| Budget Amount *help |
¥46,800,000 (Direct Cost: ¥36,000,000、Indirect Cost: ¥10,800,000)
Fiscal Year 2018: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Fiscal Year 2017: ¥14,950,000 (Direct Cost: ¥11,500,000、Indirect Cost: ¥3,450,000)
Fiscal Year 2016: ¥22,230,000 (Direct Cost: ¥17,100,000、Indirect Cost: ¥5,130,000)
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| Outline of Final Research Achievements |
The research project aimed to design molecular lattice compounds that undergo drastic changes of their physical properties such as electronic conductivity and magnetism due to the influence of chemical stimuli. The chemical stimuli were assumed as insertion/extraction of guest molecules such as solvent molecules and ubiquitous gas molecules, for which porous conductive magnets with lattice frameworks were rationally established based on the previous studies. Focusing on lattices that undergo the dynamical change of charge ordered state derived by a small modulation of structures, charge-flexible lattices were, in particular, synthesized by tuning HOMO/LUMO energy levels of electron-donor/-acceptor building units. Consequently, some characteristic materials such as magnetic sponges undergoing electronic modulations or porous magnets distinguishing electron spins of oxygen molecules were established.
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