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"Researches on Volatile Organic Compounds (VOCs) from Interior Woods of a Storage Room and Their Effects and Defense to Materials of Cultural Property"

Research Project

Project/Area Number 16500638
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Cultural property science
Research InstitutionTohoku University of Art & Design

Principal Investigator

MATSUDA Yasunori  Tohoku University of Art & Design, Dept.Art History and Conservation, Professor, 芸術学部, 教授 (70254836)

Co-Investigator(Kenkyū-buntansha) MATSUI Toshiya  Tsukuba University, Dept.World Heritage, Lecturer, 大学院, 専任講師 (60306074)
DESOKU Chang  Tohoku University of Art & Design, Dept. Art History and Conservation, Assistant Professor, 助手 (90364447)
KURIMOTO Yasuji  Akita Prefectural University, Institute of Wood Technology, Associate Professor, 木材高度加工研究所, 助教授 (60279510)
及川 規  東北歴史博物館, 学芸部, 副主任研究員
成瀬 正和  宮内庁正倉院事務所, 保存課, 保存科学室長
Project Period (FY) 2004 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 2005: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 2004: ¥3,300,000 (Direct Cost: ¥3,300,000)
KeywordsVolatile Organic Compounds / wood / materials / American red cedar / VOCs / cultural property / 収蔵庫 / 保存箱 / 保存環境 / 顔料 / 金属 / 揮発性有機化合物(VOC)
Research Abstract

(1)From the results of determining the effects to materials of objects from American red cedar, we confirmed that the volatile organic compounds(VOCs) from wood can corrodes metals such as bronze and can change the color of lead pigments, such as lead white, litharge(masicot) and lead red. Thus, it was proved that VOCs from wooden interior walls of storage rooms are possible to deteriorate some materials in objects.
(2)We determined some amended methods for eliminating the VOCs from woods : extraction with H2O and ethanol, high temp. drying etc. These methods, especially by high temp. drying, decreased the total amounts of VOCs(TVOC) from woods. However, lead white pigments can changed to yellow color and copper metal afforded corrosion by high temp. drying and by extraction with H2O, we confirmed that the deteriorations were not detected by extraction with ethanol.
(3)In the results of analysis of VOCs from paulownia and Japanese cedar and of the effects to materials of objects, it was proved that 1)diffuse amounts from the kinds of woods were less than from those of American red cedar, 2)VOCs from paulownia changed color of litharge(massicot) to white. The evidence indicates the wood can diffuse enough amount of acetic acid to affect to the materials.
(4)From the results of XRD analysis, the faded constituent of litharge(masicot) was proved to lead white and basic lead acetate. This means that acetic acid volatized from American red cedar was mainly due to this deterioration, because it has confirmed that litharge(masicot) changes chemically under existence of both carbon hydroxide and acetic acid into lead white through unstable lead acetate.

Report

(3 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • Research Products

    (15 results)

All 2006 2005 2004

All Journal Article (15 results)

  • [Journal Article] Volatile organic compounds from wood and their influences on museum artifacts II. Influence of causal substances of deterioration based on intercomparison of laser Raman spectra of deteriorated products2006

    • Author(s)
      Tadashi Oikawa, Toshiya Matsui, Yasunori Matsuda, et al.
    • Journal Title

      Journal of Wood Science 52

      Pages: 140-146

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] ベイギス揮発成分とその文化財材質への影響III.-レーザラマン分光分析法による顔料の変質原因物質の推定-2006

    • Author(s)
      及川 規
    • Journal Title

      東北歴史博物館研究紀要 7

      Pages: 27-34

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Volatile organic compounds from wood and their influences on museum artifacts II Influence of causal substances of deterioration based on intercomparison of laser Raman spectra of deteriorated products2006

    • Author(s)
      Tadashi Oikawa, Toshiya Matsui, Yasunori Matsuda, et al.
    • Journal Title

      Journal of Wood Science 52

      Pages: 140-146

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Volatile organic compounds from wood and their influences on museum artifacts I. Differences in wood species and analyses of causal substances of deterioration2005

    • Author(s)
      Tadashi Oikawa, Toshiya Matsui, Yasunori Matsuda, et al.
    • Journal Title

      Journal of Wood Science 51

      Pages: 363-369

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] ベイギス揮発成分とその文化財材質への影響II-レーザラマン分光分析法による金属の変質原因物質の推定-2005

    • Author(s)
      及川 規
    • Journal Title

      東北歴史博物館研究紀要 6

      Pages: 1-7

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 文化財保存箱用木材からの揮発性有機化合物(VOC)とその文化財材質へ与える影響〜スギ材とキリ材の再検討2005

    • Author(s)
      植竹雅子, 松田泰典, 及川規他2名
    • Journal Title

      文化財保存修復学会第27回大会研究発表要旨集

      Pages: 94-95

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 木質系収蔵庫内装材の揮発成分とその文化財材質への影響(VIII)〜文化財材質に影響を与えるベイスギ揮発成分の効果的な除去方法検討〜2005

    • Author(s)
      及川規, 松井敏也, 松田泰典他4名
    • Journal Title

      文化財保存修復学会第27回大会研究発表要旨集

      Pages: 96-97

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 木質系収蔵庫内装材の揮発成分とその文化財材質への影響(VIII)〜ベイスギ揮発成分による鉛白黄変について〜2005

    • Author(s)
      新保千枝, 松田泰典, 及川規他2名
    • Journal Title

      文化財保存修復学会第27回大会研究発表要旨集

      Pages: 98-99

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Volatile organic compounds from wood and their influences on museum artifact materials. I. Differences in wood species and analyses of causal substances of deterioration2005

    • Author(s)
      Tadashi Oikawa, Toshiya Matsui, Yasurori Matsuda, 他4名
    • Journal Title

      Journal of Wood Science 51

      Pages: 363-369

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Volatile organic compounds from wood and their influences on museum artifact materials. II. Inference of causal substances of deterioration based on intercomparison of laser Raman spectra of deteriorated products2005

    • Author(s)
      Tadashi Oikawa, Toshiya Matsui, Yasurori Matsuda, 他4名
    • Journal Title

      Journal of Wood Science 52(印刷中)

    • NAID

      10017428624

    • Related Report
      2005 Annual Research Report
  • [Journal Article] ベイスギ材,スプルース材,キリ材,スギ材の各揮発成分と文化財材質への影響2005

    • Author(s)
      及川規, 松田泰典, 高山てる子, 新沼仁, 西田康代, 星一男
    • Journal Title

      マテリアルライフ学会第16回研究発表会・特別講演会予稿集

      Pages: 103-105

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Volatile organic compounds from wood and their influences on museum artifact I --- Differences in wood species and analyses of causal substances of deterioration ---2005

    • Author(s)
      Tadashi Oikawa, Toshiya Matsui, Yasunori Matsuda et al.
    • Journal Title

      Journal of Wood Science (未定)(受理済み)

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 木質系収蔵庫内装材の揮発成分とその文化財材質への影響V〜ベイスギ揮発成分中の変質原因物質〜2004

    • Author(s)
      及川規, 松井敏也, 松田泰典, 新沼仁, 高山てる子
    • Journal Title

      文化財保存修復学会第26回大会研究発表要旨集

      Pages: 114-115

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 木質系収蔵庫内装材の揮発成分とその文化財材質への影響VI〜ベイスギ揮発成分低減化の基礎調査(電磁波や乾燥条件の影響)〜2004

    • Author(s)
      及川規, 松井敏也, 松田泰典, 西田康代, 星一男
    • Journal Title

      文化財保存修復学会第26回大会研究発表要旨集

      Pages: 116-117

    • Related Report
      2004 Annual Research Report
  • [Journal Article] 木質系収蔵庫内装材の揮発成分とその文化財材質への影響VII〜ベイスギ揮発成分の溶媒抽出法により抑制の検討〜2004

    • Author(s)
      新保千枝, 松田泰典, 松井敏也, 及川規, 新沼仁, 高山てる子
    • Journal Title

      文化財保存修復学会第26回大会研究発表要旨集

      Pages: 20-21

    • Related Report
      2004 Annual Research Report

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Published: 2004-04-01   Modified: 2016-04-21  

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