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Development of Shrinkage Crack Control Method due to Combined use of Inert Powder and Chemical Admixture

Research Project

Project/Area Number 16360271
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Building structures/materials
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

NAWA Toyoharu  Hokkaido Univ., Grad.School of Eng., Prof., 大学院工学研究科, 教授 (30292056)

Co-Investigator(Kenkyū-buntansha) IZUMO Kenji  Hokkaido Univ., Grad.School of Eng., Inst., 大学院工学研究科, 助手 (10312381)
YUASA Noboru  Nihon Univ., College of Ind.Tech., Asso.Prof., 生産工学部, 助教授 (00230607)
桂 修  北海道立北方建築総合研究所, 生産技術部・科長(研究職)
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥14,100,000 (Direct Cost: ¥14,100,000)
Fiscal Year 2006: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 2005: ¥5,300,000 (Direct Cost: ¥5,300,000)
Fiscal Year 2004: ¥5,900,000 (Direct Cost: ¥5,900,000)
KeywordsInert inorganic powder / Organic admixture / Autogenous shrinkage / Drying shrinkage / Surface tension / Calcium sulfate / Restrained cracking test / Calcium silicate hydrate / 収縮低減剤 / 拘束リング試験 / 石膏 / 高炉セメント / 無機微粉末 / 相対湿度 / 水和反応率 / 力学的性質
Research Abstract

Prevent concrete from cracking is actually one of the key issues for the design of concrete. The purpose of this study is to develop control of shrinkage crack due to combination of inert powder and chemical admixture. Most important results are summarized as follows:
(1)When the inert inorganic additives such as slowly cooled blast furnace slag powder and limestone powder were added to the mortar with the organic admixtures which consist of polycarboxylate-based and polyoxyalkylene alcohol based polymer, autogenous shrinkage of mortar decreased markedly. However, the effect varied depending on the kind of organic admixture added. On the other hand, addition of fly ash also reduced significantly the autogenous shrinkage of cement mixes, but promoted to decrease their tensile strength. The opposite effects sometimes brought out a little tensile stress / tensile strength ratio, resulting in a low resistance of cracking. Hence, it was clear that to prevent crack due to autogenous and drying shrinkage, further development of sophisticated shrinkage reducing admixtures were required.
(2)The polyethyleneimine based shrinkage reducing admixture absorbed strongly on to cement, providing no reduction of surface tension of pore solution in cement paste. However, it had an effect to reduce autogenous shrinkage and drying shrinkage, and showed good development in strength. Further, the combined use of calcium sulfate enhanced to reduce shrinkage and increase in strength.
(3)The density of C-S-H in binary blends system could be calculated from data of Rietveld analysis, selective dissolution and mercury intrusion. As a result, the density of C-S-H became lower as increasing replacement ratio of fly ash. This implied that the volume of C-S-H gel due to fly ash hydration was larger than that of OPC hydration, providing elf-healing effect. Therefore, development of new method to prevent crack by this self-healing effect will be expected in future.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (48 results)

All 2006 2005 2004

All Journal Article (47 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Effect of Chemical Structure on Steric Stabilization of Polycarboxylate-based Superplasticizer2006

    • Author(s)
      Toyoharu Nawa
    • Journal Title

      Journal of Advanced Concrete Technology 4

      Pages: 225-232

    • NAID

      130000080298

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] A New High Performance Drying Shrinkage-Reducing Admixture2006

    • Author(s)
      M.Masanaga
    • Journal Title

      ACI Special Publication SP-239

      Pages: 297-307

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effect of Advanced Hybrid Admixture on High Strength Concrete2006

    • Author(s)
      K.Saito
    • Journal Title

      ACI Special Publication SP-239

      Pages: 471-486

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effect of Water Curing Conditions on the Hydration Degree and Compressive Strengths of Fly Ash-Cement Paste2006

    • Author(s)
      Pipat Termkhajornkit
    • Journal Title

      Cement and Concrete Composites 28

      Pages: 781-789

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 収縮低減剤およびせっこうの相乗効果がモルタルの収縮挙動および強度発現に及ぼす影響2006

    • Author(s)
      名和豊春
    • Journal Title

      セメント・コンクリート論文集 60

      Pages: 89-96

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] リートベルト法及び選択溶解法による高炉スラグの反応率測定2006

    • Author(s)
      佐川孝広
    • Journal Title

      コンクリート工学年次論文集 28

      Pages: 209-214

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] リートベルト法による高炉セメントの水和反応解析2006

    • Author(s)
      佐川孝広
    • Journal Title

      コンクリート工学論文集 17

      Pages: 1-11

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 高炉セメントの水和反応に及ぼす水セメント比の影響2006

    • Author(s)
      佐川孝広
    • Journal Title

      セメント・コンクリート論文集 60

      Pages: 82-88

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 反射電子像及びエネルギー分散型X線分析により測定した元素分布像によるフライアッシュ混入セメントペーストの観察例2006

    • Author(s)
      胡桃澤清文
    • Journal Title

      日本建築学会構造系論文集 603

      Pages: 1-8

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 高温履歴を受けた高流動コンクリートの自己収縮低減に関する研究2006

    • Author(s)
      堀田智明
    • Journal Title

      日本建築学会構造系論文集 610

      Pages: 1-6

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Influence of Fly Ash Replacement Ratio on Compositions of C-S-H Gel2006

    • Author(s)
      Pipat Termkhajornkit
    • Journal Title

      コンクリート工学年次論文集 28

      Pages: 281-286

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 高強度コンクリート用ハイブリッド混和剤の性質2006

    • Author(s)
      齊藤和秀
    • Journal Title

      コンクリート工学年次論文集 28

      Pages: 143-148

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effect of Chemical Structure on Steric Stabilization of Polycarboxylate-based Superplasticizer2006

    • Author(s)
      Toyoharu Nawa
    • Journal Title

      Journal of Advanced Concrete Technology Vol 4, No.2

      Pages: 225-232

    • NAID

      130000080298

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] A New High Performance Drying Shrinkage-Reducing Admixture2006

    • Author(s)
      M.Masanaga, T.Yamamoto, T.Hirata, T.Nawa
    • Journal Title

      ACI Special Publication SP-239

      Pages: 297-307

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effect of Advanced Hybrid Admixture on High Strength Concrete2006

    • Author(s)
      K.Saito, M.Kinoshita, K.Okada, T.Nawa
    • Journal Title

      ACI Special Publication SP-239

      Pages: 471-486

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effect of Water Curing Conditions on the Hydration Degree and Compressive Strengths of Fly Ash-Cement Paste2006

    • Author(s)
      Pipat Terkmhajornkit, T.Nawa, K.Kurumisawa
    • Journal Title

      Cement and Concrete Composites Vol.28

      Pages: 781-789

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Influence of the Synergy between Organic Shrinkage Reducing Agent and Calcium Sulfate on Shrinkage and Strength of Mortar2006

    • Author(s)
      T.Nawa, S.Hori, T.Fukuda, M.Masanaga
    • Journal Title

      Cement Science and Concrete Technology No.60

      Pages: 89-96

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Determined the Hydration Ratio of Slag by Rietveld Method and Selective Dissolution Method2006

    • Author(s)
      T.Sagawa, T.Nawa
    • Journal Title

      Proceedings of the Japan Concrete Institute Vol.28

      Pages: 209-214

    • NAID

      110009696130

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Quantitative Hydration Analysis of Blast Furnace Slag by Rietveld Method2006

    • Author(s)
      T.Sagawa, T.Nawa
    • Journal Title

      Concrete Research and Technology Vol.17, No.3

      Pages: 1-11

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Quantitative Hydration Analysis of Blast Furnace Slag by Rietveld Method2006

    • Author(s)
      T.Sagawa, T.Nawa
    • Journal Title

      Cement science and Concrete Technology No.60

      Pages: 82-88

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Image Analysis of Hardened Cement Paste Mixed Fly Ash by Using Backscatter Electron Image and Energy Dispersive X-ray Analysis2006

    • Author(s)
      K.Kurumisawa, Pipat Termkhajornkit, T.Nawa
    • Journal Title

      Journal of Structural and Construction Engineering (Transaction of AIJ) No.603

      Pages: 1-8

    • NAID

      110004731911

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] A Study on Reduction of Autogenous Shrinkage of Highly Workable Concrete Subjected to High Temperature2006

    • Author(s)
      T.Horita, T.Nawa
    • Journal Title

      Journal of Structural and Construction Engineering (Transaction of AIJ) No.610

      Pages: 1-6

    • NAID

      110004862727

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Influence of Fly Ash Replacement Ratio on Compositions of C-S-H Gel2006

    • Author(s)
      Pipat Termkhajornkit, T.NAWA, J.FUJISAWA, D.MINATO
    • Journal Title

      Proceedings of the Japan Concrete Institute Vol.28

      Pages: 281-286

    • NAID

      110009696142

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] An Advanced Hybrid Admixture for High-Strength Concrete2006

    • Author(s)
      K.Saito, M.Kinosita, T.Nawa
    • Journal Title

      Proceedings of the Japan Concrete Institute Vol.28

      Pages: 143-148

    • NAID

      110009696119

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 収縮低減剤およびせっこうの相乗効果がモルタルの収縮挙動および強度発現性に及ぼす影響2006

    • Author(s)
      名和豊春, 堀伸介, 福田武嗣, 正長眞理
    • Journal Title

      セメント・コンクリート論文集 60

      Pages: 89-96

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Evaluation of Failure criteria of shrinkage cracking for restrained concrete, Proceedings of the international RILEM conference2006

    • Author(s)
      M.Ohya, T.Nawa
    • Journal Title

      RILEM Change of hardening concrete : testing and mitigation

      Pages: 215-222

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A New High Performance Drying Shrinkage-Reducing Admixture2006

    • Author(s)
      M Masanaga, T.Yamamoto, T.Hirata, T.Nawa
    • Journal Title

      ACI Special Publication SP-239

      Pages: 297-307

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Effect of Advanced Hybrid Admixture on High Strength Concrete2006

    • Author(s)
      K Saito, M.Kinoshita, K.Okada, T.Nawa
    • Journal Title

      ACI Special Publication SP-239

      Pages: 471-486

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 高強度コンクリート用ハイブリッド混和剤の性質2006

    • Author(s)
      齊藤和秀, 木之下光男, 名和豊春
    • Journal Title

      コンクリート工学年次論文集 28・1

      Pages: 143-148

    • NAID

      110009696119

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 拘束されたモルタルの収縮ひび割れ発生応力の評価2006

    • Author(s)
      名和豊春, 大矢学
    • Journal Title

      資源・素材2006(福岡)講演資料

      Pages: 125-126

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 有機混和剤の種類がモルタルの収縮挙動に及ぼす影響2006

    • Author(s)
      堀 伸介, 名和豊春, 正長眞理
    • Journal Title

      セメント・コンクリート論文集 59

      Pages: 102-108

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Effect of Fly Ash on Autogenous Shrinkage2005

    • Author(s)
      Pipat Termkhajornkit
    • Journal Title

      Cement and Concrete Research 35

      Pages: 473-482

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] A mechanism of Autogenous Shrinkage of Cementitious Materials2005

    • Author(s)
      T.Nawa
    • Journal Title

      Cement Combinations for Durable Concrete

      Pages: 427-434

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 有機混和剤の種類がモルタルの収縮挙動に及ぼす影響2005

    • Author(s)
      堀伸介
    • Journal Title

      セメント・コンクリート論文集 59

      Pages: 102-108

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effect of Fly Ash on Autogenous Shrinkage2005

    • Author(s)
      Pipat Termkhajornkit, T.Nawa, M.Nakai, T.Saito
    • Journal Title

      Cement and Concrete Research Vol.35

      Pages: 473-482

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] A mechanism of Autogenous Shrinkage of Cementitious Materials2005

    • Author(s)
      T.Nawa, T.Horita
    • Journal Title

      Cement Combinations for Durable Concrete(Edited by K.Dhir, T.A.Harrison, M.D.Newlands, Thomas Telford)

      Pages: 427-434

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Influence of Kinds of Organic Admixture on Shrinkage of Mortar2005

    • Author(s)
      S.Hori, T.Nawa, M.Masanaga
    • Journal Title

      Cement Science and Concrete Technology No.59

      Pages: 102-108

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 収縮低減剤の種類がモルタルの収縮挙動に及ぼす影響2005

    • Author(s)
      堀 伸介, 名和豊春, 正長眞理
    • Journal Title

      セメント・コンクリート論文集 58

      Pages: 346-352

    • Related Report
      2005 Annual Research Report
  • [Journal Article] A mechanism of autogeneous shrinkage of cementitious materials2005

    • Author(s)
      T.NAWA, T.HOIRTA
    • Journal Title

      Cement combination for durable concrete, Thomas Telford

      Pages: 425-434

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Influence of Organic Admixture on Shrinkage of Mortar2005

    • Author(s)
      M.OHYA, S.HORI, T.NAWA
    • Journal Title

      資源・素材2005(室蘭)企画発表・一般発表講演資料

      Pages: 231-232

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Effect of fly ash on autogenous shrinkage2005

    • Author(s)
      P.Termkhajornkit, T.Nawa
    • Journal Title

      Cement and Concrete Research 35・3

      Pages: 473-482

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 自己収縮に及ぼす収縮低減剤および無機物の影響2005

    • Author(s)
      堀 信介, 名和豊春, 正長眞理
    • Journal Title

      セメント・コンクリート論文集 58

      Pages: 346-351

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A mechanism of autogenous shrinkage of cementitious Materials2005

    • Author(s)
      T.Nawa, T.Horita
    • Journal Title

      Proceeding of the International Congress on Global Construction : Ultimate Concrete Opportunities (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 収縮低減剤の種類がモルタルの収縮挙動に及ぽす影響2005

    • Author(s)
      堀 信介, 名和豊春, 正長眞理
    • Journal Title

      第59回セメント技術大会講演要旨 (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] A Study on fly ash-cement hydration by Rietveld analysis and selective dissolution2005

    • Author(s)
      P.Termkhajornkit, T.Nawa, K.Kurumizawa
    • Journal Title

      コンクリート工学教会年次論文集 27(印刷中)

    • NAID

      110009695527

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 自己収縮に及ぼす収縮低減剤および無機物の影響2004

    • Author(s)
      堀伸介
    • Journal Title

      セメント・コンクリート論文集 58

      Pages: 346-352

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Influence of Shrinkage-Reducing Admixture and Inorganic Additives on Autogenous Shrinkage of Mortar2004

    • Author(s)
      S.Hori, T.Nawa, M.Masanaga
    • Journal Title

      Cement Science and Concrete Technology No.58

      Pages: 346-352

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 自己収縮低減剤2005

    • Inventor(s)
      名和豊春
    • Industrial Property Rights Holder
      北海道テイー・エル・オ一(株)
    • Industrial Property Number
      2005-026835
    • Filing Date
      2005-09-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary

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Published: 2004-04-01   Modified: 2016-04-21  

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