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Thermophysical Property Measurements of Non-Equilibrium Melts

Research Project

Project/Area Number 16360371
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionTohoku University

Principal Investigator

FUKUYAMA Hiroyuki  Tohoku University, Institute of Multidisciplinary Research for Advanced Materials, Associate Professor, 多元物質科学研究所, 助教授 (40252259)

Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥13,500,000 (Direct Cost: ¥13,500,000)
Fiscal Year 2006: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2005: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 2004: ¥10,300,000 (Direct Cost: ¥10,300,000)
Keywordselectromagnetic levitator / thermophysical property / silicon / modulated laser calorimetry / spectral emissivity / heat capacity / thermal conductivity / hemispherical total emissivity / 交流カロリメトリー / ステンレス鋼
Research Abstract

Thermal transport properties of high temperature liquid silicon such as isobaric molar heat capacity, hemispherical total emissivity and thermal conductivity, are key parameter for improving the numerical modeling to produce high quality of single crystalline silicon by Czochralski method. However, it is difficult to measure the thermal transport properties of high-temperature liquid silicon due to the existing of both contamination from contact material and convections. To overcome these problems, a noncontact modulated laser calorimetry in a static magnetic field was developed for simultaneous measurement of the isobaric molar heat capacity, the hemispherical total emissivity and the thermal conductivity of liquid silicon. The isobaric molar heat capacity and the hemispherical total emissivity of liquid silicon were measured at temperature between 1750 K and 2050 K in a static magnetic field from 0.5 to 4 T. The convections in the electromagnetically levitated liquid silicon droplet were effectively suppressed by imposing a static magnetic field. The thermal conductivity was measured at temperatures between 1750 K and 2050 K by imposing the static magnetic field at 2 T or larger with suppressed convections. The determined thermal conductivity shows that the electron contribution is dominant for thermal transport in liquid silicon at temperatures of 1750-2050 K.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (41 results)

All 2007 2006 2005 2004

All Journal Article (40 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Determination of Thermal Conductivity and Emissivity of Electromagnetically Levitated High-Temperature Droplet based on the Periodic Laser-Heating Method : Theory2007

    • Author(s)
      T.Tsukada
    • Journal Title

      Int. J. Heat Mass Trans. Vol. 50

      Pages: 3054-3061

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Noncontact Measurement of Thermal Conductivity of Liquid Silicon in a Static Magnetic Field2007

    • Author(s)
      H.Kobatake
    • Journal Title

      Appl. Phys. Lett Vol. 90

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Development of Modulated Laser Calorimetry using Solid Platinum Sphere as a Reference2007

    • Author(s)
      H.Fukuyama
    • Journal Title

      Meas. Sci. Technol Vol. 18

      Pages: 2059-2066

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Determination of Thermal Conductivity and Emissivity of Electromagnetically Levitated High-Temperature Droplet based on the Periodic Laser-Heating Method : Theory2007

    • Author(s)
      T.Tsukada
    • Journal Title

      Int.J.Heat Mass Trans. Vol.50

      Pages: 3054-3061

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Noncontact Measurement of Thermal Conductivity of Liquid Silicon in a Static Magnetic Field2007

    • Author(s)
      H.Kobatake
    • Journal Title

      Appl.Phys.Lett. Vol.90

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Development of Modulated Laser Calorimetry using Solid Platinum Sphere as a Reference2007

    • Author(s)
      H.Fukuyama
    • Journal Title

      Meas.Sci.Technol. Vol.18

      Pages: 2059-2066

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 静磁場印加により対流を抑制した電磁浮遊SUS304融体に対するACカロリメトリー2007

    • Author(s)
      高橋 翔
    • Journal Title

      日本金属学会概要集

      Pages: 309-309

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 静磁場中での電磁浮遊SUS304融体への周期加熱レーザーカロリメトリー2007

    • Author(s)
      小畠秀和
    • Journal Title

      材料とプロセス Vol. 20

      Pages: 129-129

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Noncontact Measurement of Thermal Conductivity of Liquid Silicon in a Static Magnetic Field2007

    • Author(s)
      H.Kobatake
    • Journal Title

      Appl. Phys. Lett. Vol. 90

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Density Measurement of Molten CaF_2 by an Electrostatic Levitator2006

    • Author(s)
      I.Minato
    • Journal Title

      International Journal of Thermophysics Vol. 27[4]

      Pages: 1173-1180

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Thermal Conductivity Measurements of Liquid Mercury and Gallium by a Transient Hot Wire Method in a Static Magnetic Field2006

    • Author(s)
      H.Fukuyama
    • Journal Title

      International Journal of Thermophysics Vol. 27[6]

      Pages: 1760-1777

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Establishment of Noncontact AC Calorimetry of High-Temperature Melts using Solid Platinum Spheres as a Reference2006

    • Author(s)
      H.Fukuyama
    • Journal Title

      16th Symposium on Thermophysical Properties (CD-ROM)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Noncontact AC Calorimetry of Liquid Silicon with Suppressing Convections in a Static Magnetic Field2006

    • Author(s)
      H.Kobatake
    • Journal Title

      16th Symposium on Thermophysical Properties (CD-ROM)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Density Measurement of Molten CaF_2 by an Electrostatic Levitator2006

    • Author(s)
      I.Minato
    • Journal Title

      International Journal of Thermophysics Vol.27[4]

      Pages: 1173-1180

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Thermal Conductivity Measurements of Liquid Mercury and Gallium by a Transient Hot Wire Method in a Static Magnetic Field2006

    • Author(s)
      H.Fukuyama
    • Journal Title

      International Journal of Thermophysics Vol.27[6]

      Pages: 1760-1777

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Establishment of Noncontact AC Calorimetry of High-Temperature Melts using Solid Platinum Spheres as a Reference2006

    • Author(s)
      H.Fukuyama
    • Journal Title

      16th Symposium on Thermophysical Properties (CO-ROM)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Noncontact AC Calorimetry of Liquid Silicon with Suppressing Convections in a Static Magnetic Field2006

    • Author(s)
      H.Kobatake
    • Journal Title

      16th Symposium on Thermophysical Properties (CO-ROM)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 静磁場印加電磁浮遊法による高温シリコン融液の熱物性値の測定2006

    • Author(s)
      塚田隆夫
    • Journal Title

      日本伝熱シンポジウム講演概要集 Vol. 1

      Pages: 283-284

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 電磁浮遊シリコン液滴内対流に及ぼす静磁場印加効果2006

    • Author(s)
      杉岡健一
    • Journal Title

      化学工学会概要集

    • Related Report
      2006 Annual Research Report
  • [Journal Article] レーザーACカロリメトリーによる固体白金の熱物性値測定2006

    • Author(s)
      高橋 翔
    • Journal Title

      日本金属学会概要集

      Pages: 211-211

    • Related Report
      2006 Annual Research Report
  • [Journal Article] シリコン融体の定圧モル熱容量,半球全放射率,熱伝導率の測定2006

    • Author(s)
      小畠秀和
    • Journal Title

      材料とプロセス 19〔4〕

      Pages: 853-853

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 静磁場を重畳した電磁浮遊液滴の熱容量,熱伝導率,放射率同時測定法の開発2006

    • Author(s)
      福山博之
    • Journal Title

      日本物理学会講演概要集 61〔2〕

      Pages: 654-654

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 高温融体の非接触ACカロリメトリー理論2006

    • Author(s)
      福山博之
    • Journal Title

      日本熱物性シンポジウム講演論文集 Y211

      Pages: 191-193

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 静磁場で対流を抑制したシリコン融体の非接触ACカロリメトリー2006

    • Author(s)
      小畠秀和
    • Journal Title

      日本熱物性シンポジウム講演論文集 Y212

      Pages: 194-196

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 溶融シリコンの非接触レーザーACカロリメトリー2006

    • Author(s)
      福山博之
    • Journal Title

      日本マイクログラビティ応用学会第22回学術講演会概要集 22

    • NAID

      10018633075

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 静磁場印加電磁浮遊技術による熱物性値測定法の数値解析による評価2006

    • Author(s)
      塚田隆夫
    • Journal Title

      日本マイクログラビティ応用学会第22回学術講演会概要集 22

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Establishment of Noncontact AC Calorimetry of High-Temperature Melts using Solid Platinum Spheres as a Reference2006

    • Author(s)
      H.Fukuyama
    • Journal Title

      16th Symposium on Thermophysical Properties

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Noncontact AC Calorimetry of Liquid Silicon with Suppressing Convections in a Static Magnetic Field2006

    • Author(s)
      H.Kobatake
    • Journal Title

      16th Symposium on Thermophysical Properties

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 静磁場と電磁浮遊による高温融体の新しい熱容量,放射率,熱伝導率同時測定法の開発2006

    • Author(s)
      福山博之
    • Journal Title

      まてりあ(日本金属学会会報) Vol.45,7月号

      Pages: 523-526

    • NAID

      10020527170

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 静磁場中非接触ACカロリメトリーによる溶融シリコンの熱容量,放射率,熱伝導率同時測定法の開発2006

    • Author(s)
      福山博之
    • Journal Title

      熱測定(日本熱測定学会) Vol.33,No.5

      Pages: 204-210

    • NAID

      10029865938

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Normal Spectral Emissivity of Undercooled Liquid Silicon2005

    • Author(s)
      H.Kawamura
    • Journal Title

      Meas. Sci. Technol. Vol. 16

      Pages: 386-393

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Density Measurement of Molten CaF_2 by an Electrostatic Levitator2005

    • Author(s)
      I.Minato
    • Journal Title

      The 17th European Conference on Thermophysical Properties

      Pages: 49-49

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Thermal Conductivity Measurements of Liquid Mercury and Gallium by a Transient Hot Wire Method in a Static Magnetic Field2005

    • Author(s)
      H.Fukuyama
    • Journal Title

      The 17th European Conference on Thermophysical Properties

      Pages: 139-139

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Normal Spectral Emissivity of Undercooled Liquid Silicon2005

    • Author(s)
      H.Kawamura
    • Journal Title

      Meas.Sci.Technol. Vol.16

      Pages: 386-393

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Gibbs Energy Change of Carbothermal Nitridation Reaction of γ-AlON and Its Thermodynamic Stability2005

    • Author(s)
      W.Nakao
    • Journal Title

      J.Am.Ceram.Soc., Vol.88[11]

      Pages: 3170-3176

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 還元窒化法によるc軸配向AlN膜の作製2005

    • Author(s)
      中村克仁
    • Journal Title

      日本金属学会講演概要集

      Pages: 218-218

    • Related Report
      2005 Annual Research Report
  • [Journal Article] a面サファイアの直接窒化によるc軸配向AlN膜の作製2005

    • Author(s)
      中村克仁
    • Journal Title

      日本金属学会講演概要集

      Pages: 454-454

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Normal Spectral Emissivity of Undercooled Liquid Silicon2005

    • Author(s)
      H.Kawamura et al.
    • Journal Title

      Measurement Science and Technology 16

      Pages: 386-393

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Normal Spectral Emissivity of Silicon in the Stable and Undercooled Liquid Measured by using Electromagnetic Levitator2004

    • Author(s)
      H.Kawamura
    • Journal Title

      2nd International Symposium on Physical Sciences in Space held jointly with Spacebound 2004

      Pages: 87-87

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Normal Spectral Emissivity of Silicon in the Stable and Undercooled Liquid Measured by using Electromagnetic Levitator2004

    • Author(s)
      H.Kawamura et al.
    • Journal Title

      2nd International Symposium on Physical Sciences in Space held jointly with Spacebound 2004

      Pages: 87-87

    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] 高温融体導電材料の熱物性測定方法及び測定装置2006

    • Inventor(s)
      福山博之, 小畠秀和, 塚田隆夫, 淡路 智
    • Industrial Property Rights Holder
      国立大学法人東北大学, 公立大学法人大阪府立大学
    • Industrial Property Number
      2006-180330
    • Filing Date
      2006-06-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary

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Published: 2004-04-01   Modified: 2016-04-21  

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