Clarification of Mechanisms for Surface Photoreactions and Improvement of Photocatalytic Activity for Visible-light Responsive Metal Oxides
| Project/Area Number |
16350114
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Osaka University |
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Principal Investigator |
NAKATO Yoshihiro Osaka University, Graduate School of Engineering Science, Professor, 大学院・基礎工学研究科, 教授 (70029502)
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| Co-Investigator(Kenkyū-buntansha) |
IMANISHI Akihito Osaka University, Graduate School of Engineering Science, Associate Professor, 大学院・基礎工学研究科, 助教授 (60304036)
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| Project Period (FY) |
2004 – 2005
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| Project Status |
Completed (Fiscal Year 2005)
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| Budget Amount *help |
¥16,100,000 (Direct Cost: ¥16,100,000)
Fiscal Year 2005: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 2004: ¥13,100,000 (Direct Cost: ¥13,100,000)
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| Keywords | solar energy / photocatalyst / metal oxides / nanoparticles / photoluminescene / reaction mechanism / oxygen evolution / surface structural control / 表面分光法 |
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| Research Abstract |
With an aim to improve the activity of TiO_2 and related metal-oxide photocatalysts for solar water splitting and photodecomposition of harmful organic compounds, we have studied molecular mechanisms of surface photoreactions on TiuO_2 (rutile) and explored new active visible-light responsive metal-oxide photocatalysts. At first, we have succeeded in preparing atomically flat and stable n-TiO_2 (rutile) (110) and (100) surfaces by a novel method of HF-etching and annealing at 550℃. This success has for the first time enabled us to reveal interesting crystal-face dependences of important properties of TiO_2 (rutile), such as the flat-band potential (U_<fb>), the hole reactivity, and the photoluminescense (PL) spectrum which arises from a precursor (called surface-trapped hole, s.t.h.) of photooxidation reaction of water on TiO_2. In addition, we have clarified that the occurrence of the photooxidation reaction of water on the atomically flat TiO_2 (110) and (100) surfaces has led to their roughening on an atomic scale together with weakening of the PL intensity. These results have been explained well by our recently proposed mechanism that the photooxidation reaction of water on TiO_2 is initiated by a nucleophilic attack of water (Lewis base) to the surface-trapped hole (s.t.h.) (Lewis acid), giving strong support to the mechanism. In order to investigate further the validity of the mechanism, we have also studied the mechanism for the water photooxidation reaction on nitrogen-containing metal oxides, such as N-doped TiO_2 and TaON, and found that the reaction proceeds by the same mechanism as on TiO_2 as well. Furthermore, we have explored new visible-light responsive metal-oxide photocatalysts and found that mixed metal oxides such as BiCu_2VO_6 and BiZn_2VO_6 show higher activity that BiVO_4 that is known as one of the most active visible-light driven photocatalysts.
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Report
(3 results)
Research Products
(27 results)
