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Dynamic Structure and Novel Functions of Dicobalt Complexes

Research Project

Project/Area Number 16350076
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionKyushu University

Principal Investigator

HISAEDA Yoshio  Kyushu University, Department of Applied Chemistry, Professor, 大学院工学研究院, 教授 (70150498)

Co-Investigator(Kenkyū-buntansha) SHIMAKOSHI Hisashi  Kyushu University, Department of Applied Chemistry, Research Associate, 大学院工学研究院, 助手 (00284539)
HAYASHI Takashi  Osaka University, Department of Applied Chemistry, Professor, 工学研究科, 教授 (20222226)
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥15,800,000 (Direct Cost: ¥15,800,000)
Fiscal Year 2006: ¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 2005: ¥5,200,000 (Direct Cost: ¥5,200,000)
Fiscal Year 2004: ¥7,400,000 (Direct Cost: ¥7,400,000)
KeywordsCobalt Complex / Ligand / Redox Behavior / Molecular Recognition / Catalytic Reaction / Molecular Container / DNA Cleavage / Dimerization Reaction / カリウムイオン / デンドリマー / 光応答性 / DNA切断活性 / コバルト-炭素結合 / ラジカル / 酸化還元応答 / 軸配位挙動 / デンドリマー構造 / 動的構造変化 / 超分子構造
Research Abstract

We constructed redox switchable molecular containers with dicobalt complexes. Molecuar switches are the attractive components of molecular electronic devices capable of inducing chemical and physical changes in response to external stimuli such as electrical current, light, and heat. In this study, switching systems were established by using the structural change of dicobalt complexes. Cobalt complexes prefer a six-coordinated structure at the Co(III) state while the Co(II) species prefer a four-coordinated structure. Reversible redox change of dicobalt complexes between Co(III) and Co(II) provides a stable molecular switching system. When diamine was used as axial ligand, each amino groups of diamine were coordinated to cobalt (III) center of planar dicobalt complex with bridged structure. Dissociation of diamines were accompanied by the reduction of dicobalt (III, III) centers to Co(II, II) form by electrochemical stimulus. The bridged structure was recovered with oxidation of cobalt … More centers. We constructed a switching system using this strategy as a molecular container containing a crown ether moiety in diamino-molecules.
One-pot syntheses of new water-soluble dicobalt complexes having two cobalt-carbon bonds were investigated. The complexes were characterized by 'H NMR and UV-vis spectroscopies as well as ESI-MS. These complexes were photo-sensitive and the photo-cleavage of the cobaltcarbon bonds upon irradiation with visible light produced methyl radicals which were detected by ESR spin-trapping techniques. The dicobalt complexes exhibited a high ability for DNA cleavage in comparison to that for the corresponding monocobalt complex.
A novel dicobalt complex, where a dinucleating ligand has two N2O2 metal-binding sites which are linked to each other with a phenyl spacer, was synthesized and its redox behavior was investigated in THF using cyclic voltammetry in comparison with that for the corresponding mononuclear complex. The controlled-potential electrolysis of alkyl halides at-1.60 V vs. Ag/AgCl in the presence of the rigid and planar dicobalt complex led to reductive coupling. The use of rigid, planar dicobalt complex to effect the reductive dimerization of alkyl halides has been demonstrated for the first time. Less

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (66 results)

All 2006 2005 2004

All Journal Article (64 results) Book (2 results)

  • [Journal Article] Oxo(2,3,6,7,12,13,16,17-octaethylporphycenato) molybdenum(V) hexamolybdate2006

    • Author(s)
      D.Maeda, et al.
    • Journal Title

      Acta Cryst.E E62

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Ligand Binding Properties of Two Kinds of Reconstituted Myoglobins with Iron Porphycene Having Propionates : Effect of b-Pyrrolic Position of Two Propionate Side Chains in Porphycene Framework2006

    • Author(s)
      T.Matsuo, et al.
    • Journal Title

      J. Inorg. Biochem 100

      Pages: 1265-1271

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Construction of glycosylated myoglobins by reconstitutional method2006

    • Author(s)
      T.Matsuo, et al.
    • Journal Title

      Chem. Commun.

      Pages: 3131-3133

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] 1,1'-(Ethenylidene)bis(4-chlorobenzene)2006

    • Author(s)
      M.A.Jabbar, et al.
    • Journal Title

      Acta Cryst.C 61・11

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Organic/Inorganic Hybrid Nanomaterials with Vitamin B_<12> Functions2006

    • Author(s)
      Y.Hisaeda, et al.
    • Journal Title

      Sci. Tech. Adv. Mater. 7・7

      Pages: 655-661

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Crystal Structure and Peroxidase Activity of Myoglobin Reconstituted with Iron Porphycene2006

    • Author(s)
      T.Hayashi et al.
    • Journal Title

      Inorg. Chem. 45・26

      Pages: 10530-10536

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Molecular Programming of Organogelators Which Can Accept [60]Fullerene by Encapsulation2006

    • Author(s)
      M.Shirakawa, N.Fujita, H.Shimakoshi, Y.Hisaeda, S.Shinkai
    • Journal Title

      Tetrahedron Vol.62

      Pages: 2016-2024

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Oxo(2,3,6,7,12,13,16,17-octaethylporphycenato) molybdenum(V) hexamolybdate2006

    • Author(s)
      D.Maeda, I.Aritome, H.Shimakoshi, Y.Hisaeda
    • Journal Title

      Acta Cryst.E Vol.E62

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Iron Porphyrin-Cyclodextrin Supramolecular Complex as a Functional Model of Myoglobin in Aqueous Solution2006

    • Author(s)
      K.Kano, H.Kitagishi, C.Dagallier, M.Kodera, T.Matsuo, T.Hayashi, Y.Hisaeda, S.Hirota
    • Journal Title

      Inorg.Chem. Vol.45, No.11

      Pages: 4448-4460

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Ligand Binding Properties of Two Kinds of Reconstituted Myoglobins with Iron Porphycene Having Propionates : Effect of β-Pyrrolic Position of Two Propionate Side Chains in Porphycene Framework2006

    • Author(s)
      T.Matsuo, T.Ikegami, H.Sato, Y.Hisaeda, T.Hayashi
    • Journal Title

      J.Inorg.Biochem. Vol.100

      Pages: 1265-1271

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Construction of glycosylated myoglobins by reconstitutional method2006

    • Author(s)
      T.Matsuo, H.Nagai, Y.Hisaeda, T.Hayashi
    • Journal Title

      Chem.Commun.

      Pages: 3131-3133

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Immobilization of a Binuclear Ruthenium(III) Complex on a Gold (111) Surface : Observations of Proton-coupled Electron Transfer and Electrochemical Durability in Aqueous Media2006

    • Author(s)
      H.Uehara, M.Abe, Y.Hisaeda, K.Uosaki, Y.Sasaki
    • Journal Title

      Chem.Lett. Vol.35, No.10

      Pages: 1178-1179

    • NAID

      10018323533

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 1,1'-(Ethenylidene)bis(4-chlorobenzene)2006

    • Author(s)
      M.A.Jabbar, I.Aritome, H.Shimakoshi, Y.Hisaeda
    • Journal Title

      Acta Cryst.C Vol.61, Part 11

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Organic/Inorganic Hybrid Nanomaterials with Vitamin B_<12> Functions2006

    • Author(s)
      Y.Hisaeda, T.Masuko, E.Hanashima, T.Hayashi
    • Journal Title

      Sci.Tech.Adv.Mater. Vol.7, No.7

      Pages: 655-661

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Crystal Structure and Peroxidase Activity of Myoglobin Reconstituted with Iron Porphycene2006

    • Author(s)
      T.Hayashi, D.Murata, M.Makino, H.Sugimoto, T.Matsuo, H.Sato, Y.Shiro, Y.Hisaeda
    • Journal Title

      Inorg.Chem. Vol.45, No.26

      Pages: 10530-10536

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Oxo(2,3,6,7,12,13,16,17-octaethylporphycenato) molybdenum(V) hexamolybdate2006

    • Author(s)
      D.Maeda, et al.
    • Journal Title

      Adta Cryst.E, E62

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Ligand Binding Properties of Two Kinds of Reconstituted Myoglobins with Iron Porphycene Having Propionates : Effect of β-Pyrrolic Position of Two Propionate Side Chains in Porphycene Framework2006

    • Author(s)
      T.Matsuo, et al.
    • Journal Title

      J. Inorg. Biochem 100

      Pages: 1265-1271

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 1,1'-(Ethenylidene)bis(4-chlorobenzene)2006

    • Author(s)
      M.A.Jabbar, et al.
    • Journal Title

      Acta Cryst.C, 61・11

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Hydrophobic Vitamin B_<12> Part 20 : Supernucleophilicity of CO(I) Heptamethyl Cobyrinate toward Various Organic Halides2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Bulletin Chemical Society of Japan 78

      Pages: 859-863

    • NAID

      10015716947

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis and Redox Behavior of Dicobalt Complexes Having Flexible and Rigid Linkers2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Bulletin Chemical Society of Japan 78

      Pages: 1040-1046

    • NAID

      10016143123

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Recycled Catalysis of a Hydrophobic Vitamin B_<12> in an Ionic Liquid2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Chem. Lett. 34・8

      Pages: 1096-1097

    • NAID

      10016648755

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] (Z)-2,3-Dichloro-1,1,4,4-tetrakis(4-chlorophenyl)but-2-ene2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Acta Cryst.E E60

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Redox Switchable Molecular Containers Consisting of Dicobalt Complexes2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Inorg. Chem. 44・25

      Pages: 9134-9136

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis and Redox Behavior of Dicobalt Complexes Having Flexible and Rigid Linkers2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Bull. Chem. Soc. Jpn. 78・6

      Pages: 1040-1046

    • NAID

      10016143123

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Dioxygen Binding to a Cobalt(II) Porphycene Complex and its Auto-oxidized Cobalt(III) Complex2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Bull. Chem. Soc. Jpn. 78・9

      Pages: 1619-1623

    • NAID

      40006863904

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Unusual Ligand Discrimination by a Myoglobin Reconstituted with a Hydrophobic Domain-Linked Heme2005

    • Author(s)
      H.Sato, M.Watanabe, Y.Hisaeda, T.Hayashi
    • Journal Title

      J.Am.Chem.Soc. Vol.127

      Pages: 56-57

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Hydrophobic Vitamin B_<12> Part 20 : Supernucleophilicity of Co(I) Heptamethyl Cobyrinate toward Various Organic Halides2005

    • Author(s)
      H.Shimakoshi, Y.Maeyama, T.Kaieda, T.Matsuo, E.Matsui, Y.Naruta, Y.Hisaeda
    • Journal Title

      Bull.Chem.Soc.Jpn. Vol.78

      Pages: 859-863

    • NAID

      10015716947

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis and Redox Behavior of Dicobalt Complexes Having Flexible and Rigid Linkers2005

    • Author(s)
      H.Shimakoshi, S.Hirose, M.Ohba, T.Shiga, H.Okawa, Y.Hisaeda
    • Journal Title

      Bull.Chem.Soc.Jpn. Vol.78

      Pages: 1040-1046

    • NAID

      10016143123

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] (Z)-2,3-Dichloro-1,1,4,4-tetrakis(4-chlorophenyl)but-2-ene2005

    • Author(s)
      H.Shimakoshi, I.Aritome, M.Tokunaga, Y.Hisaeda
    • Journal Title

      Acta Cryst.E Vol.E60

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Recycled Catalysis of a Hydrophobic Vitamin B_<12> in an Ionic Liquid2005

    • Author(s)
      H.Shimakoshi, S.Kudo, Y.Hisaeda
    • Journal Title

      Chem.Lett. Vol.34

      Pages: 1096-1097

    • NAID

      10016648755

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Gene transfection into HeLa cells by vesicles containing cationic peptide lipid2005

    • Author(s)
      Y.Ohama, Y.Heike, T.Sugahara, K.Sakata, N.Yoshimura, Y.Hisaeda, M.Hosokawa, S.Takashima, K.Kato
    • Journal Title

      Bioscience, Biotechnology and Biochemistry Vol.69

      Pages: 1453-1458

    • NAID

      130000030229

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Dioxygen Binding to a Cobalt(II) Porphycene Complex and its Auto-oxidized Cobalt(III) Complex2005

    • Author(s)
      H.Shimakoshi, I.Aritome, S.Hirota, Y.Hisaeda
    • Journal Title

      Bull.Chem.Soc.Jpn. Vol.78

      Pages: 1619-1623

    • NAID

      130004151970

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Preparation and O_2 Binding Study of Myoglobin Having a Cobalt Porphycene2005

    • Author(s)
      T.Matsuo, T.Tsuruta, K.Maehara, H.Sato, Y.Hisaeda, T.Hayashi
    • Journal Title

      Inorg.Chem. Vol.44

      Pages: 9391-9396

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Redox Switchable Molecular Containers Consisting of Dicobalt Complexes2005

    • Author(s)
      H.Shimakoshi, H.Takemoto, I.Aritome, Y.Hisaeda
    • Journal Title

      Inorg.Chem. Vol.44

      Pages: 9134-9136

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Preparation of Cationic Immunovesicles Containing Cationic Peptide Lipid for Specific Drug Delivery to Target Cells2005

    • Author(s)
      T.Sugahara, S.Kawashima, A.Oda, Y.Hisaeda, K.Kato
    • Journal Title

      Cytotechnology, International Journal of Cell Culture and Biotechnology incorporating Methods in Cell Science Vol.47

      Pages: 51-57

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis and Redox Behavior of Dicobalt Complexes Having Flexible and Rigid Linkers2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Bull.Chem.Soc.Jpn. 78・6

      Pages: 1040-1046

    • NAID

      10016143123

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Redox Switchable Molecular Containers Consisting of Dicobalt Complexes2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Inorg.Chem. 44・25

      Pages: 9134-9136

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Hydrophobic Vitamin B_<12> Part 20 : Supernucleophilicity of Co(I) Heptamethyl Cobyrinate toward Various Organic Halides2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Bull.Chem.Soc.Jpn. 78・5

      Pages: 859-863

    • NAID

      10015716947

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Recycled Catalysis of a Hydrophobic Vitamin B_<12> in an Ionic Liquid2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Chem.Lett. 34・8

      Pages: 1096-1097

    • NAID

      10016648755

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Preparation and O_2 Binding Study of Myoglobin Having a Cobalt Porphycene2005

    • Author(s)
      T.Matsuo, et al.
    • Journal Title

      Inorg.Chem. 44・25

      Pages: 9391-9396

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Hydrophobic Vitamin B12 Part 20: Supernucleophilicity of Co(I) Heptamethyl Cobyrinate toward Various Organic Halides2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Bulletin Chemical Society of Japan 78(in press)

    • NAID

      130004058678

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis and Redox Behavior of Dicobalt Complexes Having Flexible and Rigid Linkers2005

    • Author(s)
      H.Shimakoshi, et al.
    • Journal Title

      Bulletin Chemical Society of Japan 78(in press)

    • NAID

      10016143123

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis and Characterization of μ-Oxodiiron(III) Complexes of Porphyicenes with Electron-withdrawing Substituents2004

    • Author(s)
      T.Baba, et al.
    • Journal Title

      Chemistry Letters 33・7

      Pages: 906-907

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis and simple separation of β-pyrrole sulfonated porphyicenes2004

    • Author(s)
      T.Baba, et al.
    • Journal Title

      Tetrahedron Letters397 45・31

      Pages: 5973-5975

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Electrochemical reactions mediated by hydrophobic vitamin B122004

    • Author(s)
      Y.Hisaeda, et al.
    • Journal Title

      J. Porphyrins Phthalocyanines 8・1-3

      Pages: 397-397

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Reaction of β-brominated porphycene cobalt(III) with olefins2004

    • Author(s)
      I.Aritome, et al.
    • Journal Title

      J. Porphyrins Phthalocyanines 8・1-3

      Pages: 596-596

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Preparation and Electrochemical Behavior of Hydrophobic Vitamin B_<12> Covalently Immobilized onto Platinum Electrode2004

    • Author(s)
      H.Shimakoshi, M.Tokunaga, K.Kuroiwa, N.Kimizuka, Y.Hisaeda
    • Journal Title

      Chem.Commun.

      Pages: 50-51

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Hybridization of Modified-Heme Reconstitution and Distal Histidine Mutation to Functionalize Sperm Whale Myoglobin2004

    • Author(s)
      H.Sato, T.Hayashi, T.Ando, Y.Hisaeda, T.Ueno, Y.Watanabe
    • Journal Title

      J.Am.Chem.Soc. Vol.126, No.2

      Pages: 436-437

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Hydrophobic Vitamin B_<12>. Part 19. Electroorganic Reaction of DDT Mediated by Hydrophobic Vitamin B_<12>2004

    • Author(s)
      H.Shimakoshi, M.Tokunaga, Y.Hisaeda
    • Journal Title

      Dalton Trans.

      Pages: 878-882

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis and Characterization of m-Oxodiiron(III) Complexes of Porphycenes with Electron-Withdrawing Substituents2004

    • Author(s)
      T.Baba, H.Shimakoshi, I.Aritome, Y.Hisaeda
    • Journal Title

      Chem.Lett. Vol.33, No.7

      Pages: 906-907

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis and Simple Separation of b-Pyrrole Sulfonated Porphycenes2004

    • Author(s)
      T.Baba, H.Shimakoshi, Y.Hisaeda
    • Journal Title

      Tetrahedron Lett. Vol.45, No.31

      Pages: 5973-5975

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Enhancement of Enzymatic Activity for Myoglobins by Modification of Heme-Propionate Side Chains2004

    • Author(s)
      T.Hayashi, H.Sato, T.Matsuo, T.Matsuda, Y.Hitomi, Y.Hisaeda
    • Journal Title

      J.Porphyrins Phthalocyanines Vol.8

      Pages: 255-264

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Modification of Hemoproteins by Reconstitutional Methods2004

    • Author(s)
      T.Hayashi, H.Sato, T.Matsuo, Y.Hisaeda
    • Journal Title

      J.Porphyrins Phthalocyanines Vol.8

      Pages: 395-395

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Electrochemical Reactions Mediated by Hydrophobic Vitamin B_<12>,2004

    • Author(s)
      Y.Hisaeda, H.Shimakoshi, M.Tokunaga, T.Hayashi
    • Journal Title

      J Porphyrins Phthalocyanines Vol.8

      Pages: 397-397

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Reaction of β-Brominated Porphycene Cobalt(III) with Olefins2004

    • Author(s)
      I.Aritome, H.Shimakoshi, T.Hayashi, Y.Hisaeda
    • Journal Title

      J.Porphyrins Phthalocyanines Vol.8

      Pages: 596-596

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Ligand Binding Properties of Reconstituted Myoglobin with Iron Porphycene2004

    • Author(s)
      T.Matsuo, T.Hayashi, Y.Hisaeda
    • Journal Title

      J.Porphyrins Phthalocyanines Vol.8

      Pages: 763-763

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Enhancement of Peroxidase Activity in Myoglobin by Iron Porphycene as a Prosthetic Group2004

    • Author(s)
      D.Murata, H.Sato, T.Hayashi, Y.Hisaeda
    • Journal Title

      J.Porphyrins Phthalocyanines Vol.8

      Pages: 775-775

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] High Peroxidase Activity of Sperm Whale Myoglobin by Hybridization of Modified-Heme Reconstitution and Distal Histidine Mutation2004

    • Author(s)
      H.Sato, T.Hayashi, Y.Hisaeda
    • Journal Title

      J.Porphyrins Phthalocyanines Vol.8

      Pages: 823-823

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Photochemical Dechlorination of DDT Catalyzed by a Hydrophobic Vitamin B_<12> and a Photosensitizer under Irradiation with Visible Light2004

    • Author(s)
      H.Shimakoshi, M.Tokunaga, T.Baba, Y.Hisaeda
    • Journal Title

      Chem.Commun.

      Pages: 1806-1807

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 1,1,4,4-Tetrakis(4-Chloropheny1)-2,3-Dichloro-2-Butene (E, Z)2004

    • Author(s)
      H.Shimakoshi, I.Aritome, M.Tokunaga, Y.Hisaeda
    • Journal Title

      Acta Cryst.E Vol.E60

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Chemical Properties of Sperm Whale Myoglobins Reconstituted with Monopropionate Hemins2004

    • Author(s)
      T.Hayashi, T.Nakagawa, K.Harada, T.Matsuo, Y.Hitomi, Y.Hisaeda
    • Journal Title

      Chem.Lett. Vol.33, No.11

      Pages: 1512-1513

    • NAID

      10013772287

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Ligand Binding Properties of Myoglobin Reconstituted with Iron Porphycene : Unusual O_2 Binding Selectivity against CO Binding,2004

    • Author(s)
      T.Matsuo, H.Dejima, S.Hirota, D.Murata, H.Sato, T.Ikegami, H.Hori, Y.Hisaeda, T.Hayashi
    • Journal Title

      J.Am.Chem.Soc. Vol.126, No.49

      Pages: 16007-16017

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis and Characterization of μ-Oxodiiron(III) Complexes of Porphycenes with Electron-withdrawing Substituents2004

    • Author(s)
      T.Baba, et al.
    • Journal Title

      Chemistry Letters 33・7

      Pages: 906-907

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Synthesis and simple separation of β-pyrrole sulfonated porphycenes2004

    • Author(s)
      T.Baba, et al.
    • Journal Title

      Tetrahedron Letters397 45・31

      Pages: 5973-5975

    • Related Report
      2004 Annual Research Report
  • [Book] モレキュラーインフォーマティクスを拓く分子機能材料2006

    • Author(s)
      久枝良雄
    • Total Pages
      9
    • Publisher
      日刊工業新聞
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Book] 有機電解合成の新展開(金属錯体を用いる有機電解合成)2004

    • Author(s)
      久枝良雄
    • Total Pages
      22
    • Publisher
      シーエムシー出版
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2004 Annual Research Report

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Published: 2004-04-01   Modified: 2016-04-21  

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