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Microscopic origin of the simultaneous ferroelectric and magnetic phase transition of RMn_2O_5

Research Project

Project/Area Number 16340096
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionTohoku University

Principal Investigator

NODA Yukio  Tohoku University, Institute of Multidisciplinary Research for Advanced Materials, Professor, 多元物質科学研究所, 教授 (80127274)

Co-Investigator(Kenkyū-buntansha) KIMURA Hiroyuki  Tohoku University, Institute of Multiisciplinary Research for Advanced Materials, Research Associate, 多元物質科学研究所, 助手 (50312658)
小林 悟  東北大学, 多元物質科学研究所, 研究機関研究員
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥15,800,000 (Direct Cost: ¥15,800,000)
Fiscal Year 2006: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2005: ¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2004: ¥12,100,000 (Direct Cost: ¥12,100,000)
Keywordsmultiferroic / magnetic order / ferroelectric / neutron magnetic scattering / synchrotron x-ray / electro-magnetic effect / RMn_2O_5 / RMn2O5 / RMm205 / 誘電率測定
Research Abstract

We performed the following investigations and published the results.
(1)Magnetic propagation vectors q_M of RMn_2O_5(R=Er, Tb, Ho, Tm).
(2)Developing the method to measure q_M, dielectric constant E and electric polarization Ps simultaneously.
(3)Reinvestigation of the dielectric constant of RMn_2O_5,and found the generalized phase diagram.
(4)Synchrotron x-ray experiments to find new Bragg reflections corresponding to the ferroelectric.
(5)Polarized neutron scattering of HoMn_2O_5 to measure the spin-chirality.
(6)Neutron scattering experiments of HoMn_2O_5 and ErMn_2O_5 at low temperature under external magnetic field.
We confirmed that the successive magnetic and ferroelectric phase transitions in RMn_2O_5 occur at the same temperatures. Further, we show that the first ferroelectric phase transition has the same character regardless of the rare earth element R of RMn_2O_5. On the other hand, the giant electro-magnetic effect at the lowest temperature region strongly depends on R. We have s … More hown that the magnetic ordering under the external magnetic field induces such giant electro-magnetic effect. That is, magnetic ordering induces ferroelectric polarization. This result was awarded by Journal of the Physical Society of Japan. After the simultaneous measurements of q_M,ε and Ps, we have the feeling that the scenario we proposed must be changed slightly since very weak ferroelectric component is seen between the one-dimensionally moderated magnetic phase and magnetic commensurate phase. Measure part of the electric polarization shows up below the magnetic commensurate phase. Such phenomena might be related to the existence of the so-called discommensuration. We also performed synchrotron x-ray diffraction to know the true structure at the ferroelectric phase. The unit cell size is double along c-direction and the space group is Pb2_1m. Very weak new Brag reflections were measured at (001/2) and (000) positions, whose intensities are 8-order magnitude weaker than the fundamental Bragg reflections. Less

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (32 results)

All 2007 2006 2005 2004

All Journal Article (32 results)

  • [Journal Article] Temperature Dependences of Electrical Polarization and Magnetic Ordering of TmMn_2O_52007

    • Author(s)
      M.Fukunaga
    • Journal Title

      J. Korean Phys. Soc. (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Field-induced dielectric and magnetic phase transition in multiferroic compounds of RMn_2O_5(R=Er, Ho)2007

    • Author(s)
      H.Kimura
    • Journal Title

      J. Korean Phys. Soc. (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Lattice modulation in YMn_2O_5 and TbMn_2O_5studied by SR x-ray2007

    • Author(s)
      Y.Noda
    • Journal Title

      J. Korean Phys. Soc. (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Simultaneous Measurements of Magnetic Neutron Diffraction, Electrical Polarization and Permittivity of Multiferroic ErMn_2O_52007

    • Author(s)
      M.Fukunaga
    • Journal Title

      J. Phys. Soc. Jpn. 76(No7)(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Magnetically induced ferroelectricity in multiferroic compounds of RMn_2O_52007

    • Author(s)
      H.Kimura
    • Journal Title

      Ferroelectrics (印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Spiral spin structure in commensurate magnetic phase of multiferroic RMn_2O_52007

    • Author(s)
      H.Kimura
    • Journal Title

      J. Phys. Soc. Jpn. 76(No7)(印刷中)

    • NAID

      110006350770

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Temperature Dependences of Electrical Polarization and Magnetic Ordering of TmMn_2O_52007

    • Author(s)
      M.Fukunaga
    • Journal Title

      J.Korean Phys.Soc. (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Field-induced dielectric and magnetic phase transition in multiferroic compounds of RMn_2O_5(R=Er, Ho)2007

    • Author(s)
      H.Kimura
    • Journal Title

      J.Korean Phys.Soc. (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Lattice modulation in YMn_2O_5 and TbMn_2O_5 studied by SR x-ray2007

    • Author(s)
      Y.Noda
    • Journal Title

      J.Korean Phys.Soc. (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Simultaneous Measurements of Magnetic Neutron Diffraction, Electrical Polarization and Permittivity of Multiferroic ErMn_2O_52007

    • Author(s)
      M.Fukunaga
    • Journal Title

      J.Phys.Soc.Jpn. 76(No. 7)(in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Magnetically induced ferroelectricity in multiferroic compounds of RMn_2O_52007

    • Author(s)
      H.Kimura
    • Journal Title

      Ferroelectrics (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Spiral spin structure in commensurate magnetic phase of multiferroic RMn_2O_52007

    • Author(s)
      H.Kimura
    • Journal Title

      J.Phys.Soc.Jpn. 76(No.7)(in press)

    • NAID

      110006350770

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Collinear to spiral spin transformation without changing modulation wavelength upon ferroelectric transition in Tb_<1-x>Dy_xMnO_32006

    • Author(s)
      T.Arima
    • Journal Title

      Phys. Rev. Lett. 96

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Relation between Ferroelectric and Antiferromagnetic order in RMn_2O_52006

    • Author(s)
      Y.Noda
    • Journal Title

      Physica B 385-386

      Pages: 119-122

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Ferroelectricity induced by an incommensurate - commensurate magnetic phase transition in multiferroic HoMn_2O_52006

    • Author(s)
      H.Kimura
    • Journal Title

      J. Phys. Soc. Jpn. 75(NO11)

    • NAID

      110004852745

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Collinear to spiral spin transformation without changing modulation wavelength upon ferroelectric transition in Tb_<1-x> Dy_x MnO_32006

    • Author(s)
      T.Arima
    • Journal Title

      Phys.Rev.Lett. 96

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Ferroelectricity induced by an incommensurate-commensurate magnetic phase transition in multiferroic HoMn_2O_52006

    • Author(s)
      H.Kimura
    • Journal Title

      J.Phys.Soc.Jpn. 75(N011)

    • NAID

      110004852745

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Ferroelectricity induced by an incommensurate- commensurate magnetic phase transition in mutiferroic HoMn_2O_52006

    • Author(s)
      H.Kimura
    • Journal Title

      J. Phys. Soc. Jpn. 75 (NO11)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Collinear to Spiral Spin Transformation without Changing the Modulation Wavelength upon Ferroelectric Transition in Tb_<1-x>Dy_xMnO_32006

    • Author(s)
      T.Arima
    • Journal Title

      Physical Review Letters 96

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Neutron Diffraction Study of Magnetic Ordering Associated with Ferroelectricity in TmMn_2O_52005

    • Author(s)
      S.Kobayashi
    • Journal Title

      J. Phys. Soc. Jpn. 74(NO1)

      Pages: 468-472

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Reinvestigation of dielectric anomalies of RMn_2O_5 associated with successive magnetic phase transitions2005

    • Author(s)
      S.Kobayashi
    • Journal Title

      J. Korean Phys. Soc. 46

      Pages: 289-291

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Neutron Diffraction Study of Magnetic Ordering Associated With Ferroelectricity in TmMn_2O_52005

    • Author(s)
      S.Kobayashi
    • Journal Title

      J.Phys.Soc.Jpn. 74(N01)

      Pages: 468-472

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Reinvestigation of dielectric anomalies of RMn_2O_5 Associated with successive magnetic phase transitions2005

    • Author(s)
      S.Kobayahshi
    • Journal Title

      J.Korean Phys.Soc. 46

      Pages: 289-291

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Neutron Diffraction Study of Magnetic Ordering Associated with Ferroelectricity in TmMn_2O_52005

    • Author(s)
      S.Kobayashi
    • Journal Title

      Journal of the Physical Society of Japan 74

      Pages: 468-472

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Reinvestigation of dielectric anomalies of RMn_2O_5 associated with successive magnetic phase transitions2005

    • Author(s)
      S.Kobayashi
    • Journal Title

      Journal of Korean Physical Society 46

      Pages: 289-291

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 2D-to1D Modulated-to-Lock in Successive Magnetic Phase Transitions Associated with Ferfoelectricity in ErMn_2O_52004

    • Author(s)
      S.Kobayashi
    • Journal Title

      J. Phys. Soc. Jan. 73

      Pages: 1031-1035

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Reinvestigaiton of Simultaneous Magnetic and Ferroelectric Phase Transitions in YMn_2O_52004

    • Author(s)
      S.Kobayashi
    • Journal Title

      J. Phys. Soc. Jpn. 73

      Pages: 1593-1596

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Neutron Diffraction Study of Successive Magnetic Phase Transitions in Ferroelectric TbMn_2O_52004

    • Author(s)
      S.Kobayashi
    • Journal Title

      J. Phys. Soc. Jpn. 73

      Pages: 3439-3443

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 2D-to-1D Modulated-to-Lock in Successive Magnetic Phase Transitions Associated with Ferroelectricity in ErMn_2O_52004

    • Author(s)
      S.Kobayashi
    • Journal Title

      J.Phys.Soc.Jpn 73

      Pages: 1031-1035

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Reinvestigation of Simultaneous Magnetic and Ferroelectric Phase Transitions in YMn_2O_52004

    • Author(s)
      S.Kobayashi
    • Journal Title

      J.Phys.Soc.Jpn. 73

      Pages: 1593-1596

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Neutron Diffraction Study of Successive Magnetic Phase Transitions in Ferroelectric TbMn_2O_52004

    • Author(s)
      S.Kobayashi
    • Journal Title

      J.Phys.Soc.Jpn. 73

      Pages: 3439-3443

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Neutron Diffraction Study of Successive Magnetic Phase Transitions in Ferroelectric TbMn_2O_52004

    • Author(s)
      S.Kobayashi
    • Journal Title

      Journal of the Physical Society of Japan 73

      Pages: 3439-3443

    • Related Report
      2004 Annual Research Report

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Published: 2004-04-01   Modified: 2020-05-15  

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