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パノスコピック組織制御による希土類錯体超分子発光体の構築とセンシング機能

Research Project

Project/Area Number 16080217
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionOsaka City University

Principal Investigator

築部 浩  Osaka City University, 大学院・理学研究科, 教授 (00144725)

Co-Investigator(Kenkyū-buntansha) 篠田 哲史  大阪市立大学, 大学院理学研究科, 助教授 (00285280)
Project Period (FY) 2004 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥42,300,000 (Direct Cost: ¥42,300,000)
Fiscal Year 2007: ¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 2006: ¥11,200,000 (Direct Cost: ¥11,200,000)
Fiscal Year 2005: ¥17,100,000 (Direct Cost: ¥17,100,000)
Fiscal Year 2004: ¥8,000,000 (Direct Cost: ¥8,000,000)
Keywords希士類錯体 / 発光 / トランスフェリン / センシング / 分子認識 / ナノスケール / アミノ酸 / 複核錯体 / 希土類錯体 / 希土類発光 / アニオンセンシング / デンドリー / トリポード / ヒスタグタンパク / 超分子錯体 / 発光体 / ナノサイズ / 組織制御 / センシング材料 / 超分子 / ユウロピウム錯体 / トリポード配位子
Research Abstract

希土類錯体は,ダイナミックな電子構造や多様な配位化学に基づいた興味ある分子認識機能や光センシング機能を発現できる。本特定領域研究では,特徴ある合成配位子を含む発光性希土類錯体系のナノサイズ化を図り,超分子組織制御と新機能設計のための開発指針を確立するとともに,希士類科学や物質科学に新たな視点を与え,希士類系機能物質創製の基盤を築くことを目的とした。特に,ナノ配位空間を与えるテーラーメイド希士類錯体やデンドリマー希士類錯体,タンパク希士類錯体複合体などの発光性希土類錯体群を新たに創製するとともに、これらの特性に応じた階層的組織化法への展開を図り、分子認識機能と希士類発光特性の高次化とビジュアル・センシング機能材料の開発を続けた。本年度は,新たにケージ型閉鎖空間内に3d/4f金属中心を配置した複核錯体を系統的に合成し,これらが優れた増感発光特性をもつとともに,二つ金属中心を基軸とした「ねじれ運動」を行う分子カムとして機能することを明らかにした。また,近赤外発光特性を示す中性希土類錯体を活用した新たなアミノ酸発光センシング系を構築し,神経伝達に関与するアスパラギン酸やグルタミン酸に対して選択な応答機能を発揮するデバイスを開発した。さらに,pH応答機能を賦与したトランスフェリンタンパクー希土類錯体をマイクロメーターサイズを有するポリマービーズ上に固定化した希土類錯体型チップを開発するなどナノ材料化を目指した展開をも図った。

Report

(4 results)
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (30 results)

All 2008 2007 2006 2005 2004 Other

All Journal Article (17 results) (of which Peer Reviewed: 6 results) Presentation (9 results) Book (3 results) Remarks (1 results)

  • [Journal Article] Lanthanide Metal Complex-Based Membrane Electrodes for Sensing of Biological Amino Alcohols2008

    • Author(s)
      R. Mahajan, R. Kaur, S. Shinoda, H. Tsukube
    • Journal Title

      Journal of Alloys and Compounds 451

      Pages: 578-581

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transferrin-Terbium Complexes as Luminescent pH Sensing Devices2008

    • Author(s)
      Y. Kataoka, S. Shinoda, H. Tsukube
    • Journal Title

      Journal of Nanoscience and Nanotechnology (未定)(印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental and Theoretical Approaches toward Anion-Responsive Tripod-Lanthanide Complexes2008

    • Author(s)
      Y. Kataoka, D. Paul, H. Miyake, T. Yaita, E. Miyoshi, H. Mori, S. Tsukamoto, H. Tatewaki, S. Shinoda, H. Tsukube
    • Journal Title

      Chemistry:A European Journal (未定)(印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dendrimer Container for Anion-Responsive Lanthanide Complexation and on-off Switchable Near-Infrared Luminescence2007

    • Author(s)
      H. Tsukube, Y. Suzuki, D. Paul, Y. Kataoka, S. Shinoda
    • Journal Title

      Chemical Communications

      Pages: 2533-2535

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Cl^- Anion Responsive Luminescent Eu^<3+> Complex with a Chiral Tripode2007

    • Author(s)
      Y. Kataoka, D. Paul, H. Miyake, S. Shinoda, H. Tsukube
    • Journal Title

      Dalton Transactions

      Pages: 2784-2791

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lanthanide Complex Strategy for Detection and Separation of Histidine-Tagged Protein2007

    • Author(s)
      H. Tsukube, K. Yano, S. Shinoda
    • Journal Title

      Chemistry Letters 36

      Pages: 554-555

    • NAID

      10018881250

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lanthanide Complex Strategy for Detection and Separation of Histidine-Tagged Proteins2007

    • Author(s)
      Hiroshi Tsukube
    • Journal Title

      Chem. Lett. 36

      Pages: 554-555

    • NAID

      10018881250

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Dendrimer Container for Anion-Responsive Lanthanide Complexation and "ON-OFF" Switchable Near-Infrared Luminescence2007

    • Author(s)
      Hiroshi Tsukube
    • Journal Title

      Chem. Commum. (印刷中)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] CD分光法を活用する機能性金属錯体の開発 : キラリティーヤンシングとらせんスイッチング2006

    • Author(s)
      三宅 弘之
    • Journal Title

      JASCO REPORT 48

      Pages: 19-25

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Anion Sensing with Luminescent Tris(β-diketonato)europium(III) Complexes and Naked-Eye Detection of Floride Anion2006

    • Author(s)
      Hiroshi Tsukube
    • Journal Title

      Bull. Chem.. Soc. Japn. 79

      Pages: 725-730

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Anion Sensing with Luminescent Tris(β-diketonate) europium (III) Complexes and Naked-Eye Detection of Fluoride Anion2006

    • Author(s)
      H.Tsukube, A.Onimaru, S.Shinoda
    • Journal Title

      Bull.Chem.Soc.Jpn. 79(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Cholesterol-Armed Cyclens for Helical Metal Complexes Offering Chiral Self-Aggregation and Sensing of Amino Acid Anions in Aqueous Solutions.2005

    • Author(s)
      S.Shinoda, T.Okazaki, H.Tsukube 他3名
    • Journal Title

      J.Org.Chem. 70

      Pages: 1835-1843

    • Related Report
      2005 Annual Research Report
  • [Journal Article] キラリティーを活用する金属イオン認識系および希土類光センシング系の構築2005

    • Author(s)
      篠田 哲史, 片岡悠美子, 築部 浩
    • Journal Title

      有機合成化学協会誌 63

      Pages: 1209-1217

    • NAID

      10017076939

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Cholesterol-Armed Cyclens for Helical Metal Complexes Offering Chiral Self-Aggregation and Sensing of Amino Acid Anions in Aqueous Solutions2005

    • Author(s)
      S.Shinoda, T.Okazaki, T.N.Player, H.Misaki, K.Hori, H.Tsukube
    • Journal Title

      Journal of Organic Chemistry 70

      Pages: 1835-1843

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Lipophilic Lanthanide Tris(β-diketonate) Complexes as an Ionophores of Cl^- Anion-Selective Electrodes2004

    • Author(s)
      R.K.Mahajan, I.Kaur, R.Kaur, A.Onimaru, S.Shinoda, H.Tsukube
    • Journal Title

      Analytical Chemistry 76

      Pages: 7354-7359

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Naked Eye Detection of F^- Anion with Luminescent Europium Complexes2004

    • Author(s)
      H.Tsukube, A.Onimaru, S.Shinoda
    • Journal Title

      Chemical Sensors 20B

      Pages: 482-483

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Tuning of Anion Luminescence Sensing via Ligand Architecture of Lanthanide Complexes2004

    • Author(s)
      Y.Kataoka, S.Shinoda, H.Miyake, H.Tsukube
    • Journal Title

      Chemical Sensors 20B

      Pages: 484-485

    • Related Report
      2004 Annual Research Report
  • [Presentation] イッテルビウム錯体を活用するアミノ酸近赤外発光センサー2008

    • Author(s)
      築部 浩、矢野 径子、篠田 哲史
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京、立教大学
    • Year and Date
      2008-03-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] 発光性希土類錯体を活用する分子認識化学2007

    • Author(s)
      築部 浩
    • Organizer
      第20回配位化合物の光化学討論会(特別講演)
    • Place of Presentation
      兵庫県、舞子ビラ
    • Year and Date
      2007-08-07
    • Related Report
      2007 Annual Research Report
  • [Presentation] Molecular Recognition and Sensing with Luminescent Lanthanide Complexes2007

    • Author(s)
      H. Tsukube
    • Organizer
      International Symposium on Nanoscience and Photoscience(招待講演)
    • Place of Presentation
      奈良先端科学技術大学院大学
    • Year and Date
      2007-07-21
    • Related Report
      2007 Annual Research Report
  • [Presentation] 希土類-レニウム複核錯体による効率的な可視-近赤外変換2007

    • Author(s)
      篠田 哲史、杉本 秀樹、築部 浩
    • Organizer
      第24回希土類討論会
    • Place of Presentation
      東京都、学術情報総合センター
    • Year and Date
      2007-05-17
    • Related Report
      2007 Annual Research Report
  • [Presentation] キラルなトリポード配位子を活用したアニオン応答性発光Eu(III)錯体の創製2007

    • Author(s)
      片岡 悠美子、Dharam Paul、三宅 弘之、篠田 哲史、築部 浩
    • Organizer
      モレキュラーキラリティー2007
    • Place of Presentation
      東京都、東京理科大学(神楽坂キャンパス)
    • Year and Date
      2007-05-15
    • Related Report
      2007 Annual Research Report
  • [Presentation] Rhenium Complex as an Efficient Light-havesting Antenna for Lanthanide Near-Infrared Luminescence2007

    • Author(s)
      S. Shinoda, H. Sugimoto, H. Tsukube
    • Organizer
      The 5th International Conference on Rare Earth Development and Applications
    • Place of Presentation
      中国、内モンゴル、Baotou
    • Related Report
      2007 Annual Research Report
  • [Presentation] Anion-dependent Luminescence Properties of Eu(II)-Crown Ether Complexes Generated by Chemical Reduction2007

    • Author(s)
      S. Shinoda, M. Nishioka, H. Tsukube
    • Organizer
      The 5th International Conference on Rare Earth Development and Applications
    • Place of Presentation
      中国、内モンゴル、Baotou
    • Related Report
      2007 Annual Research Report
  • [Presentation] Dendrimer Container for Lanthanide Complexation and Switchable Near-Infrared Luminescence2007

    • Author(s)
      H. Tsukube, Y. Suzuki, D. Paul, Y. Kataoka, S. Shinoda
    • Organizer
      5th International Dendrimer Symposium
    • Place of Presentation
      フランス,Toulouse
    • Related Report
      2007 Annual Research Report
  • [Presentation] Self-Assembly of Guanine Induced by Lanthanide Complexation2007

    • Author(s)
      S. Shinoda, T. Nogichi, H. Tsukube
    • Organizer
      12th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      兵庫県、淡路夢舞台国際会議場
    • Related Report
      2007 Annual Research Report
  • [Book] Heterocyclic Supramolecules (in"Topics in Heterocyclic Chemistry" Series), 分担箇所 Chapter 1.Molecular Recognition with Designed Heterocycles and Their Lanthanide Complexes2008

    • Author(s)
      S. Mameri, S. Shinoda, H. Tsukube
    • Total Pages
      42
    • Publisher
      Springer Berlin/Heidelberg(印刷中)
    • Related Report
      2007 Annual Research Report
  • [Book] 希土類の材料技術(分担箇所30章第3節「希土類錯体型分子認識ツールの設計と応用」)2008

    • Author(s)
      築部 浩、篠田 哲史
    • Total Pages
      7
    • Publisher
      エヌ・テイー・エス出版(印刷中)
    • Related Report
      2007 Annual Research Report
  • [Book] Handbook on the Physics and Chemistry of Rare Earths, vol.352005

    • Author(s)
      S.Shinoda, H.Miyake, H.Tsukube
    • Total Pages
      389
    • Publisher
      Elsevier
    • Related Report
      2005 Annual Research Report
  • [Remarks]

    • URL

      http://www.sci.osaka-cu.ac.jp/chem/func/publication.html

    • Related Report
      2007 Annual Research Report

URL: 

Published: 2004-04-01   Modified: 2018-03-28  

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