• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Analysis of charge distribution on organic cations adsorbed clay surface

Research Project

Project/Area Number 16550163
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic industrial materials
Research InstitutionTokyo Metropolitan University

Principal Investigator

TACHIBANA Hiroshi  Tokyo Metropolitan University, Basic Foundation Center, Assistant Professor, 基礎教育センタ, 講師 (00163478)

Co-Investigator(Kenkyū-buntansha) INOUE Haruo  Tokyo Metropolitan University, Urban Environmental Science, Professor, 都市環境学部, 教授 (90087304)
Project Period (FY) 2004 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2005: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2004: ¥2,900,000 (Direct Cost: ¥2,900,000)
KeywordsLayered Material / Clay / Niobate / LDH / Sulfactant / Fuluolinates Azo-Benzene / Charge Density / 表面電荷分布 / 分子軌道計算 / MOPAC / カチオン性ポルフィリン / 固体表面吸着
Research Abstract

The layerd material has a ordered structure and environment of the interlayer is variety. We discussed about the adsorption behavior of the cation dye to the anion clay surface, niobate, LDH etc. The clay and the LDH have the flat surfaces, niobate has ruggedness and complex interlayer structures. The charge position, size, extent and physical properties are different with each materials.
We made the models of the crystal structure and studied by the molecular orbital calculations. The formation of in di-, tri-, tetra-catioic charged porphyrin/synthetic clay complexes was rationalized by a size-matching of distances between the charged sites in the porphyrin molecule on the clay surface ('size-matching rule').
When using the interlayer as a chemical reaction field, it is difficult to use as the solution, that is low adsorption rate of light, because of the dispersion. To decrease the dispersion, we made the optically transparent nanolayered thin films. The first successful synthesis of photo-responsive multilayer spiral nanotubes by the introduction of polyfluorinate cationic azobenzene derivative into layered niobate interlayer I by a two-step guest-guest exchange method using the intercalation compound methyl viologen as precursor. By the light irradiation, we observed the trans to cis and the cis to trans conversion.

Report

(3 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • Research Products

    (18 results)

All 2006 2005 2004 Other

All Journal Article (18 results)

  • [Journal Article] Photo responsible Multilayers Spiral Nanotubes : Intercalation of Polyfluorinated Cationic Azobenzens Surfactant into Potassium Niobate2006

    • Author(s)
      Z.Tong, S.Takagi, H.Tachibana, K.Takagi, H.Inoue
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 684-685

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photoresponsible Multilayers Spiral Nanotubes : Intercalation of Polyfluorinated Cationic Azobenzene Surfactant into Potassium Niohate2006

    • Author(s)
      Z.Tong, S.Takagi, H.Tachibana, K.Takagi, H.Inoue
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 684-685

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Photoresponsible Multilayers Spiral Nanotubes : Intercalation of Polyfluorinated Cationic Azobenzene Surfactant into Potassium Niobate2006

    • Author(s)
      Z.Tong, S.Takagi, H.Tachibana, K.Takagi, H.Inoue
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 684-685

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Optically Transparent Thin Film of Layered Niobate(K4Nb6017) Intercalated with Tris(2.2´-bipyridyl)ruthenium(II)2005

    • Author(s)
      Zhiwei Tong, Shinsuke.Takagi, Hiroshi.Tachibana, Katsuhiko.Takagi, Haruo Inoue
    • Journal Title

      Chemistry. Letters 34

      Pages: 608-609

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Preparation and Characterlization of a Transparent Thin Film of the Layered Perovskite, K2La2Yi3010, Intercalated with an Ionic Porphyrin2005

    • Author(s)
      Zhiwei Tong, Guozhen Zhang, Shinsuke Takagi, Tetsuya Shimada, Hiroshi Tachibana, Haruo Inoue
    • Journal Title

      Chemistry. Letters 34

      Pages: 632-633

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Intercalation of Tris(2,2'-bipyridine)ruthenium(II)into a Layered Perovskite Derived from Aurivillius Phase Bi2SrTa2092005

    • Author(s)
      Z.Tong, S.Takagi, H.Shimada, H.Tachibana, H.Inoue
    • Journal Title

      Chemistry. Letters 34

      Pages: 1406-1407

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Novel Soft Chemical Method for Optically Transparent Ru(bpy)3-K4Nb6017 Thin Film2005

    • Author(s)
      Z.Tong, S.Takagi, H.Tachibana, K.Takagi, H.Inoue
    • Journal Title

      J.Phys.Chem.B 109

      Pages: 21612-21617

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Optically Transparent Thin Film of Layered Niobate (K4Nb6O17) Intercalated with Tris(2,2'-bipyridyl)ruthenium(II)2005

    • Author(s)
      Zhiwei Tong, Shinsuke Takagi, Hiroshi Tachibana, Katsuhiko Takagi, Haruo Inoue
    • Journal Title

      Chemistry Letters 34

      Pages: 608-609

    • NAID

      130004423877

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Preparation and Characterization of a Transparent Thin Film of the Layered Perovskite, K2La2Ti3O10, Intercalated with an Ionic Porphyrin2005

    • Author(s)
      Zhiwei Tong, Guozhen Zhang, Shinsuke Takagi, Tetsuya shimada, Hiroshi Tachibana, Haruo Inoue
    • Journal Title

      Chemistry Letters 34

      Pages: 632-633

    • NAID

      130004423891

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 「研究成果報告書概要(欧文)」より2005

    • Author(s)
      Z.Z.Tong, S.Takagi, H.Tachibana, K.takagi, H.Inoue
    • Journal Title

      Chemistry Letters 34

      Pages: 1406-1407

    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Novel Soft Chemical Method for Optically Transparent Ru(bpy)3-K4Nb6O17 Thin Fi2005

    • Author(s)
      Z.Tong, S.Takagi, H.Tachibana, K.Takagi, H.Inoue
    • Journal Title

      J.Phys.Chem.B 109

      Pages: 21612-21617

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Optically Transparent Thin Film of Layered Niobate (K4Nb6O17) Intercalated with Tris(2,2' -bipyridyl)ruthenium (II)2005

    • Author(s)
      Zhiwei Tong, Shinsuke Takagi, Hiroshi Tachibana, Katsuhiko Takagi, Haruo Inoue
    • Journal Title

      Chemistry. Letters 34

      Pages: 608-609

    • NAID

      130004423877

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Preparation and Characterization of a Transparent Thin Film of the Layered Perovskite, K2La2Ti3O10, Intercalated with an Ionic Porphyrin2005

    • Author(s)
      Zhiwei Tong, Guozhen Zhang, Shinsuke Takagi, Tetsuya Shimada, Hiroshi Tachibana, Haruo Inou
    • Journal Title

      Chemistry. Letters 34

      Pages: 632-633

    • NAID

      130004423891

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Intercalation of Tris(2,2'-bipyridine)ruthenium(II) into a Layered Perovskite Derived from Aurivillius Phase Bi2SrTa2O92005

    • Author(s)
      Z.Tong, S.Takagi, T Shimada, H.Tachibana, H.Inoue
    • Journal Title

      Chemistry. Letters 34

      Pages: 1406-1407

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Novel Soft Chemical Method for Optically Transparent Ru(bpy)3-K4Nb6O17 Thin Film2005

    • Author(s)
      Z.Tong, S.Takagi, H.Tachibana, K.Takagi, H.Inoue
    • Journal Title

      J.Phys.Chem.B 109

      Pages: 21612-21617

    • Related Report
      2005 Annual Research Report
  • [Journal Article] The 'size matching rule' in di-, tri-,and tetra-cationic charged porphyrim/synthetic clay complexes : effect of the inter-charge distance and the number of charged sites.2004

    • Author(s)
      M.Eguchi, S.Takagi, H.Tachibana, H.Inoue
    • Journal Title

      J. Phys. Chem. Solid 65

      Pages: 403-407

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] The 'size matching rule' in di-, tri-, and tetra-cationic charged porphyrin/synthetic clay complexes : effect of the inter-charge distance and the number of charged sites.2004

    • Author(s)
      M.Eguchi, S.Takagi, H.Tachibana, H.Inoue
    • Journal Title

      J.Phys.Chem.Solid 65

      Pages: 403-407

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary 2004 Annual Research Report
  • [Journal Article] Intercalation of Tris(2,2-bipyridine)ruthenium(II) into a Layered Perovskite Derived from Aurivillius Phase Bi2SrTa2O9

    • Author(s)
      Z.Tong, S.Takagi, T.Shimada, H.Tachibana, H.Inoue
    • Journal Title

      Chemistry Letters 34

      Pages: 1406-1407

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary

URL: 

Published: 2004-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi