Organoheteroatom Chemistry Based on Transition Metal Catalysis

• Project/Area Number: 16109001
• Research Category: Grant-in-Aid for Scientific Research (S)
• Allocation Type: Single-year Grants
• Research Field: Chemical pharmacy
• Research Institution: Tohoku University
• Principal Investigator: YAMAGUCHI Masahiko Tohoku University, 原子分子材料科学高等研究機構, 教授 (30158117)
• Co-Investigator(Kenkyū-buntansha): AMEMIYA Ryo 東北大学, 大学院・薬学研究科, 助教 (20359532) ; NISHIMURA Yoshio 東北大学, 大学院・薬学研究科, 助手 (60431516)
• Project Period (FY): 2004 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥117,130,000 (Direct Cost: ¥90,100,000、Indirect Cost: ¥27,030,000); Fiscal Year 2008: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000); Fiscal Year 2007: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000); Fiscal Year 2006: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000); Fiscal Year 2005: ¥26,520,000 (Direct Cost: ¥20,400,000、Indirect Cost: ¥6,120,000); Fiscal Year 2004: ¥48,490,000 (Direct Cost: ¥37,300,000、Indirect Cost: ¥11,190,000)
• Keywords: 遷移金属触媒 / イオウ / リン / 付加反応 / 単結合メタセシス / 遷移金属 / 触媒 / 有機合成 / フルオロベンゼン / 芳香族スルフイド / 芳香族スルフィド / 有機イオウ化合物 / ロジウム触媒 / パラジウム触媒 / ホスホニウム塩 / 酸化還元反応 / アルキルチオ交換反応 / CS結合切断 / チオイソニトリル / イオウ単体 / CH結合活性化 / チオアセチレン / アルキニルホスフィン

Research Abstract

経済性, 省エネルギーと環境調和性に対する社会的要請に合致した有機イオウ・リン化合物の遷移金属触媒合成法を開発した. ロジウムとパラジウム触媒を用いる新規な合成反応を多数見いだし, 有用物質の提供を可能とした。なかでも, 付加反応およびC-H置換反応を効率的に行って短工程化を実現した. また, 平衡反応が重要であることを示し, 周期表を活用する新反応開発の方法論を提示した.

Research Products

• [Journal Article] Rhodium-Catalyzed Thiophosphinoylation Reaction of 1,2-Dienes wuth Diphosphine Disulfides (2009)
  • Author(s): M. Arisawa, and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 50 Pages: 45-47
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Methylthio Transfer Reaction between Ketone α-Positions : Reversible Single-Bond Metathesis of C-S and C-H Bonds (2009)
  • Author(s): M. Arisawa, K. Suwa, T. Ishikawa, and M. Yamaguchi
  • Journal Title: Org. Lett 11 Pages: 625-627
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Methylthio Transfer Reaction between Ketone a -Positions : Reversible Single-Bond Metathesis of C-S and C-H Bonds (2009)
  • Author(s): M. Arisawa, K. Suwa, T. Ishikawa, and M. Yamaguchi
  • Journal Title: Org. Let 11 Pages: 625-627
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Thiophosphinoylation Reaction of 1,2-Dienes wuth Diphosphine Disulfides (2009)
  • Author(s): M. Arisawa, and M. Yamaguchi
  • Journal Title: Tetrahedron Letters 50 Pages: 45-47
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Addition Reaction of Diphosphine Disul fide to Aldehydes and Ketones (2009)
  • Author(s): M. Arisawa, and M. Yamaguchi
  • Journal Title: Tetrahedron Letters 50(in press)
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Substitution Reaction of Aryl Fluorides With Disulfides : p-Orientation in the Polyarylthiolation of Polyfluorobenzenes (2008)
  • Author(s): M. Arisawa, T. Suzuki, T. Ishikawa, and M. Yamaguchi
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 12214-12215
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Alkylthio Exchange Reaction of Thioester and Disulfide (2008)
  • Author(s): M. Arisawa, T. Kubota, and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 49 Pages: 1975-1978
  • Peer Reviewed
• [Journal Article] Two types of rhodium-catalyzed CS/CS metathesis reactions : formation of CS/CS bonds and CC/SS bonds (2008)
  • Author(s): M. Arisawa, Y. Tagami, and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 49 Pages: 1593-1597
  • Peer Reviewed
• [Journal Article] Transition Metal-Catalyzed Synthesis of Organosulfur Compounds (2008)
  • Author(s): M. Arisawa and M. Yamaguchi
  • Journal Title: Pure Appl. Chemi. 80 Pages: 993-1003
  • Peer Reviewed
• [Journal Article] Trichlorogallium and trialkylgalliums in organic synthesis (2008)
  • Author(s): M. Yamaguchi and Y. Nishimura
  • Journal Title: Chem. Commun. Pages: 35-48
  • Peer Reviewed
• [Journal Article] (Z)-Selective Witting and Corey-Chaykovsky reactions of propargyl ylides using trialkylgallium bases (2008)
  • Author(s): Y. Nishimura, T. Shiraishi, and M. Yamaguchi
  • Journal Title: Tetrahedron Letters 49 Pages: 3492-3495
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Substitution Reaction of Aryl Fluorides With Disulfides : p-Orientation in the Polyarylthiolation of PolyfluorobenzenesJ (2008)
  • Author(s): M. Arisawa, T. Suzuki, T. Ishikawa, and M. Yamaguchi
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 12214-12215
  • Peer Reviewed
• [Journal Article] Trichlorogallium and trialkylgalliums in organic synthesis. (2008)
  • Author(s): M. Yamaguchi and Y. Nishimura
  • Journal Title: Chem. Commun. 35 Pages: 35-48
  • Peer Reviewed
• [Journal Article] Rhodium-Catalyzed Alkylthio Exchange Reaction of Thioester and Disulfide (2008)
  • Author(s): M. Arisawa, T. Kubota, and M. Yamaguchi
  • Journal Title: Tetrahedron Letters 49 Pages: 1975-1978
  • Peer Reviewed
• [Journal Article] Two types of rhodium-catalyzed CS/CS metathesis reactions: formation of CS/CS bonds and CC/SS bonds (2008)
  • Author(s): M. Arisawa, Y. Tagami, and M. Yamaguchi
  • Journal Title: Tetrahedron Letters 49 Pages: 1593-1597
  • Peer Reviewed
• [Journal Article] Transition Metal-Catalyzed Synthesis of Organosulfur Compounds (2008)
  • Author(s): M. Arisawa and M. Yamaguchi
  • Journal Title: Pure and Applied Chemistry 80 Pages: 993-1003
  • Peer Reviewed
• [Journal Article] 有機リンおよびイオウ化合物の遷移金属触媒合成 (2007)
  • Author(s): 有澤美枝子・山口雅彦
  • Journal Title: 有機合成化学協会誌 Vol.65 Pages: 1213-1224
  • NAID: 10020007202
  • Peer Reviewed
• [Journal Article] Gallium Trichloride-Catalyzed Exhaustive α-Ethynylation Reaction of 1-Silylacetylenes (2007)
  • Author(s): R. Amemiya, and M. Yamaguchi
  • Journal Title: Adv.Systh. Catal. 349 Pages: 1011-1014
  • Peer Reviewed
• [Journal Article] Gallium Trichloride-Catalyzed Exhaustive α-Ethynylation Reaction of 1-Silylacetylenes. (2007)
  • Author(s): R. Amemiya, and M. Yamaguchi
  • Journal Title: Adv. Systh. Catal 349 Pages: 1011-1014
  • Peer Reviewed
• [Journal Article] 有機リンおよびイオウ化合物の遷移金属触媒合成 (2007)
  • Author(s): 有澤美枝子・山口雅彦
  • Journal Title: 有機合成化学協会誌 65 Pages: 1213-1224
  • NAID: 10020007202
  • Peer Reviewed
• [Journal Article] Helix-dimer-random-coil Thermal Switching Process of Ethynylhelicene Heptamer Highly Sensitive to Its Environment. (2007)
  • Author(s): H. Sugiura, and M. Yamaguchi,
  • Journal Title: Chem. Lett. 36 Pages: 58-59
  • NAID: 10018662848
• [Journal Article] Synthesis and Structure of Optically Active 1,12-Diethyl- and 1,12-Diisopropylbenzo[c]phenanthrenes: An Isopropyl Group Can Be Smaller than a Methyl Group. (2007)
  • Author(s): H. Sugiura, D. Sakai, H. Otani, K. Teranishi, Y. Takahira, R. Amemiya, and M. Yamaguchi
  • Journal Title: Chem. Lett. 36 Pages: 72-73
  • NAID: 10018663015
• [Journal Article] Rhodium-Catalyzed Synthesis of 1-Alkynylphosphine Oxides from 1-Alkynes and Tetraphenylbiphosphine (2006)
  • Author(s): M. Arisawa, M. Onoda, C. Hori and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 47 Pages: 5211-5213
  • Peer Reviewed
• [Journal Article] α- Ethynylation Reaction of Ketones Using Catalytic Amounts of Trialkylgallium Base (2006)
  • Author(s): Y. Nishimura, R. Amemiya, and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 47 Pages: 1839-1843
  • Peer Reviewed
• [Journal Article] GaCl_3 Promoted One-Step α, α- Diethynylation and α, α-Diethenylation Reactions of Silyl Enol Ethers (2006)
  • Author(s): R. Amemiya, Y. Miyake, and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 47 Pages: 1797-1800
  • Peer Reviewed
• [Journal Article] RhCl_3-Catalyzed Disulfide Exchange Reaction Using Water Solvent in Homogeneous and Heterogeneous Systems (2006)
  • Author(s): M. Arisawa, A. Suwa, M. Yamaguchi
  • Journal Title: J. Org. Chem. 71 Pages: 1159-1168
  • Peer Reviewed
• [Journal Article] Palladium-Catalyzed Synthesis of 1-Alkylphosphonium Salts from 1-Alkenes (2006)
  • Author(s): M. Arisawa and M. Yamaguchi
  • Journal Title: J. Am. Chem. Soc. 128 Pages: 50-51
  • Peer Reviewed
• [Journal Article] GaCl_3 Promoted One-Step α, α- Diethynylation and α, α- Diethenylation Reactions of Silyl Enol Ethers. (2006)
  • Author(s): R. Amemiya, Y. Miyake, and M. Yamaguchi,
  • Journal Title: Tetrahedron Lett., 47 Pages: 1797-1800
• [Journal Article] α- Ethynylation Reaction of Ketones Using Catalytic Amounts of Trialkylgallium Base. (2006)
  • Author(s): Y. Nishimura, R. Amemiya, and M. Yamaguchi,
  • Journal Title: Tetrahedron Lett. 47 Pages: 1839-1843
• [Journal Article] Rhodium-Catalyzed Synthesis of 1-Alkynylphosphine Oxides from 1-Alkynes and Tetraphenylbiphosphine. (2006)
  • Author(s): M. Arisawa, M. Onoda, C. Hori and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 47 Pages: 5211-5213
• [Journal Article] Triethylgallium as Non-Nucleophilic Base to Generate Enolates from Ketones. (2006)
  • Author(s): Y. Nishimura, Y. Miyake, R. Amemiya, and M. Yamaguchi
  • Journal Title: Org. Lett 8 Pages: 5077-5080
• [Journal Article] Palladium-Catalyzed Synthesis of 1-Alkylphosphonium Salts from 1-Alkenes. (2006)
  • Author(s): M.Arisawa, M.Yamaguchi
  • Journal Title: J.Am.Chem.Soc. 128 Pages: 50-51
• [Journal Article] Synthesis and Ring Size Effect of Macrocyclic Ethynylhelicene Oligomers. (2006)
  • Author(s): Y.Takahira, H.Sugiura, M.Yamaguchi
  • Journal Title: J.Org.Chem. 71 Pages: 763-767
• [Journal Article] Synthesis of Helicenediamine Oligomers and Their Formation of Multilayer Structures in Aqueous Solvents. (2006)
  • Author(s): J.Mizukami, H.Sugiura, M.Yamaguchi, K.Mushiake
  • Journal Title: Bull.Chem.Soc.Jpn. 79 Pages: 317-332
  • NAID: 10017271784
• [Journal Article] RhCl_3-Catalyzed Disulfide Exchange Reaction Using Water Solvent in Homogeneous and Heterogeneous Systems. (2006)
  • Author(s): M.Arisawa, A.Suwa, M.Yamaguchi
  • Journal Title: J.Org.Chem. 691 Pages: 1159-1168
• [Journal Article] GaCl_3 Promoted One-Step α,α-Diethynylation and α,α-Diethenylation Reactions of Silyl Enol Ethers. (2006)
  • Author(s): R.Amemiya, Y.Miyake, M.Yamaguchi
  • Journal Title: Tetrahedron Lett. 47 Pages: 1797-1800
• [Journal Article] α-Ethynylation Reaction of Ketones Using Catalytic Amounts of Trialkylgallium Base. (2006)
  • Author(s): Y.Nishimura, R.Amemiya, M.Yamaguchi
  • Journal Title: Tetrahedron Lett. 47 Pages: 1839-1843
• [Journal Article] 有機ヘテロ元素化合物を遷移金属触媒で合成! (2006)
  • Author(s): 山口 雅彦
  • Journal Title: 化学 61 Pages: 30-31
• [Journal Article] GaCl_3 in Organic Synthesis (2005)
  • Author(s): R. Amemiya, and M. Yamaguchi
  • Journal Title: Eur. J. Org. Chem. Pages: 5145-5150
  • Peer Reviewed
• [Journal Article] Equilibrating C - S Bond Formation by C - H and S - S Bond Metathesis. Rhodium - Catalyzed Alkylthiolation Reaction of 1- Alkynes with Disulfides (2005)
  • Author(s): M. Arisawa, K. Fujimoto, S. Morinaka, and M. Yamaguchi
  • Journal Title: J. Am. Chem. Soc. 127 Pages: 12226-12227
  • Peer Reviewed
• [Journal Article] Oxidation/Reduction Interconversion of Thiols and Disulfides Using Hydrogen and Oxygen Catalyzed by a Rhodium Complex (2005)
  • Author(s): M. Arisawa, C. Sugata, and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 46 Pages: 6097-6099
  • Peer Reviewed
• [Journal Article] Rhodium - Catalyzed Thiophosphinylation and Phosphinylation Reactions of Disulfides and Diselenides (2005)
  • Author(s): M. Arisawa, T. Ono, and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 46 Pages: 5669-5671
  • Peer Reviewed
• [Journal Article] Rhodium - Catalyzed Sulfur Atom Exchange Reaction Between Organic Polysulfides and Sulfur (2005)
  • Author(s): M. Arisawa, K. Tanaka, and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 46 Pages: 4797-4800
  • Peer Reviewed
• [Journal Article] One-Step Synthesis of Triethynylvinylmethanes and Tetraethynylmethanes by GaC_3 - Promoted Diethynylation of 1,4 - Enynes and 1,4 - Diynes (2005)
  • Author(s): R. Amemiya, K. Suwa, J. Toriyama, Y. Nishimura, and M. Yamaguchi
  • Journal Title: J. Am. Chem. Soc. 127 Pages: 8252-8253
  • Peer Reviewed
• [Journal Article] Rhodium - catalyzed Synthesis of Isothiocyanate from Isonitrile and Sulfur (2005)
  • Author(s): M. Arisawa, M. Ashikawa, A. Suwa, and M. Yamaguchi
  • Journal Title: Tetrahedron Lett. 46 Pages: 1727-1729
  • Peer Reviewed
• [Journal Article] One-Step Synthesis of Triethynylvinylmethanes and Tetraethynylmethanes by GaCl_3-Promoted Diethynylation of 1,4-Enynes and 1,4-Diynes. (2005)
  • Author(s): R.Amemiya, K.Suwa, J.Toriyama, Y.Nishimura, M.Yamaguchi
  • Journal Title: J.Am.Chem.Soc. 127 Pages: 8252-8253
• [Journal Article] Functionalized [3+3] Cycloalkynes : Substituent Effect on Self-Aggregation by Nonplanar π-π Interactions. (2005)
  • Author(s): H.Sugiura, Y.Takahira, M.Yamaguchi
  • Journal Title: J.Org.Chem. 70 Pages: 5698-5708
• [Journal Article] Oxidation/Reduction Interconversion of Thiols and Disulfides Using Hydrogen and Oxygen Catalyzed by a Rhodium Complex. (2005)
  • Author(s): M.Arisawa, C.Sugata, M.Yamaguchi
  • Journal Title: Tetrahedron Lett. 46 Pages: 6097-6099
• [Journal Article] Rhodium-Catalyzed Sulfur Atom Exchange Reaction Between Organic Polysulfides and Sulfur. (2005)
  • Author(s): M.Arisawa, K.Tanaka, M.Yamaguchi
  • Journal Title: Tetrahedron Lett. 46 Pages: 4797-4800
• [Journal Article] Rhodium-Catalyzed Thiophosphinylation and Phosphinylation Reactions of Disulfides and Diselenides. (2005)
  • Author(s): M.Arisawa, T.Ono, M.Yamaguchi
  • Journal Title: Tetrahedron Lett. 46 Pages: 5669-5671
• [Journal Article] Equilibrating C-S Bond Formation by C-H and S-S Bond Metathesis. Rhodium-Catalyzed Alkylthiolation Reaction of 1-Alkynes with Disulfides. (2005)
  • Author(s): M.Arisawa, K.Fujimoto, S.Morinaka, M.Yamaguchi
  • Journal Title: J.Am.Chem.Soc. 127 Pages: 12226-12227
• [Journal Article] GaCl_3 in Organic Synthesis. (2005)
  • Author(s): R.Amemiya, M.Yamaguchi
  • Journal Title: Eur.J.Org.Chem. Pages: 5145-5150
• [Journal Article] 安定カルベンの合成,構造と有機金属錯体触媒 (2005)
  • Author(s): 山口 雅彦, 有澤 美枝子
  • Journal Title: 化学 60 Pages: 72-73
• [Journal Article] Rhodium-catalyzed Synthesis of Isothiocyanate from Isonitrile and Sulfur. (2005)
  • Author(s): Mieko Arisawa, Masanori Ashikawa, Atsushi Suwa, Masahiko Yamaguchi
  • Journal Title: Tetrahedron Letters 46 Pages: 1727-1729
• [Journal Article] GaCl_3-Catalyzed Ortho-ethynylation Reaction of N-Benzylanilines. (2004)
  • Author(s): Ryo Amemiya, Akiko Fujii, Masahiko Yamaguchi
  • Journal Title: Tetrahedron Letters 45 Pages: 4333-4335
• [Journal Article] SnCl_4-Promnoted Ethenylation Reaction of Hydroxylated Heteroarenes. (2004)
  • Author(s): Kensuke Akamatsu, Ryo Amemiya, Masahiko Yamaguchi
  • Journal Title: HETEROCYCLES 63 Pages: 1839-1847
• [Journal Article] GaCl_3-Catalyzed α-Ethenylation Reaction of Ketone. (2004)
  • Author(s): Ryo Amemiya, Yoshio Nishimura, Masahiko Yamaguchi
  • Journal Title: SYNTHESIS 9 Pages: 1307-1314
• [Journal Article] Marked Effect of Aromatic Solvent on Unfolding Rate of Helical Ethynylhelicene Oligomer. (2004)
  • Author(s): Hiroki Sugiura, Yasuko Nigorikawa, Yuto Saiki, Keiichi Nakamura, Masahiko Yamaguchi
  • Journal Title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 126-45 Pages: 14858-14864
• [Presentation] 遷移金属触媒を用いる新しい炭素-リン結合生成反応の開発 (2008)
  • Author(s): 山口雅彦
  • Organizer: 第27回メディシナルケミストリーシンポジウム
  • Place of Presentation: 大阪
  • Year and Date: 2008-11-26
• [Presentation] 遷移金属触媒を用いる新しい炭素-リン結合生成反応の開発 (2008)
  • Author(s): 山口雅彦
  • Organizer: 第27回ミディシナルケミストリーシンポジウム
  • Place of Presentation: メルパルク大阪
  • Year and Date: 2008-11-26
• [Presentation] 有機イオウ・リン化合物の遷移金属触媒合成 (2008)
  • Author(s): 山口雅彦
  • Organizer: 近畿化学協会第3回例会
  • Place of Presentation: 仙台
  • Year and Date: 2008-10-30
• [Presentation] 有機ヘテロ元素化合物の遷移金属触媒合成 (2008)
  • Author(s): 山口雅彦
  • Organizer: 昭和薬科大学講演会
  • Place of Presentation: 東京
  • Year and Date: 2008-10-03
• [Presentation] 遷移金属触媒を用いる有機イオウ・リン化合物の合成反応 (2008)
  • Author(s): 山口雅彦
  • Organizer: 新日本石油講演会
  • Place of Presentation: 神奈川
  • Year and Date: 2008-07-02
• [Presentation] 遷移金属触媒反応によって有機イオウ・リン化合物を合成する (2008)
  • Author(s): 山口雅彦
  • Organizer: 創造機能化学講演会
  • Place of Presentation: 東京
  • Year and Date: 2008-06-10
• [Presentation] Transition Metal-catalyzed Synthesis of Organosulfur and Organophosphorous Compounds (2008)
  • Author(s): Masahiko Yamaguchi
  • Organizer: Taiwan-Japan International Symposium on Organic Chemistry and Molecular Science
  • Place of Presentation: National Taipei Unive rsity of Technology TaTwan
  • Year and Date: 2008-04-19
• [Presentation] 精密巨大分子の化学 (2008)
  • Author(s): 山口雅彦
  • Organizer: 日本化学会先端ウオッチング
  • Place of Presentation: 東京
  • Year and Date: 2008-03-28
• [Presentation] 有機へテロ元素化合物の遷移金属触媒合成 (2008)
  • Author(s): 山口雅彦
  • Organizer: 京都大学工学部講演会
  • Place of Presentation: 京都
  • Year and Date: 2008-01-19
• [Presentation] Transition Metal-catalyzed Synthesis of Organosulfur and Organophosphorous Compounds (2008)
  • Author(s): 山口雅彦
  • Organizer: Taiwan-Japan International Symposium on Organic Chemistry and Molecular Science
  • Place of Presentation: Taiwan(招待講演)
• [Presentation] 有機イオウ・リン化合物の遷移金属触媒合成 (2007)
  • Author(s): 山口雅彦
  • Organizer: 大正製薬講演会
  • Place of Presentation: 埼玉
  • Year and Date: 2007-12-12
• [Presentation] Transition Metal-catalyzed Synthesis of Organosulfur and Organophosphorous Compounds. (2007)
  • Author(s): Masahiko Yamaguchi
  • Organizer: International Symposium on Catalysis and Fine Chemicals 2007
  • Place of Presentation: Nanyang Technological University(シンガポール)
  • Year and Date: 2007-12-08
• [Presentation] Transition Metal-catalyzed Synthesis of Organosulfur and Organophosphorous Compounds. (2007)
  • Author(s): Masahiko Yamaguchi
  • Organizer: OMCOS14
  • Place of Presentation: なら100年会館
  • Year and Date: 2007-08-04
• [Presentation] Transition Metal-catalyzed Synthesis of Organosulfur and Organophosphorous Compounds (2007)
  • Author(s): 山口雅彦
  • Organizer: International Symposium on Catalysis and Fine Chemicals 2007
  • Place of Presentation: Singapore(招待講演)
• [Presentation] Transition Metal-catalyzed Synthesis of Organosulfur and Organophosphorous Compounds (2007)
  • Author(s): 山口雅彦
  • Organizer: The 13th Korea-Japan Seminar on Organic Chemistry
  • Place of Presentation: Korea(招待講演)
• [Presentation] Transition Metal-catalyzed Synthesis of Organosulfur and Organophosphorous Compounds (2007)
  • Author(s): 山口雅彦
  • Organizer: The14th OMCOS
  • Place of Presentation: Japan(招待講演)
• [Presentation] 有機へテロ元素化合物の遷移金属触媒合成 (2006)
  • Author(s): 山口雅彦
  • Organizer: 京都大学理学部講演会
  • Place of Presentation: 京都
  • Year and Date: 2006-12-06
• [Presentation] 遷移金属触媒を用いる有機ヘテロ元素化合物の合成反応 (2006)
  • Author(s): 山口雅彦
  • Organizer: 北海道大学工学部講演会
  • Place of Presentation: 札幌
  • Year and Date: 2006-11-29
• [Presentation] 有機イオウ・リン化合物の遷移金属触媒合成 (2006)
  • Author(s): 山口雅彦
  • Organizer: 関西学院大学講演会
  • Place of Presentation: 兵庫
  • Year and Date: 2006-09-09
• [Presentation] 有機へテロ元素化合物の遷移金属触媒合成 (2006)
  • Author(s): 山口雅彦
  • Organizer: 万有シンポジウム
  • Place of Presentation: 福岡
  • Year and Date: 2006-05-27
• [Presentation] Transition Metal-Catalyzed Synthesis of Organosulfur and Organophosphorous Compounds (2006)
  • Author(s): 山口雅彦
  • Organizer: 日本台湾交流会
  • Place of Presentation: 京都
  • Year and Date: 2006-04-22
• [Presentation] Transition Metal-catalyzed Synthesis of Organosulfur and Organophosphorous Compounds (2006)
  • Author(s): 山口雅彦
  • Organizer: The 5th IFOC
  • Place of Presentation: Japan(招待講演)
• [Presentation] Palladium-Catalyzed Synthesis of 1-Alkyphosphonimum Salts from 1-Alkenes (2006)
  • Author(s): 山口雅彦
  • Organizer: 1st International Conferrence of Cutting-Edge Organic Chemistry in Asia
  • Place of Presentation: Japan
• [Presentation] Transition Metal-Catalyzed Synthesis of Organosulfur and Organophosphorous Compounds (2006)
  • Author(s): 山口雅彦
  • Organizer: 2006 Japan-Taiwan Joint Symposium on Organic Chemistry
  • Place of Presentation: Japan(招待講演)
• [Presentation] Organic synthesis using organogallium compounds (2005)
  • Author(s): 山口雅彦
  • Organizer: PACIFICHM 2005
  • Place of Presentation: U.S.A(招待講演)
• [Presentation] Transition Metal-catalyzed Synthesis of Organosulfur and Organophosphorous Compounds (2005)
  • Author(s): 山口雅彦
  • Organizer: The 18th French-Japanese Symposium on Medicinal and Fine Chemistry
  • Place of Presentation: France(招待講演)
• [Book] Ga(III) Lewis A (2008)
  • Author(s): R. Amemiya and M. Yamaguchi
  • Publisher: WILEY-VCH
• [Book] Ga(III)Lewis Acids (2008)
  • Author(s): R. Amemiya and M. Yamaguchi
  • Total Pages: 29
  • Publisher: WILEY-VCH
• [Book] Recent Developments in Carbocation and Onium Ion Chemistry (2007)
  • Author(s): M. Arisawa, and M. Yamaguchi
  • Publisher: AMERICAN CHEMICAL SOCIETY
• [Book] Synthesis of Phosphonium Salts by Metal-Catalyzed Addition Reaction (2007)
  • Author(s): M. Arisawa and M. Yamaguchi
  • Total Pages: 16
  • Publisher: AMRICAN CHEMICAL SOCIETY
• [Book] Recent Developments in Carbocation and Onium Ion Chemistry (2007)
  • Author(s): M. Arisawa, and M. Yamaguchi
  • Total Pages: 528
  • Publisher: AMRICAN CHEMICAL SOCIETY
• [Book] Strategic Applications of Named Reactions in Organic Synthesis Background and Detailed Mechanisms (2006)
  • Author(s): 山口雅彦, 他
  • Publisher: 化学同人
• [Book] Strategic Applications of Named Reactions in Organic Synthesis Background and Detailed Mechanisms. (2006)
  • Author(s): 山口雅彦(訳分担)
  • Total Pages: 554
  • Publisher: 化学同人
• [Remarks]
  • URL: http://www.pharm.tohoku.ac.jp/~sekkei/yakan-home.html
• [Remarks] 山口雅彦、有機イオウ・リン化合物の遷移金属触媒合成、Organometallic News, 2-5 (2009)
• [Remarks] 山口雅彦、有機へテロ元素化合物を遷移金属触媒で合成! 化学 Vol.61 No.4 30-31 (2006)
• [Remarks] 宮城県第二高等学校講演会, 平成18年12月
• [Remarks] 福島県安積高等学校講演会, 平成18年9月
• [Remarks] 研究室のWeb
  • URL: http://www.pharm.tohoku.ac.jp/~sekkei/yakan-home.Html
• [Remarks] グローバルプログラム「分子系高次構造体化学国際教育研究拠点」のWeb
  • URL: http://iremc.pharm.tohoku.ac.jp/index_ja.html