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Molecular-level local characterization of nano-materials and development of a STM probe-enhanced Raman spectroscopy system

Research Project

Project/Area Number 16310065
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural science
Research InstitutionTOHOKU UNIVERSITY (2006)
Ritsumeikan University (2004-2005)

Principal Investigator

FUKUMURA Hiroshi (2006)  Tohoku University, Graduate School of Science, Professor, 大学院理学研究科, 教授 (50208980)

西尾 悟 (2004-2005)  立命館大学, 理工学部, 教授 (40252340)

Co-Investigator(Kenkyū-buntansha) 福村 裕史  東北大学, 大学院・理学研究科, 教授 (50208980)
KUDRYASHOV Igor  東京インスツルメンツ, システム開発課, 次長
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥10,900,000 (Direct Cost: ¥10,900,000)
Fiscal Year 2006: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 2005: ¥2,700,000 (Direct Cost: ¥2,700,000)
Fiscal Year 2004: ¥6,800,000 (Direct Cost: ¥6,800,000)
KeywordsScanning tunneling microscope / Surface enhanced Raman / Thiophene derivative / Grating structure / Electro-conductive polymer / ビチオフェン / 走査プローブ顕微鏡 / ナノ物質 / 個別構造評価 / アブレーション / 走査トンネル顕微鏡 / 一次元グラファイト / ナノ微粒子 / 原子間力顕微鏡 / ポリペリナフタレン
Research Abstract

In this study, in order to obtain vibrational spectra in nano-regions space selectively, we have developed a measurement system as well as molecular systems for the confirmation of the system performance. The measurement system was assembled by using a scanning probe microscope and a Raman spectroscope. The excitation source for Raman spectroscopy was a 488 nm semiconductor laser and the detector was a cooled charge coupled device. Scanning probes were fabricated by chemical metal plating of silver on mechanically polished Pt/Ir wires. Silver particles were found to be 100-300 nm at the probe points by the use of a scanning electron microscope. Standard samples for space selective detection were prepared with photo-polymerization of a thiophene derivative. Grating structures of polythiophene were fabricated on transparent electro-conductive surfaces with the irradiation of 355 nm interference patterns. Under an optimal condition, structures with 2 micron line width, 3 micron spacing, 200 nm height were produced. The patterned surfaces were measured with the developed measurement system. The average signal intensity of 1400-1550 cm-1 attributed to a stretching vibrational mode of thiophene was measured at 10 x 10 points and spatially mapped. We have confirmed clear grating structures formed on surfaces with this technique. Finally, we obtained some data suggesting that the system has a resolution of about 50 nm.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (23 results)

All 2007 2006 2005 2004

All Journal Article (20 results) Book (3 results)

  • [Journal Article] Formation of 3,4,9,10-perylenetetracarboxylicdianhydride nanoparticles with perylene and polyyne byproducts by 355 nm nanosecond pulsed laser ablation of microcrystal suspension2007

    • Author(s)
      J.Hobley, T.Nakamori, S.Kajimoto, M.Kasuya, K.Hatanaka, H.Fukumura, S.Nishio
    • Journal Title

      Journal of Photochemistry and Photobiology A : Chemistry (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Ablation of metal-containing perylene tetracarboxylic dianhydride with third harmonic of Nd : YAG laser2007

    • Author(s)
      S Nishio, C Kanezawa, K Hatanaka, J Hobley, H Fukumura
    • Journal Title

      J. Phys. : Conf. Ser. 59

      Pages: 632-635

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Fornatuib of 3,4,9,10-perylenetetracarboxylicdianhydride nonoparticles with perylene and polyyne byproducts by 355 nm nanosecond pulsed laser ablation of microcrystal suspension2007

    • Author(s)
      J.Hobley, T.Nakamori, S.Kajimoto, M.Kasuya, K.Hatanaka, H.Fukumura, S.Nishio
    • Journal Title

      J.Photochem.Photobio.A : Chem. (In press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Ablation of metal-containing perylene tetracarboxylic dianhydride with third harmonic of Nd : YAG laser2007

    • Author(s)
      S Nishio, C Kanezawa, K Hatanaka, J Hobley, H Fukumura
    • Journal Title

      J.Phys. : Conf.Ser. 59

      Pages: 632-635

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Structure-property correlation of CdSe clusters using experimental results and first-principles DFT calculations2006

    • Author(s)
      R.Jose, N.U.Zhanpeisov, H.Fukumura, Y.Baba, M.Ishikawa
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 629-636

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Structure-property correlation of CdSe clusters using experimental results and first-principles DFT calculations2006

    • Author(s)
      R.Jose, N.U.Zhanpeisov, H.Fukumura, Y.Baba, M.Ishikawa
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 629-636

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Density Functional Theory Study of Vibrational Properties of the 3,4,9,10-Perylene Tetracarboxylic Dianhydride (PTCDA) Molecule : IR, Raman, and UV-vis Spectra2005

    • Author(s)
      N.U.Zhanpeisov, S.Nishio, H.Fukumura
    • Journal Title

      Intl. J. Quantum Chem 105

      Pages: 368-375

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Formation of Molecular Wires by Nanospace Polymerization of a Diacetylene Derivative Induced with a Scanning Tunneling Microscope at a Solid-Liquid Interface2005

    • Author(s)
      S.Nishio, D.I-i, H.Matsuda, M Yoshidome, H.Uji-i, H.Fukumura
    • Journal Title

      Jpn. J. Appl. Phys 44 (7B)

      Pages: 5417-5420

    • NAID

      10016677004

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Image Contrast Analysis of STM Images of Self-Assembled Dioctadecyl Chalcogenides on Graphite at the Liquid-Solid Interface2005

    • Author(s)
      H.Fukumura, D.I-i, H.Uji-i, S.Nishio, H.Sakai, A.Ohuchi
    • Journal Title

      ChemPhysChem 6

      Pages: 2383-2388

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Density Functional Theory Study of Vibrational Properties of the 3,4,9,10-Perylene Tetracarboxylic Dianhydride (PTCDA) Molecule : IR, Raman, and UV-vis Spectra2005

    • Author(s)
      N.U.Zhanpeisov, S.Nishio, H.Fukumura
    • Journal Title

      Intl.J.Quantum Chem 105

      Pages: 368-375

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Formation of Molecular Wires by Nanospace Polymerization of a Diacetylene Derivative Induced with a Scanning Tunneling Microscope at a Solid-Liquid Interface2005

    • Author(s)
      S.Nishio, D.I-i, H.Matsuda, M.Yoshidome, H.Uji-i, H.Fukumura
    • Journal Title

      Jpn.J.Appl.Phys 44(7B)

      Pages: 5417-5420

    • NAID

      10016677004

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Image Contrast Analysis of STM Images of Self-Assembled Dioctadecyl Chalcogenides on Graphite at the Liquid-Solid Interface2005

    • Author(s)
      H.Fukumura, D.I-i, H.Uji-i, S.Nishio, H.Sakai, A.Ohuchi
    • Journal Title

      Chem.Phys.Chem 6

      Pages: 2383-2388

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Electronic properties of a π-stacked pyrene derivative at a liquid-solid interface studied with scanning tunneling spectroscopy2005

    • Author(s)
      Hiroshi Fukumura, Hiroshi Uji-i, Satoru Nishio
    • Journal Title

      Chem.Phys.Lett. 408

      Pages: 112-117

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Nano-space polymerization in a monolayer of a diacetylene derivative induced with a scanning tunneling microscope at the solid-liquid interface and the effect of ionic additives2005

    • Author(s)
      Satoru Nishio, Daizo I-i, Hiroshi Uji-i, Hiroshi Fukumura
    • Journal Title

      Jpn.J.Appl.Phys. 44 7B

      Pages: 5417-5420

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Density Functional Theory Study of Vibrational Properties of the 3,4,9,10-Perylene Tetracarboxylic Dianhydride (PTCDA) Molecule : IR, Raman, and UV-vis Spectra2005

    • Author(s)
      N.U.Zhanpeisov, S.Nishio H.Fukumura
    • Journal Title

      International Journal of Quantum Chemistry 105

      Pages: 368-375

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Image Contrast Analysis of STM Images of Self-Assembled Dioctadecyl Chalcogenides on Graphite at the Liquid-Solid Interface2005

    • Author(s)
      Hiroshi Fukumura, Daizo I-i, Hiroshi Uji-i, Satoru Nishio, Hitoshi Sakai, Akihiko Ohuchi
    • Journal Title

      ChemPhysChem 6

      Pages: 2383-2388

    • Related Report
      2005 Annual Research Report
  • [Journal Article] レーザー光を用いた炭素および有機系ナノ材料創製2005

    • Author(s)
      西尾 悟
    • Journal Title

      レーザー研究 33

      Pages: 24-28

    • NAID

      10014278848

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Structure of Intermolecular Donor-acceptor Monolayers of 1-(1-Pyrenyl)-15-(p-N,N-Dimethl-aminophenyl)Pentadecane2004

    • Author(s)
      S.Nishio, M.Yoshidome, H.Ujii, H.Fukumura, K.A.Zachariasse
    • Journal Title

      Chem.Lett. 33

      Pages: 1506-1507

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Formation and Characterization of Polyperinaphthalenic Organic Semiconductor Nanoparticles by laser Ablation of Mixture Targets of a Perylene Derivative with Cobalt Powder at 355 nm2004

    • Author(s)
      S.Nishio, C.Kanezawa, H.Fukumura
    • Journal Title

      Appl.Phys.A 79

      Pages: 1449-1451

    • Related Report
      2004 Annual Research Report
  • [Journal Article] レーザーアブレーション法による有機ナノ微粒子創製とその個別構造評価2004

    • Author(s)
      西尾 悟
    • Journal Title

      第62回レーザー加工学会論文集

      Pages: 90-93

    • Related Report
      2004 Annual Research Report
  • [Book] Chapter 1, "Advanced Chemistry of Monolayers at Interfaces : Trends in Methodology and Technology"( Ed. by T. Imae)2007

    • Author(s)
      P.Brodard, H.Fukumura
    • Total Pages
      400
    • Publisher
      Academic Press Inc., (U.S.A.)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] Chapter 1, Advanced Chemistry of Monolayers at Interfaces : Trends in Methodology and Technology2007

    • Author(s)
      P.Brodard, H.Fukumura(Ed.by T.Imae)
    • Total Pages
      400
    • Publisher
      Academic Press Inc., (U.S.A.)
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] エレクトロニクス材料・技術シリーズ レーザーマイクロ・ナノプロセッシング2004

    • Author(s)
      西尾 悟他(杉岡幸次, 矢部明監修)
    • Total Pages
      386
    • Publisher
      シーエムシー出版
    • Related Report
      2004 Annual Research Report

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Published: 2004-04-01   Modified: 2016-04-21  

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