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Study of the side reaction prevention for the dissolution of organic wastes with sub-critical water

Research Project

Project/Area Number 16310063
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionUbe National College of Technology

Principal Investigator

MURAKAMI Sadaaki  Ube National College of Technology, Department of Biological and Chemical Engineering, professor (00035065)

Co-Investigator(Kenkyū-buntansha) TAKEUCHI Masami  Ube National College of Technology, Department of Biological and Chemical Engineering, Associate professor (30043889)
YAMASAKI Hirohito  Ube National College of Technology, Department of Biological and Chemical Engineering, Associate professor (20300618)
IMAI Tuyosi  Yamaguchi University, Graduate School of Science and Engineering, Associate professor (20263791)
深川 勝之  宇部工業高等専門学校, 物質工学科, 教授 (20043870)
北野 誠  石川島播磨重工業(株), 総合開発センター・環境化学システム開発部, 課長
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥12,000,000 (Direct Cost: ¥12,000,000)
Fiscal Year 2006: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2005: ¥2,700,000 (Direct Cost: ¥2,700,000)
Fiscal Year 2004: ¥8,200,000 (Direct Cost: ¥8,200,000)
Keywordssub-critical water / resource recovery from organic wastes / elucidation of side reaction mechanism / prevention of side reaction / prevention of scale / 有機廃棄物の資源化
Research Abstract

Research object
Our group has been developing the resource recovery plant from the organic wastes such as sewage sludge and kitchen garbage through that the solid wastes were dissolved in sub-critical water, then dissolved phosphorus was precipitated and collected with the MAP (magnesium ammonium phosphate) method, and finally the dissolved organic matter was converted to biogas as an energy source with methane fermentation method.
However, in the sub-critical water, in addition to the main hydrolysis reaction to dissolve the wastes, the side reaction of thermal decomposition of the wastes simultaneously proceeds to form the gaseous substance and the carbonized and tar substances which become cause of blockade of the sub-critical water equipment. The purpose of this research is (1) to elucidate the side reaction mechanism and to establish its prevention method, and (2) to design the resource recovery plant to commercialize this technology and to draw up the operating instructions of the plant.
Research results
(1) The mechanism for the thermal decomposition of organics has been outlined from experimental results using model substances. The sodium hydroxide addition was found to be effective as a method to suppress the thermal decomposition.
(2) The optimum operating conditions for sodium hydroxide addition and sub-critical water temperature were determined to suppress the thermal decompositions of sewage sludge and kitchen garbage.
(3) The resource recovery plant was basically designed and its operation guideline was drawn up.
(4) The resource recovery efficiency of energy and phosphorus and the cost performance of the plant were appraised, and it could verify that the commercialization of this technology is possible.
Prospect
We will cooperates with the domestic environmental-related plant manufacturers and aim toward the utilization and the spread of the resource recovery plant from the organic wastes with the sub critical water process as a core technology.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (33 results)

All 2007 2006 2005 2004 Other

All Journal Article (33 results)

  • [Journal Article] Determination of Optimum Operating Parameters on Phosphorus Recovery in MAP Process Using Solubilized Excess Sludge with Subcritical Water Process2007

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi, M. Ukita
    • Journal Title

      International Water Association Conference on Facing Sludge Diversities, 28-30 March 2007, Belek-Antalya, Turky、Paper2503

      Pages: 1-7

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 汚泥減量化技術の設計・操作条件と留意事項2007

    • Author(s)
      村上 定瞭、竹内 正美
    • Journal Title

      環境技術 36巻5号

      Pages: 314-321

    • NAID

      10019920134

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 亜臨界水処理による可落化余剰汚泥から溶出したMg2+を考慮した高品質MAP回収に関する研究2007

    • Author(s)
      荒金 光弘、今井 剛、村上 定瞭、竹内 正美、浮田 正夫
    • Journal Title

      土木学会論文集G 63巻4号(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Determination of Optimum Operating Parameters onPhosphorus Recovery in MAP Process UsingSolubilizedExcessSludgewithSubcriticalWater Process2007

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi, M. Ukita
    • Journal Title

      International Water Association Coference on Facing Sludge Diversities : Challenges, Risks and Opportunities(Belek-Antalya, Turky) 2503

      Pages: 1-7

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Design, Operation and Instruction for Biological Wastewater Processing with Sludge Reduction2007

    • Author(s)
      M. Murakami, M. Takeuchi
    • Journal Title

      Environmental Engineering Research(Japanese) vol.36, No.5

      Pages: 314-321

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 汚泥減量化技術の設計・操作条件と留意事項2007

    • Author(s)
      村上定瞭, 竹内正美
    • Journal Title

      環境技術 36巻・5号

      Pages: 314-321

    • NAID

      10019920134

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Resource Recovery from Excess Sludge by Subcritical Water Combined with Magnesium Ammonium Phosphate Process2006

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi, M. Ukita
    • Journal Title

      International Water Association World Water Congress and Exhibition, 10-14 September 2006, Beijing, China, Paper 599767

      Pages: 1-7

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Resource Recovery from Excess Sludge by Sucritical Water Combined with Magnesium Ammonium Phosphate Process2006

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi, M. Ukita
    • Journal Title

      Water Science&Technology 54巻9号

      Pages: 81-86

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] アルカリを添加した亜臨界水処理における余剰汚泥の可溶化に関する研究2006

    • Author(s)
      荒金 光弘、今井 剛、村上 定瞭、竹内 正美、浮田 正夫
    • Journal Title

      土木学会論文集G 62巻4号

      Pages: 427-434

    • NAID

      10019327218

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 亜臨界水処理とMAP法およびUASB法との組合せによる余剰汚泥資源化プロセスの最適化に関する研究2006

    • Author(s)
      荒金 光弘、今井 剛、村上 定瞭、竹内 正美、浮田 正夫
    • Journal Title

      環境工学研究論文集 43巻

      Pages: 393-398

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Resource Recovery from Excess Sludge by SucriticalWater Combined with Magnesium AmmoniumPhosphate Process2006

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi, M. Ukita
    • Journal Title

      International Water Association World Water Congress andExhibition, 10-14 September(Beijing, China) 599767

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Resource Recovery from Excess Sludge by SucriticalWater Combined with Magnesium AmmoniumPhosphate_Pracess2006

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi M. Ukita
    • Journal Title

      Water Science&Technology vol.54, No9

      Pages: 81-86

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Study on Solubilization of Excess Sludge by SubcriticalWater Process with Alkali Addition2006

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi, M. Ukita
    • Journal Title

      Journals of the Japan Society of Civil Engineers, Division G(Japanese) vol.62, No.4

      Pages: 427-434

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Study on Optimum Process of Resource Recovery fromSolubilized Excess Sludge Treated by Subcritical WaterProcess_Combined with_MAP_and UASB_Methods2006

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi, M. Ukita
    • Journal Title

      Environmental Engineering Research(Japanese) vol.43

      Pages: 393-398

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 亜臨界水処理とMAPおよびUSB法との組合せによる余剰汚泥資源化プロセスの最適化に関する研究2006

    • Author(s)
      荒金光弘, 今井 剛, 村上定瞭, 竹内正美, 浮田正夫, 関根雅彦
    • Journal Title

      環境工学研究論文集 43巻

      Pages: 393-398

    • Related Report
      2006 Annual Research Report
  • [Journal Article] アルカリを添加した亜臨界水処理における余剰汚泥の可溶化に関する研究2006

    • Author(s)
      荒金光弘, 今井 剛, 村上定瞭, 竹内正美, 浮田正夫, 関根雅彦
    • Journal Title

      土木学会論文集G 62巻・4号

      Pages: 427-434

    • NAID

      10019327218

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Resource Recovery from Excess Sludge by Sucritical Water Combined with Magnesium Ammonium Phosphate Process2006

    • Author(s)
      M.Arakane, T.Imai, S.Murakami, M.Takeuchi, M.Ukita
    • Journal Title

      Water Science & Technology 54巻・9号

      Pages: 81-86

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 新基準に対応したフッ素除去技術の開発2005

    • Author(s)
      竹内 正美、渡辺 美紀、村上 定瞭、石川 宗孝
    • Journal Title

      用水と廃水 47巻2号

      Pages: 150-156

    • NAID

      40006619176

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 亜臨界水及びMAP法を用いた下水汚泥からのリン回収に関する研究2005

    • Author(s)
      荒金 光弘、今井 剛、村上 定瞭、竹内 正美、浮田 正夫
    • Journal Title

      廃棄物学会論文誌 16巻4号

      Pages: 309-317

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] ポリエチレン溶着による混練押出材料の物性に及ぼす添加樹脂粒径の影響2005

    • Author(s)
      山崎 博人、加納 恵、深川 勝之、村上 定瞭
    • Journal Title

      環境技術 34巻9号

      Pages: 653-659

    • NAID

      40006918021

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 連続式亜臨界水処理法およびUASB法の組合せによる下水汚泥からのメタンガス回収に関する研究2005

    • Author(s)
      荒金 光弘、今井 剛、村上 定瞭、竹内 正美、浮田 正夫
    • Journal Title

      環境工学論文集 42巻

      Pages: 415-422

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Development of Fluoride Removal Process fromWastewater Meeting the Revised Legulation2005

    • Author(s)
      M. Takeuchi, M. Watanabe, S. Murakami, M. Ishikawa
    • Journal Title

      Journal of Water and Waste(Japanese) vol.47, No.2

      Pages: 150-156

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Development of Fluoride Removal Process fromWastewater Meeting the Revised Legulation2005

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi, M. Ukita
    • Journal Title

      Waste Management Research(Janpanese) vol.16, No.4

      Pages: 309-317

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] The Influence of Resin Particles Diameter on theMechanical Properties of Kneaded Extrusion Materialsby Melted PolyethyIne2005

    • Author(s)
      H. Yamasaki, M. Kano, M. Fukagawa, S. Murakami
    • Journal Title

      Environmental Conservation Engineering(Japanese) vol.34, No.9

      Pages: 653-659

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Methane Recovery from Sewage Sludge by SubcriticalWater Process Combined with UASB Reactor2005

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi, M. Ukita
    • Journal Title

      Environmental Engineering Research(Japanese) vol.42

      Pages: 415-422

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] ポリエチレン溶着による混練押出材料の物性に及ぼす添加樹脂粒径の影響2005

    • Author(s)
      山崎 博人, 加納 恵, 深川 勝之, 村上 定瞭
    • Journal Title

      環境技術 34巻9号

      Pages: 653-659

    • NAID

      40006918021

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 亜臨界水及びMAP法を用いた下水汚泥からのリン回収に関する研究2005

    • Author(s)
      荒金光弘, 今井 剛, 村上定瞭, 竹内正美, 浮田正夫
    • Journal Title

      廃棄物学会論文誌 16巻4号

      Pages: 309-317

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 新基準に対応したフッ素除去技術の開発2005

    • Author(s)
      竹内 正美, 渡辺 美紀, 村上 定瞭
    • Journal Title

      用水と廃水 47巻・2号

      Pages: 150-156

    • NAID

      40006619176

    • Related Report
      2005 Annual Research Report 2004 Annual Research Report
  • [Journal Article] 工業廃水中EDTA鉄(III)キレート分解処理用バイオリアクターの開発-EDTA鉄(III)キレート分解菌の固定化とその分解挙動-2004

    • Author(s)
      山崎 博人、田村 光昭、品川 恵美子、村上 定瞭
    • Journal Title

      環境技術 33巻4号

      Pages: 307-314

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Development of Bioreactor for Fe(III) EDTA ChelateDegradation Processing in the Industrial Wastewater-Immobilizations of Fe(III)EDTA Chelate-Degrading Bacteria and Their Deerediw Behaviors2004

    • Author(s)
      H. Yamasaki, M. Tamura, E. Shinagawa, S. H. Yamasaki, M. Tamura, E. Shinagawa, S. Murakami
    • Journal Title

      Environmental Conservation Engineering(Japanese) vol.33, No.4

      Pages: 307-314

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 工業廃水中EDTA鉄(III)キレート分解処理用バイオリアクターの開発-EDTA鉄(III)キレート分解菌の固定化とその分解挙動-2004

    • Author(s)
      山崎 博人, 田村 光昭, 品川 恵美子, 村上 定瞭
    • Journal Title

      環境技術 33巻・4号

      Pages: 307-314

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Study on Variation of MAP Recovery in MAP ProcessConsidering Mg2+ Released from Solubilized ExcessSludge Treated by Subcritical Water

    • Author(s)
      M. Arakane, T. Imai, S. Murakami, M. Takeuchi, M. Ukita
    • Journal Title

      Journal of the Japan Society of Civil Engineers, Division G(Japanese) vol.63, No.4

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] ポリエチレン溶着による混練押出材料の物性に及ぼす添加樹脂粒径の影響

    • Author(s)
      山崎 博人, 加納 恵, 深川 勝之, 村上 定瞭
    • Journal Title

      環境技術 34巻(印刷中)

    • NAID

      40006918021

    • Related Report
      2004 Annual Research Report

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Published: 2004-04-01   Modified: 2016-04-21  

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