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Heat and Mass Transport in Undercooled Melts of Germanium and Silicon

Research Project

Project/Area Number 16360320
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionJapan Aerospace Exploration Agency

Principal Investigator

INATOMI Yuko  Japan Aerospace Exploration Agency, Institute of Space and Astronautical Science, Associate Professor (50249934)

Co-Investigator(Kenkyū-buntansha) KURIBAYASHI Kazuhiko  Japan Aerospace Exploration Agency, Institute of Space and Astronautical Science, Professor (70092195)
NAGASHIO Kousuke  Japan Aerospace Exploration Agency, Institute of Space and Astronautical Science, Assistant (20373441)
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥5,100,000 (Direct Cost: ¥5,100,000)
Fiscal Year 2006: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 2005: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2004: ¥2,600,000 (Direct Cost: ¥2,600,000)
Keywordsundercooled melt / thermal conductivity / Wiedemann-Franz law / silicon / germanium / density / diffusion / electromagnetic levitation / 過冷却 / 半導体融液 / 電磁浮遊 / 熱物性 / 対流 / 静磁場
Research Abstract

Containerless processing by a levitation method has been used for materials science and technological applications such as rapid solidification, purification and thermophysical properties measurement of melts. An electromagnetic levitation method (EML) can be used to levitate a relatively large size of a metallic melt in a given atmosphere. However, independent control for the temperature and spatial position of the specimen is difficult and the strong Lorentz force yields electromagnetic stirring in the melt and destabilizes the shape of the melt Recently, a novel method for levitating a metallic melt by EML under a static magnetic field was developed in order to damp the convection and vibration in the melt by the Lorentz force. In the present study, stabilizing of position and shape of a levitated melt for silicon and germanium was succeeded by the new EML method, and convection in each melt was strongly damped by the strong magnetic field.
Measurements of the density and thermal conductivity of a pure silicon melt over a wide temperature range were performed by the EML, while those properties for germanium showed large data spreads due to higher evaporation rate of the melt. The emissivity of the melt showed almost constant to temperature. The determined density for silicon melt showed a linear relation with temperature, and no anomalous increase near the melting point was observed In addition the thermal expansion coefficient agreed well with the value calculated based on the metallic liquid model. Since the thermal conductivity of the melt agreed roughly with values estimated by the Wiedemann-Franz law, free electrons in a silicon melt obviously affect the thermal conductivity. In the result it was concluded that silicon melt even in an undercooled state showed metallic characteristic.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (21 results)

All 2007 2006 2005 2004

All Journal Article (21 results)

  • [Journal Article] Density and Thermal Conductivity Measurements for Silicon Melt by Electromagnetic Levitation under a Static Magnetic Field2007

    • Author(s)
      Y. Inatomi, et. al.
    • Journal Title

      International Journal of Thermophysics 28

      Pages: 44-59

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Density and Thermal Conductivity Measurements for Silicon Melt byElectromagnetic Levitation under a Static Magnetic Field2007

    • Author(s)
      Yuko Inatomi
    • Journal Title

      Int.J.Thermophys. 28

      Pages: 44-59

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 重畳磁場電磁浮遊法を用いたシリコン浮遊融液の密度測定2006

    • Author(s)
      大西 史倫, 他
    • Journal Title

      日本マイクログラビティ応用学会誌 23

      Pages: 26-29

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Density Measurement of Molten Silicon by Electromagnetic Levitator(EML) under Static Magnetic Field2006

    • Author(s)
      F. Onishi, et. al.
    • Journal Title

      Journal of the Japan Society of Microgravity Application 23

      Pages: 26-29

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Buoyancy convection in cylindrical conducting melt with low Grashof number under uniform static magnetic field2006

    • Author(s)
      Yuko Inatomi
    • Journal Title

      Int.J.Hass Transfer 49

      Pages: 4821-4830

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Measurements of interdiffusion coefficients in metallic melts at high temperature under horizontal static magnetic field2006

    • Author(s)
      Fumitomo Onisho
    • Journal Title

      Mic.Sci.tech V VIII-3/4

      Pages: 86-90

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Density Measurement of Molten Silicon by Electromagnetic Levitator (EML) under Static Magnetic Field2006

    • Author(s)
      Yuko Inatomi
    • Journal Title

      J.Jpn.Soc.Mic.Appl. 23・1

      Pages: 26-29

    • NAID

      10017253810

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Time-of-Flight Secondary Mass Spectrometry analysis of IsotopeComposition for Measurement of Self-Diffusion Coefficient2006

    • Author(s)
      Fumitomo Onishi
    • Journal Title

      Jpn.J.Appl.Phys. 45

      Pages: 5274-5276

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 重畳磁場電磁浮遊法を用いたシリコン浮遊融液の密度測定2006

    • Author(s)
      大西史倫, 長汐晃輔, 稲富裕光, 栗林一彦
    • Journal Title

      日本マイクログラビティ応用学会誌 23巻・1号

      Pages: 26-29

    • NAID

      10017253810

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Measuring equipment for thermopysical properties of droplet electromagnetically-levitated under axial static magnetic field2006

    • Author(s)
      Fumitomo Onishi, Kosuke Nagashio, Yuko Inatomi, Kazuhiko Kuribayashi
    • Journal Title

      56th International Astronautical Congress Final Program

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Measuring equipment for thermopysical properties of droplet electromagnetically-levitated under axial static magnetic field2005

    • Author(s)
      F. Onishi, et. al.
    • Journal Title

      Proceedings of 56th International Astronautical Congress

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Thermal conductivity measurement of Ievitated molten silicon by EML2005

    • Author(s)
      F. Onishi, et. al.
    • Journal Title

      Proceedings of the 26th Japan Symposium on Thermophysical Properties

      Pages: 475-477

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Measuring for thermophysical properties of electromagnetically levitatedmelt under static magnetic field2005

    • Author(s)
      F. Onishi, et. al.
    • Journal Title

      Proceedings of the 21th Space Utilization Symposium

      Pages: 39-41

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Measuring equipment for thermopysical properties of droplet electromagnetically-levitated under axial static magnetic field2005

    • Author(s)
      F. Onishi, et. al.
    • Journal Title

      Proc. 56th Tnt. Astronautical Congress,(CD-ROM) IAC-05-A2.3.05

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Thermal conductivity measurement of levitated molten silicon by EML2005

    • Author(s)
      F. Onishi, et. al.
    • Journal Title

      Proceedings of the 26th Japan Symposium on Thermophysical Properties

      Pages: 475-477

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Measuring for thermophysical properties of electromagnetically levitated melt under static magnetic field2005

    • Author(s)
      F. Onishi, et. al.
    • Journal Title

      Proceedings of the 2lth Space Utilization Symposium

      Pages: 39-41

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] シリコン浮遊融液の熱伝導率測定2005

    • Author(s)
      大西史倫, 長汐晃輔, 稲富裕光, 栗林一彦
    • Journal Title

      日本熱物性シンポジウム講演論文集

      Pages: 475-477

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 静磁場におけるSi浮遊融液の熱膨張率と熱伝導率の測定2005

    • Author(s)
      大西史倫, 長汐晃輔, 稲富裕光, 栗林一彦
    • Journal Title

      日本金属学会講演概要

      Pages: 269-269

    • Related Report
      2005 Annual Research Report
  • [Journal Article] In situ observation of electromagnetically levitated melt under static Magnetic field2004

    • Author(s)
      F. Onishi, et. al.
    • Journal Title

      Proceedings of the 25th Japan Symposium on Thermophysical Properties

      Pages: 186-188

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 静磁場における電磁浮遊融液のその場観察2004

    • Author(s)
      大西史倫, 長汐晃輔, 稲富裕光, 栗林一彦
    • Journal Title

      第25回日本熱物性シンポジウム講演論文集

      Pages: 186-188

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 静磁揚を利用した73Ge融液の自己拡散係数の測定2004

    • Author(s)
      稲富裕光, 大西史倫, 田中朋弘, 篠崎直人, 渡邊匡人, 藤本明良, 伊藤公平
    • Journal Title

      第25回日本熱物性シンポジウム講演論文集

      Pages: 189-191

    • Related Report
      2004 Annual Research Report

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Published: 2004-04-01   Modified: 2016-04-21  

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