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STUDIES ON STATIC AND DYNAMIC STRUCTURE OF EXPANDING FLUID ALKALI METALS BY USING SYNCHROTRON RADIATION

Research Project

Project/Area Number 16206063
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

TAMURA Kozaburo  Kyoto Univ., Graduate School of Engineering, Professor, 工学研究科, 教授 (30155262)

Co-Investigator(Kenkyū-buntansha) MATSUDA Kazuhiro  Kyoto Univ., Graduate School of Engineering, Assist. Professor, 工学研究科, 助手 (50362447)
INUI Masanori  Hiroshima Univ., Graduate School of Integrated Arts and Sciences, Associate Professor, 総合科学研究科, 助教授 (40213136)
HOSHINO Kozo  Hiroshima Univ., Graduate School of Integrated Arts and Sciences, Professor, 総合科学研究科, 教授 (30134951)
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥36,660,000 (Direct Cost: ¥28,200,000、Indirect Cost: ¥8,460,000)
Fiscal Year 2006: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2005: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2004: ¥27,950,000 (Direct Cost: ¥21,500,000、Indirect Cost: ¥6,450,000)
KeywordsSupercritical fluids / Synchrotron radiation / Inelastic x-ray scattering / Alkali metals / Electron gas / Negative dielectric function / High-Tc superconductors / Dynamics in fluids / 金属-非金属転移 / 高温高圧 / モリブデンセル
Research Abstract

Since Wigner's pioneering work, the anomalous behaviors of low-density electron gas has been extensively investigated A modern many-electron theory has predicted that interacting electron gas suffers a negative compressibility and the static dielectric-function (DF) becomes negative when electron density is sufficiently reduced. However, a problem has remained unsolved as to whether the low-density electron gas with negative DF really exists or not. We have measured x-ray diffraction (XD), small-angle x-ray scattering (SAXS) and inelastic x-ray scattering (IXS) of expanding fluid rubidium using synchrotron radiation at SPring-8 by reducing electron density down to the range where the DF has been theoretically predicted to become negative. It was clearly observed by the XD measurement that the interatomic distance decreases in spite of the fact that mean interatomic distance increases with expansion, suggesting that an attractive interaction among like charges, ions in this case, is enhanced. It was also found by the SAXS measurement that density fluctuations start to appear at the density where the DF becomes negative. From the IXS measurement we have obtained the dynamic structure-factor and the dispersion relation as a function of density. It was revealed that the sound velocity estimated from the dispersion relation at the small momentum-transfer region becomes large compared with the adiabatic sound velocity at the density where the DF becomes negative. These findings indicate that the observed structural features are evidence of the compressional instability and the existence of negative DF of three dimensional electron gas. The negative DF is especially interesting because electrons attract each other and electron-pairs can be generated in a medium of electron gas with negative DF, which gives a possibility of a new type of superconductors without assistance of phonon.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (56 results)

All 2007 2006 2005 2004 Other

All Journal Article (56 results)

  • [Journal Article] Instability of the electron gas in an expanding metal2007

    • Author(s)
      K.Matsuda
    • Journal Title

      Physical Review Letters 98

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Medium-range fluctuations accompanying the metal-nonmetal transition in expanded fluid Hg2007

    • Author(s)
      M.Inui
    • Journal Title

      Physical Review Letters 98

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Small-angle x-ray scattering measurements of expanded fluid Sein semiconductor-metal transition region using synchrotron radiation2007

    • Author(s)
      M.Inui
    • Journal Title

      Journal of Applied Crystallography 40

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Reverse Monte-Carlo analysis for small-angle scattering of expanded fluid Hg : Connection to the wide-angle structure factor2007

    • Author(s)
      K.Hagita
    • Journal Title

      Journal of Applied Crystallography 40

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] X-ray diffraction measurement of liquid As2Se3 by using third generation synchrotron radiation2007

    • Author(s)
      Y.Kaj ihara
    • Journal Title

      Journal of Non-Crystalline Solids 353

      Pages: 1985-1989

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Laser-induced pattern formation in liquid sulfur : An indication of laser-induced phase transition to ordered polymer2007

    • Author(s)
      Y.Sakaguchi
    • Journal Title

      The European Physical Journal E 22

      Pages: 315-324

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Instability of the electron gas in an expanding metal.2007

    • Author(s)
      K.Matsuda et al.
    • Journal Title

      Physical Review Letters 98

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Medium-range fluctuations accompanying the metal-nonmetal transition in expanded fluid Hg.2007

    • Author(s)
      M.Inui et al.
    • Journal Title

      Physical Review Letters 98

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Small-angle x-ray scattering measurements of expanded fluid Se in semiconductor-metal transition region using synchrotron radiation.2007

    • Author(s)
      M.Inui et al.
    • Journal Title

      Journal of Applied Crystallography 40

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Reverse Monte-Carlo analysis for small-angle scattering of expanded fluid Hg : Connection to the wide-angle structure factor.2007

    • Author(s)
      K.Hagita et al.
    • Journal Title

      Journal of Applied Crystallography 40

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] X-ray diffraction measurement of liquid As_2Se_3 by using third generation synchrotron radiation.2007

    • Author(s)
      Y.Kajihara et al.
    • Journal Title

      Journal of Non-Crystalline Solids 353

      Pages: 1985-1989

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Laser-induced pattern formation in liquid sulfur : An indication of laser-induced phase transition to ordered polymer.2007

    • Author(s)
      Y.Sakaguchi et al.
    • Journal Title

      The European Physical Journal E 22

      Pages: 315-324

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Instability of the electron gas in an expanding metal.2007

    • Author(s)
      K.Matsuda
    • Journal Title

      Physical Review Letters 98

      Pages: 964011-964014

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Medium-range fluctuations accompanying the metal-nonmetal transition in expanded Hg2007

    • Author(s)
      M.Inui
    • Journal Title

      Physical Review Letters (to be published)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Accumulation and Decay Processes in Photodarkening of Amorphous Chalcogenide2007

    • Author(s)
      Y.Sakaguchi
    • Journal Title

      Journal of Physics and Chemistry of Solids (to be published)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A possibility of photo-induced semiconductor-metal transitionin liquid selenium2007

    • Author(s)
      Y.Sakaguchi
    • Journal Title

      Journal of Non-Crystalline Solids (to be published)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Photodarkening Process in Amorphous Chalcogenide -Measurements of Transient Photo-induced Optical Absorption-2007

    • Author(s)
      Y.Sakaguchi
    • Journal Title

      Materials in Electronics (to be published)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Laser-induced lattern formation in Liquid surrui-An Indication of Laser-incuced Phase Transition to Ordered Polymer2007

    • Author(s)
      Y.Sakaguchi
    • Journal Title

      The European Physical Journal E - Soft Matter (to be published)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 液体イオウの光誘起構造変化2007

    • Author(s)
      坂口佳史
    • Journal Title

      硫酸と工業 (印刷中)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Structural studies of expanded fluid rubidium up to the supercritical regions2006

    • Author(s)
      K.Matsuda
    • Journal Title

      Science and Technology of Advanced Materials 7

      Pages: 483-489

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Structural studies of expanded fluid rubidium up to the supercritical regions.2006

    • Author(s)
      K.Matsuda et al.
    • Journal Title

      Science and Technology of Advanced Materials 7

      Pages: 483-489

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Structural studies of expanded fluid rubidium up to the supercritical regions.2006

    • Author(s)
      K.Matsuda
    • Journal Title

      Science and Technology of Advanced Materials 7

      Pages: 483-489

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Dynamics of Photodarkening in amorphous arsenic chalcogenide2006

    • Author(s)
      Y.Sakaguchi
    • Journal Title

      Journal of Optoelectronics and Advanced Materials 8

      Pages: 2101-2107

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Photo-induced Metastable State of S8 Clusters in Liquid Sulfur2006

    • Author(s)
      Y.Sakaguchi
    • Journal Title

      Mterial Research Society Synposium Proceedings 918

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Fast Photodarkening in Amorphous and Liquid Sulfur2006

    • Author(s)
      Y.Sakaguchi
    • Journal Title

      Mterial Research Society Synposium Proceedings 918

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 液体イオウの光誘起重合転移2006

    • Author(s)
      坂口 佳史
    • Journal Title

      高分子加工 55・2

      Pages: 51-61

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 高エネルギーX線による超臨界金属流体の小角散乱2006

    • Author(s)
      乾 雅祝
    • Journal Title

      日本結晶学会誌 48・1

      Pages: 76-80

    • NAID

      10020535250

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Observation of fast sound in metal-nonmetal transition in liquid Hg2005

    • Author(s)
      M.Inui
    • Journal Title

      Journal of physics and Chemistry of Solids 66

      Pages: 2223-2229

    • NAID

      120005822816

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Observation of fast sound in metal-nonmetal transition in liquid Hg.2005

    • Author(s)
      M.Inui et al.
    • Journal Title

      Journal of Physics and Chemistry of Solids 66

      Pages: 2223-2229

    • NAID

      120005822816

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Observation of fast sound in metal-nonmetal transition in liquid Hg2005

    • Author(s)
      M.Inui
    • Journal Title

      Journal of Physics and Chemistry of Solids 66

      Pages: 2223-2229

    • NAID

      120005822816

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Pressure-induced structural change of liquid carbon studied by ab initio molecular-dynamics simulations2005

    • Author(s)
      A.Harada
    • Journal Title

      Journal of Physical Society of Japan 74

      Pages: 2017-2024

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structural and electronic properties of liquid arsenic sulfide at high temperatures : ab initio molecular-dynamics simulations2005

    • Author(s)
      F.Shimojo
    • Journal Title

      Journal of Physical Society of Japan 74

      Pages: 621-625

    • Related Report
      2005 Annual Research Report
  • [Journal Article] A possibility of photo-induced semiconductor-metal transition in liquid selenium2005

    • Author(s)
      Y.Sakaguchi
    • Journal Title

      Journal of Non-Crystalline Solids (印刷中)(to be published)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Structural instability and the metal-non-metal transition in expanded fluid metals2005

    • Author(s)
      K.Tamura
    • Journal Title

      Journal of Non-Crystalline Solids (印刷中)(to be published)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Wide and small angle x-ray scattering measurements for expanded fluid Se accompanying the semiconductor-metal and meta-non-metal transition2005

    • Author(s)
      M.Inui
    • Journal Title

      Journal of Non-Crystalline Solids (印刷中)(to be published)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] X-ray diffraction studies of fluid rubidium : From liquid to dense vapor2005

    • Author(s)
      K.Matsuda
    • Journal Title

      Journal of Non-Crystalline Solids (印刷中)(to be published)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Sound wave anomaly in expanded fluid Hg near the metal-non-metal transition measured by high-resolution inelastic x-ray scattering2005

    • Author(s)
      D.Ishikawa
    • Journal Title

      Journal of Non-Crystalline Solids (印刷中)(to be published)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] X-ray diffraction measurements for liquid Ge-Si alloys using synchrotron radiation2005

    • Author(s)
      Y.Naito
    • Journal Title

      Journal of Non-Crystalline Solids (印刷中)(to be published)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Fast sound in expanded fluid Hg accompanying the metal-non-metal transition2004

    • Author(s)
      D.Ishikawa
    • Journal Title

      Physical Review Letters 93

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Molybdenum cell for x-ray diffraction measurements of fluid alkali metals at high temperatures and high pressures2004

    • Author(s)
      K.Matsuda
    • Journal Title

      Review of Scientific Instruments 75

      Pages: 709-712

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Collective dynamics in dense Hg vapour2004

    • Author(s)
      D.Ishikawa
    • Journal Title

      Journal of Physics : Condense Matter 16

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Temperature driven semiconductor-metal transition and structural changes in liquid AS_2Se_32004

    • Author(s)
      S.Hosokawa
    • Journal Title

      Journal of Physics : Condense Matter 16

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Fast sound in expanded fluid Hg accompanying the metal-nonmetal transition.2004

    • Author(s)
      D.Ishikawa et al.
    • Journal Title

      Physical Review Letters 93

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Molybdenum cell for x-ray diffraction measurements of fluid alkali metals at high temperatures and high pressures.2004

    • Author(s)
      K.Matsuda et al.
    • Journal Title

      Review of Scientific Instruments 75

      Pages: 709-712

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Collective dynamics in dense Hg vapor.2004

    • Author(s)
      D.Ishikawa et al.
    • Journal Title

      Journal of Physics : Condense Matter 16

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Temperature driven semiconductor-metal transition and structural changes in liquid As_2Se_3.2004

    • Author(s)
      S.Hosokawa et al.
    • Journal Title

      Journal of Physics : Condense Matter 16

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 超臨界金属流体の構造 -隠されていたもうひとつのゆらぎ-2004

    • Author(s)
      田村剛三郎
    • Journal Title

      SPring-8利用者情報 Vol.9, No.3

      Pages: 203-213

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 放射光を用いた流体水銀の構造研究 -金属-非金属転移とゆらぎ-2004

    • Author(s)
      田村剛三郎
    • Journal Title

      リガクジャーナル Vol.35, No.2

      Pages: 28-36

    • NAID

      40006495458

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Molybdenum cell for x-ray diffraction measurements of fluid alkali metals at high temperatures and high pressures2004

    • Author(s)
      K.Matsuda
    • Journal Title

      Review of Scientific Instruments Vol.75, No.3

      Pages: 709-712

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Collective dynamics in dense Hg vapour2004

    • Author(s)
      D.Ishikawa
    • Journal Title

      Journal of Physics : Condensed Matter Vol.16

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Fast sound in expanded fluid Hg accompanying the Metal-nonmetal transition2004

    • Author(s)
      D.Ishikawa
    • Journal Title

      Physical Review Letters Vol.93, No.9

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Temperature driven semiconductor-metal transition and structural changes in liquid As_2Se_32004

    • Author(s)
      S.Hosokawa
    • Journal Title

      Journal of Physics : Condensed Matter Vol.16

    • Related Report
      2004 Annual Research Report
  • [Journal Article] The metal-nonmetal transition and structural instability in expanded fluid metals

    • Author(s)
      K.Tamura
    • Journal Title

      Journal of Non-Crystalline Solids (in press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] X-ray diffraction studies of fluid rubidium : From liquid to dense vapor

    • Author(s)
      K.Matsuda
    • Journal Title

      Journal of Non-Crystalline Solids (in press)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] The metal-nonmetal transition and structural instability in expanded fluid metals.

    • Author(s)
      K.Tamura et al.
    • Journal Title

      Journal of Non-Crystalline Solids (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] X-ray diffraction studies of fluid rubidium : From liquid to dense vapor.

    • Author(s)
      K.Matsuda et al.
    • Journal Title

      Journal of Non-Crystalline Solids (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary

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Published: 2004-04-01   Modified: 2016-04-21  

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