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Complete Oxidation of Methane at The Interface Between Anode and Electrolyte with Highly-Dispersed Fine Particles of Electrically-Conductive Oxides

Research Project

Project/Area Number 16560628
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionNagaoka University of Technology

Principal Investigator

SATO Kazunori  Nagaoka University of Technology, Department of Engineering, Professor, 工学部, 教授 (20143828)

Co-Investigator(Kenkyū-buntansha) 菅沼 茂明  新光電気工業株式会社, 開発統括部, 研究員
Project Period (FY) 2004 – 2005
Project Status Completed (Fiscal Year 2005)
Budget Amount *help
¥3,700,000 (Direct Cost: ¥3,700,000)
Fiscal Year 2005: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2004: ¥2,600,000 (Direct Cost: ¥2,600,000)
KeywordsMethane / Solid oxide fuel cell / Metal oxide / Anode / Anodic oxidation reaction / Polarization resistance / Cermet
Research Abstract

The synthesis of electrically conductive fine oxide particles and its application to the electrocatalyst for the anode of solid oxide fuel cells have been investigated. The delafossite oxide, PdCoO_2, was obtained by heating the precipitate precursors from PdCl_2 and CoCl_2 with an aqueous NaOH. The specific valence states of the metallic ions allowed methane to easily react on the surface of these electrocatalyst particles with the oxide ions transported through the oxide electrolytes. This effect is expected to enhance the electrochemical oxidation of methane for the Ni_<1-X>Co_X-electrolyte (yttria- or ceria-based) cermet anode.

Report

(3 results)
  • 2005 Annual Research Report   Final Research Report Summary
  • 2004 Annual Research Report
  • Research Products

    (20 results)

All 2006 2005 2004

All Journal Article (17 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Enhancement of methane oxidation at the Ni_<1-X>Co_X-zirconia cermet anode in solid oxide fuel cells.2006

    • Author(s)
      K.Sato, K.Ogasa
    • Journal Title

      ITE Letters on Batteries, New Technologies & Medicine 7・1

      Pages: 39-42

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Enhancement of methane oxidation at the Ni_<1-X>Co_X-zirconia cermet anode in solid oxide fuel cells.2006

    • Author(s)
      K.Sato, K.Ogasa
    • Journal Title

      ITE Letters on Batteries, New Technologies & Medicine 7-1

      Pages: 39-42

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Cr poisoning suppression in solid oxide fuel cells by using LaNi(Fe)O_3 electrodes.2006

    • Author(s)
      T.Komatsu, K.Sato, et al.
    • Journal Title

      Electrochem. Solid-State Lett. Vol.9

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Enhancement of methane oxidation at the Ni_<1-x>Co_x-zirconia cermet anode in solid oxide fuel cells.2006

    • Author(s)
      K.Sato, K.Ogasa
    • Journal Title

      ITE Lett. Batteries. Vol.7, NO.1

      Pages: 39-42

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 水酸化鉄粒子による水質中の鉛イオン優先吸着および金属酸化物表面のプロトンがもたらす酸化反応活性化効果2006

    • Author(s)
      佐藤一則
    • Journal Title

      まてりあ 第44巻,第6号

      Pages: 447-481

    • NAID

      10016439674

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Microstructure of the proton-exchanged product for LiCoO_2 and its electrocatlytic property for hydrogen oxidation in a stabilized-zirconia electrolyte cell.2005

    • Author(s)
      K.Sato
    • Journal Title

      ITE Letters on Batteries, New Technologies & Medicine 6・2

      Pages: 110-113

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Enhancement of the electrochemical oxidation of methane in the nickel-cobalt SDC cermet anode.2005

    • Author(s)
      K.Sato, Y.Kato et al.
    • Journal Title

      Electrochem.Soc.Proc. 2005・7

      Pages: 1403-1409

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] 水酸化鉄粒子による水質中の鉛イオン優先吸着および金属酸化物表面のプロトンがもたらす酸化反応活性化効果2005

    • Author(s)
      佐藤一則
    • Journal Title

      日本金属学会報 まてりあ 44・6

      Pages: 477-481

    • NAID

      10016439674

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Microstructure of the proton-exchanged product for LiCoO_2 and its electrocatlytic property for hydrogen oxidation in a stabilized-zirconia electrolyte cell2005

    • Author(s)
      K.Sato
    • Journal Title

      ITE Letters on Batteries, New Technologies & Medicine 6-2

      Pages: 110-113

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Enhancement of the electro-chemical oxidation of methane in the nickel-cobalt SDC cermet anode2005

    • Author(s)
      K.Sato.Y.Kato et al.
    • Journal Title

      Electrochem.Soc.Proc. 2005-7

      Pages: 1403-1409

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Preferential adsorption of lead ions on the Surface of hydrous ferric oxide particles and the activity for the oxidation reaction caused by the surface protons of transition metal oxides.2005

    • Author(s)
      K.Sato
    • Journal Title

      Materia Japan 44-6

      Pages: 477-481

    • NAID

      10016439674

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Enhancement of the electrochemical oxidation of methane in the nickel-cobalt SDC cermet anode.2005

    • Author(s)
      K.Sato, Y.Kato, et al.
    • Journal Title

      Electrochem. Soc. Proc., Vol.2005-07

      Pages: 1403-1409

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Microstructure of the proton-exchanged Product for LiCoO_2 and its electrochemical property for hydrogen oxidation in a stabilized-zirconia electrolyte cell.2005

    • Author(s)
      K.Sato
    • Journal Title

      ITE Lett. Batteries. Vol.6,No.2

      Pages: 110-113

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Retardation of carbon deposition on Ni-YSZ anode in a solid oxide fuel cell by addition of carbon dioxide to methane.2004

    • Author(s)
      K.Ogasa, K.Sato et al.
    • Journal Title

      J.Ceram.Soc.Jpn. 112・5

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Retardation of carbon deposition on Ni-YSZ anode in a solid oxide fuel cell by addition of carbon dioxide to methane2004

    • Author(s)
      K.Ogasa, K.Sato et al.
    • Journal Title

      J.Ceram.Soc. 112-5

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Journal Article] Retardation of carbon deposition on Ni-YSZ anode in a solid oxide fuel cell by addition of carbon dioxide to methane2004

    • Author(s)
      K.Ogasa, K.Sato, et al.
    • Journal Title

      J.Ceram.Soc.Jpn. 112・5

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Microstructure of the proton-exchanged transition metal oxides obtained by acid treatement and their catalytic properties2004

    • Author(s)
      K.Sato, Y.Inoue
    • Journal Title

      Ionic & Mixed Ionic Cond.Ceram.,Electrochem.Soc.Proc. (印刷中)

    • Related Report
      2004 Annual Research Report
  • [Patent(Industrial Property Rights)] 電極材料及び燃料電池2005

    • Inventor(s)
      佐藤一則外
    • Industrial Property Rights Holder
      長岡技術科学大学, 新光電気工業
    • Industrial Property Number
      2005-140285
    • Filing Date
      2005-05-12
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 電極材料及び燃料電池2005

    • Inventor(s)
      佐藤一則外
    • Industrial Property Rights Holder
      長岡技術科学大学, 新光電気工業
    • Industrial Property Number
      2005-140353
    • Filing Date
      2005-05-12
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2005 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 電極材料及び燃料電池2005

    • Inventor(s)
      佐藤 一則ほか
    • Industrial Property Rights Holder
      長岡技術科学大学, 新光電気工業
    • Industrial Property Number
      2005-140285
    • Filing Date
      2005-05-12
    • Related Report
      2005 Annual Research Report

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Published: 2004-04-01   Modified: 2016-04-21  

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