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Development of galvanic corrosion-resistant CFRP/aluminum laminates

Research Project

Project/Area Number 16560600
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Composite materials/Physical properties
Research InstitutionKYUSHU UNIVERCITY

Principal Investigator

WANG Wen-Xue  Kyushu University, Research Institute for Appied Mechanics, Associate Professor, 応用力学研究所, 助教授 (40240569)

Co-Investigator(Kenkyū-buntansha) TAKAO Yoshihiro  Kyushu University, Research Institute for Appied Mechanics, Professor, 応用力学研究所, 教授 (30108766)
Project Period (FY) 2004 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥3,700,000 (Direct Cost: ¥3,700,000)
Fiscal Year 2006: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2005: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2004: ¥1,700,000 (Direct Cost: ¥1,700,000)
KeywordsCFRP / Al laminate / Galvanic corrosion-resistance / Coating method for aluminum / Sol-Gel coating / ゾル・ゲル法 / アルミ合金積層複合材料 / ゾルゲル法 / 表面処理 / 陽極酸化
Research Abstract

In this project, the main attention is focused on the galvanic corrosion problem of CFRP/A1 laminates. A galvanic corrosion-resistant CFRP/Al is created based on a new surface treatment method, namely nano-composite coating. Aluminum alloy 2024-T3 is selected as the metal layer. Nano-composite coating surface treatment method consists of a sulfuric acid anodizing process and a SiO_2 nano-particle reinforced inorganic/organic hybrid sol-gel coating process. Environmental considerations motivate us to utilize sulfuric acid anodizing to replace chromic acid anodizing. The combination of two coating processes provides a composite protection layer including an anodized layer and a nano-particle reinforced layer to aluminum alloy. Electrochemistry tests are conducted to evaluate the properties of galvanic corrosion resistance of aluminum alloy treated by nano-composite coating. Next, CFRP/Al is fabricated by the use of aluminum alloy sheet with the nano-composite coating and commercially available carbon fiber/epoxy prepreg. The curing process using an autoclave is the same with that used for the fabrication of conventional carbon fiber/epoxy laminates without aluminum sheets. The microstructure of cross-section of CFRP/A1 is investigated by means of scanning electron microscope (SEM) and electron probe micro analyzer (EPMA), which shows that fine composite coating is formed. Corrosion tests of aluminum alloy with and without nano-composite coating are conducted. Furthermore, mechanical properties of CFRP/A1 are evaluated based on tensile and fatigue tests of specimens with and without an open hole. The effects of thermal residual stress on the mechanical properties of CFRP/A1 are investigated. Experimental results show that CFRP/A1 has better corrosion-resistance and strength than original aluminum.

Report

(4 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (31 results)

All 2007 2006 2005 2004 Other

All Journal Article (28 results) Book (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] CFRP/Al-FRML Based on Nano-composite Coating and Its Mechanical Properties2007

    • Author(s)
      Wang, W.X., Takao, Y., Kashima, I., Matsubara, T.
    • Journal Title

      AIAA-2007-2268

      Pages: 1-11

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Test methods for evaluating the interlaminar shear strength of CFML2007

    • Author(s)
      Wang, W.X., Higashijima, M., Takao, Y., Matsubara, T.
    • Journal Title

      Proceedings of The Internation Conference on Advanced Technology in Experimental Mechanics '07

      Pages: 1-6

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 複合皮膜による耐ガルバニック腐食CFMLの創製2007

    • Author(s)
      汪文学, 高雄善裕, 松原監壮, 内村治弘, 馬場俊輪, 東島誠
    • Journal Title

      材料、Vol. 56, No. 5 56・5

      Pages: 1-6

    • NAID

      130002085886

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Temperature on the Bearing strength of CF/Epoxy Pinned Joints2007

    • Author(s)
      Hirano, N., Takao, Y., Wang, W.X.
    • Journal Title

      Journal of Composite Materials 41・3

      Pages: 335-351

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] New Solution Method for Homogenization Analysis and its Application to the Prediction of Macroscopic Elastic Constants of Materials with Periodic Microstructures2007

    • Author(s)
      Wang, W.X., Luo, D.M., Takao, Y., Kakimoto, K.
    • Journal Title

      Computer & Structure 84

      Pages: 991-1001

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] CFRP/Al-FRML Based on Nano-composite Coating and Its Mechanical Properties2007

    • Author(s)
      Wang, W.X., Takao, Y., Kashima, I., Matsubara, T.
    • Journal Title

      AIAA paper AIAA-2007-2268

      Pages: 1-11

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Test methods for evaluating the interlaminar shear strength of CFML2007

    • Author(s)
      Wang, W.X., Higashijima, M., Takao, Y., Matsubara, T.
    • Journal Title

      The International Conference on Advanced Technology in Experimental Mechanics '07,Fukuoka, Japan Paper No.90286

      Pages: 1-6

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effects of Temperature on the Bearing Strength of CF/Epoxy Pinned Joints,2007

    • Author(s)
      Hirano, N., Takao, Y., Wang, W.X.
    • Journal Title

      Journal of Composite Materials Vol.41, No.3

      Pages: 335-351

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] CFRP/A1-FRML Based on Nano-composite Coating and Its Mechanical Properties2007

    • Author(s)
      Wang, W.X., Takao, Y., Kashima, I., Matsubara, T.
    • Journal Title

      AIAA-2007-2268

      Pages: 1-11

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Test methods for evaluating the interlaminar shear strength of CFML2007

    • Author(s)
      Wang, W.X., Higashijima, M., Takao, Y., Matsubara, T.
    • Journal Title

      Proceedings of The International Conference on Advancea Technology in Experimental Mechanics '07,

      Pages: 1-6

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 複合皮膜による耐ガルバニック腐食CFMLの創製2007

    • Author(s)
      汪文学, 高雄善裕, 松原監壮, 内村治弘, 馬場後輔, 東島誠
    • Journal Title

      材料、Vol.56, No.5 56・5

      Pages: 1-6

    • NAID

      130002085886

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Effects of Temperature on the Bearing Strength of CF/Epoxy Pinned Joints2007

    • Author(s)
      Hirano, N., Takao, Y., Wang, W.X.
    • Journal Title

      Journal of Conposite Naterials 41・3

      Pages: 335-351

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Development of carbon fiber reinforced aluminum laminates2006

    • Author(s)
      W.X.Wang, Y.Takao, T.Matsubara
    • Journal Title

      Innovative Developments, Characterizations and Applications of Composites (Edited by Y. Zhang and Q.Q. Ni), China Agricultural Science and Technology Press

      Pages: 94-103

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Development of carbon fiber reinforced aluminum laminates,2006

    • Author(s)
      W.X.Wang, Y.Takao, T.Matsubara
    • Journal Title

      Innovative Developments, Characterizations and Applications of Composites (Edited by Y.Zhang and Q.Q.Ni)(China Agricultural Science and Technology Press)

      Pages: 94-103

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] New Solution Method for Homogenization Analysis and its Application to the Prediction of Macroscopic Elastic Constants of Materials with Periodic Microstructures,2006

    • Author(s)
      Wang, W.X., Luo, D.M., Takao, Y., Kakimoto, K.
    • Journal Title

      Computer & Structure 84

      Pages: 991-1001

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Development of carbon fiber reinforced aluminum laminates2006

    • Author(s)
      W.X.Wang, Y.Takao, T.Matsubara
    • Journal Title

      Innovative Developments, Characterizations and Applications of Composites (Edited by Y. Zhang and Q. Q. Ni), China Agricultural Science and Technology Press

      Pages: 94-103

    • Related Report
      2006 Annual Research Report
  • [Journal Article] New method to determine the exact periodic boundary conditions for Macro-microscopic homogenization analysis and its application on the Prediction of effective elastic constants of periodic materials2006

    • Author(s)
      D.M.Luo, W.X.Wang, Y.Takao, K.Kakimoto
    • Journal Title

      Journal of Mechanical Strength (To appear)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] New solution method for homogenization analysis and its application Of macroscopic elastic constants of materials with periodic microstructures2006

    • Author(s)
      W.X.Wang, D.M.Luo, Y.Takao, K.Kakimoto
    • Journal Title

      Computers & Structures (To appear)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Strength of metal impregnated C/C under tensile cyclic loading2006

    • Author(s)
      M.Moriyama, Y.Takao, W.X.Wang, T.Matsubara
    • Journal Title

      Composite Science and Technology (To appear)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Prediction of the stiffness and stress for carbon nano-tube composites based on homogenization analysis2005

    • Author(s)
      D.M.Luo, W.X.Wang, Y.Takao, K.Kakimoto
    • Journal Title

      Report of Research Institute for Applied Mechanics, Kyushu University 129

      Pages: 37-45

    • NAID

      120005306676

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Tensile cyclic strength and macroscopic failure characteristics Of C/C and the metal impregnated C/C2005

    • Author(s)
      M.Moriyama, Y.Takao, W.X.Wang, T.Matsubara
    • Journal Title

      Report of Research Institute for Applied Mechanics, Kyushu University 129

      Pages: 25-30

    • NAID

      120005306674

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Numerical prediction of the stiffmess and local stresses for Nano-composites with periodic distributions of nanotubes2005

    • Author(s)
      W.X.Wang, D.M.Luo, Y.Takao, K.Kakimoto
    • Journal Title

      Preceedings of ICCM-15, ID-p102(CDROM)

      Pages: 1-10

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Isoparameteric Finite Point Method in Computational Mechanics2004

    • Author(s)
      W.X.Wang, Y.Takao
    • Journal Title

      Computational Mechanics 33

      Pages: 481-490

    • Related Report
      2004 Annual Research Report
  • [Journal Article] CF/Epoxyピン継手ベアリング強度に及ぼす温度効果の基礎的検討2004

    • Author(s)
      平野憲芳, 高雄善裕, 松原 監壮, 汪 文学
    • Journal Title

      日本複合材料学会誌 30

      Pages: 102-110

    • NAID

      10012964203

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Nano-whisker reinforced glass ceramics for artificial tooth2004

    • Author(s)
      Y.Takao, Y.Suematsu, T.Mtsubara, W.X.Wang, N.Miyano, S.Ukon
    • Journal Title

      Proceeding of the 11th US-Japan Conference on Composite Materials

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Strength of metal impregnanted C/C under tensile and fatigue loading2004

    • Author(s)
      M.Moriyama, Y.Takao, W.X.Wang, T.Matsubara
    • Journal Title

      Proceeding of the 11th US-Japan Conference on Composite Materials

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Effects of anodizing on the interlaminar shear strength of carbon fiber reinforced aluminum laminates2004

    • Author(s)
      S.Baba, Y.Takao, W.X.Wang, T.Matsubara
    • Journal Title

      Proceeding of the 5th Korea/Japan Joint Workshop on Aeronautics and Astronautics

      Pages: 1-6

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Development of galvanic corrosion-resistant CFML based on composite coating

    • Author(s)
      Wang, W.X., Higashijima, M., Takao, Y., Matsubara, T., Uchimura, N., Baba, S., Higashijima, M.
    • Journal Title

      Journal of The Society of Materials Science, Japan Vol.56, No.5

      Pages: 1-6

    • NAID

      130002085886

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] 高分子基複合材料:先進複合材料(魯雲等編集)第1章2004

    • Author(s)
      汪 文学
    • Total Pages
      67
    • Publisher
      (中国)機械工業出版社,北京
    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] クロムフリーアルミ合金表面耐食処理方法及び耐ガルバニック腐食CFRP/アルミ合金積層板の製造法2006

    • Inventor(s)
      汪 文学, 高雄善裕, 松原監壮
    • Industrial Property Rights Holder
      3人共同
    • Industrial Property Number
      2006-060173
    • Filing Date
      2006-02-06
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Patent(Industrial Property Rights)] クロムフリーアルミ合金表面耐食処理方法及び耐ガルバニック腐食CFRP/アルミ合金積層板の製造法2006

    • Inventor(s)
      汪 文学, 高雄 善裕, 松原 監壮
    • Industrial Property Rights Holder
      3人共同
    • Filing Date
      2006-02-06
    • Related Report
      2005 Annual Research Report

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Published: 2004-04-01   Modified: 2016-04-21  

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