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Study of the Discoloration Mechanism at the Interface between Alkaline and Acidic Paper

Research Project

Project/Area Number 16300287
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Cultural property science
Research InstitutionTokyo National University of Fine Arts and Music

Principal Investigator

INABA Masamitsu  Tokyo National University of Fine Arts and Music, Graduate School of Fine Arts, Professor, 大学院美術研究科, 教授 (50135183)

Co-Investigator(Kenkyū-buntansha) KIRINO Fumiyoshi  Tokyo National University of Fine Arts and Music, Graduate School of Fine Arts, Associate Professor, 大学院美術研究科, 助教授 (10334484)
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥11,900,000 (Direct Cost: ¥11,900,000)
Fiscal Year 2006: ¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2005: ¥5,000,000 (Direct Cost: ¥5,000,000)
Fiscal Year 2004: ¥4,600,000 (Direct Cost: ¥4,600,000)
Keywordsacidic paper / alkaline paper / neutral paper / discoloration / insertion-method / accelerated ageing test
Research Abstract

Insertion-accelerated ageing test of paper in a condition that more resembles the real preservation condition of paper materials was conducted. This test showed that greater discoloration often occurs at the interface of acidic and alkaline papers. The result refutes the conventional idea that alkaline paper is preferable for conservation treatment of acidic paper and was received seriously by the conservation community.
Larger discoloration of acidic paper occurred with the increase of relative humidity up to 80%RH. But in the case of 95%RH with pressure, discoloration was lowered. After accelerated ageing at 80°C and 95 %RH with pressure, it was found that SO_4 and Al components from the sheets of acidic paper moved to the adjacent sheets of neutral or alkaline paper booklets. Additionally, when acidic paper was inserted into an alkaline paper booklet, Ca was also transferred from the alkaline paper. Faster migration of these components was observed under higher pressure. The migration of acidic and alkaline components contributes to the pH increase of acidic paper and reduces the degree of discoloration of acidic paper during moist heat ageing.
By insertion-accelerated ageing test using an alkaline paper booklet, paper containing aluminium sulphate showed a tendency for greater discoloration than one without it even at the same pH of paper. Thus, it may be said that aluminium sulphate-free paper is preferable for use in conservation.
Since several types of commercial alkaline paper are predominantly used in the conservation field, we examined the effect of alkaline or neutral paper on the discoloration of acidic paper. As a result, it may be said that even good quality alkaline paper causes discoloration of acidic paper inserted in a booklet. It is assumed that lower pH of alkaline paper causes less discoloration of inserted acidic paper.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (5 results)

All 2007 2005

All Journal Article (5 results)

  • [Journal Article] 挿入法による紙劣化試験(III)色変化に及ぼす硫酸アルミニウム成分移行の影響2007

    • Author(s)
      山口佳奈, 勝亦京子, 桐野文良, 稲葉政満
    • Journal Title

      文化財保存修復学会誌 52

      Pages: 53-60

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Insertion-accelerated ageing test of paper (III) Effect of migration of aluminum sulfate components on discoloration2007

    • Author(s)
      YANAGUCHI, Kana, KATSUMATA, Kyoko, KIRINO, Fumiyoshi, INABA, Masamitsu
    • Journal Title

      Bunkazai Hozon-syuhukuku Gakkaisi 52

      Pages: 53-60

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 挿入法による紙劣化試験-色変化に及ぼす圧力および湿度の影響-2005

    • Author(s)
      稲葉政満, 高木彰子, 山口佳奈, 桐野文良, 木部徹
    • Journal Title

      文化財保存修復学会誌 49

      Pages: 100-107

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Insertion-accelerated ageing test of paper : Effects of pressure and relative humidity on discoloration2005

    • Author(s)
      INABA, Masamitsu, TAKAGI, Akiko, YAMAGUCHI, Kana, KIRINO, Fumiyoshi, KIBE, Toru
    • Journal Title

      Bunkazai Hozon-syuhukuku Gakkaisi 49

      Pages: 100-107

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 挿入法による紙劣化試験-色変化に及ぼす圧力および湿度の影響-2005

    • Author(s)
      稲葉政満(他4名)
    • Journal Title

      文化財保存修復学会誌 第49号

      Pages: 100-107

    • Related Report
      2005 Annual Research Report

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Published: 2004-04-01   Modified: 2016-04-21  

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