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Function cultivation in abundant oxide utilizing nano-structures and active anion species

Research Project

Project/Area Number 16GS0205
Research Category

Grant-in-Aid for Creative Scientific Research

Allocation TypeSingle-year Grants
Research InstitutionTokyo Institute of Technology

Principal Investigator

HOSONO Hideo  Tokyo Institute of Technology, フロンティア研究センター, 教授 (30157028)

Co-Investigator(Kenkyū-buntansha) HIRAYAMA Hiroyuki  東京工業大学, 大学院・総合理工学研究科, 教授 (60271582)
KAMIYA Toshio  東京工業大学, 応用セラミックス研究所, 准教授 (80233956)
KAWAJI Hitoshi  東京工業大学, 応用セラミックス研究所, 准教授 (10214644)
HAYASHI Katuro  東京工業大学, 応用セラミックス研究所, 准教授 (90397034)
TAKEUCHI Daisuke  東京工業大学, 資源化学研究所, 准教授 (90311662)
YANAGI Hiroshi  東京工業大学, 応用セラミックス研究所, 助教 (30361794)
MATSUISHI Satoru  東京工業大学, フロンティア研究センター, 助教 (30452006)
TANAKA Isao  山梨大学, 大学院・医学工学総合研究部, 教授 (40155114)
Research Collaborator アレクサンドラ, シュルガーロンドン大学UCL, 教授
Project Period (FY) 2004 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥544,700,000 (Direct Cost: ¥419,000,000、Indirect Cost: ¥125,700,000)
Fiscal Year 2008: ¥117,000,000 (Direct Cost: ¥90,000,000、Indirect Cost: ¥27,000,000)
Fiscal Year 2007: ¥110,500,000 (Direct Cost: ¥85,000,000、Indirect Cost: ¥25,500,000)
Fiscal Year 2006: ¥113,360,000 (Direct Cost: ¥87,200,000、Indirect Cost: ¥26,160,000)
Fiscal Year 2005: ¥104,260,000 (Direct Cost: ¥80,200,000、Indirect Cost: ¥24,060,000)
Fiscal Year 2004: ¥99,580,000 (Direct Cost: ¥76,600,000、Indirect Cost: ¥22,980,000)
Keywordsナノ構造 / 活性アニオン / 元素戦略 / エレクトラド / C12A7 / 超伝導 / 単結晶 / エレクトライド / 電子比熱 / イオン伝導 / 酸素イオン導電体 / 金属・絶縁体転移 / 仕事関数 / 拡散 / ユビキタス元素戦略 / 金属絶縁体転移 / 電子放出材料 / 光誘起変化 / イオン注入 / ナノポーラス材料 / アルミン酸カルシウム / 活性酸素 / 無機レジスト
Research Abstract

ありふれた元素から構成される12CaO・7Al2O3(C12A7)のナノケージ中に性アニオン種(O-, H-, Au-, および電子)を対イオンとして導入することで、新しい機能発現を試みた.電子ドープにより、絶縁性から金属状態に転化し、そして低温では超伝導状態が実現した.また、この物質の仕事関数(2.4V)はアルカリ金属並みに小さく、しかも化学的・熱的に安定というユニークな物性が発見され、電子放出源、水中で使える還元剤, 有機EL のカソードなどへの応用が有望であることがわかった.また、O-を含有するC12A7 は、背面から酸素ガスを供給することにより、O-ビームを定常的に取り出すことができた.

Report

(6 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • 2004 Annual Research Report
  • Research Products

    (108 results)

All 2009 2008 2007 2006 2005 2004 Other

All Journal Article (65 results) (of which Peer Reviewed: 47 results) Presentation (8 results) Book (10 results) Remarks (2 results) Patent(Industrial Property Rights) (23 results) (of which Overseas: 5 results)

  • [Journal Article] Sustainable Thermionic O- Emission from Stoichiometric 12CaO・ 7Al_2O_3 with Nanoporous Crystal Structure2009

    • Author(s)
      Jiang Li, Katsuro Hayashi, Masahiro Hirano and Hideo Hosono
    • Journal Title

      Journal of Electrochemical Society 156

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sustainable Thermionic O. Emission from Stoichiometric 12CaO・7Al_2O_3 with Nanoporous Crystal Structure2009

    • Author(s)
      Jiang Li, et. al.
    • Journal Title

      Journal of Electrochemical Society 156

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Humidity-Sensitive Electrical Conductivity in Ca_<12>Al_<14-x>Si_xO_<32>Cl_<2+x>(0<x<3. 4) Ceramics2009

    • Author(s)
      Katsuro Hayashi, et. al.
    • Journal Title

      Electrochemical and Solid-State Letters 12

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single crystal growth of nanoporous C12A7:e by controlling melt state2009

    • Author(s)
      S. G. Yoon, et. al.
    • Journal Title

      Journal of Nanoscience and Nanotechnology, in press (in press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Field-assisted sustainable O^- ion emission from fluorine-substituted 12CaO・7Al_2O_3 with improved thermal stability2009

    • Author(s)
      Jiang Li, et. al.
    • Journal Title

      Solid State Ionics, accepted for publication (in press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen Ion Conduction in 12CaO・7Al_2O_3:O^<2-> conduction and possibility of O^- fast conduction2009

    • Author(s)
      Hideo Hosono, et. al.
    • Journal Title

      Solid State Ionics, in press (in press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evidence forBardeen-Cooper-Schrieffer-typesuperconducting behavior in the electride(CaO)_<12>(Al_2O_3)_7 : e^- from heat capacitymeasurements2008

    • Author(s)
      Yoshimitsu Kohama, Sung Wng Kim, TakeoTojo, Hitoshi Kawaji, Tooru Atake, SatoruMatsuishi and Hideo Hosono
    • Journal Title

      Phys. Rev B77

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pore-Free 12CaO・7Al_2O_3 Single-Crystal Growth by Melt State Control using the Floating Zone Method2008

    • Author(s)
      Seok Gyu Yoon, Sung Wng Kim, Masahiro Hirano, Dae Ho Yoon and Hideo Hosono
    • Journal Title

      Cryst, Growth & Design 8

      Pages: 1271-1271

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Localized and Delocalized Electrons in Room-Temperature Stable Electride [Ca_<24>Al_<28>O_<64>]^<4+>(O^<2->)_<2-x>(e-)_<2x> : Analysis of Optical Reflectance Spectra2008

    • Author(s)
      Satoru Matsuishi, Sung Wng Kim, Toshio Kamiya, Masahiro Hirano and Hideo Hosono
    • Journal Title

      J. Phys. Chem C112

      Pages: 4753-4760

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Localized and Delocalized Electrons in Room- Temperature Stable Electride [Ca_<24>Al_<28>O_<64>]^<4+>(O^<2->)_<2-x>(e-)_<2x> : Analysis of Optical Reflectance Spectra2008

    • Author(s)
      S. Matsuishi, S.W. Kim, T. Kamiya, M.Hirano and H. Hosono
    • Journal Title

      J. Phys. Chem C112

      Pages: 4753-4760

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Evidence for Bardeen-Cooper-Schrieffer-type superconducting behavior in the electride (CaO)_<12>(Al_2O_3)_7:e^- from heat capacity measurements2008

    • Author(s)
      Yoshimitsu Kohama, et. al.
    • Journal Title

      Phys. Rev 1377

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Localized and Delocalized Electrons in Room-Temperature Stable Electride [Ca_<24>Al_<28>O_<64>]^<4+>(O^<2->)_<2-x>(e-)_<2x>: Analysis of Optical Reflectance Spectra2008

    • Author(s)
      Satoru Matsuishi, et. al.
    • Journal Title

      J. Phys. Chem C112

      Pages: 4353-4760

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Insulator-conductor transition in 12CaO・7Al_2O_3 films: On the stability of the crystal lattice under Ar^+ bombardment2008

    • Author(s)
      Peter V, et. al.
    • Journal Title

      Thin Solid Films 516

      Pages: 1350-1350

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pore-Free 12CaO・7Al_2O_3 Single-Crystal Growth by Melt State Controlusing the Floating Zone Method2008

    • Author(s)
      Seok Gyu Yoon, et. al.
    • Journal Title

      Cryst, Gwwth & Design 8

      Pages: 1271-1271

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thin film and bulk fabrication of room-temperature-stable electride C12A7:e^- utilizing reduced amorphous 12CaO・7Al_2O_3 (C12A7)2008

    • Author(s)
      Hideo Hosono, et. al.
    • Journal Title

      J. Non-Cryst. Sol 354

      Pages: 2772-2776

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sungwng Kim, Masahiro Hirano, Hideo Hosono: Growth of 12CaO・7Al_2O_3 single crystal with tetragonal symmetry by Czochralski method2008

    • Author(s)
      Kazuhisa Kurashige, et. al.
    • Journal Title

      Thin Solid Films 516

      Pages: 5772-5776

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and transport properties of 12CaO・7Al_2O_3 (C12A7) electride nanowire2008

    • Author(s)
      Y. Nishio, et. al.
    • Journal Title

      phys. stat. solidi (a) 205

      Pages: 2047-2051

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Superconducting Transition in Electron-doped 12CaO・7Al_2O_32008

    • Author(s)
      S. W. Kim, et. al.
    • Journal Title

      Mater. Trans 49

      Pages: 1748-1752

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solid State Syntheses of 12SrO・7Al_2O_3 and Formation of High Density Oxygen Radical Anions, O^- and <O_2>^-2008

    • Author(s)
      Katsuro Hayashi, et. al.
    • Journal Title

      Chemistry of Materials 20

      Pages: 5987-5996

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metallic State in a Lime-Alumina Compound with Nanoporous Structure2007

    • Author(s)
      S.W.Kim, S.Matsuishi, T. Nomura, Y. Kubota, MTakata, K.Hayashi, T.Kamiya, M.Hirano and H. Hosono
    • Journal Title

      Nano Letters 7

      Pages: 1138-1143

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Superconductivity in an Inorganic Electride 12CaO・7Al_2O_3 : e-2007

    • Author(s)
      M. Miyakawa, S.W. Kim, M. Hirano, Y. Kohama, H. Kawaji, T. Atake, H. Ikegami, K. Kono, H. Hosono
    • Journal Title

      J. Am. Chem. Soc 129

      Pages: 7270-7271

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Work Function of a Room-Temperature, Stable Electride [Ca_<24>Al_<28>O_<64>]^<4+>(e-)_42007

    • Author(s)
      Y..Toda, H.Yanagi, T.Kamiya, M.Hirano and H.Hosono
    • Journal Title

      Adv. Mater 19

      Pages: 3564-3569

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] From Insulator to Electride : A Theoretical Model of Nanoporous Oxide 12CaO・7Al_2O_32007

    • Author(s)
      Peter V. Sushko, Alexander L. Shluger, Masahiro Hirano and Hideo Hosono
    • Journal Title

      J. Am. Chem. Soc 129

      Pages: 942-951

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] High electron doping to a wide band gap semiconductor 12CaO・7Al_2O_3 thin film2007

    • Author(s)
      Masashi Miyakawa, Masahiro Hirano, Toshio Kamiya and Hideo Hosono
    • Journal Title

      Applied Physics Letters 90

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoelectron SpectroscopicStudy of C12A7 : e- and Alq3 Interface : The Formation of a LowElectron-Injection Barrier2007

    • Author(s)
      Ki-Beom Kim, Maiko Kikuchi, Masashi Miyakawa, Hiroshi Yanagi, Toshio Kamiya, Masahiro Hirano and Hideo Hosono
    • Journal Title

      J. Phys. Chem. C111

      Pages: 8403-8406

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Superconductivity in an Inorganic Electride 12CaO・7Al_2O_3:e^-2007

    • Author(s)
      M. Miyakawa, et al.
    • Journal Title

      J. Am. Chem. Soc 129

      Pages: 7270-7171

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metallic State in a Lime-Alumina Compound with Nanoporous Structure2007

    • Author(s)
      Sung Wng Kim, et al.
    • Journal Title

      Nano Letters 7

      Pages: 1138-1143

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanoporous Crystal 12CaO・7Al_2O_3: A Playground for Studies of Ultra violet Optical Absorption of Negative Ions2007

    • Author(s)
      K. HAYASHI, et al.
    • Journal Title

      J. Phys. Chem B111

      Pages: 1946-1956

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Theoretical Model of Nanoporous Oxide 12CaO・7Al_2O_32007

    • Author(s)
      Peter V. Sushko, et al.
    • Journal Title

      J. Am. Chem. Soc 129

      Pages: 942-951

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Functionalities of a Nanoporous Crystal 12CaO・7Al_2O_3 Originating from the Incorporation of Active Anions2007

    • Author(s)
      Katsuro Hayashi, et al.
    • Journal Title

      Bull. Chem. Soc. Jpn 80

      Pages: 872-884

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High electron doping to a wide band gap semiconductor 12CaO・7Al_2O_3 thin film2007

    • Author(s)
      Masashi Miyakawa, et al.
    • Journal Title

      Applied Physics Letters 90

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] otoelectron Spectroscopic Study of C12A7:e- and Alq_3 Interface: The Formation of a Low Electron-Injection Barrier2007

    • Author(s)
      Ki-Beom Kim, et al.
    • Journal Title

      J. Phys. Chem C111

      Pages: 8403-8406

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anion Incorporation-induced Cage Deformation in 12CaO・7Al_2O_3 Crystal2007

    • Author(s)
      Takatoshi Nomura, et al.
    • Journal Title

      Chemistry Letters 36

      Pages: 902-903

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of room temperature-stable 12CaO・7Al_2O_3 electride: A review2007

    • Author(s)
      Sung-Wng Kim, et al.
    • Journal Title

      J Mater Sci. Mater Electron 18

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel room temperature stable electride 12SrO/7Al_2O_3 thin films: fabrication, optical and electron transport properties2007

    • Author(s)
      M Miyakawa, et al.
    • Journal Title

      Journal of the Ceramic Society of f Japan 115

      Pages: 568-568

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Room Temperature-Stable Electride as a Synthetic Organic Reagent: Application to Pinacol Coupling Reaction in Aqueous Media2007

    • Author(s)
      Haritha Buchammagari, et al.
    • Journal Title

      Organic Letters 9

      Pages: 4287-4289

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Vibrational Dynamics and Oxygen Diffusion in a Nanoporous Oxide Ion Conductor 12CaO・7Al_2O_3 Studied by ^<18>O Labeling and icro-Raman Spectroscopy2007

    • Author(s)
      Koichi Kajihara, et al.
    • Journal Title

      J. Phys. Chem C111

      Pages: 14855-14861

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Work Function of a Room-Temperature, Stable Electride [Ca_<24>Al_<28>O_<64>]^<4+>(e^-)_42007

    • Author(s)
      Yoshitake Toda, et al.
    • Journal Title

      Adv. Mater 19

      Pages: 3564-3569

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanisms of oxygen ion diffusion ina nanoporous complex oxide12CaO・7Al_2O_32006

    • Author(s)
      P.V.Sushko, A.L.Shluger, K. Hayashi, M.Hirano and H. Hosono
    • Journal Title

      Phys. Rev B73

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanisms of oxygen iondiffusion in a nanoporous complex oxide12CaO・7Al_2O_32006

    • Author(s)
      Peter V. Sushko, Alexander L. Shluger, Katsuro Hayashi, Masahiro Hirano and Hideo Hosono
    • Journal Title

      Phys. Rev B73

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoluminescence from Au ion-implanted nanoporous single-crystal 12CaO・7Al_2O_32006

    • Author(s)
      Masashi Miyakawa, Hayato Kamioka, Masahiro Hirano, Toshio Kamiya, Peter V.Sushko, Alexander L. Shluger, NoriakiMatsunami, and Hideo Hosono
    • Journal Title

      Phys. Rev B73

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electron Carrier Generation in a RefractoryOxide 12CaO・7Al_2O_3 by Heating inReducing Atmosphere : Conversion from anInsulator to a Persistent Conductor2006

    • Author(s)
      Sung-Wng Kim, Katsuro Hayashi, Masahiro Hirano, Hideo Hosono and Isao Tanaka
    • Journal Title

      J. Am. Ceram. Soc 89

      Pages: 3294-3298

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Role of hydrogen atoms in the photoinduced formation of stable electron centers in H-doped 12CaO-7Al_2O_3;2006

    • Author(s)
      P.Sushko et al.
    • Journal Title

      PHYSICAL REVIEW B 73

      Pages: 45120-45120

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Mechanisms of oxygen ion diffusion in a nanoporous complex oxide 12CaO-7Al_2O_32006

    • Author(s)
      P.Sushko et al.
    • Journal Title

      12CaO-7Al_2O_3; Phys. Rev. B, 73

      Pages: 14101-14101

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Disorder of O^2 ion and incorporation of O and O^2 radicals in nanoporous crystal 12CaO-7Al_2O_3 studied by low-temperature heat capacity measurements2006

    • Author(s)
      Y.Kohama
    • Journal Title

      Chem. Phys. Lett., 421

      Pages: 558-558

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Synthesis of a Room Temperature Stable 12CaO-7Al_2O_3 Electride from the Melt and Its Application as an Electron Field Emitter2006

    • Author(s)
      S.W.Kim et al.
    • Journal Title

      Chem. Mater., 18

      Pages: 1938-1938

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Photoluminescence from Au ion-implanted nanoporous single-crystal 12CaO-7Al_2O_3;2006

    • Author(s)
      M.Miyakawa et al.
    • Journal Title

      Physical Review B 73

      Pages: 205108-205108

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Electron Carrier Generation in a Refractory Oxide 12CaO-7Al_2O_3 by Heating in Reducing Atmosphere : Conversion from an Insulator to a Persistent Conductor2006

    • Author(s)
      S.W.Kim et al.
    • Journal Title

      J. Am. Ceram. Soc. 89

      Pages: 3294-3294

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Hydride Ion as a Two-Electron Donor in a Nanoporous Crystalline Semiconductor 12CaO・7Al_2O_32005

    • Author(s)
      H. HAYASHI, P. SUSHKO, A. SHLUGER, M. HIRANO and H. HOSONO
    • Journal Title

      J. Phys. Chem B109

      Pages: 23836-23842

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Energetics ofFormation and Oxidation of MicroporusCalcium Aluminates : A New Class ofElectrides and Ionic Conductors2005

    • Author(s)
      TROFYMLUK, Y. TODA, H. HOSONO and A. NAVEOTSKY
    • Journal Title

      Chem. Mater 17

      Pages: 5574-5579

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of inorganic electride thin films via site-selective extrusion by energetic inert gas ions2005

    • Author(s)
      M. MIYAKAWA, Y. TODA, K. HAYASHI, M. HIRANO, T. KAMIYA, N. MATSUNAMI and H. HOSONO
    • Journal Title

      J. Appl. Phys 97

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] ElectronicInsulator-Conductor Conversion inHydride Ion-Doped 12CaO・7Al_2O_3 byElectron-Beam Irradiation2005

    • Author(s)
      K. HAYASHI, Y. TODA, T. KAMIYA, M. HIRANO, M. YAMANAKA, I. TANAKA, T. YAMAMOTO and H HOSONO
    • Journal Title

      Appl. Phys. Lett 80

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Simple and Efficient Fabrication of RoomTemperature Stable Electride : Melt-Solidification and Glass Ceramics2005

    • Author(s)
      S. W. KIM, M. MIYAKAWA, K. HAYASHI, T. SAKAI, M. HIRANO, H. HOSONO
    • Journal Title

      J. Am. Chem. Soc 127

      Pages: 1370-1371

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electronic Insulator-Conductor Conversion in Hydride Ion-Doped 12CaO・7AL_2O_3 by Electron-Beam Irradiation2005

    • Author(s)
      K.HAYASI, et al.
    • Journal Title

      Applied Phycics Leeters 86

      Pages: 22109-22109

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Formation of inorganic electride thin films via site-selective extrusion by energetic inert gas ions2005

    • Author(s)
      M.MIYAKAWA, et al.
    • Journal Title

      J. Applied Physics、 97

      Pages: 23510-23510

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Phoyoindced generation of electron anions in H-doped nanoporous oxide 12CaO・Al_2O_32005

    • Author(s)
      P.V.SHSHKO, et al.
    • Journal Title

      Applied Phycics Leeters 86

      Pages: 92101-92101

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Hydride Ion as a Two-Electron Donor in a Nanoporous Crystalline Semiconductor 12CaO・7Al_2O_32005

    • Author(s)
      K.HAYASHI, et al.
    • Journal Title

      J. Physical Chemistry B109

      Pages: 23836-23836

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Hydride Ion as photoelectron donor in microporous crystal2005

    • Author(s)
      S.MATSUISHI, et al.
    • Journal Title

      J. American Chemical Society 127

      Pages: 12454-12454

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Intense thermal field emission from room-temperature stable electride2005

    • Author(s)
      Y.TODA, et al.
    • Journal Title

      Applied Phycics Leeters 87

      Pages: 254103-254103

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Simple and Efficient Fabrication of Room Temperature Stable Electride : Melt-Solidification and Glass Ceramics2005

    • Author(s)
      S.W.Kim et al.
    • Journal Title

      Journal of American Chemical Society 127

      Pages: 1370-71

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Field emission of electron anions clathrated in subnanometer-sized cages of [Ca_<24>Al_<28>O_<64>]^<4+>(4e^-)2004

    • Author(s)
      Y.Toda et al.
    • Journal Title

      Advanced Materials 16

      Pages: 685-689

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Partial oxidation of methane to syngas over promoted C12A72004

    • Author(s)
      S.Yang et al.
    • Journal Title

      Applied Catalysis A : General 277

      Pages: 239-246

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Superoxide Ion Encaged in Nanoporous Crystal 12CaO 7Al_2O_3 Studied by Contious Wave and Pulsed Electron Paramagnetic Resonance2004

    • Author(s)
      S.Matsuishi et al.
    • Journal Title

      Journal of Physical Chemistry 108

      Pages: 18557-18568

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Formation of Oxygen Radicals in 12CaO・7Al_2O_3 : Instability of Extraframework Oxide Ions and uptake of Oxygen Gas2004

    • Author(s)
      K.Hayashi et al.
    • Journal Title

      Journal of Physical Chemistry 108

      Pages: 8920-8925

    • Related Report
      2004 Annual Research Report
  • [Journal Article] Observation of Jonscher law in ac hopping conduction of the electron-doped nanoporous crystal ; 12CaO・7Al_2O_3 in a THz frequency range

    • Author(s)
      H.Harimochi et al.
    • Journal Title

      Physical Review B70

      Pages: 193104-193104

    • Related Report
      2004 Annual Research Report
  • [Presentation] Low-voltage operation of inverted OLED using low-injection barrier electrodes, CuxSe and C12A7:e-2008

    • Author(s)
      Hiroshi Yanagi, H. Hosono, et. al.
    • Organizer
      2008 MRS Fall Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2008-12-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] Insulator-Metal-Superconductor Transition in 12CaO_7Al_2O_32008

    • Author(s)
      H.Hosono
    • Organizer
      2nd International Conference on Structure-Property Relationship in Solid State Materials
    • Place of Presentation
      ナント, フランス
    • Year and Date
      2008-07-03
    • Related Report
      2008 Final Research Report
  • [Presentation] Insulator-Metal-Superconductor Transition in 12CaO7Al2O32008

    • Author(s)
      H. Hosono, et. al.
    • Organizer
      2nd INternational Conference on Structure-Property Relationship in Solid State Materials
    • Place of Presentation
      ナント, フランス
    • Year and Date
      2008-07-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] Carrier transport and subgap states in highly-doped a-In-Ga-Zn-O films2008

    • Author(s)
      Kenji Nomura, H. Hosono, et. al.
    • Organizer
      2nd International Symposium on Transparent Conductive Oxides (IsTCO2008)
    • Place of Presentation
      Hersonissos, Crete, Greece
    • Related Report
      2008 Annual Research Report
  • [Presentation] Coordination around rare-earth ion in doped silica glasses: elucidation of co-doping effects2007

    • Author(s)
      Hideo Hosono, Akira Saito, Satoru Matsuishi
    • Organizer
      E-MRS
    • Place of Presentation
      Starusburg, France
    • Year and Date
      2007-05-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] RT-Stable electrides for display application2007

    • Author(s)
      H.Hosono, T.Kamiya
    • Organizer
      Asian Display 2007 International Conference
    • Place of Presentation
      上海, 中国
    • Year and Date
      2007-03-17
    • Related Report
      2008 Final Research Report
  • [Presentation] controlling electron transport properties in transparent amorp hous oxide semiconductors2007

    • Author(s)
      Hideo Hosono, Kenji Nomura, Yoichi Ogo, Toshio Kamiya
    • Organizer
      2nd International Conference on Amorphopus and Nanocrystalline Semiconductors
    • Place of Presentation
      Coloradao, US
    • Related Report
      2007 Annual Research Report
  • [Presentation] Superconductivity in electron-doped 12CaO・7Al_2O_32007

    • Author(s)
      Sung-Wng Kim, Masashi Miyakawa, Masahiro Hirano, Hideo Hosono
    • Organizer
      2007 Korea-Japan Workshop on Nanomate rials for IT
    • Place of Presentation
      Sungkyunkwan University, korea
    • Related Report
      2007 Annual Research Report
  • [Book] chap1.Fundamentels andResent Progress in Transparent OxideSemiconductors in TransparertElectronics2009

    • Author(s)
      H.Hosono
    • Publisher
      Ed.by Tobin .Marks, John-Wiley(in press)
    • Related Report
      2008 Final Research Report
  • [Book] Transparent Conductive Oxide : materials, processing, and applications2009

    • Author(s)
      D.Ginley, H.Hosono and D.Paine
    • Publisher
      Springer(in press)
    • Related Report
      2008 Final Research Report
  • [Book] Transparent Conductive Oxide: Fundamental to Applications2009

    • Author(s)
      D. Ginley, H. Hosono, D. Paine
    • Total Pages
      600
    • Publisher
      Springei
    • Related Report
      2008 Annual Research Report
  • [Book] chap 1 Fundamentels and Resent Progress in Transparent Oxide Semiconductors in Transparert Electronics, Ed. by Tobin. Marks2009

    • Author(s)
      H. Hosono
    • Publisher
      John-Wiley(in Press)
    • Related Report
      2008 Annual Research Report
  • [Book] 参加カルシウムと酸化アルミニウムと水で高機能材料を創る2006

    • Author(s)
      細野秀雄、林克郎
    • Publisher
      チャンピオンレコードをもつ金属錯体最前線、第12章化学同人
    • Related Report
      2008 Final Research Report
  • [Book] 透明酸化物機能材料とその応用2006

    • Author(s)
      細野秀雄, 平野正浩(監修/著)
    • Publisher
      シーエムシー出版
    • Related Report
      2008 Final Research Report
  • [Book] 透明金属が拓く脅威の世界 不可能に挑むナノテクノロジーの錬金術2006

    • Author(s)
      細野秀雄, 神谷利夫
    • Publisher
      ソフトバンク クリエイティブ株式会社
    • Related Report
      2008 Final Research Report
  • [Book] 第3章透明導電膜の基礎的な性質は何か第4 章 透明導電膜の新しい展開 ; 透明導電膜の技術 改訂第2版2006

    • Author(s)
      細野秀雄, 植田和茂
    • Publisher
      日本学術振興会透明酸化物光・電子材料第166 委員会編、オーム社
    • Related Report
      2008 Final Research Report
  • [Book] Function Cultivation in Transparent Oxides Utilizing Natural and Artificial Nanostructures2006

    • Author(s)
      M.Hirano and H.Hosono
    • Publisher
      in : Nanomaterials : from research to applications ; Elsevier(ed. Hosono, これらの成果に関して Mishima, Takezoe, and Mackenzie)
    • Related Report
      2008 Final Research Report
  • [Book] Nanomaterials : from research to applications2006

    • Author(s)
      H.Hosono et al.
    • Total Pages
      458
    • Publisher
      Elsevier
    • Related Report
      2006 Annual Research Report
  • [Remarks]

    • URL

      http://lucid.msl.titech.ac.jp/~www/

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://lucid.msl.titech.ac.jp/~www/

    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 抵抗変化型不揮発性メモリー及びその製法2008

    • Inventor(s)
      細野秀雄, 神谷利夫, 平野正浩, 金聖雄, 足立泰
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2008-287236
    • Filing Date
      2008-11-08
    • Related Report
      2008 Final Research Report
  • [Patent(Industrial Property Rights)] 表面処理した電気伝導性12CaO・7Al2O3 化合物2008

    • Inventor(s)
      松石聡, 細野秀雄, 戸田喜丈, 金聖雄, 平野正浩
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2008-208753
    • Filing Date
      2008-08-13
    • Related Report
      2008 Final Research Report
  • [Patent(Industrial Property Rights)] ホール注入電極2008

    • Inventor(s)
      細野秀雄, 神谷利夫, 柳博, 平野正浩, 平松秀典, 金起範
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2008-048755
    • Filing Date
      2008-02-28
    • Related Report
      2008 Final Research Report
  • [Patent(Industrial Property Rights)] 抵抗変化型不揮発性メモリー及びその製法2008

    • Inventor(s)
      細野秀雄
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2008-287236
    • Filing Date
      2008-11-08
    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] 表面処理した電気伝導性12CaO・7Al_2O_3化合物2008

    • Inventor(s)
      細野秀雄
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2008-208753
    • Filing Date
      2008-08-13
    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] ホール注入電極2008

    • Inventor(s)
      細野秀雄
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2008-048755
    • Filing Date
      2008-02-28
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 抗酸化剤2007

    • Inventor(s)
      細野秀雄, 平野正浩, 林克郎, 金辰也, 最上理映, 阪口博之
    • Industrial Property Rights Holder
      細野秀雄
    • Filing Date
      2007-10-25
    • Related Report
      2008 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] ジオール若しくはポリジオール、又は2 級アルコール若しくはジケトン化合物の製法2007

    • Inventor(s)
      細野秀雄, 平野正浩, 戸田喜丈, 小坂田耕太郎, 竹内大介, ブッチャマガリハリサ
    • Industrial Property Rights Holder
      細野秀雄
    • Filing Date
      2007-09-28
    • Related Report
      2008 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 抗酸化剤及び抗酸化化粧料2007

    • Inventor(s)
      細野秀雄, 平野正浩, 林克郎, 金辰也,最上理映, 阪口博之
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2007-321581
    • Filing Date
      2007-12-13
    • Related Report
      2008 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 複合金属酸化物及び伝導性複合金属酸化物の製造方法2007

    • Inventor(s)
      三田村哲理, 松山博圭, 細野秀雄, 平野正浩, 宮川仁
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2007-279093
    • Filing Date
      2007-10-26
    • Related Report
      2008 Final Research Report
  • [Patent(Industrial Property Rights)] 電気伝導性複合化合物の製造方法2007

    • Inventor(s)
      細野秀雄, 平野正浩, 金聖雄, 松山博圭, 三田村哲理
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2007-115159
    • Filing Date
      2007-04-25
    • Related Report
      2008 Final Research Report
  • [Patent(Industrial Property Rights)] 抗酸化剤2007

    • Inventor(s)
      細野秀雄, 平野正浩, 林克郎, 金辰也, 最上理映, 阪口博之
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2007-009423
    • Filing Date
      2007-01-18
    • Related Report
      2008 Final Research Report
  • [Patent(Industrial Property Rights)] 電気伝導性12CaO・7Al2O3 を用いたケトン化合物の還元反応2007

    • Inventor(s)
      細野秀雄, 平野正浩, ブッチャマガリハリサ, 戸田喜丈, 小坂田耕太郎, 竹内大介
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2007-056820
    • Filing Date
      2007-03-07
    • Related Report
      2008 Final Research Report
  • [Patent(Industrial Property Rights)] 多孔質シリカゲル及びシリカガラスの製造方法2007

    • Inventor(s)
      細野秀雄, 平野正浩, 梶原浩一
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2007-066988
    • Filing Date
      2007-03-15
    • Related Report
      2008 Final Research Report
  • [Patent(Industrial Property Rights)] 抗酸化剤及び抗酸化化粧料2007

    • Inventor(s)
      細野秀雄
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2007-321581
    • Filing Date
      2007-12-13
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 抗酸化剤2007

    • Inventor(s)
      細野秀雄
    • Industrial Property Rights Holder
      細野秀雄
    • Filing Date
      2007-10-25
    • Related Report
      2007 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 複合金属酸化物及び伝導性複合金属酸化物の製造方法2007

    • Inventor(s)
      細野秀雄
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2007-279093
    • Filing Date
      2007-10-26
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] ジオール若しくはポリジオール、又は2級アルコール若しくはジケトン化合物の製法2007

    • Inventor(s)
      細野秀雄
    • Industrial Property Rights Holder
      細野秀雄
    • Filing Date
      2007-09-28
    • Related Report
      2007 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 電気伝導性複合化合物の製造方法2007

    • Inventor(s)
      細野秀雄
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2007-115159
    • Filing Date
      2007-04-25
    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] ジオール又はポリジオールの製法2006

    • Inventor(s)
      細野秀雄, 平野正浩, ブッチャマガリハリサ, 戸田喜丈, 小坂田耕太郎, 竹内大介
    • Industrial Property Rights Holder
      細野秀雄
    • Industrial Property Number
      2006-268796
    • Filing Date
      2006-09-29
    • Related Report
      2008 Final Research Report
  • [Patent(Industrial Property Rights)] ジオールまたはポリジオールの製法2006

    • Inventor(s)
      細野秀雄他
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      2006-268796
    • Filing Date
      2006-09-28
    • Related Report
      2006 Annual Research Report
  • [Patent(Industrial Property Rights)] 導電性マイエナイト型化合物の製造方法2005

    • Inventor(s)
      細野秀雄他
    • Industrial Property Rights Holder
      東工大
    • Industrial Property Number
      2005-157881
    • Filing Date
      2005-05-30
    • Related Report
      2005 Annual Research Report
  • [Patent(Industrial Property Rights)] 電気伝導性複合酸化物結晶化合物およびその製造方法2004

    • Inventor(s)
      細野 秀雄他
    • Industrial Property Rights Holder
      東京工業大学
    • Industrial Property Number
      2004-136942
    • Filing Date
      2004-04-30
    • Related Report
      2004 Annual Research Report

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Published: 2004-04-01   Modified: 2021-09-01  

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