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Study on preparation of organicinorganic hybrid separation membrane responsive stimuli

Research Project

Project/Area Number 16350115
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionUniversity of Hyogo

Principal Investigator

YAZAWA Tetsuo  University of Hyogo, Graduate school of engineering, Professor, 大学院工学研究科, 教授 (50347522)

Co-Investigator(Kenkyū-buntansha) YUSA Shinichi  University of Hyogo, Graduate school of engineering, Assistant Professor, 大学院工学研究科, 助教 (00301432)
JIN Tetsuro  National Institute of Advanced Industrial Science and Technology, Researcher, 環境科学技術研究部門, 研究員 (30357248)
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥13,400,000 (Direct Cost: ¥13,400,000)
Fiscal Year 2006: ¥4,200,000 (Direct Cost: ¥4,200,000)
Fiscal Year 2005: ¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 2004: ¥5,800,000 (Direct Cost: ¥5,800,000)
KeywordsPorous glass / Phase separation / Separation membrane / organic-inorganic nanohybrid / Response to stimuli / pH response / Temperature response / Light response
Research Abstract

Recently active researches have been carried out on novel membranes responsive to outer stimulus. Such the membranes are widely applicable for various kinds of fields, for instance drug delivery system, nanomachines, control release etc. Much attention has been paid to organic polymer membranes for its high shaping ability and elasticity. However such the organic polymer membranes are weak to organic solvents and easily swollen by organic solvents and water. For these reasons, it is very difficult to prepare a membrane responsive to outer stimulus with recognition of organic molecule by organic polymer. On the other hand, porous glass membranes which possess relatively sharp pore size distribution are now actively investigated because of their high gas selectivity, ease of control of pore size and easily molding. Inorganic membrane such as porous glass membrane has high resistance for organic compounds and does not have such the swelling. This means the pore size of porous glass membrane is unchanged by swelling. Additionally there is some possibility the speed of response is fast, and can be avoidable for the fatigue of response because of the existence of such the rigid nanopore. In this research, pH, temperature and light responsive membrane with molecular recognition can be obtained successfully by surface modification of the porous glass membrane for the first time.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (52 results)

All 2007 2006 2005 2004

All Journal Article (45 results) Book (7 results)

  • [Journal Article] Preparation of CO_2-selective separation membranes with highly chemical and thermal stability prepared from inorganic-organic nanohybrids containing branched polyethrs2007

    • Author(s)
      T.Yazawa, M.Kishimoto, T.Inoue, A.Mineshige, M.Kobune, K.Kuraoka
    • Journal Title

      J. Mat. Sci. 47

      Pages: 723-727

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Preparation of CO_2-selective separation membranes with highly chemical and thermal stability prepared from inorganic-organic nanohybrids containing branched polyethers2007

    • Author(s)
      T.Yazawa, M.Kishimoto, T.Inoue, A.Mineshige, M.Kobune, K.Kuraoka
    • Journal Title

      J. Mat. Sci. 47

      Pages: 723-727

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Polyelectrolyte Chain Stiffness, Charge Mobility, and Charge Sequences on Binding to Proteins and Micelles2006

    • Author(s)
      Cooper.C.L., Goulding, A., Kayitmazer, A.B., Ulrich, S., Stoll, S., Turksen, S., Yusa.S., Kumar, A., Dubin, P.L.
    • Journal Title

      Biomacromolecues 7

      Pages: 1025-1035

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Characterization of pH-dependent micellization of polystyrene-based cationic block copolymers prepared by reversible addition-fragmentation chain transfer (RAFT) radical polymerization2006

    • Author(s)
      Yoshiro Mitsukami, Akihito Hashidzume, Shin-ich Yusa, Yotaro Morishima, Andrew B. Lowe, Charles L. McCormick
    • Journal Title

      Polymer 47

      Pages: 4333-4340

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Single-Line EPR Spectra from Radicals Encapsulated in Aggregates of Amphiphilic Block Copolymers with Hydrophobic Dendritic Pendants in Water2006

    • Author(s)
      Kana Tamano, Toshiyuki Tanaka, Kunio Awaga, Toyoko Imae, Shin-ichi Yusa, Yoshihiko Shimada
    • Journal Title

      Macromolecular Rapid Communications 27

      Pages: 1764-1768

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] CA Resist with Side Chain PAG Group for EUV Resist2006

    • Author(s)
      Takeo Watanabe, Yasuyuki Fukushima, Hideaki Shiotani, Masamichi Hayakawa, Satoshi Ogi, Yusuke Endo, Tomotaka Yamanaka, Shinichi Yusa, Hiroo Kinoshita
    • Journal Title

      J. Photopolym. Sci. Technol. 19

      Pages: 521-524

    • NAID

      130004833129

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Light-Response of N2 Permeation Using Gold Colloid Coated Porous Glass Modified By Azo Derivative Including Thiol2006

    • Author(s)
      T.Jin, S.Yusa, T.Yazawa
    • Journal Title

      Chemistry Letters 35

      Pages: 1294-1295

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Effects of Polyelectrolyte Chain Stiffness. Charge Mobility, and Charge Sequences on Binding to Proteins and Micelles2006

    • Author(s)
      Cooper, C.L., Goulding, A., Kayitmazer, A.B., Ulrich, S., Stoll, S., Turksen, S., Yusa, S., Kumar, A., Dubin, P.L.
    • Journal Title

      Biomacromolecues 7

      Pages: 1025-1035

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Characterization of pH-dependent micellization of polystyrene-based cationic block copolymers prepared by reversible addition-fragmentation chain transfer (RAFT) radical polymerization2006

    • Author(s)
      Y.Mitsukami, A.Hashidzume, S.Yusa, Y.Morishima, A.B.Lowe, C.L.McCormick
    • Journal Title

      Polymer 47

      Pages: 4333-4340

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Single-Line EPR Spectra from Radicals Encapsulated in Aggregates of Amphiphilic Block Copolymers with Hydrophobic Dendritic Pendants in Water2006

    • Author(s)
      K.Tamano, T.Tanaka, K.Awaga, T.Imae, S.Yusa, Y.Shimada
    • Journal Title

      Macromol.Rapid Commun. 27

      Pages: 1764-1768

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Light-Response of N2 Permeation Using Gold Colloid Coated Porous Glass Modified By Azo Derivative Including Thiol2006

    • Author(s)
      T.Jin, S.Yusa, T.Yazawa
    • Journal Title

      Chem. Lett. 35

      Pages: 1294-1295

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Polyelectrolyte Chain Stiffness, Charge Mobility, and Charge Sequences on Binding to Proteins and Micelles2006

    • Author(s)
      Cooper, C.L, Goulding, A, Kayitmazer, a.B, Ulrich, S, Stoll, S, Turksen, S, Yusa.S, Kumar, A, Dubin, P.L.
    • Journal Title

      Biomacromolecues 7

      Pages: 1025-1035

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Characterization of pH-dependent micellization of polystyrene-based cationic block copolymers prepared by reversible addition-fragmentation chain transfer (RAFT) radical polymerization2006

    • Author(s)
      Yoshiro Mitsukami, Akihito Hashidzume, Shin-ich Yusa, Yotaro Morishima, Andrew B. Lowe, Charles L, Mc Cormick
    • Journal Title

      Polymer 47

      Pages: 4333-4340

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Structure-Selective Dye Uptake into an Aggregate of a Copolymer with Linear Polyelectrolyte Block an 〓〓〓〓〓〓〓〓〓〓〓〓〓〓〓〓2005

    • Author(s)
      K.Tamano, T.Imae, S.Yusa, Y.Shimada
    • Journal Title

      J. Phys. Chem. B 109

      Pages: 1226-1230

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Facilitated transport of C2H4 in a SiO2-poly (N-vinylpyrrolidone) -Ag+ inorganic-organic hybrid membrane2005

    • Author(s)
      C.SU, K.Kuraoka, T.Yazawa
    • Journal Title

      J. Sol-Gel Science and Technology 33

      Pages: 327-332

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Stability and pore size effect of proton-conducting organic-inorganic hybrid membranes prepared through surface modification of porous glass2005

    • Author(s)
      T.Kikukawa., K.Kuraoka, M.Yamashita, K.Fukumi, K.Hirao, T.Yazawa
    • Journal Title

      J. Memb. Sci. 259

      Pages: 161-166

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Thin palladium film support on SiO2-modified porous stainless steel for a high-hydrogen-flux membrane2005

    • Author(s)
      C.SU, T.Jin, K.Kuraoka, Y.Matsumura, T.Yazawa
    • Journal Title

      Ind. Eng. Chem. Res. 44

      Pages: 3053-3058

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Conformational effects on the performance and selectivity of a polymeric pseudostationary phase in electrokinetic chromatography2005

    • Author(s)
      J.P.McCarney, R.D.Loflin, E.Rauk, S.Yusa, C.P.Palmer
    • Journal Title

      Electrophoresis 26

      Pages: 841-848

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Synthesis of Well-Defined Amphiphilic Block Copolymers Having Phospholipid Polymer Sequences as a Novel Biocompatible Polymer Micelle Reagent2005

    • Author(s)
      S.Yusa, K.Fukuda, T.Yamamoto, K.Ishihara, Y.Morishima
    • Journal Title

      Biomacromolecules 6

      Pages: 663-670

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] pH-Responsive Micellization of Cationic Diblock Copolymers Prepared by Reversible Addition-Fragmentation Chain Transfer (RAFT) Radical Polymerization2005

    • Author(s)
      S.Yusa, Y.Konishi, Y.Mitsukami, T.Yamamoto, Y.Morishima
    • Journal Title

      Polymer Journal 37

      Pages: 480-488

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Effect of calcium additive on structural changes under heat treatment in sodium borosilicate glasses2005

    • Author(s)
      H.Miyoshi, D.Chen, H.Masui, T.Yazawa, T.Akai
    • Journal Title

      J. Sol-Gel Science and Technology 33

      Pages: 327-332

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Stability and pore size effect of proton-conducting organic-inorganic hybrid membranes prepared through surface modification of porous glass2005

    • Author(s)
      T.Kikukawa, K.Kuraoka, M.Yamashita, K.Fukumi, K.Hirao, T.Yazawa
    • Journal Title

      Ind. Eng. Chem. Res. 44

      Pages: 3053-3058

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Thin palladium film support on Si02-modified porous stainless steel for a high-hydrogen-flux membrane2005

    • Author(s)
      C.SU, T.Jin, K.Kuraoka, Y.Matsumura, T.Yazawa
    • Journal Title

      J. Sol-Gel Science and Technology 33

      Pages: 327-332

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Facilitated transport of C2H4 in a Si02-poly (N-vinylpyrrolidone)-Ag+ inorganic-organic hybrid membrane2005

    • Author(s)
      C.SU, K.Kuraoka, T.Yazawa
    • Journal Title

      Electrophoresis 26

      Pages: 841-848

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Conformational effects on the performance and selectivity of a polymeric pseudostationary phase in electrokinetic chromatography2005

    • Author(s)
      J.P.McCarney, R.D.Loflin, E.Rauk, S.Yusa, C.P.Palmer
    • Journal Title

      Biomacromolecules 6

      Pages: 663-670

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis of Well-Defined Amphiphilic Block Copolymers Having Phospholipid Polymer Sequences as a Novel Biocompatible Polymer Micelle Reagent2005

    • Author(s)
      S.Yusa, K.Fukuda, T.Yamamoto.K.Ishihara, Y.Morishima
    • Journal Title

      Biomacromolecues 6

      Pages: 663-670

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Facilitated transport of C2H4 in a SiO2-poly(N-vinylpyrrolidone)-Ag+ inorganic- organic hybrid membrane2005

    • Author(s)
      C.SU, K.Kuraoka, T.Yazawa
    • Journal Title

      J.Sol-Gel Science and Technology 33

      Pages: 327-332

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Stability and pore size effect of proton-conducting organic-inorganic hybrid membranes prepared through surface modification of porous glass2005

    • Author(s)
      T.Kikukawa, K.Kuraoka, M.Yamashita, K.Fukumi, K.Hirao, T.Yazawa
    • Journal Title

      J.Memb.Sci. 259

      Pages: 161-166

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Thin palladium film support on SiO2-modified porous stainless steel for a high-hydrogen-flux membrane2005

    • Author(s)
      C.SU, T.Jin, K.Kuraoka, Y.Matsumura, T.Yazawa
    • Journal Title

      Ind.Eng.Chem.Res. 44

      Pages: 3053-3058

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structure-Selective Dye Uptake into an Aggregate of a Copolymer with Linear Polyelectrolyte Block and Hydrophobic Block Carrying Pendant Dendritic Moiety in Water2005

    • Author(s)
      K.Tamano, T.Imae, S.Yusa, Y.Shimada
    • Journal Title

      J.Phys.Chem.B 109

      Pages: 1226-1230

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Preparation of an organic-inorganic hybrid ionic conductive material with thermal and chemical stabilit2004

    • Author(s)
      T.Kikukawa, K.Kuraoka, K.Kawabe, T.Yazawa
    • Journal Title

      J.Am. Ceram.Soc. 87(3)

      Pages: 504-506

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Preparation of a membrane with aligned nanopores using an organic-inorganic hybrid technique2004

    • Author(s)
      K.Kuraoka, Y.Tanaka, M.Yamashita, T.Yazawa
    • Journal Title

      Chem. Commun

      Pages: 1198-1199

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Preparation of a porous ITO electrode2004

    • Author(s)
      H.Lin, T.Jin, A.Dmytruk, M.Saito, T.Yazawa
    • Journal Title

      J.Photochem.and Photobiol. A : Chemistry 164

      Pages: 173-177

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Heat-Induced Association and Dissociation Behavior of Amphiphilic Diblock Copolymer Synthesized via〓〓〓〓〓〓〓〓〓〓〓〓〓〓〓2004

    • Author(s)
      S.Yusa, Y.Shimada, Y.Mitsukami, T.Yamamoto, Y.Morishim
    • Journal Title

      Macromolecules 37

      Pages: 7507-7513

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] NMR study of structural changes of alkali borosilicate glasses with heat treatment2004

    • Author(s)
      D.Chen, H.Miyoshi, H.Masui, T.Akai, T.Yazawa
    • Journal Title

      J. Non - Cryst. Solids 345&346

      Pages: 104-107

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Preparation of an organic-inorganic hybrid ionic conductive material with thermal and chemical stability2004

    • Author(s)
      T.Kikukawa, K.Kuraoka, K.Kawabe, T.Yazawa
    • Journal Title

      J.Am.Ceram.Soc. 87

      Pages: 504-506

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Preparation of a membrane with aligned nanopores using an organic-inorganic hybrid technique2004

    • Author(s)
      K.Kuraoka, Y.Tanaka, M.Yamashita, T.Yazawa
    • Journal Title

      Chem.Commun.

      Pages: 1198-1199

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Preparation of a porous ITO electrode2004

    • Author(s)
      H.Lin, T.Jin, ADmytruk, M.Saito, T.Yazawa
    • Journal Title

      Photochem.and Photobiol. A : Chemistiry 164

      Pages: 173-177

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Heat-Induced Association and Dissociation Behavior of Amphiphilic Diblock Copolymer Synthesized via Reversible Addition-Fragmentation Chain Transfer Radical Polymer2004

    • Author(s)
      S.Yusa, Y Shimada, Y.Mitsukami, T Yamamoto, Y.Morishima
    • Journal Title

      J. Non-Cryst. Sol ids 345&346

      Pages: 99-103

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Facilitated transport of C2H4 in Si02-poly(N-vinylpyrrolidone)-Ag+ inorganic-organic hybrid membrane2004

    • Author(s)
      C.SU, K.Kuraoka, T.Yazawa
    • Journal Title

      J. Memb. Sci. 256

      Pages: 161-166

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Preparation of an organic-inorganic hybrid ionic conductive material with thermal and chemical stability2004

    • Author(s)
      T.Kikukawa, K.Kuraoka, K.Kawabe, T.Yazawa
    • Journal Title

      J.Am.Ceram.Soc. 87(3)

      Pages: 504-506

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Preparation of a membrane with aligned nanopores using an organic-inorganic hybrid technique2004

    • Author(s)
      K.Kuraoka, Y.Tanaka, M.Yamashita, T.Yazawa
    • Journal Title

      Chem.Commun

      Pages: 1198-1199

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Preparation of a porous ITO electrode2004

    • Author(s)
      H.Lin, T.Jin, A.Dmytruk, M.Saito, T.Yazawa
    • Journal Title

      J.Photochem.and Photobiol A : Chemistry 164

      Pages: 173-177

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Heat-Induced Association and Dissociation Behavior of Aniphiphilic Diblock Copolymer Synthesized via Reversible Addition-Fragmentation Chain Transfer Radical Polymerization2004

    • Author(s)
      S.Yusa, Y.Shimada, Y.Mitsukami, T.Yamamoto, Y.Morishima
    • Journal Title

      Macromolecules 37

      Pages: 7507-7513

    • Related Report
      2004 Annual Research Report
  • [Journal Article] NMR study of structural changes of alkali borosilicate glasses with heat treatment2004

    • Author(s)
      D.Chen, H.Miyoshi, H.Masui, T.Akai, T.Yazawa
    • Journal Title

      J.Non-Cryst.Solids 345&346

      Pages: 104-107

    • Related Report
      2004 Annual Research Report
  • [Book] 機能性ガラス・ナノガラスの最新技術2006

    • Author(s)
      矢澤哲夫(分担)
    • Total Pages
      446
    • Publisher
      エヌ・ティー・エス
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Book] ケイ素化合物の選定と最適利用技術 (下巻)2006

    • Author(s)
      矢澤哲夫(分担)
    • Total Pages
      524
    • Publisher
      技術情報協会
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] 最新 添加剤全集2006

    • Author(s)
      矢澤哲夫(分担)
    • Total Pages
      562
    • Publisher
      技術情報協会
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Book] ケイ素化合物の選定と最適利用技術(下巻)2006

    • Author(s)
      矢澤哲夫(分担)
    • Total Pages
      524
    • Publisher
      技術情報協会
    • Related Report
      2006 Annual Research Report
  • [Book] 多孔質ガラス2005

    • Author(s)
      矢澤 哲夫
    • Publisher
      エヌ・ティー・エス
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] 多孔質ガラス(分担執筆)2005

    • Author(s)
      矢澤 哲夫
    • Total Pages
      5
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2005 Annual Research Report
  • [Book] 有機・無機ナノ複合材料の新局面2004

    • Author(s)
      矢澤哲夫ら(共著)
    • Total Pages
      270
    • Publisher
      エヌ・ティー・エス
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2004 Annual Research Report

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Published: 2004-04-01   Modified: 2016-04-21  

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