メゾポーラス材料を使った新しい電子材料の創生とデバイスへの応用

• Project/Area Number: 16F16371
• Research Category: Grant-in-Aid for JSPS Fellows
• Allocation Type: Single-year Grants
• Section: 外国
• Research Field: Electronic materials/Electric materials
• Research Institution: National Institute for Materials Science
• Principal Investigator: 知京 豊裕 国立研究開発法人物質・材料研究機構, 統合型材料開発・情報基盤部門, 副拠点長 (10354333)
• Co-Investigator(Kenkyū-buntansha): MOHAMED MOHAMED 国立研究開発法人物質・材料研究機構, 統合型材料開発・情報基盤部門, 外国人特別研究員
• Project Period (FY): 2016-10-07 – 2019-03-31
• Project Status: Completed (Fiscal Year 2018)
• Budget Amount: ¥2,300,000 (Direct Cost: ¥2,300,000); Fiscal Year 2018: ¥1,000,000 (Direct Cost: ¥1,000,000); Fiscal Year 2017: ¥600,000 (Direct Cost: ¥600,000); Fiscal Year 2016: ¥700,000 (Direct Cost: ¥700,000)
• Keywords: mesoporous / Sol-gel / phase transformation / ion conductivity / oxide / multi layer / sol-gel / BaTiO3 / SrTiO3 / Sol-gel science / mesoporous frameworks / metal oxides / films / thermal stability / dielectrics / ferromagnetism / capacitors

Outline of Annual Research Achievements

Mesoporous HfO2 thin films (around 20 nm thick) were fabricated by sol-gel-based spin-coating process at 600 oC to realize the ion conducting media for the ionics (e.g. Na+ and K+ for rechargeable ion batteries) for battery application.. Another film of aluminum metal (10 nm thick) was deposited by DC sputtering to soak into the mesoporous to control the conductivity. The obtained mesostructured HfO2/Al2O3 films show rather good conductivity which is enough for bias for ion conduction. At the meantime, among all the thin films the mesostructured HfO2/Al2O3 composite thin films showed the smallest Nyquist arc diameter in 1 M KOH electrolyte, implying lower impedance at the electrode/electrolyte interface, reflecting better ions diffusion and movement.
Also we have developed a mesostructured HfO2/Al2O3 composite thin films with much reduced leakage current compared to HfO2 or HfO2/Al thin films.
We have reported simple chemical route for preparation of polycrystalline Ni-Co PBA thin films on the surface of silicon wafers. Several kinds of homogeneous pyramidal structures formed on the surface. The thin films showed paramagnetic properties which may allow applications of these materials in molecular spintronic devices. Our thin films did not show a negative magnetization compared to the previously reported PBAs thin films. This method could be extended for demonstrating multiferroic thin films by forming the multilayered or heterostructures for electric applications in the future.

Research Progress Status

平成30年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

平成30年度が最終年度であるため、記入しない。

Research Products

• [Int'l Joint Research] Tanta University(Egypt)
• [Journal Article] Graphene‐Wrapped Nanoporous Nickel‐Cobalt Oxide Flakes for Electrochemical Supercapacitors (2018)
  • Author(s): A. Azhar, M. B. Zakaria,* J. Lin, T. Chikyow, D. J. Martin, Y. G. Alghamdi, A. A. Alshehri, Y. Bando, M. S. A. Hossain, K. C. W. Wu, A. K. Nanjundan, Y. Yamauchi
  • Journal Title: ChemistrySelect Volume: 3 Pages: 8505-8510
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Chemical Synthesis of Multilayered Nanostructured Perovskite Thin Films with Dielectric Features for Electric Capacitors (2018)
  • Author(s): Zakaria Mohamed Barakat、Nagata Takahiro、Matsuda Asahiko、Yasuhara Yudai、Ogura Atsushi、Hossain Md. Shahriar A.、Billah Motasim、Yamauchi Yusuke、Chikyow Toyohiro
  • Journal Title: ACS Applied Nano Materials Volume: 1 Issue: 2 Pages: 915-921
  • DOI: 10.1021/acsanm.7b00310
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Three-Dimensional Macroporous Graphitic Carbon for Supercapacitor Application (2018)
  • Author(s): R. R. Salunkhe, J. Wang, A. Azhar, J. Lin, V. Malgras, Y. Bando, Mohamed B. Zakaria, A. Ali Alshehri, J. Kim, Y. Yamauchi, K. C.-W. Wu
  • Journal Title: ChemistrySelect, Volume: 3 Issue: 16 Pages: 4522-4526
  • DOI: 10.1002/slct.201800545
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Gold nanoparticles supported on mesoporous iron oxide for enhanced CO oxidation reaction (2018)
  • Author(s): Tanaka Shunsuke, Lin Jianjian, Kaneti Yusuf Valentino, Yusa Shin-ichi, Jikihara Yohei, Nakayama Tsuruo, Zakaria Mohamed Barakat, Alshehri Abdulmohsen Ali, You Jungmok, Hossain Md. Shahriar A., Yamauchi Yusuke
  • Journal Title: Nanoscale Volume: 10 Issue: 10 Pages: 4779-4785
  • DOI: 10.1039/c7nr08895g
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Cyanide Bridged Coordination Polymer Nanoflakes Thermally Derived Ni3C and fcc-Ni Nanoparticles (2017)
  • Author(s): Mohamed B. Zakaria, E. M. Ebeid, M. M. Abdel-Galil, T. Chikyow
  • Journal Title: New. J. Chem Volume: 41 Issue: 24 Pages: 14890-14897
  • DOI: 10.1039/c7nj03311g
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Recent Advances in Prussian Blue and Prussian Blue Analogues: Synthesis and Thermal Treatments (2017)
  • Author(s): Mohamed B. Zakaria, T. Chikyow
  • Journal Title: Coord. Chem. Rev. Volume: 352 Pages: 328-345
  • DOI: 10.1016/j.ccr.2017.09.014
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Synergetic Nanoporous Mn-Ru Oxides as An Efficient Electrocatalyst for Oxygen Reduction Reaction, (2017)
  • Author(s): ;Mohamed B. Zakaria, T. Chikyow
  • Journal Title: New. J. Chem., Volume: 41 Issue: 16 Pages: 8196-8202
  • DOI: 10.1039/c7nj01408b
  • Peer Reviewed
• [Journal Article] Prussian blue derived iron oxide nanoparticles wrapped in graphene oxide sheets for electrochemical supercapacitors (2017)
  • Author(s): Tanaka Shunsuke, Salunkhe Rahul R., Kaneti Yusuf Valentino, Malgras Victor, Alshehri Saad M., Ahamad Tansir, Zakaria Mohamed B., Dou Shi Xue, Yamauchi Yusuke, Hossain Md. Shahriar A.
  • Journal Title: RSC Advances Volume: 7 Issue: 54 Pages: 33994-33999
  • DOI: 10.1039/c7ra03179c
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Dual-textured Prussian Blue nanocubes as sodium ion storage materials (2017)
  • Author(s): Dae Sik Kima, Mohamed B. Zakariab, Min-Sik Parkd, Azhar Alowasheeir,Saad M. Alshehrie,Yusuke Yamauchi, Hansu Kima
  • Journal Title: Electrochimica Acta Volume: 240 Pages: 300-306
  • DOI: 10.1016/j.electacta.2017.04.054
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Presentation] Layer-by-layer assembly of organic-inorganic sheets into well-defined 3D structures for multiple functional hybrids (2018)
  • Author(s): Mohamed B. Zakaria
  • Organizer: The 69th Colloid and Interfacial Chemistry Debate
• [Presentation] Chemical Synthesis of Multilayered Nanostructured Perovskite Thin Films and Investigation of Dielectric Features (2018)
  • Author(s): Mohamed B. Zakaria
  • Organizer: European Advanced Materials Congress (EAMC)
  • Int'l Joint Research
• [Presentation] Graphene-CoNi CPs Hybrid Layers Thermally Derived Well-Retained Graphene-Co2NiO4 Nanocomposite for Hybrid Supercapacitors (2018)
  • Author(s): Mohamed B. Zakaria
  • Organizer: European Advanced Materials Congress (EAMC)
  • Int'l Joint Research
• [Presentation] Formation of Molecular Magnetic Thin Films of Ni-Co Cyano-Bridged Coordination Polymers on Silicon Wafers (2018)
  • Author(s): Mohamed B. Zakaria, E. M. Ebeid, M. M. Abdel-Galil, T. Chikyow
  • Organizer: MANA International Symposium2018
• [Presentation] Chemical Synthesis of Multilayered Nanostructured Perovskite Thin Films and Investigation of Dielectric Features (2018)
  • Author(s): Zakaria Mohamed Barakat、Nagata Takahiro、Matsuda Asahiko、Yasuhara Yudai、Ogura Atsushi、Hossain Md. Shahriar A.、Billah Motasim、Yamauchi Yusuke、Chikyow Toyohiro
  • Organizer: European Advanced Materials Congress (EAMC)
  • Invited
• [Presentation] Graphene-CoNi CPs Hybrid Layers Thermally Derived Well-Retained Graphene-Co2NiO4 Nanocomposite for Hybrid Supercapacitors, (2018)
  • Author(s): Zakaria Mohamed Barakat、Nagata Takahiro、Matsuda Asahiko、Yasuhara Yudai、Ogura Atsushi、Hossain Md. Shahriar A.、Billah Motasim、Yamauchi Yusuke、Chikyow Toyohiro
  • Organizer: European Advanced Materials Congress (EAMC)
• [Presentation] Mesostructured SrTiO3/BaTiO3 Hybrid Films by Surfactant-Templated Sol-Gel Pathway with Robust Ferroelectricity (2017)
  • Author(s): Zakaria Mohamed Barakat、Nagata Takahiro、Matsuda Asahiko、Yasuhara Yudai、Ogura Atsushi、Hossain Md. Shahriar A.、Billah Motasim、Yamauchi Yusuke、Chikyow Toyohiro
  • Organizer: IUMRS-ICAM 2017
  • Invited
• [Presentation] Chemical Synthesis of Multilayered Nanostructured Perovskite Thin Films and Investigation of Dielectric Features (2017)
  • Author(s): Zakaria Mohamed Barakat、Nagata Takahiro、Matsuda Asahiko、Yasuhara Yudai、Ogura Atsushi、Hossain Md. Shahriar A.、Billah Motasim、Yamauchi Yusuke、Chikyow Toyohiro
  • Organizer: 5th Nano Today Conference
• [Presentation] ;Rational design of Mn-Ru cyano-bridged coordination polymer nanocubes derived well-retained nanoporous Mn-Ru mixed oxides for efficient electrocatalysts, has been accepted for a poster presentation (2017)
  • Author(s): ;Mohamed B. Zakaria, T. Chikyow
  • Organizer: 5th Nano Today Conference