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Design of carbon nanotube-based advanced materials for environmental friendly energy-oriented society

Research Project

Project/Area Number 16H02083
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials chemistry
Research InstitutionKyushu University

Principal Investigator

Nakashima Naotoshi  九州大学, カーボンニュートラル・エネルギー国際研究所, 特任教授 (80136530)

Co-Investigator(Kenkyū-buntansha) 白木 智丈  九州大学, 工学研究院, 准教授 (10508089)
Project Period (FY) 2016-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥41,600,000 (Direct Cost: ¥32,000,000、Indirect Cost: ¥9,600,000)
Fiscal Year 2020: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2019: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2018: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2017: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2016: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Keywordsカーボンナノチューブ / 超分子化学 / 可溶化ナノチューブ / フラビン / 非白金触媒 / 酸素還元反応 / 酸素発生反応 / 空気ー亜鉛電池 / 半導体性ナノチューブ / 選択分離 / フラビン誘導体 / 水分解触媒 / 半導体/金属ナノチューブ分量 / 分離 / 超分子科学 / 長鎖フラビン / ハイブリッド触媒 / 非白金型触媒 / 非白金型燃料電池触媒 / スピネル触媒 / 半導体性ナノチューブ選択分離 / イソアロキサジン / 触媒還元反応 / 半導体性/金属製ナノチューブ分離 / 電池材料 / 高分子被覆 / ナノ構造デザイン / 燃料電池 / ナノ材料 / 半導体性SWNTと金属性SWNT分離 / ナノチューブ・フラーレン / 半導体性/金属性ナノチューブ分離 / 白金型燃料電池触媒 / ナノチューブ / 半導体ナノチューブ / 分子認識
Outline of Final Research Achievements

A research on advanced material design of nanocarbon materials for ecology energy and useful for environmental society was carried out, and the obtained important results are summarized as follows. (1) We developed a phthalocyanine iron (II) complex/ carbon nanotube (CNT) composite with high oxygen reduction ability. (2) A new high-performance bifunctional electrode catalyst made from nickel, iron, and sulfur was developed, and applied the material for fabrication of a high-performance Zn-air battery. (3) A nickel coordinated polymer / nanocarbon-based molecular catalyst was developed. (4) Various flavin derivatives having long-chain groups were designed and synthesized, and their self-assembly on the surface of the single-walled CNTs (SWNTs) was used to achieve highly selective separation of semiconducting SWNTs. The separation mechanism was elucidated by computational chemistry. These achievements are of importance for simple selective separation of semiconducting SWNTs.

Academic Significance and Societal Importance of the Research Achievements

カーボンナノチューブ(CNT)は、溶媒に不溶であるが、本申請者は、世界先駆けて「可溶化CNT」のコンセプトを提案、推進してきた。本研究では、この新素材「溶解CNT」を用い、社会が求める画期的な電池材料開発、ならびに簡便かつ超高効率での半導体性CNT分離研究を展開した。具体的には、CNTを素材として、高性能の酸素還元能、並びに酸素還元、酸素発生能の2官能性電極触媒能を持つ電極触媒の開発に成功し、これらを用いて高性能空気―亜鉛電池を開発した。本研究は、電池や分子触媒における先端エネルギー材料の開発にとって重要な成果であるとともに、簡便なSWNTの選択的分離に対する大きな進展である。

Report

(6 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (41 results)

All 2022 2021 2020 2019 2018 2017

All Journal Article (16 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 16 results,  Open Access: 1 results) Presentation (24 results) (of which Int'l Joint Research: 8 results,  Invited: 8 results) Book (1 results)

  • [Journal Article] Designing an Fe(III)-Doped Nickel Sulfide/Carbon Nanotube Hybrid Catalyst for Alkaline Electrolyte Membrane Water Electrolyzers and Zn-Air Battery Performances2020

    • Author(s)
      Ganesan Pandian、Staykov Aleksandar、Shu Hiroaki、Uejima Mitsugu、Nakashima Naotoshi
    • Journal Title

      ACS Applied Energy Materials

      Volume: 3 Issue: 11 Pages: 10961-10975

    • DOI

      10.1021/acsaem.0c01931

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular chemistry-based one-pot high-efficient separation of solubilizer-free pure semiconducting single-walled carbon nanotubes: molecular strategy and mechanism2020

    • Author(s)
      4.N. Nakashima, M. Fukuzawa, K. Nishimura, T. Fujigaya, Y. Kato, A. Staykov
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 142 Issue: 27 Pages: 11847-11856

    • DOI

      10.1021/jacs.0c03994

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Carbon Nanotube‐Based Non‐Precious Metal Electrode Catalysts for Fuel Cells, Water Splitting and Zinc‐Air Batteries2019

    • Author(s)
      Yang Jun、Ganesan Pandian、Ishihara Akimitsu、Nakashima Naotoshi
    • Journal Title

      ChemCatChem

      Volume: 11 Issue: 24 Pages: 5929-5944

    • DOI

      10.1002/cctc.201901785

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Tailoring Different Molecular Weight Phenylene?Polybenzimidazole Membranes with Remarkable Oxidative Stability and Conductive Properties for High-Temperature Polymer Electrolyte Fuel Cells2019

    • Author(s)
      Berber Mohamed R.、Nakashima Naotoshi
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 11 Issue: 49 Pages: 46269-46277

    • DOI

      10.1021/acsami.9b18314

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Wrapping Multiwalled Carbon Nanotubes with Anatase Titanium Oxide for the Electrosynthesis of Glycolic Acid2019

    • Author(s)
      Yang Jun、Cheng Junfang、Tao Jie、Higashi Manabu、Yamauchi Miho、Nakashima Naotoshi
    • Journal Title

      ACS Applied Nano Materials

      Volume: 2 Issue: 10 Pages: 6360-6367

    • DOI

      10.1021/acsanm.9b01357

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Impact of Ir-Valence Control and Surface Nanostructure on Oxygen Evolution Reaction over a Highly Efficient Ir?TiO2 Nanorod Catalyst2019

    • Author(s)
      Cheng Junfang、Yang Jun、Kitano Sho、Juhasz Gergely、Higashi Manabu、Sadakiyo Masaaki、Kato Kenichi、Yoshioka Satoru、Sugiyama Takeharu、Yamauchi Miho、Nakashima Naotoshi
    • Journal Title

      ACS Catalysis

      Volume: 9 Issue: 8 Pages: 6974-6986

    • DOI

      10.1021/acscatal.9b01438

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Individual Solubilization Behavior of Single-Walled Carbon Nanotubes by Riboflavin (Vitamin B2) in Water and Its Analyses Using Regression Approach and Computational Simulations2019

    • Author(s)
      Toshimitsu Fumiyuki、Ishimaru Wataru、Nakashima Naotoshi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 92 Issue: 10 Pages: 1679-1683

    • DOI

      10.1246/bcsj.20190141

    • NAID

      130007728631

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Selective Chemical Reaction of Flavin-Derivative-Wrapped Semiconducting Single-Walled Carbon Nanotubes Based on a Specific Recognition2018

    • Author(s)
      Ozono Keita、Fukuzawa Masashi、Toshimitsu Fumiyuki、Shiraki Tomohiro、Fujigaya Tsuyohiko、Nakashima Naotoshi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 91 Issue: 11 Pages: 1646-1651

    • DOI

      10.1246/bcsj.20180206

    • NAID

      130007511413

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Potential Polymer formulation of a Durable Carbon-black Catalyst with a Significant Fuel Cell Performance over a Wide Operating Temperature Range2018

    • Author(s)
      M. R. Berber, T. Fujigaya, N. Nakashima
    • Journal Title

      Materials Today Energy

      Volume: 10 Pages: 161-168

    • DOI

      10.1016/j.mtener.2018.08.016

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Multistep Wavelength Switching of Near‐Infrared Photoluminescence Driven by Chemical Reactions at Local Doped Sites of Single‐Walled Carbon Nanotubes2018

    • Author(s)
      Shiraki Tomohiro、Shiga Tamehito、Shiraishi Tomonari、Onitsuka Hisashi、Nakashima Naotoshi、Fujigaya Tsuyohiko
    • Journal Title

      Chemistry - A European Journal

      Volume: 24 Issue: 72 Pages: 19162-19165

    • DOI

      10.1002/chem.201805342

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Control of the Near Infrared Photoluminescence of Locally Functionalized Single-Walled Carbon Nanotubes via Doping by Azacrown-Ether Modification2018

    • Author(s)
      Onitsuka Hisashi、Fujigaya Tsuyohiko、Nakashima Naotoshi、Shiraki Tomohiro
    • Journal Title

      Chemistry - A European Journal

      Volume: 24 Issue: 37 Pages: 9393-9398

    • DOI

      10.1002/chem.201800904

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Pristine carbon nanotube/iron phthalocyanine hybrids with a well-defined nanostructure show excellent efficiency and durability for oxygen reduction reaction2017

    • Author(s)
      J. Yang, F. Toshimitsu, T. Fujigaya, N. Nakashima
    • Journal Title

      J. Mater. Chem. A

      Volume: 5 Issue: 3 Pages: 1184-1191

    • DOI

      10.1039/c6ta07882f

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Decorating unoxidized-carbon nanotubes with homogeneous Ni-Co spinel nanocrystals show superior performance for oxygen evolution/reduction reactions2017

    • Author(s)
      J. Yang, T. Fujigaya, N. Nakashima
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 45384-45384

    • DOI

      10.1038/srep45384

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A highly efficient and durable carbon nanotube-based anode electrocatalyst for water electrolyzers2017

    • Author(s)
      T. Fujigaya, Y. Shi, J. Yang, H. Li, K. Ito, N. Nakashima
    • Journal Title

      J. Mater. Chem. A

      Volume: 5 Issue: 21 Pages: 10584-10590

    • DOI

      10.1039/c7ta01318c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Near infrared photoluminescence modulation by defect site design using aryl isomers in locally functionalized single-walled carbon nanotubes2017

    • Author(s)
      Shiraki Tomohiro、Uchimura Shunsuke、Shiraishi Tomonari、Onitsuka Hisashi、Nakashima Naotoshi
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 93 Pages: 12544-12547

    • DOI

      10.1039/c7cc06663e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Substituent effects on the redox states of locally functionalized single-walled carbon nanotubes revealed by in situ photoluminescence spectroelectrochemistry2017

    • Author(s)
      Shiraishi Tomonari、Shiraki Tomohiro、Nakashima Naotoshi
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 43 Pages: 16900-16907

    • DOI

      10.1039/c7nr05480g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Carbon Nanotubes as Materials for Non-precious Metal Electrocatalysts with High ORR and OER Performances and their Applications2022

    • Author(s)
      Pandian Ganesan,, Aleksandar Staykov,,Hiroaki Shu, 上島 貢, 中嶋直敏
    • Organizer
      62回フラーレンナノチューブグラフェン総合シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] カーボンナノチューブを用いた白金フリー電池触媒のデザイン・作製2022

    • Author(s)
      Pandian Ganesan,, Aleksandar Staykov,,Hiroaki Shu, 上島 貢, 中嶋直敏
    • Organizer
      89回電気化学会春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] カーボンナノチューブを素材とした貴金属を使わない新しい高性能電池触媒デザイン2022

    • Author(s)
      Pandian Ganesan,, Aleksandar Staykov,,Hiroaki Shu, 上島 貢, 中嶋直敏
    • Organizer
      日化102回春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Design and Fabrication of Carbon Nanotube-based Non-precious Metal Electrocatalysts with High ORR and OER Performances and their Applications2021

    • Author(s)
      Pandian Ganesan, Aleksandar Staykov,Hiroaki Shu, Mitsugu Uejima, Naotoshi Nakashima
    • Organizer
      60回フラーレンナノチューブグラフェン総合シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] 貴金属を使わないFe/Ni/S系高性能酸素還元・酸素発生触媒の構築と応用2021

    • Author(s)
      Pandian Ganesan,, Aleksandar Staykov,,Hiroaki Shu, 上島 貢, 中嶋直敏
    • Organizer
      2021年 電気化学会第88回大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 超分子化学をベースとした高効率半導体性カーボンナノチューブ分離の戦略・メカニズム2021

    • Author(s)
      中嶋直敏・福澤将史・西村加奈子・藤ケ谷剛彦・Aleksandar Staykov
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Carbon nanotube-based PMG-free Electrocatalysts with High OER and ORR Activities2020

    • Author(s)
      P. Ganesan, J. Nishida, C. Kim, J. Matsuda, H. Shu, M. Uejima, N. Nakashima
    • Organizer
      PRiME 2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A simple way for preparation of catalysts with homogeneous nano-metal and metal oxides on nanocarbons: Fundamental and applications for energy conversion2019

    • Author(s)
      中嶋直敏
    • Organizer
      Invited seminar at Taiwan University of Science and Technology
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 貴金属を用いない高性能燃料電池/水分解触媒のデザインと電気化学分析2019

    • Author(s)
      Jun Yang, Junfang Cheng、中嶋直敏
    • Organizer
      第79回分析化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ナノカーボンを素材とした貴金属を用いない高性能電池触媒の合成2019

    • Author(s)
      Jin Nishida, Jun Yang, Shunsuke Uchimura, Junko Matsuda, Naotoshi Nakashima
    • Organizer
      2019電気化学秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Carbon Nanotube-based Non-precious Metal Electrocatalysts with High Performance and Durability2019

    • Author(s)
      Jin Nishida, Jun Yang, Shunsuke Uchimura, Junko Matsuda, Naotoshi Nakashima
    • Organizer
      236th ECS meeting
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nanocarbon-based Non-precious Metal Catalysts with High Performance2019

    • Author(s)
      Naotoshi Nakashima
    • Organizer
      18th Asian Chemical Congress:ACC2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノカーボンを素材とした貴金属を用いない高性能電池触媒のデザイン、合成2019

    • Author(s)
      Jin Nishida, Jun Yang, Shunsuke Uchimura, Junko Matsuda, Naotoshi Nakashima
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Tiナノチューブ上に形成された高性能Irベース水分解触媒のデザイン、合成2019

    • Author(s)
      中嶋直敏
    • Organizer
      日本化学会 第99春季年会 (2019)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Two Different Carbon Nanotube-based Non-Pt Fuel Cell Catalysts with High Performance and Durability2018

    • Author(s)
      Naotoshi Nakashima
    • Organizer
      233rd Electrochemical Society Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Method to Fabricate Nanocrystals of Metal Oxides on Carbon Nanotube Surfaces2018

    • Author(s)
      N. Nakashima
    • Organizer
      234th Electrochemical Society Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Tiナノチューブ上に形成された高性能Irベース水分解触媒のデザイン、合成2018

    • Author(s)
      中嶋直敏
    • Organizer
      56回フラーレンナノチューブグラフェンシンポジウム’
    • Related Report
      2018 Annual Research Report
  • [Presentation] Molecular Requirement for Compounds Toward Facile Isolation of Adsorbent-Free Semiconducting Single-walled Carbon Nanotubes Based on Supramolecular Chemistry2018

    • Author(s)
      N. Nakashima
    • Organizer
      233th Electrochemical Society Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] エネルギ変換材料としてのカーボンナノチューブ2018

    • Author(s)
      中嶋直敏
    • Organizer
      セラミック協会第31回秋季シンポジウム2018
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Facile Isolation of Adsorbent-Free Long Semiconducting Single-walled Carbon Nanotubes Based on Supramolecular Chemistry2017

    • Author(s)
      N. Nakashima
    • Organizer
      231st Electrochemical Society Meeting
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Carbon Nanotube-based “Immortal” and Non-precious Metal Fuel Cell Catalysts2017

    • Author(s)
      N. Nakashima
    • Organizer
      Invited semina at Daegu Gyeongbuk Institute of Science and Technology
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Invited
  • [Presentation] Carbon Nanotubes As an Advanced Functional Nanomaterial -Current and Future-2017

    • Author(s)
      N. Nakashima
    • Organizer
      23rd Joint Seminar of the Busan Branch of the KCS and the Kyushu Branch of the CSJ
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] カーボンナノチューブを素材とする革新的エネルギー材料創生2017

    • Author(s)
      中嶋直敏
    • Organizer
      ファインケミカルジャパン2017
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 先端ナノ材料としてのカーボンナノチューブー基礎ならびにエネルギー材料への応用ー2017

    • Author(s)
      中嶋直敏
    • Organizer
      電気化学会秋季年会2017
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Book] Nanocarbons for Energy Conversion-Supramolecular Approaches2018

    • Author(s)
      N. Nakashima
    • Total Pages
      564
    • Publisher
      Springer
    • ISBN
      9783319929156
    • Related Report
      2018 Annual Research Report

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Published: 2016-04-21   Modified: 2023-01-30  

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