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Surface reaction control by the use of Laser detonation and STM observation

Research Project

Project/Area Number 16350002
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

TAKAOKA Tsuyoshi  Tohoku University, Institute of multidisciplinary research for advanced materials, lecturer, 多元物質科学研究所, 講師 (90261479)

Co-Investigator(Kenkyū-buntansha) KOMEDA Tadahiro  Tohoku University, Institute of multidisciplinary research for advanced materials, professor, 多元物質科学研究所, 教授 (30312234)
Project Period (FY) 2004 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥14,100,000 (Direct Cost: ¥14,100,000)
Fiscal Year 2005: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2004: ¥12,200,000 (Direct Cost: ¥12,200,000)
Keywordssurface / molecular beam / Laser / STM / FTIR / chemical reaction / catalysis / oxidation
Research Abstract

The object of this research is the chemical reaction control by the use high-speed beam of atoms and molecules prepared with Laser detonation technique. To perform the experiment, inlet of gaseous atoms and molecules, Laser detonation apparatus, STM apparatus to observe the surface reaction, and UHV chamber are required. Among them, Laser detonation apparatus and STM were developed in the research.
1. Laser detonation apparatus
Laser detonation apparatus is composed of Laser source, mirrors to adjust the Laser direction, a focusing mirror to focus the Laser, gas vessel with a nozzle, pipes through which gases are led. The translational energy of atoms and molecules are measured from the time difference between Laser discharge and time of the arrival of the molecule at the mass spectrometer. Timing control system was developed to measure the time of the arrival of the molecule at the mass spectrometer.
2. STM
The species, structure and position of the molecule on the surface after the sample surface is irradiated with high-speed molecules are observed with STM. Position where high-speed molecules are incident on and STM area should be overlapped to observe the STM image after the sample surface are irradiated with the molecules. So, we came up with some ideas. Moreover, piezoelectric parts, which play a very important role in STM system, are easily affected by vibrational noise. However, the noise from pumps is more than we expected. So we came up with some ideas to suppress the noise.

Report

(3 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • Research Products

    (2 results)

All 2004

All Journal Article (2 results)

  • [Journal Article] Ammonia adsorption on and diffusion into thin ice films grown on Pt(111).2004

    • Author(s)
      T.Takaoka
    • Journal Title

      J. Chem. Phys. 121

      Pages: 4331-4338

    • NAID

      120002338513

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Ammonia adsorption on and diffusion into thin ice films grown on Pt(111).2004

    • Author(s)
      T.Takaoka
    • Journal Title

      J.Chem.Phys. 121

      Pages: 4331-4338

    • NAID

      120002338513

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary

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Published: 2004-04-01   Modified: 2016-04-21  

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