• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Research on storage process of high-pressure fluid into nano-structures of minerals

Research Project

Project/Area Number 16540443
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionNational Institute for Materials Science

Principal Investigator

YUSA Hitoshi  National Institute for Materials Science, Advanced Materials Laboratory, Senior Researcher, 物質研究所, 主幹研究員 (10343865)

Project Period (FY) 2004 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 2005: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2004: ¥1,700,000 (Direct Cost: ¥1,700,000)
Keywordsnanotubes / diamond anvil cell / x-ray diffraction / fluid storage / argon / hot isostatic pressing / 貯蔵 / X線回析
Research Abstract

The present candidates for the storage application of high pressure fluid are carbon nanotubes. First of all, we examined the mechanical strength of carbon nanotubes to know a capability for storage of high-pressure fluids. Then, we conducted in-situ X-ray diffraction experiments under high pressure using a diamond anvil cell (DAC) combined with x-ray from synchrotron radiation. No interlayer interaction such as sp^3 hybridization that could lead to hexagonal diamond in graphite was observed under compression up to 52 GPa. Furthermore, despite the history of non-hydrostatic compression, electron microscopic observation revealed that the structure remained nested tubular. This reversibility suggests the nanotubes have strong durability on non-hydrostatic compression under extreme pressures.
Next, we tried to make experiments of gas loading to the nanotubes under pressure. In advance, a gas loading system was built for the purpose of controlling the pressure in loading gas into DAC. After … More loading argon into the sample chamber, where nanotubes sample was placed, the pressure applied up to 6 GPa. The sample was heated to 1000 K by a CO_2 laser. The heated sample was recovered at ambient condition, and then analyzed by a scanning electron microscope equipped with EDAX detector. A very small amount of argon was detected. However, the detected potion was inhomogeneous due to temperature gradient by the laser heating. Thus we change the experiments from the laser heated DAC to the hot isostatic pressing (HIP) apparatus. A large amount of sample can be kept at the 800-1000 deg C under 300 MPa argon pressure for 10 hrs in this apparatus. Several samples of open and closed end multi-walled nanotubes, bundled single-walled nanotubes, and fullerene are treated in this apparatus at the same condition. The recovered samples are carefully examined by analytical transmitted electron microscopes (ATEM and STEM). According to the EDX mapping of argon in the samples, a large amount of argon are only detected from the bundled single walled carbon nanotubes. Hence, we can conclude that argon can be trapped in an interstitial position of bundled single-walled nanotubes. Less

Report

(3 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • Research Products

    (6 results)

All 2006 2005

All Journal Article (6 results)

  • [Journal Article] 超高圧化でのナノチューブの研究2006

    • Author(s)
      遊佐 斉
    • Journal Title

      高圧力の科学と技術 16・3

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Study of nanotubes under high pressure2006

    • Author(s)
      H.Yusa
    • Journal Title

      Review of High Pressure Science Technology 16(to be published)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 超高圧下でのナノチューブの研究2006

    • Author(s)
      遊佐 斉
    • Journal Title

      未来を拓く高圧力科学技術セミナーシリーズ 31

      Pages: 21-26

    • NAID

      10019280721

    • Related Report
      2005 Annual Research Report
  • [Journal Article] X-ray diffraction of multiwalled carbon nanotube under high pressure : Structural durability on static compression2005

    • Author(s)
      H.Yusa, T.Watanuki
    • Journal Title

      Carbon 43

      Pages: 519-523

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] X-ray diffraction of multiwalled carbon nanotube under high pressure Structural durability on static compression2005

    • Author(s)
      H.Yusa, T.Watanuki
    • Journal Title

      Carbon 43

      Pages: 519-523

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] X-ray Diffraction of Multiwalled Carbon Nanotube under High Pressure : Structural Durability on Static Compression2005

    • Author(s)
      H.Yusa, T.Watanuki
    • Journal Title

      CARBON 43

      Pages: 519-523

    • Related Report
      2004 Annual Research Report

URL: 

Published: 2004-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi