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Creation of chemistry in organic-inorganic nanomatrix structure

Research Project

Project/Area Number 16H02291
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionNagaoka University of Technology

Principal Investigator

Kawahara Seiichi  長岡技術科学大学, 工学研究科, 教授 (00242248)

Co-Investigator(Kenkyū-buntansha) 山本 祥正  東京工業高等専門学校, 機械工学科, 准教授 (90444190)
Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥46,800,000 (Direct Cost: ¥36,000,000、Indirect Cost: ¥10,800,000)
Fiscal Year 2019: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Fiscal Year 2018: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Fiscal Year 2017: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2016: ¥22,490,000 (Direct Cost: ¥17,300,000、Indirect Cost: ¥5,190,000)
Keywordsナノマトリックス構造 / 有機材料 / 無機ナノ粒子 / 高分子マイクロ粒子 / 動的粘弾性 / 動的粘弾性井
Outline of Final Research Achievements

This study was devoted to an establishment of a new scientific principle for generation of outstanding properties and functions by preparing organic materials with an organic-inorganic nanomatrix structure. The organic materials with the organic-inorganic nanomatrix structure were prepared by binding inorganic nanoparticles onto polymer microparticles in water followed by coagulation or film formation. The organic materials with the organic-inorganic nanomatrix structure was found to have not only entropic elasticity but also energetic elasticity by adjusting spacial distribution of organic microparticles and inorganic nanoparticles. The energetic elasticity was attributed to an increase in potential energy due to a restraint of the polymers in a narrow space between the inorganic nanoparticles, i.e., less than 10 nm, which was revealed by synchrotron radiation X-ray scattering technique, three-dimensional transmission electron microscopy and atomic force microscopy.

Academic Significance and Societal Importance of the Research Achievements

有機無機ナノマトリックス構造は、本申請者らが天然ゴムの構造解析を行う過程で発見したナノマトリックス構造に基づく独創的な新概念である。これは、コロイド結晶、ナノコンポジットおよびハイブリット材料とは異なり、高分子マイクロ粒子だけではなく無機ナノ粒子の配置構造を精密制御することにより物性や機能をチューニングできる可能性を秘めている。また、有機無機ナノマトリックス構造は、有機材料の物性が多量成分とマトリックス成分に支配されるという経験則に基づき、多量成分の有機物質およびマトリックス成分の無機物質の優れた物性と機能を相乗的に発現できることから、その社会的意義および産業的意義は大きい。

Report

(5 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (110 results)

All 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (28 results) (of which Int'l Joint Research: 15 results,  Peer Reviewed: 28 results,  Open Access: 1 results,  Acknowledgement Compliant: 5 results) Presentation (77 results) (of which Int'l Joint Research: 33 results,  Invited: 17 results) Book (2 results) Remarks (1 results)

  • [Int'l Joint Research] Hanoi University of Technology(Phan Trung Nghia)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Mahidol University(Krisda Suchiva)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Nanodiamond Glass with Rubber Bond in Natural Rubber2020

    • Author(s)
      Kawahara Seiichi、Gannoruwa Asangi、Nakajima Ken、Liang Xiaobin、Akiba Isamu、Yamamoto Yoshimasa
    • Journal Title

      Advanced Functional Materials

      Volume: 30 Issue: 15 Pages: 1909791-1909791

    • DOI

      10.1002/adfm.201909791

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Latex-state 13C-NMR spectroscopy for poly(butyl acrylate)2019

    • Author(s)
      Iizuka Yusuke、Yamamoto Yoshimasa、Kawahara Seiichi
    • Journal Title

      Colloid and Polymer Science

      Volume: 297 Issue: 1 Pages: 133-139

    • DOI

      10.1007/s00396-018-4444-2

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanism of Prevulcanization of Natural Rubber through Latex-State NMR Spectroscopy2019

    • Author(s)
      Seiichi Kawahara, Kewwarin Sae-heng, Kenichiro Kosugi, Warunee Ariyawiriyanan
    • Journal Title

      Kautsch. Gummi Kunst.

      Volume: 72(1-2) Pages: 26-30

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Preparation of phenyl-modified natural rubber in latex stage2019

    • Author(s)
      Choothong Nuorn、Shioyama Shintaro、Yamamoto Yoshimasa、Kawahara Seiichi
    • Journal Title

      Polymers for Advanced Technologies

      Volume: 30 Issue: 4 Pages: 1044-1050

    • DOI

      10.1002/pat.4537

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Preparation of hydrogenated natural rubber with nanomatrix structure2019

    • Author(s)
      Nguyen Thu Ha、Do Quoc Viet、Tran Anh Dung、Kawahara Seiichi
    • Journal Title

      Polymers for Advanced Technologies

      Volume: 31 Issue: 1 Pages: 86-93

    • DOI

      10.1002/pat.4749

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Formation of an in situ nanosilica nanomatrix via graft copolymerization of vinyltriethoxysilane onto natural rubber2019

    • Author(s)
      Nghiem Thuong、Nguyen Linh、Phan Nghia、Yusof Nurul、Kawahara Seiichi
    • Journal Title

      Polymers for Advanced Technologies

      Volume: 31 Issue: 3 Pages: 482-491

    • DOI

      10.1002/pat.4785

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Analysis of Biosynthesis Process of Natural Rubber Using Computational chemistry2018

    • Author(s)
      KEINO Tatsuya、UCHIDA Nozomu、KAWAHARA Seiichi、AKIYAMA Kazuki
    • Journal Title

      Journal of Computer Chemistry, Japan

      Volume: 17 Issue: 5 Pages: 235-236

    • DOI

      10.2477/jccj.2018-0048

    • NAID

      130007623994

    • ISSN
      1347-1767, 1347-3824
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Distribution of Nanodiamond Inside the Nanomatrix in Natural Rubber2018

    • Author(s)
      Gannoruwa Asangi、Kawahara Seiichi
    • Journal Title

      Langmuir

      Volume: 34 Issue: 23 Pages: 6861-6868

    • DOI

      10.1021/acs.langmuir.8b00761

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] DETERMINATION OF A SUITABLE CONDITION OF GRAFT COPOLYMERIZATION OF VINYLTRIETHOXYSILANE ONTO NR TO FORM NANOMATRIX STRUCTURE2018

    • Author(s)
      Zhou Yuanbing、Yamamoto Yoshimasa、Kawahara Seiichi
    • Journal Title

      Rubber Chemistry and Technology

      Volume: 91 Issue: 4 Pages: 767-775

    • DOI

      10.5254/rct.18.81545

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Detection of isomerization in commercial natural rubber2018

    • Author(s)
      Nghiem Thi Thuong, Phan Trung Nghia, Seiichi Kawahara
    • Journal Title

      Vietnam Journal of Chemistry

      Volume: 56 Issue: 5 Pages: 574-578

    • DOI

      10.1002/vjch.201800050

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Factors influencing green strength of commercial natural rubber2018

    • Author(s)
      Thi Thuong Nghiem、Trung Nghia Phan、Kawahara Seiichi
    • Journal Title

      Green Processing and Synthesis

      Volume: 7 Issue: 5 Pages: 399-403

    • DOI

      10.1515/gps-2018-0019

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Thermal degradation of deproteinized natural rubber2018

    • Author(s)
      Yamamoto Yoshimasa、Binti Norulhuda Siti Nadiah、Nghia Phan Trung、Kawahara Seiichi
    • Journal Title

      Polymer Degradation and Stability

      Volume: 156 Pages: 144-150

    • DOI

      10.1016/j.polymdegradstab.2018.08.003

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of strain-induced crystallization on the tear strength of natural rubber/styrene butadiene rubber blend2018

    • Author(s)
      Noguchi Fumitoshi、Zhou Yuanbing、Kosugi Kenichiro、Yamamoto Yoshimasa、Nghia Phan Trung、Fukuda Masao、Kawahara Seiichi
    • Journal Title

      Advances in Polymer Technology

      Volume: 37 Issue: 6 Pages: 1850-1858

    • DOI

      10.1002/adv.21843

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Removal of Protein from Natural Rubber in Pilot Scale Toward Production of Low Protein Rubber Gloves2018

    • Author(s)
      Nghiem Thi Thuong, Tran Anh Dung, Do Quoc Viet, Nguyen Ngoc Tue, Nguyen Thu Ha, Tran Thi Thuy, Phan Trung Nghia, Yoshimasa Yamamoto and Seiichi Kawahara,
    • Journal Title

      Journal of Science and Technology

      Volume: 126 Pages: 1-4

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Crystallization Behavior and Mechanical Property of Epoxidized Natural Rubber/Poly(lactic acid) Blend2018

    • Author(s)
      Yoshimasa Yamamoto, Takuya Ishida, Kenichiro Kosugi, Phan Trung Nghia, Masao Fukuda, Seiichi Kawahara
    • Journal Title

      Kautsch. Gummi Kunst

      Volume: 71(4) Pages: 32-38

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Low Ozone-Resistivity of Isoprene rubber Mixed with a Wax as an Antiozonant at Below Freezing2018

    • Author(s)
      Yuka Iwase, Toru Shindo, Hiroaki Kondo, Yoshito Ohtake and Seiichi Kawahara
    • Journal Title

      Kautsch. Gummi Kunst.

      Volume: 71(3) Pages: 32-36

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] NMR による市販天然ゴムの劣化の解析2018

    • Author(s)
      Nghiem Thi Thuong, 山本祥正, 齊藤貴之, 渡邊智子, 大武義人, 河原成元
    • Journal Title

      成形加工

      Volume: 30 Pages: 437-443

    • NAID

      130007890553

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 天然ゴムおよび脱タンパク質化天然ゴムの熱劣化2018

    • Author(s)
      山本祥正, Siti Nadiah Binti Norulhuda, 齊藤貴之, 大武義人, 河原成元
    • Journal Title

      日本ゴム協会誌

      Volume: 91 Pages: 109-114

    • NAID

      130007403002

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly enhanced mechanical properties in natural rubber prepared with a nanodiamond nanomatrix structure2017

    • Author(s)
      Gannoruwa Asangi、Sumita Masao、Kawahara Seiichi
    • Journal Title

      Polymer

      Volume: 126 Pages: 40-47

    • DOI

      10.1016/j.polymer.2017.08.025

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Latex-state NMR spectroscopy for quantitative analysis of epoxidized deproteinized natural rubber2017

    • Author(s)
      Sae-heng Kewwarin、Kanya Tanongsak、Choothong Nuorn、Kosugi Kenichiro、Ariyawiriyanan Warunee、Kawahara Seiichi
    • Journal Title

      Polymers for Advanced Technologies

      Volume: 28 Issue: 9 Pages: 1156-1161

    • DOI

      10.1002/pat.4008

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of brominated natural rubber by solution-state 2D NMR spectroscopy2017

    • Author(s)
      Choothong Nuorn、Kosugi Kenichiro、Yamamoto Yoshimasa、Kawahara Seiichi
    • Journal Title

      Reactive and Functional Polymers

      Volume: 113 Pages: 6-12

    • DOI

      10.1016/j.reactfunctpolym.2017.02.004

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative NEXAFS and solid-stateNMR studies of sp3/(sp2+sp3) ratio in the hydrogenated DLC films2017

    • Author(s)
      X. L. Zhou, S. Tunmee, T. Suzuki, P. Phothongkam, K. Kanda, K. Komatsu, S. Kawahara,
    • Journal Title

      Diamond and Related Materials

      Volume: 73 Pages: 232-240

    • DOI

      10.1016/j.diamond.2016.09.026

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Effect of naturally occurring crosslinking junctions on green strength of natural rubber2017

    • Author(s)
      Thuong Nghiem Thi、Yamamoto Oraphin、Nghia Phan Trung、Cornish Katrina、Kawahara Seiichi
    • Journal Title

      Polymers for Advanced Technologies

      Volume: 28 Issue: 3 Pages: 303-311

    • DOI

      10.1002/pat.3887

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Organic Inorganic Nanomatrix Structure with Nanosilica Networks and Its Effect on Properties of Rubber2016

    • Author(s)
      K. Kosugi, H. Arai, Y. Zhou, S. Kawahara
    • Journal Title

      Polymer

      Volume: 102 Pages: 106-111

    • DOI

      10.1016/j.polymer.2016.09.005

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Analysis of Damage in Commercial Natural Rubber through NMR Spectroscopy2016

    • Author(s)
      N. T. Thuong, Y. Yamamoto, P. T. Nghia, S. Kawahara
    • Journal Title

      Polym. Degrad. Stabil.

      Volume: 123 Pages: 155-161

    • DOI

      10.1016/j.polymdegradstab.2015.11.025

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Preparation and Characterization of Poly(Stearyl Methacrylate) Grafted Natural Rubber in Latex Stage2016

    • Author(s)
      N. H. Yusof, K. Kosugi, T. K. Song, S. Kawahara
    • Journal Title

      Polymer

      Volume: 88 Pages: 43-51

    • DOI

      10.1016/j.polymer.2016.02.005

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Characterization of Ozone-Degraded Composite of Crosslinked Polydimethylsiloxane with Silica in Water2016

    • Author(s)
      S. Miwa, Y. Ohtake, S. Kawahara
    • Journal Title

      Polym. Degrad. Stabil.

      Volume: 128 Pages: 193-199

    • DOI

      10.1016/j.polymdegradstab.2016.02.013

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Mechanism of Heterogeneous Hydrogenation of Natural Rubber in Latex2016

    • Author(s)
      N. T. Ha, K. Kosugi, P. T. Nghia, S. Kawahara
    • Journal Title

      Kautsch. Gummi Kunst.

      Volume: 69(10) Pages: 71-76

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Mechanical and Viscoelastic Properties of Natural Rubber Prepared with a Nanodiamond Nanomatrix Structure2019

    • Author(s)
      Seiichi Kawahara
    • Organizer
      RubberCon 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of bound rubber on mechanical properties of natural rubber with inorganic nanomatrix structure2019

    • Author(s)
      Seiichi Kawahara
    • Organizer
      International Rubber Conference 2019 (IRC2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation and Mechanical Properties of Natural Rubber-Nanodiamond Hybrid2019

    • Author(s)
      Seiichi Kawahara
    • Organizer
      第13回中日先進高分子材料研究討論会
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation and Characterization of Natural Rubber with Nanodiamond Nanomatrix Structure2019

    • Author(s)
      Seiichi Kawahara
    • Organizer
      44th International Conference and Exposition on Advanced Ceramics and Composites
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 水に浸漬したタンパク質フリー天然ゴムの劣化2019

    • Author(s)
      程傲然、河原成元
    • Organizer
      日本ゴム協会2019年年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ラテックスの状態での天然ゴムの電気化学的エポキシ化における塩基の効果2019

    • Author(s)
      山本祥正、小俣綾香、河原成元
    • Organizer
      日本ゴム協会2019年年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Latex-State 13C-NMR spectroscopy for poly(butyl acrylate)2019

    • Author(s)
      Yusuke Iizuka、Seiichi Kawahara
    • Organizer
      日本ゴム協会2019年年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Preparation of Phenyl-modified Natural Rubber in Latex Stage2019

    • Author(s)
      Seiichi Kawahara, Nuorn Choothong, Yoshimasa Yamamoto
    • Organizer
      日本ゴム協会2019年年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Atom transfer radical polymerization of styrene onto natural rubber2019

    • Author(s)
      Quentin TEVENOT, Seiichi Kawahara
    • Organizer
      日本ゴム協会2019年年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] カップリング剤を配合したナノダイヤモンド複合天然ゴムの調製2019

    • Author(s)
      渡部健人、河原成元、信岡俊宏
    • Organizer
      日本ゴム協会2019年年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 天然ゴムの電気化学的エポキシ化における塩基の効果2019

    • Author(s)
      山本祥正、小俣綾香、河原成元
    • Organizer
      高分子学会第68回年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ナノダイヤモンドのナノマトリックス構造を有する天然ゴムの物性2019

    • Author(s)
      河原成元、三原大空、山本祥正
    • Organizer
      高分子学会第68回年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ゴムNMR法による加硫ゴムの構造解析2019

    • Author(s)
      河原成元、山本祥正
    • Organizer
      高分子学会第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 天然ゴム-ナノダイヤモンドハイブリッドの力学物性2019

    • Author(s)
      河原成元、山本祥正
    • Organizer
      高分子学会第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 天然ゴムと無機フィラーからなるナノマトリックス構造の形成と力学物性2019

    • Author(s)
      山本祥正、三原大空、河原成元
    • Organizer
      高分子学会第68回高分子討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ナノマトリックス構造を有するシリカ含有天然ゴムの調製と力学物性2019

    • Author(s)
      山本祥正、三原大空、河原成元
    • Organizer
      日本レオロジー学会第67 回レオロジー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 天然ゴム-ナノダイヤモンドハイブリッドの調製と力学物性2019

    • Author(s)
      河原成元、山本祥正
    • Organizer
      日本レオロジー学会第67 回レオロジー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ゴムNMR法を用いた加硫配合天然ゴムの構造解析と物性2019

    • Author(s)
      山野将輝、河原成元
    • Organizer
      高分子学会第68回北陸支部大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ゴムNMR法を用いた加硫配合天然ゴムの構造解析と物性2019

    • Author(s)
      山野将輝、河原成元
    • Organizer
      日本ゴム協会第30回エラストマー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ナノマトリックス構造を有するシリカ含有天然ゴムの調製と力学物性2019

    • Author(s)
      山本祥正、三原大空、河原成元
    • Organizer
      日本ゴム協会第30回エラストマー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 天然ゴムの構造と物性2019

    • Author(s)
      河原成元、山本祥正
    • Organizer
      日本ゴム協会第30回エラストマー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] カップリング剤を配合したナノダイヤモンド複合天然ゴムの調製と物性2019

    • Author(s)
      渡部健人、河原成元、能島士貴
    • Organizer
      日本ゴム協会第30回エラストマー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Electrochemical Epoxidation of Natural Rubber in Latex Stage2019

    • Author(s)
      Yoshimasa Yamamoto, Seiichi Kawahara
    • Organizer
      日本ゴム協会第30回エラストマー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Latex-state 13C-NMR spectroscopy for poly(alkyl acrylate)2019

    • Author(s)
      Yusuke Iizuka, Seiichi Kawahara
    • Organizer
      日本ゴム協会第30回エラストマー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Preparation and characterization of natural rubber grafted with styrene via ATRP2019

    • Author(s)
      Quentin TEVENOT, Seiichi Kawahara
    • Organizer
      日本ゴム協会第30回エラストマー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Rubber-state NMR spectroscopy for vulcanized natural rubber2019

    • Author(s)
      Seiichi Kawahara, Yoshimasa Yamamoto
    • Organizer
      日本ゴム協会第30回エラストマー討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ゴム製品のポジティブリスト2019

    • Author(s)
      河原成元
    • Organizer
      日本ゴム協会衛生問題技術研究分科会シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 無機フィラーナノマトリックス構造を有する天然ゴムの調製と物性2018

    • Author(s)
      三原大空、野口賢至、河原成元
    • Organizer
      日本ゴム協会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノダイヤモンドナノマトリックス構造を有する天然ゴムの調製と物性2018

    • Author(s)
      毛利学人、Asangi Gannoruwa、河原成元
    • Organizer
      日本ゴム協会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノマトリックス構造を有する合成イソプレンゴムの調製2018

    • Author(s)
      西岡央成、河原成元、山本祥正
    • Organizer
      日本ゴム協会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 天然ゴムの加硫における非ゴム成分のナノマトリックス構造の効果2018

    • Author(s)
      佐藤皓大、河原成元
    • Organizer
      日本ゴム協会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ゴムNMR 法により解析されたクロロプレンゴムの構造と物性の関係2018

    • Author(s)
      太田翔也、河原成元、永谷直人、齋藤俊裕
    • Organizer
      日本ゴム協会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ラテックスの状態での天然ゴムの電気化学的エポキシ化2018

    • Author(s)
      山本祥正、工藤孝也、河原成元
    • Organizer
      日本ゴム協会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Degradation of Natural Rubber and Deproteinized2018

    • Author(s)
      河原成元、山本祥正、齋藤貴之、大武義人
    • Organizer
      日本ゴム協会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] NMR 法による加硫天然ゴムの構造解析(2)~ゴム1H NMR法による解析~2018

    • Author(s)
      齊藤貴之、仲山和海、大武義人、河原成元
    • Organizer
      日本ゴム協会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノマトリックス構造を有する合成イソプレンゴムの調製2018

    • Author(s)
      西岡 央成、河原 成元、山本 祥正
    • Organizer
      高分子学会第67回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノダイヤモンドのナノマトリックス構造を有する天然ゴムの物性2018

    • Author(s)
      河原 成元、Gannoruwa Asangi、山本 祥正
    • Organizer
      高分子学会第67回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 二酸化炭素存在下での水プロセスにおける天然ゴムの電気化学的エポキシ化2018

    • Author(s)
      山本 祥正、工藤 孝也、河原 成元
    • Organizer
      高分子学会第67回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノダイヤモンドナノマトリックス構造を有する天然ゴムの調製と物性2018

    • Author(s)
      河原 成元、Gannoruwa Asangi、山本 祥正
    • Organizer
      高分子学会第67回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電気分解によるエポキシ化天然ゴムおよび臭素化天然ゴムの調製と構造解2018

    • Author(s)
      山本 祥正、河原 成元
    • Organizer
      高分子学会第67回討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノマトリックス構造を有する合成イソプレンゴムの調製と物性2018

    • Author(s)
      西岡 央成、河原 成元、山本 祥正
    • Organizer
      日本ゴム協会第29 回エラストマー討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 天然ゴム製品の溶出タンパク質量と窒素含有率2018

    • Author(s)
      山本祥正、石井宏幸、河原成元
    • Organizer
      日本ゴム協会第29 回エラストマー討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 天然ゴムの脱タンパク質化反応装置のスケールアップ2018

    • Author(s)
      石井宏幸、山本祥正、河原成元、Phan Trung Nghia
    • Organizer
      日本ゴム協会第29 回エラストマー討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] タンパク質フリー天然ゴムの調製2018

    • Author(s)
      河原成元、山本祥正、石井宏幸
    • Organizer
      日本ゴム協会第29 回エラストマー討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノダイヤモンドのナノマトリックス構造を有する天然ゴムの力学物性2018

    • Author(s)
      河原成元、Asangi Gannoruwa、山本祥正
    • Organizer
      日本ゴム協会第29 回エラストマー討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ナノダイヤモンドのナノマトリックス構造を有する天然ゴムの力学物性2018

    • Author(s)
      河原成元、Asangi GannoruwaAsangi、山本祥正
    • Organizer
      日本レオロジー学会代66回レオロジー討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 無機ナノ粒子とゴム粒子の複合化による機能発現2018

    • Author(s)
      河原成元
    • Organizer
      高分子学会九州支部フォーラム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Preparation and Mechanical Properties of Natural Rubber with Nanodiamond Nanomatrix Structure2018

    • Author(s)
      Seiichi Kawahara
    • Organizer
      13th Fall Rubber Colloquium (KHK 2018), Germany
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mechanical Propertise of Natural Rubber with Nanomatrix Structure2018

    • Author(s)
      Seiichi Kawahara
    • Organizer
      International Rubber Conference 2018 (IRC2018), Malaysia
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Characterization of vulcanized natural rubber through rubber state NMR spectroscopy2018

    • Author(s)
      Seiichi Kawahara
    • Organizer
      The International Polymer Conference of Thailand (PCT-8), Thailand
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structure and Mechanical Properties of Natural Rubber2018

    • Author(s)
      Seiichi Kawahara
    • Organizer
      The 4th Thai-Japan Rubber Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structure of crosslinking junctions of network polymers through rubber state NMR spectroscopy2018

    • Author(s)
      Seiichi Kawahara
    • Organizer
      255th ACS National Meeting & Exposition
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structure of Natural Rubber2017

    • Author(s)
      Seiichi Kawahara
    • Organizer
      The 3rd Asia Pacific Rubber Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structure of Natural Rubber2017

    • Author(s)
      Seiichi Kawahara
    • Organizer
      RUBBERCON 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 天然ゴムの構造と物性2017

    • Author(s)
      河原成元
    • Organizer
      日本ゴム協会第28回エラストマー討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Hierarchic Structures and Propeties of Natural Rubber2016

    • Author(s)
      Seiichi Kawahara
    • Organizer
      9th International Conference on Materials Science and Technology (MSAT-9)
    • Place of Presentation
      Swissotel Le Concorde Bangkok
    • Year and Date
      2016-12-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structure and Properties of Natural Rubber with Silica Nanomatrix Structure2016

    • Author(s)
      Seiichi Kawahara, ○ Kenichiro Kosugi
    • Organizer
      The 11th SPSJ International Polymer Conference (IPC 2016)
    • Place of Presentation
      Fukuoka International Congress Center
    • Year and Date
      2016-12-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノマトリックス構造を有する天然ゴムのFIB加工2016

    • Author(s)
      山本 祥正,河原 成元
    • Organizer
      2016年度高分子基礎物性研究会・高分子計算機科学研究会・高分子ナノテクノロジー研究会 合同討論会
    • Place of Presentation
      東京農工大学小金井キャンパス 新1号館グリーンホール
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] シリカナノマトリックス構造を有する天然ゴムのモルフォロジーと物性2016

    • Author(s)
      周 遠兵,河原 成元
    • Organizer
      2016年度高分子基礎物性研究会・高分子計算機科学研究会・高分子ナノテクノロジー研究会 合同討論会
    • Place of Presentation
      東京農工大学小金井キャンパス 新1号館グリーンホール
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ウェットマスターバッチによる有機-無機ナノマトリックス構造を有する天然ゴムの調製2016

    • Author(s)
      高木 司,河原 成元
    • Organizer
      2016年度高分子基礎物性研究会・高分子計算機科学研究会・高分子ナノテクノロジー研究会 合同討論会
    • Place of Presentation
      東京農工大学小金井キャンパス 新1号館グリーンホール
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Minor Constituents on the Mechanical Properties of Natural Rubber2016

    • Author(s)
      Seiichi Kawahara
    • Organizer
      12th Fall Rubber Colloquium (KHK 2016)
    • Place of Presentation
      Crowne Plaza Hotel Hannover
    • Year and Date
      2016-11-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Wet-Masterbatch Procedure for the Preparation of Natural Rubber with Organicinorganic Nanomatrix Structure2016

    • Author(s)
      Tsukasa Takagi, Seiichi Kawahara
    • Organizer
      12th Fall Rubber Colloquium (KHK 2016)
    • Place of Presentation
      Crowne Plaza Hotel Hannover
    • Year and Date
      2016-11-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation and Properties of Natural Rubber with Silica Nanomatrix Structure2016

    • Author(s)
      Yuanbing Zhou, Seiichi Kawahara
    • Organizer
      12th Fall Rubber Colloquium (KHK 2016)
    • Place of Presentation
      Crowne Plaza Hotel Hannover
    • Year and Date
      2016-11-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] タンパク質のナノマトリックスを有する天然ゴムの調製と物性2016

    • Author(s)
      名倉 拓実,河原 成元,小杉 健一朗
    • Organizer
      第65回高分子学会北陸支部研究発表会
    • Place of Presentation
      福井大学文京キャンパス
    • Year and Date
      2016-11-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポリアルキルアクリレートのラテックスNMR分解能と温度の関係2016

    • Author(s)
      飯塚 悠介,河原 成元
    • Organizer
      第65回高分子学会北陸支部研究発表会
    • Place of Presentation
      福井大学文京キャンパス
    • Year and Date
      2016-11-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study on Hierarchal Structure of Natural Rubber2016

    • Author(s)
      Seiichi Kawahara
    • Organizer
      International Rubber Conference 2016 (IRC 2016)
    • Place of Presentation
      Kitakyushu International Conference Center
    • Year and Date
      2016-10-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Morphology and Properties of Natural Rubber with Naturally Occurring Nanomatrix Structure2016

    • Author(s)
      Kenichiro Kosugi, Seiichi Kawahara
    • Organizer
      International Rubber Conference 2016 (IRC 2016)
    • Place of Presentation
      Kitakyushu International Conference Center
    • Year and Date
      2016-10-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Nanomatrix Structure on Mechanical Properties for Natural Rubber Grafted with Polystyrene2016

    • Author(s)
      Kota Endo, Kenichiro Kosugi, Seiichi Kawahara
    • Organizer
      International Rubber Conference 2016 (IRC 2016)
    • Place of Presentation
      Kitakyushu International Conference Center
    • Year and Date
      2016-10-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ラテックスNMR法による一次構造の定量分析2016

    • Author(s)
      河原 成元,Sae-heng Kewwarin,小杉 健一朗
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] タンパク質のナノマトリックス構造を有する天然ゴムの調製と物性2016

    • Author(s)
      名倉 拓実,小杉 健一朗,河原 成元
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mechanical Properties of Natural Rubber with Silica-Nanomatrix Structure2016

    • Author(s)
      Seiichi Kawahara
    • Organizer
      The XVIIth International Congress on Rheology (ICR2016)
    • Place of Presentation
      Kyoto TERRSA
    • Year and Date
      2016-08-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機-無機ナノマトリックス構造を有する天然ゴムの調製と物性2016

    • Author(s)
      高木 司,河原 成元
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場・展示場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] シリカナノマトリックス構造を有する天然ゴムのモルフォロジーと物性2016

    • Author(s)
      周 遠兵,河原 成元
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場・展示場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高タンパク質化天然ゴムのモルフォロジーと物性2016

    • Author(s)
      小杉 健一朗,河原 成元
    • Organizer
      日本ゴム協会2016年年次大会
    • Place of Presentation
      大宮ソニックシティ
    • Year and Date
      2016-05-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 市販天然ゴムの構造解析2016

    • Author(s)
      恩蔵 賢,Nghiem Thi Thuong,小杉 健一朗,河原 成元
    • Organizer
      日本ゴム協会2016年年次大会
    • Place of Presentation
      大宮ソニックシティ
    • Year and Date
      2016-05-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] NMR法による市販天然ゴムの構造解析2016

    • Author(s)
      河原 成元,Nghiem Thi Thuong,小杉 健一朗,山本 祥正
    • Organizer
      日本ゴム協会2016年年次大会
    • Place of Presentation
      大宮ソニックシティ
    • Year and Date
      2016-05-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 天然ゴムの電子線架橋における促進剤の反応率と物性の関係2016

    • Author(s)
      山本 祥正,藤田 和杜,Oraphin Yamamoto,河原 成元,Krisda Suchiva
    • Organizer
      日本ゴム協会2016年年次大会
    • Place of Presentation
      大宮ソニックシティ
    • Year and Date
      2016-05-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Book] “Rubber-state NMR Spectroscopy”, in “NMR methods for Characterization of Synthetic and Natural Polymers”2019

    • Author(s)
      Seiichi Kawahara, Yoshimasa Yamamoto, Takayuki Saito
    • Publisher
      Royal Society of Chemistry
    • Related Report
      2019 Annual Research Report
  • [Book] 動的粘弾性チャートの解釈事例集2016

    • Author(s)
      小杉 健一朗, 河原 成元
    • Total Pages
      399
    • Publisher
      技術情報協会
    • Related Report
      2016 Annual Research Report
  • [Remarks] http://mst.nagaokaut.ac.jp/

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2022-08-26  

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