Studies on Microporous Materials towards Green Chemical Catalysis

• Project/Area Number: 16310056
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Environmental technology/Environmental materials
• Research Institution: Gifu University
• Principal Investigator: SUGI Yoshihiro Gifu University, Faculty of Engineering, Professor, 工学部, 教授 (90281047)
• Co-Investigator(Kenkyū-buntansha): KOMURA Kenichi Gifu University, Faculty of Engineering, Research Associate, 工学部, 助手 (40377685) ; 窪田 好浩 横浜国立大学, 大学院・工学研究科, 助教授 (30283279)
• Project Period (FY): 2004 – 2006
• Project Status: Completed (Fiscal Year 2006)
• Budget Amount: ¥15,800,000 (Direct Cost: ¥15,800,000); Fiscal Year 2006: ¥3,400,000 (Direct Cost: ¥3,400,000); Fiscal Year 2005: ¥3,400,000 (Direct Cost: ¥3,400,000); Fiscal Year 2004: ¥9,000,000 (Direct Cost: ¥9,000,000)
• Keywords: green chemical process / solid acid catalyst / esterification of fatty acid / zeolite / mesoporous silica / alkylation / nano-sized zeolite / zeolite framework / 骨格 / 環境調和性 / 形状選択性 / メソポーラスシリカ / 多価金属塩 / 超臨界CO_2 / フェノールのt-ブチル化 / 触媒 / メタン酸化 / ピリジン-遷移金属錯体

Research Abstract

We studied on the synthesis and tuning of preparation of new type of zeolites and functionalization of mesoporous materials in order to find microporous materials as catalysts for green chemical processes. Principal results in this work are as follows :
1) New type of BEA zeolite containing lanthana and ceria (La-BEA and Ce-BEA) were synthesized and applied for the hydrocarbon conversion. The decrease in coke-formation by using these zeolites as catalysts resulted in the low deactivation during their catalysis.
2) The synthesis of nano-sized BEA was synthesized by using TEAOH and cetyltrimethylammonium chloride as dual temperate in order to enhance the availability of channels of zeolites with particle size of 30-50 nm.
3) Three dimensional MCM-68 zeolite with 12-10-10-MR channel system was synthesized and applied for the isopropylation of biphenyl (BP), resulting in the selective formation of 4,4'-diisopropylbiphenyl (4,4'-DIPB). This is due to the discrimination of 4,4'-DIPB from its other DIPB isomers by the restriction in channels.
4) Multi-valent metal salts, such as FeCI_3 6H_2O, AICI_3 6H_2O, ZrOCl_2 6H_2O, were active for the esterification of fatty acid with fatty alcohol. The catalytic species are bore on the cationic cluster formed by the hydrolysis of multi-valent metal salt. The catalytic activity as improved by the loading of cluster cation on mesoporous silica. Multi-valent metal salts were also active for the esterification of lauric acid with glycerin. Monolaurin and dilaurin were obtained in presence of excess glycerin by using these salts.
5) The t-butylation of phenol was examined over H-Y zeolite and Sc(OTf)_3 in supercritical CO_2 medium, resulting in the high yield of 2,4-di-t-butylphenol over H-Y zeolite and 2,4,6-tri-t-butylphenol over Sc(OTf)_3 supported on mesoporous silica. These high yields compared to those in vapor and liquid phases are due to low coke-formation in supercritical CO_2 medium.

Research Products

• [Journal Article] Shape-selective Alkylation of Biphenyl over Metalloaluminophosphates with AFI Topology (2007)
  • Author(s): H.Maekawa, S.K.Saha, S.Abdul, R.Mulla, S.B.Waghmode, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J. Mol. Catal. A : Chemical 263 Pages: 238-246
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Shape-Selective Alkylation of Biphenyl over H-[Al]-SSZ-24 Zeolites with AFI Topology (2007)
  • Author(s): H.Maekawa, A.Ito, H.Kawagoe, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Bull. Chem. Soc. Jpn. 80 Pages: 215-223
  • NAID: 10018708865
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Layered Silicate PLS-1 : A New Solid Base Ccatalyst for C-C Bond Forming Reactions (2007)
  • Author(s): K.Komura, T.Kawamura, Y.Sugi
  • Journal Title: Catal. Commun. 8 Pages: 644-648
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Hydrothermal Synthesis of Calcium and Boron Containing MFI-type Zeolites by using Organic Amine as Structure Directing Agent (2007)
  • Author(s): R.Kawase, A.Iida, Y.Kubota, K.Komura, Y.Sugi, K.Oyama, H.Itoh
  • Journal Title: Ind. Eng. Chem. Res 46 Pages: 1091-1098
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Hydrothermal Synthesis of Metallosilicate SSZ-24 from Metallosilicate Beta as Precursors (2007)
  • Author(s): Y.Kubota, H.Maekawa, S.Miyata, T.Tatsumi, Y.Sugi
  • Journal Title: Micropor. Mesopor. Mater. 101 Pages: 115-126
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Shape-selective Alkylation of Biphenyl over Metalloaluminophosphates with AFI Topology (2007)
  • Author(s): H.Maekawa, S.K.Saha, S.A.R.Mulla, S.B.Waghmode, K.Komura, Y.Kubota, Y.Sugi, H.Maekawa, S.K.Saha, S.A.R.Mulla, S.B.Waghmode, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J. Mol. Catal. A : Chemical 263 Pages: 238-246
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Shape-selective Alkylation of Biphenyl over H-[Al]-SSZ-24 Zeolites with AFI Topology (2007)
  • Author(s): H.Maekawa, A.Ito, H.Kawagoe, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Bull. Chem. Soc. Jpn. 80 Pages: 215-223
  • NAID: 10018708865
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Layered Silicate PLS-1 : A New Solid Base Catalyst for C-C Bond Forming Reactions (2007)
  • Author(s): K.Komura, T.Kawamura, Y.Sugi
  • Journal Title: Catal. Commun. 8 Pages: 644-648
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Hydrothermal Synthesis of Calcium and Boron Containing MFI-Type Zeolites using Organic Amine as Structure Directing Agent (2007)
  • Author(s): R.Kawase, A.Iida, Y.Kubota, K.Komura, Y.Sugi, K.Oyama, H.Itoh
  • Journal Title: Ind. Eng. Chem. Res. 46 Pages: 1091-1098
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Layered Silicate PLS-1 : A New Solid Base Catalyst for C-C Bond Forming Reactions, (2007)
  • Author(s): K.Komura, T.Kawamura, Y.Sugi
  • Journal Title: Catal.Commun 8 Pages: 644-648
• [Journal Article] Shape-selective Alkylation of Biphenyl over Metalloaluminophosphates with AFI Topology, (2007)
  • Author(s): H.Maekawa, S.K.Saha, S.Abdul, R.Mulla, S.B.Waghmode, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J.Mol.Catal.A : Chem 263 Pages: 238-246
• [Journal Article] Shape-Selective Alkylation of Biphenyl over H-[AI]-SSZ-24 Zeolites with AFI Topology (2007)
  • Author(s): H.Maekawa, A.Ito, H.Kawagoe, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Bull.Chem.Soc.Jpn. 80 Pages: 215-223
• [Journal Article] Hydrothermal Synthesis of Calcium and Boron Containing MFI-type Zeolites by using Organic Amine as Structure Directing Agent (2007)
  • Author(s): R.Kawase, A.Iida, Y.Kubota, K.Komura, Y.Sugi, K.Oyama, H.Itoh
  • Journal Title: Ind.Eng.Chem.Res 46 Pages: 1091-1098
• [Journal Article] Multi-Valent Metal Salt Hydrates as Catalysts for the Esterification of Fatty Acids and Alcohols (2007)
  • Author(s): K.Mantri, R.Nakamura, Y.Miyata, K.Komura, Y.Sugi
  • Journal Title: Mater.Sci.Forum 534-543 Pages: 2317-2322
• [Journal Article] Beta Zeolites Modified with Lantanum and Cerium Oxides for the Isomerization of Hexane (2007)
  • Author(s): Y.Haga, Pusparatu, K.Aoyama, K.Komura, Y.Nishimura, Y.Sugi, J.-H.Kim, G.Seo
  • Journal Title: Mater.Sci.Forum 534-543 Pages: 2323-2328
• [Journal Article] Hydrothermal synthesis of metallosilicate SSZ-24 from metallosilicate beta as precursors, (2007)
  • Author(s): Y.Kubota, H.Maekawa, S.Miyata, T.Tatsumi, Y.Sugi
  • Journal Title: Micropor.Mesopor.Mater. 101 Pages: 115-126
• [Journal Article] The chloromethylation of Biphenyls Catalyzed by Group 3 and 4 Metal Triflates (2006)
  • Author(s): T.Kishida, T.Yamauchi, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J. Mol. Catal. A : Chemical 246 Pages: 268-275
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] tert-Butylation of Toluene over Mordenite and Cerium-modified Mordenite Catalysts (2006)
  • Author(s): G.Kostrab, D.Mravec, M.Bajus, I.Janotka, Y.Sugi, C.S.J.Cho, J.H.Kim
  • Journal Title: Appl. Catal. A : General 299 Pages: 122-130
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Shape-selective Alkylation and Related Reactions of Mononuclear Aromatic Hydrocarbons over H-ZSM-5 Zeolites Modified with Lanthanum and Cerium Oxides (2006)
  • Author(s): Y.Sugi, Y.Kubota, K.Komura, N.Sugiyama, M.Hayashi, J.-H.Kim, G.Seo
  • Journal Title: Appl. Catal. A : General 299 Pages: 157-166
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Organic-Inorganic Hybrid Ccatalysts Based on Ordered Porous Structures for Michael Reaction (2006)
  • Author(s): Y.Kubota, H.Ikeya, Y.Sugi, T.Yamada, T.Tatsumi
  • Journal Title: J. Mol. Catal. A : Chemical 249 Pages: 181-190
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] The Ddi-t-butylation of p-Cresol with t-Butanol in Supercritical CO_2 over Tungstophosphoric Aacid Supported on Ordered Mesoporous Silica (2006)
  • Author(s): G.Kamalakar, K.Komura, Y.Sugi
  • Journal Title: Catal. Lett. 108 Pages: 31-35
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Mesoporous Materials from Leached Calcium Silicates with Hollow Structure (2006)
  • Author(s): Y.Goto, Y.Fukushima, Y.Kubota, Y.Sugi
  • Journal Title: J. Porous Mater. 13 Pages: 147-152
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Friedel-Crafts Benzylation of Aromatics with Benzyl Alcohols Catalyzed by Heteropolyacids Supported on Mesoporous Silica (2006)
  • Author(s): G.Kamalakar, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J. Chem. Technol. Biotechnol 81 Pages: 981-988
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] The tert-Butylation of Phenol over Ordered Solid Acid Catalysts in Supercritical Carbon Dioxide : Efficient Synthesis of 2,4-Di-tert-butylphenol and 2,4,6-Tri-tert-butylphenol (2006)
  • Author(s): G.Kamalakar, K.Komura, Y.Sugi
  • Journal Title: Ind. Eng. Chem. Res. 45 Pages: 6118-6126
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Liquid-Phase Degradation of HDPE over Alkali-Treated MFI Zeolites with Mesopores (2006)
  • Author(s): D.-H.Choi, J.W.Park, J.-Ho Kim, Y.Sugi, G.Seo
  • Journal Title: Polym. Degrad. Stabil. 91 Pages: 2860-2866
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Vapor-phase Ethylation of Biphenyl over MTW Zeolites (2006)
  • Author(s): S.A.R.Mulla, S.B.Waghmode, S.Watanabe, H.Maekawa, K.Komura, Y.Kubota, Y.Sugi, J.-H.Kim, G.Seo
  • Journal Title: Bull. Chem. Soc. Jpn 79 Pages: 1451-1461
  • NAID: 10018243715
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Tungstophosphoric Acid Supported on MCM-41 Mesoporous Silicate : An Efficient Catalyst for the Di-tert-butylation of Cresols with tert-Butanol in Supercritical Carbon Dioxide (2006)
  • Author(s): G.Kamalakar, K.Komura, Y.Sugi
  • Journal Title: Appl. Catal. A : General 310 Pages: 155-163
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] The Chloromethylation of Biphenyls Catalyzed by Group 3 and 4 Metal Triflates (2006)
  • Author(s): T.Kishida, T.Yamauchi, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J. Mol. Catal. A : Chemical 246 Pages: 268-275
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Tert-Butylation of Toluene over Mordenite and Cerium-modified Mordenite Catalysts (2006)
  • Author(s): G.Kostrab, D.Mravec, M.Bajus, I.Janotka, Y.Sugi, C.S.J.Cho, J.H.Kim
  • Journal Title: Appl. Catal. A : General 299 Pages: 122-130
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Organic-inorganic Hybrid Catalysts Based on Ordered Porous Structures for Michael Reaction (2006)
  • Author(s): Y.Kubota, H.Ikeya, Y.Sugi, T.Yamada, T.Tatsumi
  • Journal Title: J. Mol. Catal. A : Chemical 249 Pages: 181-190
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] The Di-t-butylation of p-Cresol with t-Butanol in Supercritical CO_2 over Tungstophosphoric Acid Supported on Ordered Mesoporous Silica (2006)
  • Author(s): G.Kamalakar, K.Komura, Y.Sugi
  • Journal Title: Catal. Lett. 108 Pages: 31-35
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Mesoporous Materials from Leached Calcium Silicates with Hollow Structure, (2006)
  • Author(s): Y.Goto, Y.Fukushima, Y.Kubota, Y.Sugi
  • Journal Title: J. Porous Mater. 13 Pages: 147-152
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Friedel-Crafts Benzylation of Aromatics with Benzyl Alcohols Catalyzed by Heteropolyacids Supported on Mesoporous Silica (2006)
  • Author(s): G.Kamalakar, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J. Chem. Technol. Biotechnol. 81 Pages: 981-988
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] The t-Butylation of Phenol over Ordered Solid Acid Catalysts in Supercritical Carbon Dioxide : Efficient Synthesis of 2,4-Di-tert-butylphenol and 2,4,6-Tri-tert-butylphenol (2006)
  • Author(s): G.Kamalakar, K.Komura, Y.Sugi
  • Journal Title: Ind. Eng. Chem. Res. 45 Pages: 6118-6126
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Vapor-phase Ethylation of Biphenyl over MTW Zeolites (2006)
  • Author(s): S.A.R.Mulla, S.B.Waghmode, S.Watanabe, H.Maekawa, K.Komura, Y.Kubota, Y.Sugi, J.-H.Kim, G.Seo
  • Journal Title: Bull. Chem. Soc. Jpn. 79 Pages: 1451-1461
  • NAID: 10018243715
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Friedel-Crafts Benzylation of Aromatics with Benzyl Alcohols Catalyzed by Heteropolyacids Supported on Mesoporous Silica (2006)
  • Author(s): G.Kamalakar, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J.Chem.Technol.Biotechnol 81 Pages: 981-988
• [Journal Article] Vapor-phase Ethylation of Biphenyl over MTW Zeolites (2006)
  • Author(s): S.A.R.Mulla, S.B.Waghmode, S.Watanabe, H.Maekawa, K.Komura, Y.Kubota, Y.Sugi, J.-H.Kim, G.Seo
  • Journal Title: Bull.Chem.Soc.Jpn 79 Pages: 1451-1461
  • NAID: 10018243715
• [Journal Article] Shape-Selective Catalysis over Zeolite.An Attempt in the Alkylation of Biphenyl (2006)
  • Author(s): Y.Sugi, K.Komura, J.-H.Kim
  • Journal Title: J.Korean Ind.Eng.Chem 17 Pages: 235-242
• [Journal Article] The tert-Butylation of Phenol over Ordered Solid Acid Catalysts in Supercritical Carbon Dioxide : Efficient Synthesis of 2,4-Di-tert-butylphenol and 2,4,6-Tri-tert-butylphenol (2006)
  • Author(s): G.Kamalakar, K.Komura, Y.Sugi
  • Journal Title: Ind.Eng.Chem.Res. 45 Pages: 6118-6126
• [Journal Article] Liquid-Phase Degradation of HDPE over Alkali-Treated MFI Zeolites with Mesopores (2006)
  • Author(s): D.-H.Choi, J.W.Park, J.-Ho Kim, Y.Sugi, G.Seo
  • Journal Title: Polymer Degradation and Stability 91 Pages: 2860-2866
• [Journal Article] 環境負荷削減のための触媒技術 (2006)
  • Author(s): 西村陽一, 杉 義弘
  • Journal Title: 工業材料 54#11 Pages: 48-51
• [Journal Article] The Chloromethylation of Biphenyls Catalyzed by Group 3 and 4 Metal Triflates (2006)
  • Author(s): T.Kishida, T.Yamauchi, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J..Mol.Catal.A : Chemical 246 Pages: 268-275
• [Journal Article] Mesoporous materials from leached calcium silicates with hollow structure (2006)
  • Author(s): Y.Goto, Y.Fukushima, Y.Kubota, Y.Sugi
  • Journal Title: J.Porous Mater. 13 Pages: 147-152
• [Journal Article] Organic-inorganic hybrid catalysts based on ordered porous structures for Michael reaction (2006)
  • Author(s): Y.Kubota, H.Ikeya, Y.Sugi, T.Yamada, T.Tatsumi
  • Journal Title: Journal of Molecular Catalysis A : Chemical 249 Pages: 181-190
• [Journal Article] tert-Butylation of toluene over mordenite and cerium-modified mordenite catalysts (2006)
  • Author(s): G.Kostrab, D.Mravec, M.Bajus, I.Janotka, Y.Sugi, C.S.J.Cho, J.H Kim
  • Journal Title: Applied Catalysis A : General 299 Pages: 122-130
• [Journal Article] The Transethylation of Biphenyl with Diethylbenzenes over H-Y Zeolite (2005)
  • Author(s): J.Qiu, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Bull. Chem. Soc. Jpn. 78 Pages: 1160-1166
  • NAID: 10016143721
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Efficient Esterification of Long Chain Aliphatic Carboxylic Acids and Alcohols over ZrOC12 catalyst (2005)
  • Author(s): K.Mantri, K.Komura, Y.Sugi
  • Journal Title: Synthesis Pages: 1939-1944
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Pyridine-derived ruthenium and platinum complexes immobilized on ordered mesoporous silica as catalysts for Heck vinylation (2005)
  • Author(s): J.Horniakova, H.Nakamura, R.Kawase, Y.Kubota, Y.Sugi
  • Journal Title: Journal of Molecular Catalysis A : Chemical 233 Pages: 49-54
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Friedel-Crafts Alkylation of Aromatics with Benzyl alcohols Catalyzed by Rare Earth Metal Triflates Supported on MCM-41 Mesoporous Silica (2005)
  • Author(s): K.Mantri, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Journal of Molecular Catalysis A : Chemical 236 Pages: 168-175
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] The Hydroamination of Methyl Acrylates with Amines over Zeolites (2005)
  • Author(s): J.Horniakova, K.Komura, H.Osaki, Y.Kubota, Y.Sugi
  • Journal Title: Catal. Lett. 102 Pages: 191-196
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] The t-Butylation of Phenol in Supercritical Carbon Dioxide over H-Y Zeolite. Remarkable Enhancement of Catalytic Performance for the Formation of 2,4-Di-t-butylphenol (2005)
  • Author(s): G.Kamalakar, K.Komura, Y.Sugi
  • Journal Title: Chem. Lett. 34 Pages: 1446-1445
  • NAID: 10019352555
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Esterification of Long Chain Aliphatic Acids with Long Chain Alcohols Catalyzed by Multi-valent Metal Salts (2005)
  • Author(s): K.Mantri, R.Nakamura, K.Komura, Y.Sugi
  • Journal Title: Chem. Lett. 34 Pages: 1502-1503
  • NAID: 10016844048
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Magnesioaluminophosphate Molecular Sieves with ATS Topology : Synthesis by Dry-Gel Conversion Method and Catalytic Properties in the Isopropylation of Biphenyl (2005)
  • Author(s): S.K.Saha, S.B.Waghmode, H.Maekawa, R.Kawase, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Micropor. Mesopor. Mater. 81 Pages: 277-287
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Synthesis of Aluminophosphate Molecular Sieves with AFI Topology Substituted by Alkaline Earth Metal and Their Application to Solid Acid Catalysis (2005)
  • Author(s): S.K.Saha, S.B.Waghmode, H.Maekawa, K.Komura, Y.Kubota, Y.Sugi, Y.Oumi, T.Sano
  • Journal Title: Micropor. Mesopor. Mater. 81 Pages: 289-303
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] ZrOCl_2・8H_2O Catalysts for the Esterification of Long Chain Aliphatic Carboxylic Acids and Alcohols. The Enhancement of Catalytic Performance by Supporting on Ordered Mesoporous Silica (2005)
  • Author(s): K.Mantri, K.Komura, Y.Sugi
  • Journal Title: Green Chem. 7 (2005) 7 Pages: 677-682
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Standardization of Catalyst Preparation Using Reference Catalyst : Ion Exchange of Mordenite Type Zeolite 1. Remarkable Dealumination Accompanying Ion Exchange (2005)
  • Author(s): Y.Sugi, et al.
  • Journal Title: Appl. Catal. A : General 283 Pages: 63-74
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Standardization of Catalyst Preparation Using Reference Catalyst : Ion Exchange of Mordenite Type Zeolite 2. Origin of Dealumination and Recommended Standard Conditions (2005)
  • Author(s): Y.Sugi, et al.
  • Journal Title: Appl. Catal. A : General 283 Pages: 75-84
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Seeding on the Synthesis of MCM-22 (MWW) Zeolite by Dry-Gel Conversion Method and its Catalytic Properties on the Skeleton Isomerization and the Cracking of Hexane (2005)
  • Author(s): S.K.Saha, Pusparatu, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Mater. Trans. 46 Pages: 2651-2658
  • NAID: 10017149406
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Zincoaluminophosphate Molecular Sieves with AFI and ATS Topologies : Synthesis by Dry-Gel Conversion Methods and Their Catalytic Properties in the Isopropylation of Biphenyl (2005)
  • Author(s): S.K.Saha, H.Maekawa, S.B.Waghmode, S.A.R.Mulla, K.Komura, Y.Kubota, Y.Sugi, S.Cho
  • Journal Title: Mater. Trans. 46 Pages: 2659-2667
  • NAID: 10017149439
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Efficient Esterification of Long Chain Aliphatic Carboxylic Acids and Alcohols over ZrOCI_2 catalyst (2005)
  • Author(s): K.Mantri, K.Komura, Y.Sugi
  • Journal Title: Synthesis 1939-1944
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Pyridine-derived ruthenium and platinum complexes immobilized on ordered mesoporous silica as catalysts for Heck vinylation (2005)
  • Author(s): J.Horniakova, H.Nakamura, R.Kawase, Y.Kubota, Y.Sugi
  • Journal Title: J. Mol. Catal., A : Chemical 233 Pages: 49-54
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Friedel-Crafts Alkylation of Aromatics with Benzyl Alcohols Catalyzed by Rare Earth Metal Triflates Supported on MCM-41 Mesoporous Silica (2005)
  • Author(s): K.Mantri, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J. Mol. Catal., A : Chemical 236 Pages: 168-175
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] The Hydroamination of Methyl Acrylate with Aniline over Zeolites (2005)
  • Author(s): J.Horniakova, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Catal. Lett. 102 Pages: 191-196
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Esterification of Long Chain Aliphatic Acids with Long Chain Alcohols Catalyzed by Multi-Valent Metal Salts (2005)
  • Author(s): K.Mantri, R.Nakamura, K.Komura, Y.Sugi
  • Journal Title: Chem. Lett. 34 Pages: 1502-1503
  • NAID: 10016844048
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Magnesioaluminophosphate Molecular Sieves with ATS Topology : Synthesis by Dry-gel Conversion Method and Catalytic Properties in the Isopropylation of Biphenyl (2005)
  • Author(s): S.K.Saha, S.B.Waghmode, H.Maekawa, R.Kawase, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Micropor. Mesopor. Mater. 81 Pages: 277-287
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] ZrOCI_2.8H_2O Catalysts for the Esterification of Long Chain Aliphatic Carboxylic Acids and Alcohols. The Enhancement of Catalytic Performance by Supporting on Ordered Mesoporous Silica (2005)
  • Author(s): K.Mantri, K.Komura, Y.Sugi
  • Journal Title: Green Chem. 7 Pages: 677-682
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Standardization of Catalyst Preparation Using Reference Catalyst. Ion Exchange of Mordenite Type Zeolite 1 : Remarkable Dealumination Accompanying Ion Exchange (2005)
  • Author(s): N.Katada, T.Takeguchi, T.Suzuki, T.Fukushima, K.Inagaki, S.Tokunaga, H.Shimada, K.Sato, Y.Oumi, T.Sano, K.Segawa, K.Nakai, H.Shoji, P.Wu, T.Tatsumi, T.Komatsu, T.Masuda, K.Domen, E.Yoda, J.N.Kondo, T.Okuhara, Y.Kageyama, M.Niwa, M.Ogura, M.Matsukata, E.Kikuchi, N.Okazaki, M.Takahashi, A.Tada, S.Tawada, Y.Kubota, Y.Sugi, Y.Higashio, M.Kamada, Y.Kioka, K.Yamamoto, T.Shouji, Y.Arima, Y.Okamoto, H.Matsumoto
  • Journal Title: Appl. Catal., A : General 283 Pages: 63-74
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Standardization of Catalyst Preparation Using Reference Catalyst. Ion Exchange of Mordenite Type Zeolite 2 : Origin of Dealumination and Recommended Standard Conditions (2005)
  • Author(s): N.Katada, T.Takeguchi, T.Suzuki, T.Fukushima, K.Inagaki, S.Tokunaga, H.Shimada, K.Sato, Y.Oumi, T.Sano, K.Segawa, K.Nakai, H.Shoji, P.Wu, T.Tatsumi, T.Komatsu, T.Masuda, K.Domen, E.Yoda, J.N.Kondo, T.Okuhara, T.Kanai, M.Niwa, M.Ogura, M.Matsukata, E.Kikuchi, N.Okazaki, M.Takahashi, A.Tada, S.Tawada, Y.Kubota, Y.Sugi, Y.Higashio, M.Kamada, Y.Kioka, K.Yamamoto, T.Shouji, S.Satokawa, Y.Arima, Y.Okamoto, H.Matsumoto
  • Journal Title: Appl. Catal., A : General 283 Pages: 75-84
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Zincoaluminophosphate Molecular Sieves with AFI and ATS Topologies : Synthesis by Dry-Gel Conversion Methods and Their Catalytic Properties in the Isopropylation of Biphenyl (2005)
  • Author(s): S.K.Saha, H.Maekawa, S.B.Waghmode, S.A.R.Mulla, K.Komura, Y.Kubota, Y.Sugi, S.-J.Cho
  • Journal Title: Mater. Trans. 46 Pages: 2659-2667
  • NAID: 10017149439
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Standardization of catalyst preparation using reference catalyst : ion exchange of mordenite type zeolite 1. Remarkable dealumination accompanying ion exchange (2005)
  • Author(s): Y.Sugi, et al.
  • Journal Title: Applied Catalysis A : General 283 Pages: 63-74
• [Journal Article] Standardization of catalyst preparation using reference catalyst : ion exchange of mordenite type zeolite 2. Remarkable dealumination accompanying ion exchange (2005)
  • Author(s): Y.Sugi, et al.
  • Journal Title: Applied Catalysis A : General 283 Pages: 75-84
• [Journal Article] The Transethylation of Biphenyl with Diethylbenzenes over H-Y Zeolite (2005)
  • Author(s): J.Qiu, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Bull.Chem.Soc.Jpn. 78 Pages: 1160-1166
  • NAID: 10016143721
• [Journal Article] The Hydroamination of methyl acrylates with amines over zeolites (2005)
  • Author(s): J.Horniakova, K.Komura, H.Osaki, Y.Kubota, Y.Sugi
  • Journal Title: Catalysis Letters 102 Pages: 191-196
• [Journal Article] The t-Butylation of Phenol in Supercritical Carbon Dioxide over H-Y Zeolite. Remarkable Enhancement of Catalytic Performance for the Formation of 2,4-Di-t-butylphenol (2005)
  • Author(s): G.Kamalakar, K.Komura, Y.Sugi
  • Journal Title: Chemistry Letters 34 Pages: 1445-1446
  • NAID: 10019352555
• [Journal Article] Esterification of Long Chain Aliphatic Acids with Long Chain Alcohols Catalyzed by Multi-valent Metal Salts (2005)
  • Author(s): K.Mantri, R.Nakamura, K.Komura, Y.Sugi
  • Journal Title: Chemistry Letters 34 Pages: 1502-1503
  • NAID: 10016844048
• [Journal Article] ZrOCl_2・8H_2O catalysts for the esterification of long chain aliphatic carboxylic acids and alcohols. The enhancement of catalytic performance by supporting on ordered mesoporous silica (2005)
  • Author(s): K.Mantri, K.Komura, Y.Sugi
  • Journal Title: Green Chem. 7 Pages: 677-682
• [Journal Article] Friedel-Crafts alkylation of aromatics with benzyl alcohols catalyzed by rare earth metal triflates supported on MCM-41 mesoporous silica (2005)
  • Author(s): K.Mantri, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Journal of Molecular Catalysis A : Chemical 236 Pages: 168-175
• [Journal Article] The chloromethylation of biphenyls catalyzed by group 3 and 4 metal triflates (2005)
  • Author(s): T.Kishida, T.Yamauchi, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Journal of Molecular Catalysis A : Chemical 246 Pages: 268-275
• [Journal Article] Seeding on the Synthesis of MCM-22 (MWW) Zeolite by Dry-Gel Conversion Method and its Catalytic Properties on the Skeleton Isomerization and the Cracking of Hexane (2005)
  • Author(s): S.K.Saha, Pusparatu, K.i Komura, Y.Kubota, Y.Sugi
  • Journal Title: Materials Transactions 46 Pages: 2651-2658
  • NAID: 10017149406
• [Journal Article] Zincoaluminophosphate Molecular Sieves with AFI and ATS Topologies : Synthesis by Dry-Gel Conversion Methods and Their Catalytic Properties in the Isopropylation of Biphenyl (2005)
  • Author(s): S.K.Saha, H.Maekawa, S.B.Waghmode, S.A.R.Mulla, K.Komura, Y.Kubota, Y.Sugi, S.Cho
  • Journal Title: Materials Transactions 46 Pages: 2659-2667
  • NAID: 10017149439
• [Journal Article] Magnesioaluminophosphate molecular sieves with ATS topology : Synthesis by dry-gel conversion method and catalytic properties in the isopropylation of biphenyl (2005)
  • Author(s): S.K.Saha, S.B.Waghmode, H.Maekawa, R.Kawase, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Microporous and Mesoporous Materials 81 Pages: 277-287
• [Journal Article] Synthesis of aluminophosphate molecular sieves with AFI topology substituted by alkaline earth metal and their application to solid acid catalysis (2005)
  • Author(s): S.K.Saha, S.B.Waghmode, H.Maekawa, K.Komura, Y.Kubota, Y.Sugi, Y.Oumi, T.Sano
  • Journal Title: Microporous and Mesoporous Materials 81 Pages: 289-303
• [Journal Article] Efficient Esterification of Long Chain Aliphatic Carboxylic Acids with Alcohols over ZrOCl_2・8H_2O Catalyst, 2005 (2005)
  • Author(s): K.Mantri, K.Komura, Y.Sugi
  • Journal Title: Synthesis Pages: 1939-1944
• [Journal Article] H-ZSM-5 Modified with Lanthanum and Cerium Oxides in Shape-Selective Ethylation of Ethylbenzene. The Deactivation of External Acid Sites and the Control of Pore Entrance (2005)
  • Author(s): Y.Sugi, Y.Kubota, K.Komura, N.Sugiyama, M.Hayashi, J.-H.Kim
  • Journal Title: Studies Surface Science and Catalysis 158 Pages: 1279-1286
• [Journal Article] Heck Reaction Catalyzed by Transition Metal Complexes with Quinoline-Derived Ligands Immobilized on Mesoporous Silica (2005)
  • Author(s): J.Horniakova, H.Nakamura, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Studies Surface Science and Catalysis 158 Pages: 1597-1604
• [Journal Article] Pore Structure and Shape-selectivity in trhe Isoporpylationof Biphenyl Catalyzed by One-dimensional Large Pore Zeolites (2005)
  • Author(s): Y.Sugi, Y.Kubota, A.Ito, H.Maekawa, R.K.Ahedi, S.Tawada, S.Watanabe, I.Toyama, C.Asaoka, H.-S.Lee, J.-H.Kim, G.Seo
  • Journal Title: Proc. 14th Inter.Zeolite Conf.25-30 April 2004 Pages: 2228-2238
• [Journal Article] Heck Vinylation Catalyzed by Quinoline-derived Ruthenium and Platinum Complexes Immobilized on Ordered Mesoporous Silica (2005)
  • Author(s): J.Horniakova, H.Nakamura, R.Kawase, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J.Mol.Catal., A : Chemical (印刷中)
• [Journal Article] Standardization of Catalyst Preparation Using Reference Catalyst. Ion Exchange of Mordenite Type Zeolite 1:Remarkable Dealumination Accompanying Ion Exchange (2005)
  • Author(s): N.Katada, T.Takeguchi, S.Tawada, Y.Kubota, Y.Sugi, et al.
  • Journal Title: Appl.Catal.,A : General (印刷中)
• [Journal Article] Standardization of Catalyst Preparation Using Reference Catalyst. Ion Exchange of Mordenite Type Zeolite 2:Origin of Dealumination and Recommended Standard Conditions (2005)
  • Author(s): N.Katada, T.Takeguchi, S.Tawada, Y.Kubota, Y.Sugi, et al.
  • Journal Title: Appl.Catal.,A : General (印刷中)
• [Journal Article] Friedel-Crafts Alkylation of Aromatics with Benzyl Alcohols Catalyzed by Rare Earth Metal Triflates Supported on MCM-41 Mesoporous Silica (2005)
  • Author(s): K.Mantri, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: J.Mol.Catal.,A : Chemical (印刷中)
• [Journal Article] The Transethylation of Biphenyl with Diethylbenzenes over H-Y Zeolite (2005)
  • Author(s): Q.Jun.K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Bull.Chem.Soc.Jpn. (印刷中)
  • NAID: 10016143721
• [Journal Article] Efficient Esterification of Long Chain Aliphatic Carboxylic Acids and Alcohols over ZrOCl_2 catalyst (2005)
  • Author(s): K.Mantri, K.Komura, Y.Sugi
  • Journal Title: Synthesis (印刷中)
• [Journal Article] The Hydroamination of Methyl Acrylate with Aniline over Zeolites (2005)
  • Author(s): J.Horniakova, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Catal.Lett. (印刷中)
• [Journal Article] Magnesioaluminophosphate Molecular Sieves with ATS Topology : Synthesis by Dry Gel Conversion Method and Catalytic Properties in the Isopropylation of Biphenyl (2005)
  • Author(s): S.K.Saha, S.B.Waghmode, H.Maekawa, R.Kawase, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Micopor.Mespor.Mater. (印刷中)
• [Journal Article] Synthesis of Aluminophosphate Molecular Sieves with AFI Topology Substituted by Alkaline Earth Metal and their Application to Solid Acid Catalysis (2005)
  • Author(s): S.K.Saha, S.B.Waghmode, H.Maekawa, K.Komura, Y.Kubota, Y.Sugi, Y.Oumi, T.Sano
  • Journal Title: Micopor.Mespor.Mater. (印刷中)
• [Journal Article] H-ZSM-5 Modified with Lanthanum and Cerium Oxides in Shape-Selective Ethylation of Ethylbenzene. The Deactivation of External Acid Sites and the Control of Pore Entrance (2005)
  • Author(s): Y.Sugi, Y.Kubota, K.Komura, N.Sugiyama, M.ayashi, J.-H.Kim
  • Journal Title: Stud.Surf.Sci.Catal. (印刷中)
• [Journal Article] Heck Reaction Catalyzed by Transition Metal Complexes with Quinoline-Derived Ligands Immobilized on Mesoporous Silica (2005)
  • Author(s): J.Horniakova, H.Nakamura, K.Komura, Y.Kubota, Y.Sugi
  • Journal Title: Stud.Surf.Sci.Catal. (印刷中)
• [Journal Article] Rare-earth Metal Triflates as Vversatile Catalysts for the Chloromethylation of Aromatic Hydrocarbons (2004)
  • Author(s): T.Kishida, T.Yamauchi, Y.Kubota, Y.Sugi
  • Journal Title: Green. Chem. 6 Pages: 57-62
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Selective Isopropylation of Biphenyl to 4,4'-DIPB over Mordenite (MOR) type Zeolite Obtained from a Layered Sodium Silicate Magadiite (2004)
  • Author(s): T.Selvam, G.T.P.Mabande, W.Schwieger, Y.Sugi, I.Toyama, Y.Kubota, H.-S.Lee, J.-H.Kim
  • Journal Title: Catal. Lett. 94 Pages: 17-24
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Hydrothermal Synthesis of [Al]-SSZ-24 from [Al]-Beta Zeolite ([Al]-BEA) as Precursors (2004)
  • Author(s): H.Maekawa, Y.Kubota, Y.Sugi
  • Journal Title: Chem. Lett. 33 Pages: 1126-1127
  • NAID: 10013527437
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] The Isopropylation of Biphenyl over H-Mordenite. The Deactivation of External Acid Sites by Silica Modification (2004)
  • Author(s): M.Hayashi, S.Tawada, Y.Kubota, Y.Sugi, J.-H.Kim
  • Journal Title: React. Kinet. Catal. Lett. 83 Pages: 329-335
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Organic-silicate Hybrid Catalysts Based on Various Defined Structures for Knoevenagel Condensation (2004)
  • Author(s): Y.Kubota, Y.Nishizaki, H.Ikeya, M.Saeki, T.Hida, S.Kawazu, M.Yoshida, H.Fujii, Y.Sugi
  • Journal Title: Micropor. Mesopor. Mater. 70 Pages: 135-149
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Synthesis of AFI Aluminophosphate Molecular Sieves Partly Substituted with Magnesium by Dry-Gel Conversion Method (2004)
  • Author(s): S.K.Saha, S.B.Waghmode, Y Kubota, Y.Sugi
  • Journal Title: Mater. Lett. 58 Pages: 2918-2923
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Pyridine-derived Palladium Complexes Immobilized on Ordered Mesoporous Silica as Catalysts for Heck-type Reactions (2004)
  • Author(s): J.Horniakova, T.Raja, Y.Kubota, Y.Sugi
  • Journal Title: J. Mol. Catal. A : Chemical 217 Pages: 73-80
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Isopropylation of Benzene with 2-Propanol over AFI Aluminophosphate Molecular Sieves Substituted with Alkaline Earth Metal (2004)
  • Author(s): S.B.Waghmode, S.K.Saha, Y.Kubota, Y.Sugi
  • Journal Title: J. Catal. 228 Pages: 192-205
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] The Isopropylation of Biphenyl over H-Mordenites. Roles of External Surface in Shape-Selective Catalysis (2004)
  • Author(s): S.Tawada, Y.Kubota, Y.Sugi, Y.Kiyozumi, T.Hanaoka, F.Mizukami
  • Journal Title: J. Jpn Inst. Energ. 83 Pages: 1045-1052
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Organic-Silicate Hybrid Catalysts Based on Various Defined Structures for Knoevenagel Condensation (2004)
  • Author(s): Y.Kubota, Y.Nishizaki, H.Ikeya, M.Saeki, T.Hida, S.Kawazu, M.Yoshida, H.Fujii, Y.Sugi
  • Journal Title: Micropor. Mesopor. Mater. 70 Pages: 135-149
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Synthesis of AFI Aluminophosphate Molecular Sieves Partly Substituted with Magnesium by Dry-Gel Conversion Method (2004)
  • Author(s): S.K.Saha, S.B.Waghmode, Y.Kubota, Y.Sugi
  • Journal Title: Mater. Lett. 58 Pages: 2918-2923
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Pyridine-Derived Palladium Complexes Immobilized on Ordered Mesoporous Silica as Catalysts for Heck-type Reactions (2004)
  • Author(s): J.Horniakova, T.Raja, Y.Kubota, Y.Sugi
  • Journal Title: J. Mol. Catal. A : Chemical 217 Pages: 73-80
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] The Isoporpylation of Biphenyl over H-Mordenites. Roles of External Surface in Shape-Selective Catalysis (2004)
  • Author(s): S.Tawada, Y.Kubota, Y.Sugi, Y.Kiyozumi, T.Hanaoka, F.Mizukami
  • Journal Title: J. Jpn Inst. Energ. 83 Pages: 1045-1052
  • NAID: 110004083731
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] The Isopropylation of Biphenyl over H-Mordenite. The Deactivation of External Acid Sites by Silica Modification (2004)
  • Author(s): M.Hayashi, S.Tawada, Y.Kubota, Y.Sugi, J.-H.Kim
  • Journal Title: React.Kinet.Catal.Lett. 83 Pages: 329-335
• [Journal Article] Organic-silicate Hybrid Catalysts Based on Various Defined Structures for Knoevenagel Condensation (2004)
  • Author(s): Y.Kubota, Y.Nishizaki, H.Ikeya, M.Saeki, T.Hida, S.Kawazu, M.Yoshida, H.Fujii, Y.Sugi
  • Journal Title: Micropor.Mesopor.Mater. 70 Pages: 135-149
• [Journal Article] Synthesis of AFI Aluminophosphate Molecular Sieves Partly Substituted with Magnesium by Dry-Gel Conversion Method (2004)
  • Author(s): S.K.Saha, S.B.Waghmode, Y.Kubota, Y.Sugi
  • Journal Title: Mater.Lett. 58 Pages: 2918-2923
• [Journal Article] Pyridine-derived Palladium Complexes Immobilized on Ordered Mesoporous Silica as Catalysts for Heck-type Reactions (2004)
  • Author(s): J.Horniakova, T.Raja, Y.Kubota, Y.Sugi
  • Journal Title: J.Mol.Catal.A : Chemical 217 Pages: 73-80
• [Journal Article] Isopropylation of Benzene with 2-Propanol over AFI Aluminophosphate Molecular Sieves Substituted with Alkaline Earth Metal (2004)
  • Author(s): S.B.Waghmode, S.K.Saha, Y.Kubota, Y.Sugi
  • Journal Title: J.Catal. 228 Pages: 192-205
• [Journal Article] The Isoporpylation of Biphenyl over H-Mordenites. Roles of External Surface in Shape-Selective Catalysis (2004)
  • Author(s): S.Tawada, Y.Kubota, Y.Sugi, Y.Kiyozumi, T.Hanaoka, F.Mizukami
  • Journal Title: J.Jpn Inst.Energ. 83 Pages: 1045-1052
  • NAID: 110004083731
• [Journal Article] Selective Isopropylation of Biphenyl to 4,4'-DIPB over Mordenite (MOR) type Zeolite Obtained from a Layered Sodium Silicate Magadiite (2004)
  • Author(s): T.Selvam, G.T.P.Mabande, W.Schwieger, Y.Sugi, I.Toyama, Y.Kubota, H.-S.Lee, J.-H.Kim
  • Journal Title: Catal.Lett. 94 Pages: 17-24
• [Journal Article] Hydrothermal Synthesis of [Al]-SSZ-24 from [Al]-Beta Zeolite ([Al]-BEA) as Precursors (2004)
  • Author(s): H.Maekawa, Y.Kubota, Y.Sugi
  • Journal Title: Chem.Lett. 33 Pages: 1126-1127
  • NAID: 10013527437
• [Journal Article] Environmentally Benign Catalysts for C-C Bond Forming Reactions (2004)
  • Author(s): Y.Kubota, K.Goto, S.Miyata, T.Nagaya, S.Kawazu, Y.Sugi
  • Journal Title: Trans.Mater.Soc.Jpn. 29 Pages: 1991-1994
• [Journal Article] ZSM-12 Zeolite Catalyzed Shape-selective Ethylation of Biphenyl to 4,4'-Diethylbiphenyl (2004)
  • Author(s): S.B.Waghmode, S.Watanabe, Y.Kubota Y.Sugi
  • Journal Title: Trans.Mater.Soc.Jpn. 29 Pages: 2179-2182
• [Journal Article] Synthesis of Aluminophosphate-type Molecular Sieve MAPO-36 (ATS) by Dry-Gel Conversion (DGC) Method and its Application to Shape-selective Catalysis (2004)
  • Author(s): S.K.Saha, H.Maekawa, Y.Kubota, Y.Sugi
  • Journal Title: Trans.Mater.Soc.Jpn. 29 Pages: 2187-2190
• [Journal Article] Synthesis of Aluminophosphate-type M-AFI Molecular Sieves with Isomorphous Substitution of Aluminum with Alkaline Earth Metals (2004)
  • Author(s): S.K.Saha, S.B.Waghmode, Y.Kubota, Y.Sugi
  • Journal Title: Trans.Mater.Soc.Jpn. 29 Pages: 2195-2198
• [Journal Article] Zeolite Beta by Dry Gel Conversion (DGC) Method : An Efficient Catalyst for the Isomerization of Hexane (2004)
  • Author(s): Pusparatu, Y.Kubota, Y.Nishimura, Y.Sugi
  • Journal Title: Trans.Mater.Soc.Jpn. 29 Pages: 2190-2194
• [Journal Article] The Esterification of Glycerine with Lauric Acid Catalyzed by Multi-valent Metal Salts. Selective Formation of Mono- and Dilaurins
  • Author(s): R.Nakamura, K.Komura, Y.Sugi
  • Journal Title: Catal Commun. (印刷中)
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Esterification of Glycerol by Lauric Acid over Aluminium and Zirconium Containing Mesoporous Molecular Sieves under Supercritical Carbon Dioxide Medium
  • Author(s): A.Sakthivel, R.Nakamura, K.Komura, Y.Sugi
  • Journal Title: J. Supercritical Fluid (印刷中)
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Novel Route to Synthesize of Nano-sized Zeolite-□ with High Surface Area
  • Author(s): A.Sakthivel, K.Komura, Y.Sugi
  • Journal Title: Chem. Lett. (印刷中)
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] The Alkylation of Biphenyl over Fourteen-Membered Ring Zeolites. The Influence of Zeolite Structure and Bulkiness of Alkylating Agent on the Selectivity for 4,4'-Dialkylbiphenyl
  • Author(s): Y.Sugi, H.Maekawa, S.A.R.Mulla, A.Ito, C.Naitoh, K.Nakagawa, K.Komura, Y.Kubota, J.H.Kim, G.Seo
  • Journal Title: Bull. Chem. Soc. Jpn. (印刷中)
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Shape-Selective Isopropylation of Biphenyl over CIT-5 Zeolites with CFI Topology
  • Author(s): H.Maekawa, C.Naitoh, K.Nakagawa, A.Iida, K.Komura, Y.Kubota, Y.Sugi, J.-H.Kim, G.Seo
  • Journal Title: J. Mol. Catal. A : Chemical (印刷中)
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] The Alkylation of Biphenyl over Fourteen-Membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for 4,4'-Dialkylbiphenyl
  • Author(s): Y.Sugi, H.Maekawa, S.A.R.d Mulla, A.Ito, C.Naitoh, K.Komura, Y.Kubota, J.-H.Kim, G.Seo
  • Journal Title: Bull. Chem. Soc. Jpn. (印刷中)
  • NAID: 10019528008
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] The Esterification of Glycerin with Lauric Acid Catalyzed by Multi-valent Metal Salts. Selective Formation of Mono-and Dilaurins
  • Author(s): R.Nakamura, K.Komura, Y.Sugi
  • Journal Title: Catal. Commun. (in press)
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Esterification of Glycerin by Lauric Acid over Aluminum and Zirconium containing Mesoporous Molecular Sieves under Super critical Carbon Dioxide Medium
  • Author(s): A.Sakthivel, R.Nakamura, K.Komura, Y.Sugi
  • Journal Title: J. Superfluids Chem. (in press)
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Novel Route to Synthesize Nano-sized □-Zeolite with High Surface Area
  • Author(s): A.Sakthivel, K.Komura, Y.Sugi
  • Journal Title: Chem. Lett. (in press)
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] The Isopropylation of Biphenyl over Fourteen-Membered Zeolites with CFI, SFH, and DON Topologies
  • Author(s): Y.Sugi, H.Maekawa, S.A.R.Mulla, A.Ito, C.Naitoh, K.Nakagawa, K.Komura, Y.Kubota, J.-H.Kim, G.Seo
  • Journal Title: Bull. Chem. Soc. Jpn. (in press)
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] The Shape-Selective Isopropylation of Biphenyl over CIT-5 Zeolites with CFI Topology
  • Author(s): H.Maekawa, A.Iida, C.Naitoh, K.Nakagawa, K.Komura, Y.Kubota, Y.Sugi, J.-H.Kim, G.Seo
  • Journal Title: J. Mol. Catal. A : Chemical (in press)
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] The Alkylation of Biphenyl over One-Dimensional Twelve-Membered Ring Zeolites. The Influence of Zeolite Structure and Alkylating Agent on the Selectivity for 4,4'-Dialkylbiphenyl
  • Author(s): Y.Sugi, H.Maekawa, A.Ito, C.Ozawa, T.Shibata, A.Niimi, C.Asaoka, K.Komura, Y.Kubota, J.-Y.Lee, J.-H.Kim, G.Seo
  • Journal Title: Bull. Chem. Soc. Jpn. (in press)
  • NAID: 10019795649
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] The Esterification of Glycerine with Lauric Acid Catalyzed by Multi-valent Metal Salts.Selective Formation of Mono- and Dilaurins
  • Author(s): R.Nakamura, K.Komura, Y.Sugi
  • Journal Title: Catal Commun. (印刷中)
• [Journal Article] The Alkylation of Biphenyl over Fourteen-Membered Ring Zeolites. The Influence of Zeolite Structure and Bulkiness of Alkylating Agent on the Selectivity for 4,4'-Dialkylbiphenyl,
  • Author(s): Y.Sugi, H.Maekawa, S.A.R.Mulla, A.Ito, C.Naitoh, K.Nakagawa, K.Komura, Y.Kubota, J.H.Kim, G.Seo
  • Journal Title: BullChem.Soc.Jpn. (印刷中)
• [Journal Article] Shape-Selective Isopropylation of Biphenyl over CIT-5 Zeolites with CFI Topology
  • Author(s): H.Maekawa, C.Naitoh, K.Nakagawa, A.Iida, K.Komura, Y.Kubota, Y.Sugi, J.-H.Kim, G.Seo
  • Journal Title: J.Mol.Catal.A : Chemical (印刷中)
• [Journal Article] Na-Y Zeolite as a Versatile Solid Catalyst for the Hydroamination of Methyl Acrylate with Amines
  • Author(s): K.Komura, J.Tsutsui, R.Hongo, Y.Sugi
  • Journal Title: Stud.Surf.Sci.Catal. (印刷中)
• [Journal Article] Novel route to synthesize of nano-sized zeolite-β with high surface area
  • Author(s): A.Sakthivel, K.Komura, Y.Sugi
  • Journal Title: Chem.Lett. (印刷中)
• [Book] 環境対応型セラッミクスの技術と応用 (2007)
  • Author(s): 小村賢一, 杉 義弘
  • Total Pages: 292
  • Publisher: シーエムシー
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] ベータ(β)-ゼオライトの合成方法 (2007)
  • Inventor(s): A.Sakthivelほか
  • Industrial Property Rights Holder: 杉 義弘及び触媒化成
  • Industrial Property Number: 2007-086089
  • Filing Date: 2007-03-28
• [Patent(Industrial Property Rights)] カルボン酸多価アルコールエステルの製造方法 (2007)
  • Inventor(s): 杉義弘, 小村賢一, 中村亮
  • Industrial Property Rights Holder: 杉 義弘及び触媒化成
  • Industrial Property Number: 2007-008896
  • Filing Date: 2007-01-18
• [Patent(Industrial Property Rights)] Process for Producing Carboxylic Acid Ester and Esterification Catalyst (2005)
  • Inventor(s): 杉義弘, 小村賢一, K.Mantri
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2005-12-05
  • Acquisition Date: 2006-06-22
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] ピロメリット酸の製造方法 (2005)
  • Inventor(s): 清原義博, 山内孝介, 米谷徹, 岩井圭介, 杉義弘, 小村賢一
  • Industrial Property Rights Holder: (株)日生化学工業所, 岐阜県研究開発財団, 杉義弘
  • Patent Publication Number: 2006-206549
  • Filing Date: 2005-01-31
  • Acquisition Date: 2006-08-10
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] ポリアリレート共重合体 (2005)
  • Inventor(s): 杉 義弘, 三輪實, 小村賢一, 岸田徹, 山内孝介
  • Industrial Property Rights Holder: 岐阜大学, (株)日生化学工業所
  • Patent Publication Number: 2006-233094
  • Filing Date: 2005-02-25
  • Acquisition Date: 2006-09-07
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] ハロメチル芳香族炭化水素の製造方法 (2005)
  • Inventor(s): 山内孝介, 岸田徹, 杉義弘, 窪田好浩
  • Industrial Property Rights Holder: 岐阜大学, (株)日生化学工業所
  • Patent Publication Number: 2007-022974
  • Filing Date: 2005-07-19
  • Acquisition Date: 2007-02-01
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] イソパラフィン-オレフィンアルキル化用ゼオライト触媒および該ゼオライト触媒を用いたアルキル化法 (2005)
  • Inventor(s): 杉義弘, 窪田好浩, 小村賢一, 白川和憲, 小柳嗣雄
  • Industrial Property Rights Holder: 触媒化成(株)
  • Patent Publication Number: 2007-083121
  • Filing Date: 2005-09-20
  • Acquisition Date: 2007-04-05
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] カルボン酸の製造方法及びエステル化触媒 (2005)
  • Inventor(s): 杉 義弘, 小村 賢一
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2005-06-08
• [Patent(Industrial Property Rights)] 炭化水素ハロメチル化触媒 (2005)
  • Inventor(s): 杉 義弘, 小村 賢一
  • Industrial Property Rights Holder: 岐阜大学
  • Industrial Property Number: 2005-209258
  • Filing Date: 2005-07-19
• [Patent(Industrial Property Rights)] Catalyst composition for the Isomerization of n-Paraffin and a Process for Isomerization of n-Paraffin (2004)
  • Inventor(s): Y.Sugi, Y.Kubota, Y.Nishimura, Puspartu
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2004-03-10
  • Acquisition Date: 2006-10-10
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] 結晶性微粒子亜鉛アルミノホスフェートの製造方法 (2004)
  • Inventor(s): 杉義弘, 窪田好浩, S. K. Saha
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2004-02-27
  • Acquisition Date: 2006-12-08
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] ピロメリット酸の製造方法 (2004)
  • Inventor(s): 山内孝介, 岩井圭介, 米谷徹, 岸田徹, 橋本圭介, 杉義弘, 窪田好浩
  • Industrial Property Rights Holder: (株)日生化学工業所, 岐阜大学, 岐阜県研究開発財団
  • Patent Publication Number: 2005-239643
  • Filing Date: 2004-02-26
  • Acquisition Date: 2005-09-08
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] イソパラフィン-オレフィンアルキル化用ゼオライト触媒および該ゼオライト触媒を用いたアルキル化法 (2004)
  • Inventor(s): 杉義弘, 窪田好浩, 小村賢一, 白川和憲, 小柳嗣雄
  • Industrial Property Rights Holder: 触媒化成(株)
  • Patent Publication Number: 2005-262159
  • Filing Date: 2004-03-22
  • Acquisition Date: 2005-09-29
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] 9,10-ジヒドロフェナンスレンの製造方法 (2004)
  • Inventor(s): 山内孝介, 米谷 徹, 岩井圭介, 杉義弘, 窪田好浩
  • Industrial Property Rights Holder: 岐阜大学, (株)日生化学工業所, 科学技術振興機構
  • Patent Publication Number: 2006-062975
  • Filing Date: 2004-08-24
  • Acquisition Date: 2006-03-09
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] プラスチック熱分解炉及びプラスチックの熱分解方法 (2004)
  • Inventor(s): 町野邦文, 橋場稔, 杉義弘
  • Industrial Property Rights Holder: (株)アパックス
  • Patent Publication Number: 2006-169280
  • Filing Date: 2004-12-13
  • Acquisition Date: 2006-06-29
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] カルボン酸エステルの製造方法及びエステル化触媒 (2004)
  • Inventor(s): 杉 義弘, 小村賢一, K.Mantri
  • Industrial Property Rights Holder: 岐阜大学
  • Industrial Property Number: 2004-359319
  • Filing Date: 2004-12-13
• [Patent(Industrial Property Rights)] プラスチック分解炉及びプラスチックの熱分解方法 (2004)
  • Inventor(s): 町野邦文, 橋場稔, 杉 義弘
  • Industrial Property Rights Holder: アパックス
  • Industrial Property Number: 2004-359626
  • Filing Date: 2004-12-13
• [Patent(Industrial Property Rights)] n-パラフィンの異性化用触媒組成物及びn-パラフィンの異性化方法 (2003)
  • Inventor(s): 杉義弘, 窪田好浩, 西村陽一, Pusparatu
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2003-03-10
  • Acquisition Date: 2006-01-06
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] アリールアントラセン化合物の製造方法 (2003)
  • Inventor(s): 杉義弘, 窪田好浩, T. Raja
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2003-06-26
  • Acquisition Date: 2006-08-04
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] AFI構造を有する新規アルカリ土類金属アルミノホスフェート及びその前駆体 (2003)
  • Inventor(s): 杉義弘, 窪田好浩, S.K.Saha, S.B. Wagmode
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2003-10-06
  • Acquisition Date: 2006-08-11
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] 結晶性アルカリ土類金属アルミノホスフェートの製造方法 (2003)
  • Inventor(s): 杉義弘, 窪田好浩, S.K.Saha, S,B. Wagmode
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2003-10-06
  • Acquisition Date: 2006-08-11
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] AFI構造を有する結晶性アルミノシリケートの製造方法 (2003)
  • Inventor(s): 杉義弘, 窪田好浩, 前川弘吉
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2003-09-11
  • Acquisition Date: 2006-08-18
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] 4, 4'-ジイソプロピルビフェニルの合成方法及び触媒 (2002)
  • Inventor(s): 杉義弘, 窪田好浩, 伊藤亨
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2002-04-17
  • Acquisition Date: 2006-01-27
  • Description: 「研究成果報告書概要(和文)」より
• [Patent(Industrial Property Rights)] β-ヒドロキシケトンの合成方法及び触媒 (2002)
  • Inventor(s): 杉義弘, 窪田好浩, 後藤邦雄
  • Industrial Property Rights Holder: 岐阜大学
  • Filing Date: 2002-07-10
  • Acquisition Date: 2006-08-11
  • Description: 「研究成果報告書概要(和文)」より