| Project/Area Number |
16205026
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Hokkaido University |
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Principal Investigator |
MURAKOSHI Kei Hokkaido University, Faculty of Science, Professor (40241301)
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| Co-Investigator(Kenkyū-buntansha) |
木口 学 北海道大学, 大学院・理学研究院, 助教 (70313020)
並河 英紀 北海道大学, 大学院・理学研究院, 助教 (30372262)
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| Project Period (FY) |
2004 – 2007
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| Project Status |
Completed (Fiscal Year 2007)
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| Budget Amount *help |
¥50,570,000 (Direct Cost: ¥38,900,000、Indirect Cost: ¥11,670,000)
Fiscal Year 2007: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2006: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2005: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Fiscal Year 2004: ¥28,470,000 (Direct Cost: ¥21,900,000、Indirect Cost: ¥6,570,000)
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| Keywords | energy conversion / quantum conductance / asymmetric architecture / optical property / surface / interface property / nano-contact / carbon nanotube / molecular separation / 選択励起 / 量子化伝道測定 / 分子架橋 / 脂質二分子膜 / 自発展開 / ブラウニアンラチェット / 単原子ワイヤ / 分子伝導 / 金属微小構造 / 表面増強ラマン / ナノチューブ・フラーレン / 量子細線 / 表面吸着イオン / 単原子鎖 / プラズモン吸収 / 電気化学電位 / 2次元規則配列構造 |
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| Research Abstract |
In this project, we have fabricated structurally well-defined metallic nano-architectures that are capable of energy conversion among thermal, photon, kinetic, and electro-chemical energies. Especially, we have concentrated three subjects below. First is a controlling of an electron conduction process in a metal atomic wire. In the atomic wire connected by a single atom junction, electron conduction characteristics can be controlled by external electro-chemical energy. We have succeeded in controlling of energy-and spin-selective electron conduction based on the electro-chemical potential at both electrode of the junction. Additionally, an in-situ measurement of vibrational spectrum has clarified the insertion process of a small molecule in the junction. Second is a conversion of photon energy to molecular vibration energy. To realize an effective conversion, we focused locally enhanced electric field around metal nano-architecture. Electrons in the architecture collectively oscillate by a light-irradiation with resonant energy. This causes highly enhanced electric field around the architecture. By measuring a Raman scattering signal from a single molecule situating at a close proximity of the architecture, we have found that the scattering cross-section was increased by the order of 10^10 compared with normal Raman process. Third is a controlling a molecular diffusion energy by using of metallic architecture. Two-dimensional array of metallic nano-architecture has demonstrated rectification ability concerning a collective flow of a molecular assembly. These research results in the present project will offers new molecular/electron manipulation, rectification, and detection systems in a future nano-devices.
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