 307-312

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 固体酸化物燃料電池における破壊ダイナミクスの可視化法2007

    • Author(s)
      福井健一, 佐藤一永, 水崎純一郎, 斉藤和己, 沼尾正行
    • Journal Title

      情報科学技術レターズ 6

      Pages: 5-8

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 雰囲気制御高温微重量天秤による金属酸化物の酸素不定比量の精密測定法2007

    • Author(s)
      大石昌嗣,八代圭司,水崎純一郎
    • Journal Title

      熱測定 解説 34(5)

      Pages: 206-213

    • NAID

      10029866566

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrode Performance at Hetero-interface of Perovskite-related Oxides, (La, Sr)CoO3-d / (La, Sr)2CoO4-d2007

    • Author(s)
      K. Yashiro, T. Nakamura, M. Sase, F. Hermes, K. Sato, T. Kawada, J. Mizusaki
    • Journal Title

      Electrochemical Society transactions 7(1)

      Pages: 1287-1292

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microstructural Changes of Ni/YSZ Cermet under Repeated Redox Reaction in Environmental Scanning Electron Microscope (ESEM)2007

    • Author(s)
      Y. Nakagawa, K. Yashiro, K. Sato, T. Kawada, J. Mizusaki
    • Journal Title

      Electrochemical Society transactions 7(1)

      Pages: 1373-1380

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrical Properties of Nb-Doped SrTiO3 Ceramics with Excess TiO2 for Anodes and Interconnects of SOFCs2007

    • Author(s)
      Fumimasa Horikiri, Li Qun Han, Naofumi Iizawa, Kazuhisa Sato, Keiji Yashiro, Tatsuya Kawada, Junichiro Mizusaki
    • Journal Title

      Electrochemical Society transactions 7(1)

      Pages: 1639-1644

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reliability Evaluation of SOFC under Simulated Operating Condition2007

    • Author(s)
      K. Sato, N. Imanaka, K. Fukui, M. Numao, S. Kyotani, K. Yashiro, T. Kawada, T. Hashida, J. Mizusaki
    • Journal Title

      Electrochemical Society transactions 7(1)

      Pages: 455-458

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen nonstoichiometry of B-site doped LaCrO32007

    • Author(s)
      Masatsugu Oishi, 他
    • Journal Title

      Solid State Ionics 178

      Pages: 307-312

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 固体酸化物燃料電池における破壊ダイナミクスの可視化法2007

    • Author(s)
      福井健一, 他
    • Journal Title

      情報科学技術レターズ 6

      Pages: 5-8

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrode Performance at Hetero-interface of Perovskite-related Oxides, (La, Sr)CoO3-d/(La, Sr)2CoO4-d2007

    • Author(s)
      K. Yashiro, 他
    • Journal Title

      ECS Transactions 7

      Pages: 1287-1292

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstructural Changes of Ni/YSZ Cermet under Repeated Redox Reaction in Environmental Scanning Electron Microscope2007

    • Author(s)
      Y. Nakagawa, 他
    • Journal Title

      ECS Transactions 7

      Pages: 1373-1380

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical Properties of Nb-Doped SrTiO3 Ceramics with Excess TiO2 for Anodes and Interconnects of SOFCs2007

    • Author(s)
      Fumimasa Horikiri, 他
    • Journal Title

      ECS Transactions 7

      Pages: 1639-1644

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 雰囲気制御高温微重量天秤による金属酸化物の酸素不定比量の精密測定法2007

    • Author(s)
      大石昌嗣, 他
    • Journal Title

      熱測定 34

      Pages: 206-213

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Concept of Chemical Potential Pumping Effect of Nonstoichiometric Oxides and the Nox Sensing Mechanism of the Perovskite-Type La0.5Sr0.5FeO32006

    • Author(s)
      J. Mizusaki, H. Ohama, K. Yashiro, T. Kawada
    • Journal Title

      Electrochemistry 74(12)

      Pages: 949-955

    • NAID

      130002150999

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tracking the onset of damage mechanism in ceria-based solid oxide fuel cells under simulated operating conditions2006

    • Author(s)
      K. Sato, H. Omura, T. Hashida, K. Yashiro, H. Yugami, T. Kawada, J. Mizusaki
    • Journal Title

      Journal of Testing and Evaluation 34(3)

      Pages: 246-250

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nonstoichimetry of the perovskite-type solid solution La0.9Ca0.1Cr1-yAlyO3-d2006

    • Author(s)
      J. Mizusaki, M. Hasegawa, K. Yashiro, H. Matsumoto, T. kawada
    • Journal Title

      Solid State Ionics 177

      Pages: 1925-1928

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrode reaction and microstructure of La0.6Sr0.4CoO3-d thin films2006

    • Author(s)
      M. Sase, J. Suzuki, K. Yashiro, T. Otake, A. Kaimai, T. Kawada, J. Mizusaki, H. Yugami
    • Journal Title

      Solid State Ionics 177

      Pages: 1961-1964

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] The influence of grain boundary on the conductivity of donor doped SrTiO32006

    • Author(s)
      F. Horikiri, L. Q. Han, A. Kaimai, T. Otake, K. Yashiro, T. Kawada, J. Mizusaki
    • Journal Title

      Solid State Ionics 177

      Pages: 2555-2559

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Charactaristics of Damage and Fracture Process of Solid Oxide Fuel Cells UnderSimulated Operating Conditions by Using AE Method2006

    • Author(s)
      K.Sato, T.Hashida, H.Yugami, K.Yashiro, T.Kawada, J.Mizusaki
    • Journal Title

      The Japanese Society for NDI, Progress in Acoustic Emission XIII

      Pages: 269-276

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] 銅系ペロブスカイト関連化合物の高温物性と機能 -特に2-1-4系La2-xSrxCuO4-dについて-2006

    • Author(s)
      水崎純一郎
    • Journal Title

      セラミックス 41(3)

      Pages: 189-194

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Concept of Chemical Potential Pumping Effect of Nonstoichiometric Oxides and the NO_x Sensing Mechanism of the Perovskite-Type La_<0.5>Sr_<0.5>FeO_32006

    • Author(s)
      J.Mizusaki
    • Journal Title

      Electrochemistry 74・12

      Pages: 949-955

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Tracking the onset of damage mechanism in ceria-based solid oxide fuel cells under simulated operating conditions2006

    • Author(s)
      K.Sato
    • Journal Title

      Journal of Testing and Evaluation 34・3

      Pages: 246-250

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Nonstoichimetry of the perovskite-type solid solution La_<0.9>Ca_<0.1>Cr_<1-y>Al_yO_<3-δ>2006

    • Author(s)
      J.Mizusaki
    • Journal Title

      Solid State Ionics 177

      Pages: 1925-1928

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Electrode reaction and microstructure of La_<0.6>Sr_<0.4>CoO_<3-δ> thin films2006

    • Author(s)
      M.Sase
    • Journal Title

      Solid State Ionics 177

      Pages: 1961-1964

    • Related Report
      2006 Annual Research Report
  • [Journal Article] The influence of grain boundary on the conductivity of donor doped SrTiO_32006

    • Author(s)
      F.Horikiri
    • Journal Title

      Solid State Ionics 177

      Pages: 2555-2559

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 銅系ペロブスカイト関連化合物の高温物性と機能 -特に2-1-4系La_<2-x>Sr_xCuO_<4-d>について- (解説)2006

    • Author(s)
      水崎純一郎
    • Journal Title

      セラミックス 41・3

      Pages: 189-194

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Mechanical Damage Evaluation of Solid Oxide Fuel Cells under Simulated Operationing Conditions2005

    • Author(s)
      Kazuhisa Sato, Toshiyuki Hashida, Keiji Yashiro, Hiroo Yugami, Tatsuya Kawada, Junichiro Mizusaki
    • Journal Title

      J. Ceram. Soc. Jpn 113(8)

      Pages: 562-564

    • NAID

      110002292383

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic chemical potential shift on the surface of nonstoichiometric oxides under non-equilibrium gas atmosphere2005

    • Author(s)
      Keiji Yashiro, Shigenori Onuma, Maya Sase, Atsushi Kaimai, Takanori Otake, Hiroshige Matsumoto, Tatsuya Kawada, Junichiro Mizusaki
    • Journal Title

      Solid State Ionics 176 (31-34)

      Pages: 2411-2416

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fracture properties of (CeO2)1-x(RO1.5)x (R = Y, Gd, and Sm; x = 0.02-0.20) ceramics2005

    • Author(s)
      T. Ishida, F. Iguchi, K. Sato, T. Hashida, H. Yugami
    • Journal Title

      Solid State Ionics 176(31-34)

      Pages: 2417-2421

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] (CeO2)1-x (SmO1.5)x電解質を用いた積層型燃料電池単セルの破壊挙動の評価に関する研究2005

    • Author(s)
      佐藤一永, 橋田俊之, 八代圭司, 湯上浩雄, 川田達也, 水崎純一郎
    • Journal Title

      粉末および粉末冶金 52(11)

      Pages: 836-839

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] (CeO2)1-x (YO1.5)xの合成と弾性特性の評価に関する研究2005

    • Author(s)
      佐藤一永, 橋田俊之, 鈴木研, 湯上浩雄, 川田達也, 水崎純一郎
    • Journal Title

      粉末および粉末冶金 52(11)

      Pages: 840-844

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical Damage Evaluation of Solid Oxide Fuel Cells under Simulated Operating Conditions2005

    • Author(s)
      K.Sato 他
    • Journal Title

      Journal of Ceramic Society of Japan 113(8)

      Pages: 562-564

    • NAID

      110002292383

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Catalytic chemical potential shift on the surface of nonstoichiometric oxides under nonequilibrium gas atmosphere2005

    • Author(s)
      K.Yashiro他
    • Journal Title

      Solid State Ionics 176(31-34)

      Pages: 2411-2416

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Fracture properties of (CeO_2)_<1-x>(RO_<1.5>)_x (R=Y, Gd, and Sm ; x=0.02-0.20) ceramics2005

    • Author(s)
      T.Ishida 他
    • Journal Title

      Solid State Ionics 176(31-34)

      Pages: 2417-2421

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Microscopic states of water and methanol in Nafion membrane observed by NMR micro imaging2005

    • Author(s)
      J.Kawamura 他
    • Journal Title

      Solid State Ionics 176(31-34)

      Pages: 2451-2456

    • Related Report
      2005 Annual Research Report
  • [Journal Article] (CeO_2)_<1-x>(SmO_<1.5>)_x電解質を用いた積層型燃料電池単セルの破壊挙動の評価に関する研究2005

    • Author(s)
      佐藤一永 他
    • Journal Title

      粉末および粉末冶金 52(11)

      Pages: 836-839

    • NAID

      130000056253

    • Related Report
      2005 Annual Research Report
  • [Journal Article] (CeO_2)_<1-x>(YO_<1.5>)_xの合成と弾性特性の評価に関する研究2005

    • Author(s)
      佐藤一永 他
    • Journal Title

      粉末および粉末冶金 52(11)

      Pages: 840-844

    • NAID

      130000056254

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 高温環境下におけるセリア系セラミックスの破壊特性に関する研究2005

    • Author(s)
      佐藤一永他3名
    • Journal Title

      2004年度 傾斜機能材料論文集 (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Electrical properties and defect structure of niobia-doped ceria2004

    • Author(s)
      K. Yashiro, T. Suzuki, A. Kaimai, H. Matsumoto, Y. Nigara, T. Kawada, J. Mizusaki, J. Sfeir, J. Van herle
    • Journal Title

      Solid State Ionics 175(1-4)

      Pages: 341-344

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] In situ XRD study on oxygen-excess LaMnO32004

    • Author(s)
      S. Miyoshi, A. Kaimai, H. Matsumoto, K. Yashiro, Y. Nigara, T. Kawada, J. Mizusaki
    • Journal Title

      Solid State Ionics 175(1-4)

      Pages: 383-386

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chemical stability of La1 xSrxCrO3 in oxidizing atmospheres2004

    • Author(s)
      Shogo Miyoshi, Shigenori Onuma, Atsushi Kaimai, Hiroshige Matsumoto, Keiji Yashiro, Tatsuya Kawada, Junichiro Mizusaki, and Harumi Yokokawa
    • Journal Title

      J. Solid State Chem 177(11)

      Pages: 4112-4118

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chemical stability of La1-xSrxCrO3 in oxidizing atmosphere2004

    • Author(s)
      Shogo Miyoshi et al.
    • Journal Title

      Journal of Solid State Chemistry 177(11)

      Pages: 4112-4118

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Electrical properties and defect structure of niobia-doped ceria2004

    • Author(s)
      K.Yashiro et al.
    • Journal Title

      Solid State Ionics 175(1-4)

      Pages: 341-344

    • Related Report
      2004 Annual Research Report
  • [Journal Article] In situ XRD study on oxygen-excess LaMnO32004

    • Author(s)
      S.Miyoshi et al.
    • Journal Title

      Solid State Inoics 175(1-4)

      Pages: 383-386

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Hydrogen isotope sensor using high temperature proton conductor2004

    • Author(s)
      H.Matsumoto et al.
    • Journal Title

      Solid State Ionics 175(1-4)

      Pages: 491-495

    • Related Report
      2004 Annual Research Report
  • [Presentation] バトラーポルマー式の再検証 : 電荷移動律速と化学反応律速2008

    • Author(s)
      水崎純一郎
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京
    • Year and Date
      2008-12-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] Reaction kinetics and electrochemical stress of SOFC gas electrodes2008

    • Author(s)
      Junichiro Mizusaki, 他
    • Organizer
      2008 KOREA-JAPAN-CHINA SOFC SYMPOSIUM
    • Place of Presentation
      POHANG, KOREA
    • Year and Date
      2008-09-19
    • Related Report
      2008 Annual Research Report
  • [Presentation] Nanosize and Interfacial Effects in Nanoionics Materials2008

    • Author(s)
      Junichiro Mizusaki
    • Organizer
      Workshop on Thermodynamics of Nanostructured Materials and Materials under Exotic and Unusual Conditions
    • Place of Presentation
      Japan, Tokyo
    • Year and Date
      2008-08-11
    • Related Report
      2008 Final Research Report
  • [Presentation] Nanosize and Interfacial Effects in Nanoionics Materials2008

    • Author(s)
      Junichiro Mizusaki
    • Organizer
      Workshop on Thermodynamics of Nanostructured Materials and Materials under Exotic and Unusual Conditions
    • Place of Presentation
      東京
    • Year and Date
      2008-08-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] Carbon deposition and electrochemical reaction of anode for SOFC in methane containing atmosphere2008

    • Author(s)
      KYASHIRO, 他
    • Organizer
      Gordon Research Conferences, HIGH TEMPERATURE MATERIALS, PROCESSES & DIAGNOSTICS
    • Place of Presentation
      Waterville USA
    • Year and Date
      2008-07-22
    • Related Report
      2008 Annual Research Report
  • [Presentation] Evaluation Method for Mechanical Performance of Solid Oxide Fuel Cell under Simulated Operating Conditions2008

    • Author(s)
      Kazuhisa Sato, 他
    • Organizer
      ASME 6th International Fuel Cell Science, Engin eering & Technology Conference
    • Place of Presentation
      Denver, USA
    • Year and Date
      2008-06-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] n型SrTiO3単結晶を用いた高温ショットキーデバイスにおける障壁形成メカニズム2008

    • Author(s)
      堀切文正, 他
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      甲府
    • Year and Date
      2008-03-30
    • Related Report
      2008 Final Research Report
  • [Presentation] 環境制御SEMによる固体酸化物燃料電池燃料極の微細構造評価2008

    • Author(s)
      八代圭司, 他
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      甲府
    • Year and Date
      2008-03-29
    • Related Report
      2008 Final Research Report
  • [Presentation] 固体酸化物形燃料電池のメタン使用時の炭素析出と燃料極反応2008

    • Author(s)
      八代圭司, 他
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      甲府
    • Year and Date
      2008-03-29
    • Related Report
      2008 Final Research Report
  • [Presentation] In Situ Evalution of Reliability on SOFC Electrodes under Operating Condition2008

    • Author(s)
      Kazuhisa Sato
    • Organizer
      International Workshop on Irregular Porous Materials in Fuel Cells
    • Place of Presentation
      Japan, Sendai
    • Year and Date
      2008-02-21
    • Related Report
      2008 Final Research Report
  • [Presentation] セラミックス電解質・電極材料の導電性と応力場 : 特に安定化ジルコニアとカソード酸化物材料について2008

    • Author(s)
      泉徹, 他
    • Organizer
      第17回SOFC研究発表会
    • Place of Presentation
      東京
    • Related Report
      2008 Annual Research Report 2008 Final Research Report
  • [Presentation] バトラーボルマー式の再検証 : 電荷移動律速と化学反応律速2008

    • Author(s)
      水崎純一郎
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京
    • Related Report
      2008 Final Research Report
  • [Presentation] 欠陥化学に基づくSrTiO3を用いた高温電子・光デバイスの設計指針2008

    • Author(s)
      堀切文正, 他
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京
    • Related Report
      2008 Final Research Report
  • [Presentation] 水素-水蒸気雰囲気下における白金-Y添加BaCdO3界面の電極反応過程2008

    • Author(s)
      阿子島聡志, 他
    • Organizer
      第34回固体イオニクス討論会
    • Place of Presentation
      東京
    • Related Report
      2008 Final Research Report
  • [Presentation] Reaction kinetics and electrochemical stress of SOFC gas electrodes2008

    • Author(s)
      Junichiro Mizusaki, 他
    • Organizer
      2008 KOREA-JAPAN-CHINA SOFC SYMPOSIUM
    • Place of Presentation
      KOREA, POHANG
    • Related Report
      2008 Final Research Report
  • [Presentation] 固体酸化物燃料電池用セラミックスの機械的特性に及ぼす還元処理の影響に関する研究2008

    • Author(s)
      武山陽平, 他
    • Organizer
      M&M 2008 材料力学カンファレンス
    • Place of Presentation
      滋賀
    • Related Report
      2008 Final Research Report
  • [Presentation] Carbon deposition and electrochemical reaction of anode for SOFC in methane containing atmosphere2008

    • Author(s)
      K.YASHIRO, 他
    • Organizer
      Gordon Research Conferences, HIGH TEMPERATURE MATERIALS, PROCESSES & DIAGNOSTICS
    • Place of Presentation
      USA, Waterville
    • Related Report
      2008 Final Research Report
  • [Presentation] Evaluation Method for Mechanical Performance of Solid Oxide Fuel Cell under Simulated Operating Conditions2008

    • Author(s)
      Kazuhisa Sato, 他
    • Organizer
      ASME 6th International Fuel Cell Science, Engineering & Technology Conference
    • Place of Presentation
      USA, Denver
    • Related Report
      2008 Final Research Report
  • [Presentation] n型チタン酸ストロンチウムのショットキー界面を用いたデバイスの検討2008

    • Author(s)
      堀切文正, 他
    • Organizer
      第46回セラミックス基礎科学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Final Research Report
  • [Presentation] Bサイト混合系ペロブスカイト型酸化物LaCrO3の欠陥構造解析2007

    • Author(s)
      大石昌嗣, 他
    • Organizer
      第16回SOFC研究発表
    • Place of Presentation
      東京
    • Year and Date
      2007-12-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] SOFCの機械的損傷のその場観察2007

    • Author(s)
      佐藤一永, 他
    • Organizer
      第16回SOFC研究発表
    • Place of Presentation
      東京
    • Year and Date
      2007-12-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] イットリア安定化ジルコニアバルク材料におけるひずみと導電率の関係2007

    • Author(s)
      佐藤一永, 他
    • Organizer
      第16回SOFC研究発表
    • Place of Presentation
      東京
    • Year and Date
      2007-12-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 固体酸化物燃料電池の電極反応へのその場測定の適用2007

    • Author(s)
      八代圭司, 他
    • Organizer
      第16回SOFC研究発表
    • Place of Presentation
      東京
    • Year and Date
      2007-12-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] 高温導電性酸化物YSZバルク体におけるひずみと導電率の関係2007

    • Author(s)
      佐藤一永, 他
    • Organizer
      第33回固体イオニクス討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-12-08
    • Related Report
      2007 Annual Research Report
  • [Presentation] n型SrTiO3の欠陥化学2007

    • Author(s)
      堀切文正, 他
    • Organizer
      第33回固体イオニクス討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2007-12-07
    • Related Report
      2007 Annual Research Report
  • [Presentation] 酸化物の科学〜酸素の不定比組成が生み出すさまざまな性質 (招待講演)2007

    • Author(s)
      水崎純一郎
    • Organizer
      文部科学省原子力試験研究 新クロスオーバー研究合同シンポジウム(放射線研究の限界への挑戦 低線量域での生体反応と高線量域での燃料微細変化の予測)
    • Place of Presentation
      東京
    • Year and Date
      2007-11-12
    • Related Report
      2007 Annual Research Report
  • [Presentation] Nonstoichiometry, Conductivity, and Defect Equilibrium of BaCe0.9(Nd or Y)0.1O3 and Some Other Proton Conducting Perovskite-Type Oxides(Invited)2007

    • Author(s)
      J. Mizusaki, 他
    • Organizer
      Materials Science & Technology 2007 Conference and Exhibition
    • Place of Presentation
      Detroit, USA
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] 高温導電性セラミックスの薄膜化と電子物性・酸素不定比性2007

    • Author(s)
      八代圭司, 他
    • Organizer
      2007年電気化学秋季大会
    • Place of Presentation
      東京
    • Year and Date
      2007-09-19
    • Related Report
      2007 Annual Research Report
  • [Presentation] Determinant Factors for Kinetics and Reaction Path of Perovskite-Type Oxide Cathodes (invited)2007

    • Author(s)
      Junichiro Mizusaki
    • Organizer
      The 1st China-Japan Workshop on SOFC
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-07-06
    • Related Report
      2007 Annual Research Report
  • [Presentation] IN-SITU OBSERVATION OF Ni/ZIRCONIA ANODE FOR SOFC UNDER HYDROCARBON ATMOSPHERE2007

    • Author(s)
      M. Takase, 他
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-07-03
    • Related Report
      2007 Annual Research Report
  • [Presentation] ELECTRIC TRANSPORTATION PROPERTIES OF POLY-CRYSTALLINE Sr2Nb2O7 MATERIALS2007

    • Author(s)
      Liqun Han, 他
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-07-03
    • Related Report
      2007 Annual Research Report
  • [Presentation] OXYGEN NONSTOICHIOMETRY AND DEFECT STRUCTURE OF THE PEROVSKITE-TYPE OXIDES BaCe0.9M0.1O3-d(M=Y, Yb, Nd, Tb, and Sm)2007

    • Author(s)
      Masatsugu Oishi, 他
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-07-03
    • Related Report
      2007 Annual Research Report
  • [Presentation] SLOW RELAXATION KINETICS OF Sr(Zr, Y)O3 IN WET ATMOSPHERE2007

    • Author(s)
      Takase Kudo, 他
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-07-03
    • Related Report
      2007 Annual Research Report
  • [Presentation] DETERMINATION OF THE REACTION AREA IN GADOLINIA-DOPED CERIA ANODE FOR SOFC BY ELECTROCHEMICAL MEASUREMENTS2007

    • Author(s)
      Takashi Nakamura, 他
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-07-02
    • Related Report
      2007 Annual Research Report
  • [Presentation] DEFECT EQUILIBRIUM AND ELECTRON TRANSPORT IN THE BULK OF SINGLE CRYSTAL SrTi1-xNbxO3(x=0.01,0.001,0.0002)2007

    • Author(s)
      Fumimasa Horikiri, 他
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2007-07-02
    • Related Report
      2007 Annual Research Report
  • [Presentation] Electrical Properties of Nb-Doped SrTiO3 Ceramics with Excess TiO2 for Anodes and Interconnects of SOFCs2007

    • Author(s)
      Fumimasa Horikiri, 他
    • Organizer
      10th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-06-07
    • Related Report
      2007 Annual Research Report
  • [Presentation] Electrochemical Behaviors of Mixed Conducting Oxide Anode for SOFC2007

    • Author(s)
      Takashi Nakamura, 他
    • Organizer
      10th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-06-07
    • Related Report
      2007 Annual Research Report
  • [Presentation] Microstructural Changes of Ni/YSZ Cermet under Repeated Redox Reaction in Environmental Scanning Electron Microscope(ESEM)2007

    • Author(s)
      Y. Nakagawa, 他
    • Organizer
      10th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-06-07
    • Related Report
      2007 Annual Research Report
  • [Presentation] Reliability Evaluation of SOFC under Simulated Operating Condition2007

    • Author(s)
      K. Sato, 他
    • Organizer
      10th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-06-06
    • Related Report
      2007 Annual Research Report
  • [Presentation] Electrode Performance at Hetero-interface of Perovskite-related Oxides,(La, Sr)CoO3-d/(La, Sr)2CoO4-d2007

    • Author(s)
      K. Yashiro, 他
    • Organizer
      10th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2007-06-05
    • Related Report
      2007 Annual Research Report
  • [Presentation] 高温導電性酸化物La1-xSrxCoO3-d薄膜における電子物性と酸素不定比性2007

    • Author(s)
      水崎純一郎, 他
    • Organizer
      第33回固体イオニクス討論会
    • Place of Presentation
      名古屋
    • Related Report
      2008 Final Research Report 2007 Annual Research Report
  • [Presentation] Nonstoichiometry, Conductivity, and Defect Equilibrium of BaCe0.9(Nd or Y)0.1O3 and Some Other Proton Conducting Perovskite-Type Oxide2007

    • Author(s)
      J.Mizusaki, 他
    • Organizer
      Materials Science & Technology 2007 Conference and Exhibition
    • Place of Presentation
      America, Detroit
    • Related Report
      2008 Final Research Report
  • [Presentation] Determinant Factors for Kinetics and Reaction Path of Perovskite-Type Oxide Cathodes2007

    • Author(s)
      Junichiro Mizusaki
    • Organizer
      The First China-Japan Workshop on Solid Oxide Fuel Cells
    • Place of Presentation
      China
    • Related Report
      2008 Final Research Report
  • [Presentation] DEFECT EQUILIBRIUM AND ELECTRON TRANSPORT IN THE BULK OF SINGLE CRYSTAL SrTi1-xNbxO3(x=0.01, 0.001, 0.0002)2007

    • Author(s)
      Fumimasa Horikiri, 他
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      China, Shanghai
    • Related Report
      2008 Final Research Report
  • [Presentation] DETERMINATION OF THE REACTION AREA IN GADOLINIA-DOPED CERIA ANODE FOR SOFC BY ELECTROCHEMICAL MEASUREMENTS2007

    • Author(s)
      Takashi Nakamura, 他
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      China, Shanghai
    • Related Report
      2008 Final Research Report
  • [Presentation] IN-SITU OBSERVATION OF Ni/ZIRCONIA ANODE FOR SOFC UNDER HYDROCARBON ATMOSPHERE2007

    • Author(s)
      M.Takase, 他
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      China, Shanghai
    • Related Report
      2008 Final Research Report
  • [Presentation] OXYGEN NONSTOICHIOMETRY AND DEFECT STRUCTURE OF THE PEROVSKITE-TYPE OXIDES BaCe0.9M0.1O3-d(M=Y, Yb, Nd, Tb, and Sm)2007

    • Author(s)
      Masatsugu Oishi, Kazuhisa Sato, Keiji Yashiro, Tatsuya Kawada, Junichiro Mizusaki
    • Organizer
      16th International Conference on Solid State Ionics
    • Place of Presentation
      China, Shanghai
    • Related Report
      2008 Final Research Report
  • [Presentation] Compositional Effects on Sol-Gel Prepared Nano-Sized NiO-YSZ Composite2007

    • Author(s)
      G. J. Park, 他
    • Organizer
      第44回セラミックス基礎討論会国際セッション
    • Place of Presentation
      仙台
    • Related Report
      2008 Final Research Report
  • [Presentation] ナノ構造化による高温プロトン導電体の導電挙動への影響2005

    • Author(s)
      井坂真也, 他
    • Organizer
      2005年電気化学会秋季大会
    • Place of Presentation
      千葉
    • Related Report
      2008 Final Research Report
  • [Book] ナノイオニクス-最新技術とその展望-, (5章ナノイオニクス構造高機能固体酸化物形燃料電池の創製)2008

    • Author(s)
      水崎純一郎, (共著)
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Final Research Report
  • [Book] The 21st Century COE Program International COE of Flow Dynamics Lecture Series Volume 9, Nano-Mega Scale Flow Dynamics in Energy Systems, Chapter 2. Nano-Scale Energy and Mass Transport Phenomena Involved in Fuel Cell Processes2008

    • Author(s)
      Junichiro Mizusaki, Keiji Yashiro, (共著)
    • Publisher
      東北大学出版会
    • Related Report
      2008 Final Research Report
  • [Book] ナノイオニクス構造高機能固体酸化物形燃料電池の創製, ナノイオニクス-最新技術とその展望-監修 山口周2008

    • Author(s)
      水崎純一郎(分担著)
    • Publisher
      シーエムシー出版
    • Related Report
      2007 Annual Research Report
  • [Book] Chapter Two Nano-Scale Energy and Mass Transport Pheonomena Involved in Fuel Cell Processes: in Nano-Mega Sclae Flow Dynamics in Energy Systems, The 21st Century COE Program, International COE of Folw Dynamics, Lecture Series, Vol.9. Ed Shigenao Maruyama,2008

    • Author(s)
      Junichiro Mizusaki他(分担著)
    • Publisher
      Tohoku Univ. Press
    • Related Report
      2007 Annual Research Report
  • [Book] Charactaristics of Damage and Fracture Process of Solid Oxide Fuel Cells under Simulated Operating Conditions by Using AE Method in Progress in Acoustic Emission XIII2006

    • Author(s)
      K.Sato
    • Publisher
      The Japanese Society for NDI
    • Related Report
      2006 Annual Research Report
  • [Book] ナノコンポジットマテリアル, (5章ナノコンポジットセラミクスの応用 1.ナノ燃料電池)2005

    • Author(s)
      水崎純一郎, (共著)
    • Publisher
      フロンティア出版
    • Related Report
      2008 Final Research Report
  • [Book] 燃料電池の解析手法(高須・吉武・石原編)2005

    • Author(s)
      水崎純一郎 他 (分担著)
    • Total Pages
      12
    • Publisher
      化学同人
    • Related Report
      2005 Annual Research Report
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/labo/mizusaki/

    • Related Report
      2008 Final Research Report
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/labo/mizusaki/

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/labo/mizusaki/

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2004-04-01   Modified: 2018-03-28  

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