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NEW FINDING ON YIELDING IN AMORPHOUS POLYMERS AND ITS APPLICATION

Research Project

Project/Area Number 16560064
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Materials/Mechanics of materials
Research InstitutionKanazawa University, Graduate School of Natural Science and Technology

Principal Investigator

KITAGAWA Masayoshi  KANAZAWA UNIVERSITY, NATURAL SCIENCE & TECHNOLOGY, PROFESSOR, 自然科学研究科, 教授 (80007773)

Co-Investigator(Kenkyū-buntansha) YAMADA Yoshinori  KANAZAWA UNIVERSITY, NATURAL SCIENCE & TECHNOLOGY, PROFESSOR, 自然科学研究科, 教授 (20126626)
Project Period (FY) 2004 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥3,700,000 (Direct Cost: ¥3,700,000)
Fiscal Year 2005: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2004: ¥3,100,000 (Direct Cost: ¥3,100,000)
KeywordsAmorphous polymer / Yielding / Shear test / Quench / Slip line / Shear band / Fatigue crack growth / Striation / 降伏機構 / ガラス転移温度 / ECAP加工
Research Abstract

It was pointed out previously that yield mode was very different between as-received (AR) and quenched (Q) amorphous polymers in a constant strain rate shear test. In AR samples, the yielding occurs by the initiation of slip lines and the nucleation and growth of shear bands (Intense shear band type). On the other hands, in Q samples, the yielding starts at the sudden initiation of vague plastic zone without slip lines and shear bands (Week shear band type). The stress-strain curves of both type of yielding are different. In order to investigate this difference of yield mode, these experiments such as observation of yield process, measurement of residual stress, effect of temperature and strain rate etc.have been performed using amorphous polymers PC,PVC and PET. It was shown that 1. the difference of the yield mode is not caused by the existence of residual stress, 2. the free volume increase resulted from quenching make polymer chains mobile easily leading to the yield mode difference. Furthermore, fatigue crack growth tests were executed using the AR and Q samples. It was shown that 1. the length of the plastic zone forming in front of the crack tip is coincident with the Dugdale equation in both AR and Q samples, 2. fatigue crack growth rates are nearly the same for both samples and 3.the shape of striation peculiar to fatigue crack growth is very different between both samples.

Report

(3 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report

Research Products

(6 results)

All 2006 2005 2004

All Journal Article (6 results)

  • [Journal Article] ポリプロピレンのECAP加工2006

    • Author(s)
      北川正義, 小崎高弘
    • Journal Title

      材料 55・1

      Pages: 37-41

    • NAID

      110006570821

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] 焼き入れした非結晶性高分子材料PC,PVCおよびPETの疲労き裂成長2006

    • Author(s)
      北川正義, 西大輔
    • Journal Title

      材料 55・1

      Pages: 61-65

    • NAID

      110006570825

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Annual Research Report 2005 Final Research Report Summary
  • [Journal Article] ECAP Process in Polypropylene2006

    • Journal Title

      J.of the Society of Materials Science, Japan Vol.55 No.1

      Pages: 37-41

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Fatigue Crack Growth of Quenched Amorphous Polymers PC, PVC and PET2006

    • Journal Title

      J.of the Society of Materials Science, Japan Vol.55 No.1

      Pages: 61-65

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Yielding and Constitutive Laws in Amorphous Polymers2005

    • Journal Title

      J.of the Japan Society of Polymer Processing '05 Symposia, Sendai

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 熱処理した非結晶性高分子材料の降伏過程2004

    • Author(s)
      北川正義, 石田真一, 柴垣憲吾, 山田良穂
    • Journal Title

      材料 53・3

      Pages: 327-332

    • NAID

      110006266240

    • Related Report
      2004 Annual Research Report

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Published: 2004-03-31   Modified: 2016-04-21  

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