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Research on energy transfer via nanocrystals and their new functionality as optical materials

Research Project

Project/Area Number 16201022
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural science
Research InstitutionKobe University

Principal Investigator

HAYASHI Shinji  Kobe University, Faculty of Engineering, Professor, 工学部, 教授 (50107348)

Co-Investigator(Kenkyū-buntansha) FUJII Minoru  Kobe University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (00273798)
YANAGI Hisao  Nara Institute of Science and Technology, Graduate School of Materials Science., Professor, 物質創成科学研究所, 教授 (00220179)
MORIWAKI Kazuyuki  Kobe University, Graduate School of Science and Technology, Associate Professor, 自然科学研究科, 助教授 (50322194)
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥40,300,000 (Direct Cost: ¥31,000,000、Indirect Cost: ¥9,300,000)
Fiscal Year 2006: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Fiscal Year 2005: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
Fiscal Year 2004: ¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Keywordsenergy transfer / nanocrystals / plasmon
Research Abstract

In this work, a new function of nanocrystals as "energy donor" or "energy transmitter" in an energy transfer process is studied. Followings are the list of results obtained in this work. 1. The mechanism of energy transfer from Si nanocrystals to Er ions is studied and the existence of two different energy transfer processes is revealed. 2. The evidence of the interaction between impurities (P and/or B atoms) in Si nanocrystals and Er ions is shown and efficient deexcitation of Er ions by Auger type energy transfer to impurities in Si nanocrystals is clarified. 3. The rate of energy transfer from Si nanocrystals to Er ions is shown to be modified by placing a metal thin film nearby. The results strongly suggest that the energy transfer efficiency can be enhanced by using a metal layer. 4. The enhancement of PL from Er in glasses by simultaneoulsy doping gold nanocrystals is demonstrated and the contribution of surface plasmon polaritons of Au nanocrystals for the enhancement is clarified. 5. Excitation of surface plasmon polaritons of a gold thin film by energy transfer from Si nanocrystals is demonstrated by placing a gold thin film and organic grating near Si nanocrystals.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (42 results)

All 2006 2005 2004

All Journal Article (39 results) Book (3 results)

  • [Journal Article] Size dependence of photoluminescence quantum efficiency of Si nanocrystals2006

    • Author(s)
      Satoru Miura
    • Journal Title

      Physical Review B 73

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Enhancement and suppression of energy transfer from Si nanocrystals to Er ions through a control of the photonic mode density2006

    • Author(s)
      Toshihiro Nakamura
    • Journal Title

      Physical Review B 74

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Polarization dependence of stimulated resonance Raman scattering from a single-crystal of biphenyl-capped thiophene2006

    • Author(s)
      Hisao Yanagi
    • Journal Title

      Japanese Journal of Applied Physics 45・1

      Pages: 483-487

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Enhancement of photoluminescence from Yb and Er co-doped Al_2O_3 films by an asymmetric metal cavity2006

    • Author(s)
      Nobuto Managaki
    • Journal Title

      Applied Physics Letters 88・4

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Stimulated resonance Raman scattering from dye-doped polymer waveguides2006

    • Author(s)
      Isao Sakata
    • Journal Title

      Applied Physics Letters 88

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Low threshold amplified spontaneous emission from near-infrared dye-doped polymer waveguide2006

    • Author(s)
      Kenichi Yamashita
    • Journal Title

      Applied Physics Letters 88

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Surface plasmon polariton mediated photoluminescence from excitons in silicon nanocrystals2006

    • Author(s)
      Eiji Takeda
    • Journal Title

      Applied Physics Letters 89

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Stimulated resonance Raman scattering from polyphenylenevinylene thin film waveguides2006

    • Author(s)
      Hisao Yanagi
    • Journal Title

      Applied Physics Letters 89・14

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Enhancement and suppression of energy transfer from Si nanocrystals to Er ions through a control of the photonic mode density2006

    • Author(s)
      Size dependence of photoluminescence quantum efficiency of Si nanocrystals
    • Journal Title

      Physical Review B 74

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Polarization dependence of stimulated resonance Raman scattering from a single-crystal of biphenyl-capped thiophene2006

    • Author(s)
      Hisao, Yanagi
    • Journal Title

      Japanese Journal of Applied Physics

      Pages: 483-487

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Enhancement of photoluminescence from Yb and Er co-doped Al2O3 films by an asymmetric metal cavity.2006

    • Author(s)
      Nobuto, Managaki
    • Journal Title

      Applied Physics Letters 88-4

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Surface plasmon polariton mediated photoluminescence from excitons in silicon nanocrystals.2006

    • Author(s)
      Eiji, Takeda
    • Journal Title

      Applied Physics Letters 89

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Stimulated resonance Raman scattering from dye-doped polymer waveguides.2006

    • Author(s)
      Isao, Sakata
    • Journal Title

      Applied Physics Letters 88

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Low threshold amplified spontaneous emission from near-infrared dye-doped polymer waveguide.2006

    • Author(s)
      Kenichi, Yamashita
    • Journal Title

      Applied Physics Letters 88

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Stimulated resonance Raman scattering from polyphenylenevinylene thin film waveguides.2006

    • Author(s)
      Hisao, Yanagi
    • Journal Title

      Applied Physics Letters 89-14

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Interaction between Er ions and shallow impurities in Si nanocrystals2005

    • Author(s)
      Kenji Imakita
    • Journal Title

      Physical Review B 71・11

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Spectrally resolved energy transfer from excitons in Si nanocrystals to Er ions2005

    • Author(s)
      Kenji Imakita
    • Journal Title

      Physical Review B 71・19

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Photoluminescence from impurity co-doped and compensated Si nanocrystals2005

    • Author(s)
      Minoru Fujii
    • Journal Title

      Applied Physics Letters 87・21

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Modification of energy transfer from Si nanocrystals to Er^<3+> near Au thin film2005

    • Author(s)
      Toshihiro Nakamura
    • Journal Title

      Physical Review B 72・23

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Enhancement of 1.54 micrometer emission from Er doped sol-gel SiO_2 films by Au nanoparticles doping2005

    • Author(s)
      Masanori Fukushima
    • Journal Title

      Journal of Applied Physics 98・2

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Photoluminescence from Si nanocrystals embedded in SiO_xN_y thin films2005

    • Author(s)
      Kimiaki Matsumoto
    • Journal Title

      Japanese Journal of Applied Physics 44・50

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Interaction between Er ions and shallow impurities in Si nanocrystals2005

    • Author(s)
      Minoru, Fujii
    • Journal Title

      Physical Review B 71-11

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Spectrally resolved energy transfer from excitons in Si nanocrystals to Er ions2005

    • Author(s)
      Kenji, Imakita
    • Journal Title

      pplied Physics Letters

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Photoluminescence from impurity co-doped and compensated Si nanocrystals2005

    • Author(s)
      Minoru, Fujii
    • Journal Title

      Physical Review B 71-19

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Modification of energy transfer from Si nanocrystals to Er3+ near Au thin film2005

    • Author(s)
      Toshihiro, Nakamura
    • Journal Title

      Physical Review B 72-23

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Enhancement of 1.54 micrometer emission from Er doped sol-gel SiO2 films by Au nanoparticles doping2005

    • Author(s)
      Masanori, Fukushima
    • Journal Title

      Journal of Applied Physics 98-2

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Photoluminescence from Si nanocrystals embedded in SiOxNy thin films2005

    • Author(s)
      Kimiaki, Matsumoto
    • Journal Title

      Japanese Journal of Applied Physics 44-50

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Size dependence of photoluminescence quantum efficiency of Si nanocrystals2005

    • Author(s)
      Satoru, Miura
    • Journal Title

      Physical Review B 73

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Photoluminescence from Impurity Co-doped and Compensated Si Nanocrystals2005

    • Author(s)
      Minoru Fujii
    • Journal Title

      Applied Physics Letters 87・21

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Spectrally resolved energy transfer from excitons in Si nanocrystals to Er ions2005

    • Author(s)
      Kenji Imakita
    • Journal Title

      Physical Review B 71-19

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Control of photoluminescence properties of Si nanocrystals by simultaneously doping n-and p-type impurities2004

    • Author(s)
      Minoru Fujii
    • Journal Title

      Applied Physics Letters 85・7

      Pages: 1158-1160

    • NAID

      120000946047

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Generation of singlet oxygen at room temperature mediated by energy transfer from photo-excited porous Si2004

    • Author(s)
      Minoru Fujii
    • Journal Title

      Physical Review B 70

    • NAID

      120000942418

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Chemical reaction mediated by excited states of Si nanocrystals-Singlet oxygen formation in solution2004

    • Author(s)
      Minoru Fujii
    • Journal Title

      Journal of Applied Physics 95・7

      Pages: 3689-3693

    • NAID

      120000946368

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Control of photoluminescence properties of Si nanocrystals by simultaneously doping n-and p-type impurities2004

    • Author(s)
      Minoru, Fujii
    • Journal Title

      pplied Physics Letters 85-7

      Pages: 1158-1160

    • NAID

      120000946047

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Generation of singlet oxygen at room temperature mediated by energy transfer from photo-excited porous Si2004

    • Author(s)
      Minoru, Fujii
    • Journal Title

      Physical Review B 70

    • NAID

      120000942418

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Chemical reaction mediated by excited states of Si nanocrystals-Singlet oxygen formation in solution2004

    • Author(s)
      Minoru, Fujii
    • Journal Title

      Journal of Applied Physics 95-7

      Pages: 3689-3693

    • NAID

      120000946368

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Control of Photoluminescence Properties of Si Nanocrystals by Simultaneously Doping n- and p-Type Impurities2004

    • Author(s)
      M.Fujii
    • Journal Title

      Applied Physics Letters 85・7

      Pages: 1158-1160

    • NAID

      120000946047

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Generation of Singlet Oxygen at Room Temperature Mediated by Energy Transfer from Photo-excited Porous Si2004

    • Author(s)
      M.Fujii
    • Journal Title

      Physical Review B 70・085311

      Pages: 1-5

    • NAID

      120000942418

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Chemical Reaction Mediated by Excited States of Si Nanocrystals-Singlet Oxygen Formation in Solution2004

    • Author(s)
      M.Fujii
    • Journal Title

      Journal of Applied Phtsics 95・7

      Pages: 3689-3693

    • NAID

      120000946368

    • Related Report
      2004 Annual Research Report
  • [Book] プラズモンナノ材料の設計と応用技術2006

    • Author(s)
      林真至(分担執筆)
    • Publisher
      シーエムシー出版
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Book] エコマテリアルハンドブックIII 2.2.6 金属ナノ粒子の光学応答2006

    • Author(s)
      林真至(分担執筆)
    • Publisher
      丸善株式会社
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] エコマテリアルハンドブック III 2.2.6金属ナノ粒子の光学応答2006

    • Author(s)
      林真至(分担執筆)
    • Publisher
      丸善株式会社
    • Related Report
      2006 Annual Research Report

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Published: 2004-04-01   Modified: 2016-04-21  

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