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Unique Properties of the Interfacial Phase of the Adsorbed Reverse Micelle and Development of a New Chromatographic Separation Method

Research Project

Project/Area Number 16550076
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionHIROSHIMA UNIVERSITY

Principal Investigator

FUJIWARA Terufumi  Hiroshima University, Graduate School of Science, Professor, 大学院・理学研究科, 教授 (80127703)

Co-Investigator(Kenkyū-buntansha) TSUKAHARA Satoshi  Hiroshima University, Graduate School of Science, Associate Professor, 大学院・理学研究科, 助教授 (50207338)
OKAMOTO Yasuaki  Hiroshima University, Graduate School of Science, Assistant, 大学院・理学研究科, 助手 (40213988)
Project Period (FY) 2004 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥3,700,000 (Direct Cost: ¥3,700,000)
Fiscal Year 2005: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2004: ¥2,600,000 (Direct Cost: ¥2,600,000)
Keywordsreverse micelle / adsorption / interface / silica / surfactant / electric quartz crystal microbalance / liquid chromatography / separation / シリカゲル / 幾何異性体 / 水和 / 顕微蛍光法
Research Abstract

There has been increased interest in the unique properties of reverse micelles. Further, reverse micelles have been viewed as versatile microreactors. Use of reverse micelles in chemical analysis has received considerable attention. In this work, reverse micelles of the surfactant cetyltrimethylammonium chloride (CTAC) were successfully attached to porous silica gels or a glass surface. The resultant reversed admicellar phase will exhibit many of the reversed micellar properties associated with the conventional micellar media and in addition the CTAC-water-silica interface can be expected to bear unique properties of material recognition and separation and to be used as a stationary phase in liquid chromatography. There appears to be no prior report concerning the immobilization of reverse micelles on solid supports such as silica gel, despite a considerable amount of information about the properties of the reverse micelles.
In order to obtain the knowledge which contributes to our understanding of the role of the interfacial phase of the reversed admicelle and to develop a new chromatographic separation method using the reversed admicellar stationary phase, this research focused on the followings : (1)The quartz crystal microbalance study on the adsorption of the CTAC reverse micelle on a glass surface as well as the entrapping of the hydrogen peroxide in the aqueous phase of the adsorbed CTAC micelle, and its application to the reversed micellar mediated chemiluminescence determination of hydrogen peroxide in toluene using a single line flow injection system ; (2)the effect of the molar ratio of water to surfactant in the reversed micellar bulk solution on the reversed micellar adsorption of CTAC and water onto porous silica gels of various pore sizes ; (3)the preparation, characterization and unique chromatographic performance of the reversed admicellar stationary phase by immobilizing the CTAC reversed micelles on silica gel in a commercial HPLC column.

Report

(3 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • Research Products

    (30 results)

All 2006 2005 2004

All Journal Article (28 results) Book (2 results)

  • [Journal Article] An improved method for the flow-injection determination of iodine using the luminol chemiluminescence reaction in a reversed micellar medium of cetyltrimethylammonium chloride in 1-hexanol-cyclohexane2006

    • Author(s)
      FUJIWARA, Terufumi
    • Journal Title

      Analytical Sciences 22・1

      Pages: 67-71

    • NAID

      10017166117

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] Recent Analytical Methodologies on Equilibrium, Kinetics, and Dynamics at Liquid/Liquid Interface2006

    • Author(s)
      TSUKAHARA, Satoshi
    • Journal Title

      Anal. Chim. Acta 556・1

      Pages: 16-25

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Measurement of Orderd Associate of Protnated Tetraphenyloporphine Formed at Toluence/Aqueous H_2SO_4 Interface by Attenuated Total Internal Reflection Spectroscopy with Plarized Light2006

    • Author(s)
      TSUKAHARA, Satoshi
    • Journal Title

      Anal. Chim. Acta 556・1

      Pages: 112-120

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] An Improved Method for the Flow-Injection Determination of Iodine Using the Luminol Chemiluminescence Reaction in a Reversed Micellar Medium of Cetyltrimethylammonium Chloride in 1-Hexanol-Cyclohexane2006

    • Author(s)
      T.Fujiwara
    • Journal Title

      Anal.Sci. 22-1

      Pages: 67-71

    • NAID

      10017166117

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Recent Analytical Methodologies on Equilibrium, Kinetics, and Dynamics at Liquid/Liquid Interface2006

    • Author(s)
      S.Tsukahara
    • Journal Title

      Anal.Chim.Acta 556-1

      Pages: 16-25

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Measurement of Ordered Associate of Protonated Tetraphenylporphine Formed at Toluene/Aqueous H_2SO_4 Interface by Attenuated Total Internal Reflection Spectroscopy with Polarized Light2006

    • Author(s)
      S.Tsukahara
    • Journal Title

      Anal.Chim.Acta 556-1

      Pages: 112-120

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Recent Analytical Methodologies on Equilibrium, Kinetics, and Dynamics at Liquid/Liquid Interface2006

    • Author(s)
      TSUKAHARA, Satoshi
    • Journal Title

      Anal.Chim.Acta 556・1

      Pages: 16-25

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Measurement of Ordered Associate of Protonated Tetraphenylporphine Formed at Toluene/Aqueous H_2SO_4 Interface by Attenuated Total Internal Reflection Spectroscopy with Polarized Light2006

    • Author(s)
      TSUKAHARA, Satoshi
    • Journal Title

      Anal.Chim.Acta 556・1

      Pages: 112-120

    • Related Report
      2005 Annual Research Report
  • [Journal Article] On-Line Liquid-Liquid Extraction Coupled to a Reversed Micellar-Mediated Chemiluminescence Detecition System : Application to the Determination of Amino/nitroaromatic Compounds2005

    • Author(s)
      MOHAMMADZAI, Imdad Ullah
    • Journal Title

      J. Chinese Chem. Soc. 52・5

      Pages: 1037-1042

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microscopic Dielectrophoresis of Single DNA in the Presence of Some Substances in Aqueous Solutions2005

    • Author(s)
      NISHIKAWA, Ayaka
    • Journal Title

      Bunseki Kagaku 54・6

      Pages: 459-465

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] In Situ Fluorescence Microscopic Measurements of Complexation Reactions at Liquid/Liquid Interface2005

    • Author(s)
      TSUKAHARA, Satoshi
    • Journal Title

      Int. J. Soc. Mater. Eng. Res. 13・1

      Pages: 1-8

    • NAID

      130003920843

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Lactone Cleavage Raction Kinetics of Rhodamine Dye at Liquid/Liquid Interfaces Studied by Micro-Two-Phase Sheath Flow/Two-Photon Excitation Fluorescence Microscopy2005

    • Author(s)
      TOKIMOTO, Takahira
    • Journal Title

      Langmuir 21・4

      Pages: 1299-1304

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 液液海面分析法2005

    • Author(s)
      塚原 聡
    • Journal Title

      ぶんせき 4号

      Pages: 186-191

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] On-Line Liquid-Liquid Extraction Coupled to a Reversed Micellar-Mediated Chemiluminescence Detection System : Application to the Determination of Amino/nitroaromatic Compounds2005

    • Author(s)
      I.U.Mohammadzai
    • Journal Title

      J.Chinese Chem.Soc. 52-5

      Pages: 1037-1042

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microscopic Dielectrophoresis of Single DNA in the Presence of Some Substances in Aqueous Solutions2005

    • Author(s)
      A.Nishikawa
    • Journal Title

      Bunseki Kagaku 54-6

      Pages: 459-465

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] In Situ Fluorescence Microscopic Measurements of Complexation Reactions at Liquid/Liquid Interface2005

    • Author(s)
      S.Tsukahara
    • Journal Title

      Int.J.Soc.Mater.Eng.Res. 13-1

      Pages: 1-8

    • NAID

      130003920843

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Lactone Cleavage Reaction Kinetics of Rhodamine Dye at Liquid/Liquid Interfaces Studied by Micro-Two-Phase Sheath Flow/Two-Photon Excitation Fluorescence Microscopy2005

    • Author(s)
      T.Tokimoto
    • Journal Title

      Langmuir 21-4

      Pages: 1299-1304

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Analytical Chemistry on Liquid-Liquid Interfaces2005

    • Author(s)
      S.Tsukahara
    • Journal Title

      Bunseki No.4

      Pages: 186-191

    • NAID

      10015514187

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] On-Line Liquid-Liquid Extraction Coupled to a Reversed Micellar-Mediated Chemiluminescence Detection System : Application to the Determination of Amino/nitroaromatic Compounds2005

    • Author(s)
      MOHAMMADZAI, Imdad Ullah
    • Journal Title

      J.Chinese Chem.Soc. 52・5

      Pages: 1037-1042

    • Related Report
      2005 Annual Research Report
  • [Journal Article] In Situ Fluorescence Microscopic Measurements of Complexation Reactions at Liquid/Liquid Interface2005

    • Author(s)
      TSUKAHARA, Satoshi
    • Journal Title

      Int.J.Soc.Mater.Eng.Res. 13・1

      Pages: 1-8

    • NAID

      130003920843

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Lactone Cleavage Reaction Kinetics, of Rhodamine Dye at Liquid/Liquid Interfaces Studied by Micro-Two-Phase Sheath Flow/Two-Photon Excitation Fluorescence Microscopy2005

    • Author(s)
      TOKIMOTO, Takahira
    • Journal Title

      Langmuir 21・4

      Pages: 1299-1304

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 液液界面分析法2005

    • Author(s)
      塚原 聡
    • Journal Title

      ぶんせき 4号

      Pages: 186-191

    • NAID

      10015514187

    • Related Report
      2005 Annual Research Report
  • [Journal Article] A flow method for the determination of oxine-copper based on a reversed micellar mediated chemiluminescence detection system following on-line extraction2004

    • Author(s)
      UECHI, Masato
    • Journal Title

      Bunseki Kogaku 53・4

      Pages: 285-290

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Magnetic Field Enhanced Microextraction Rate of Europium(III) with 2-Thenoyltrifluoroacetone and Oxalate at Dodecane-Water Interface.2004

    • Author(s)
      TSUKAHARA, Satoshi
    • Journal Title

      Analytical Sciences 20・11

      Pages: 1515-1521

    • NAID

      40006493961

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A Flow Method for the Determination of Oxine-Copper Based on a Reversed Micellar Mediated Chemiluminescence Detection System Following On-Line Extraction2004

    • Author(s)
      M.Uechi
    • Journal Title

      Bunseki Kagaku 53-4

      Pages: 285-290

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Magnetic Field Enhanced Microextraction Rate of Europium(III) with 2-Thenoyltrifluoroacetone and Oxalate at Dodecane-Water Interface2004

    • Author(s)
      S.Tsukahara
    • Journal Title

      Anal.Sci. 20-11

      Pages: 1515-1521

    • NAID

      40006493961

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] A flow method for the determination of oxine-copper based on a reversed micellar mediated chemiluminescence detection system following on-line extraction2004

    • Author(s)
      UECHI, Masato
    • Journal Title

      Bunseki Kagaku 53・4

      Pages: 285-290

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Magnetic Field Enhanced Microextraction Rate of Europium(III) with-2-Thenovltrifluoroacetone and Oxalate at Dodecane-Water Interface.2004

    • Author(s)
      TSUKAHARA, Satoshi
    • Journal Title

      Analytical Sciences 20・11

      Pages: 1515-1521

    • Related Report
      2004 Annual Research Report
  • [Book] Interfacial Nanochemistry - Molecular Science and Engineering at Liquid-Liquid Interfaces -2005

    • Author(s)
      WATARAI, Hitoshi
    • Total Pages
      27
    • Publisher
      Kluwer Academic/Plenum Publishers
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Book] Interfacial Nanochemistry-Molecular Science and Engineering at Liquid/Liquid Interface2005

    • Author(s)
      H.Watarai
    • Publisher
      Kluwer Academic/Plenum
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary

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Published: 2004-04-01   Modified: 2016-04-21  

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